催化动力学光度法测定痕量Fe(Ⅲ)的研究进展

论文探讨和论述了近年来催化动力学光度法测定痕量铁的研究进展。具体探讨和评述内容包括:比较催化光度法与原子吸收法、萃取光度法的优缺点;介绍催化动力学光度法的原理;评述催化褪色动力学光度法研究进展、催化显色动力学光度法研究进展、阻抑显色催化动力学光度法研究进展、阻抑褪色催化动力学光度法研究进展;包括指示反应及其条件、方法的检出限、干扰情况、测定范围、应用等。论文还探讨和展望了催化动力学光度法未来的研究方向和发展前景。内容包括:①对传统显色剂改性或合成新的高灵敏度、高选择性显色剂;②活性剂增敏研究;③加强相关催化机理的研究和探讨;④开展酶催化动力学光度法研究。     

催化动力学光度法测定痕量锰的研究进展

评述了近年来催化动力学光度法测定痕量锰的研究进展。具体内容包括: 催化褪色动力学光度法测定痕量锰的研究进展;催化显色动力学光度法测定痕量锰的研究进展。在研究方法方面,内容包括指示反应及其条件、方法的检出限、测定范围、应用等。展望了催化动力学光度法未来的研究方向和发展前景;如加强活性剂增敏的研究、方法的选择性研究、相关催化机理的研究和酶催化动力学光度法的研究。     

催化动力学光度法测定痕量铜的研究进展

本文探讨和论述了近年来催化动力学光度法测定痕量铜的研究进展，比较了催化光度法与原子吸收法、萃取光度法的优缺点；介绍了催化动力学光度法的原理；评述了催化褪色光度法、催化显色光度法、催化荧光光度法等的研究进展，探讨和展望了催化动力学光度法未来的研究方向和发展前景，包括：1．对传统显色剂改性或合成新的高灵敏度、高选择性显色剂；2．活性剂增敏研究；3．加强相关催化机理的研究和探讨。全文参考文献29篇。     

催化动力学光度法测定铬(Ⅵ)的研究进展

综述了近十年来国内催化动力学光度法测定痕量铬(Ⅵ)的某些进展,按照不同催化体系,从反应条件、灵敏度、测定范围和应用等方面加以归纳和讨论。     

催化动力学光度法测定痕量铁

论文研究和建立了催化动力学褪色光度法测定痕量Fe(Ⅲ)的新体系,反应介质为盐酸-邻苯二甲酸氢钾(pH2.2)缓冲溶液,催化体系为痕量Fe(Ⅲ)催化过硫酸铵氧化邻甲氧基酚的自聚反应。研究了此反应体系的最佳条件、动力学参数及反应机理,考察了21种干扰离子的影响,建立了一种新型催化动力学光度法测定痕量Fe(Ⅲ)的方法。本法的线性范围0.07～1.1μg·(25mL)~(-1)。方法灵敏度远远高于普通光度法,检出限为5.4×10~(-8)g·L~(-1)。方法应用于自来水、河水、城市污水、豆奶粉和茶叶中痕量Fe(Ⅲ)的测定,相对标准偏差为0.36％～3.4％,标准加入回收率为97.3％～102.7％,结果满意。     

催化动力学光度法测定微量钼——钼(Ⅵ)-硫酸肼-甲苯胺兰体系

本文研究了在硫酸介质中,微量钼(Ⅵ)催化加速硫酸肼还原甲苯胺兰褪色及动力学条件,建立了催化动力学光度法测定微量钼(Ⅵ)的方法。其检出限为5.154×10     

钒的痕量分析方法与应用的研究进展

综述了近年来测定钒中痕量组分分析方法的最新研究进展.主要内容包括:催化动力学光度法、电化学分析法、荧光光谱法、原子光谱法以及液相色谱法等,同时简要阐述了钒样品的预处理方法,最后对测定钒分析方法未来的研究方向以及发展前景进行了展望.     

孔雀石绿-溴酸钾催化分光光度法测量亚硝酸根

采用流动注射技术和催化分光光度法相结合,研究了在磷酸介质中,亚硝酸根对溴酸钾氧化孔雀石绿褪色反应的催化作用及其动力学条件,建立了催化动力学光度法测定痕量亚硝酸根的新方法。方法检出限为0.9ng/mL,测定的线性范围为5—60ng/mL,且线性相关系数为0.9983,对于浓度为30ng/mL的亚硝酸根标准液测定的相对标准偏差仅为1.0。该方法适用范围广,具有较好的准确性、稳定性和灵敏度,且实验操作方便、快速。利用此方法测定不同水样中的亚硝酸根,加标回收率在88.6%—104.8%之间,分析结果令人满意。     

酶催化动力学光度法测定抗坏血酸

基于抗坏血酸对血红蛋白模拟酶催化体系的抑制作用,建立酶催化动力学光度法测定抗坏血酸的新方法。研究了体系的最佳条件及动力学行为,测定的线性范围为2.0×10-7—5.9×10-5mol/L,方法检出限为7.0×10-8mol/L。对6.0×10-6mol/L的抗坏血酸进行11次平行测定相对标准偏差为2.5%。此方法可用于药剂和蔬菜中抗坏血酸含量的测定。     

催化动力学光度法测定痕量锡（Ⅱ）

研究了稀硫酸介质中，锡（Ⅱ）催化溴酸钾氧化酸性蓝Ｋ的褪色反应，建立了催化动力学光度法测定痕量锡（Ⅱ）的新方法。用于天然水中痕量锡（Ⅱ）的测定，结果满意。     

钛光度分析的某些进展

综述了光度法测定钛近 5年来研究的某些进展 ,涉及经典光度法、动力学光度法、计算光度法及流动注射光度法测钛 ,引文 6 0篇。     

多光谱问题中辐射量与光度量之间的关系

本文简要阐述了光度量与辐射度量的基本概念和它们之间的相互转换关系。按照每个量的定义式，理论计算出在特定的辐射源下，某种光敏器件达到某一电压输出值时，分别所需要的光度量和辐射度量量值。在工作实验中，使用了２７９３Ｋ卤钨灯照射ＣＣＤ１４３Ａ光电器件，同时分别测量了光度量与辐射度量，其结果与计算值相近。证明理论与实践是吻合的     

高铁酸钾降解苯并芘的荧光光谱研究

在优化的反应条件下, 研究了高铁酸钾与苯并芘(BaP)的降解反应过程, 通过联合应用同步, 三维(EEM), 时间扫描及荧光光度定量等多种荧光光谱分析方法所提供的多角度的荧光光谱信息, 揭示了BaP分子在降解过程中浓度随时间变化规律, 尤其高铁酸钾与BaP作用过程的动力学特征。同步荧光和三维荧光光谱共同揭示出, 高铁酸钾在20 s内能降解91%的BaP, 60 s以后反应趋于缓慢的变化规律; 由时间扫描荧光光谱结合发射和同步两种荧光光度定量方法, 便捷地获得了高铁酸钾与BaP的反应过程中的动力学方程: ln(F₀/F_t)=0.563 2t+0.171 2, (R2=0.994 2), 由此推测高铁酸钾与BaP的反应过程符合一级反应动力学规律。为研究高铁酸钾降解其他污染物反应过程的机理提供了十分有益的参考。     

The effect of determined chaos on light collection in optical systems

In terms of the dynamic approach, the collection of light in optical systems and the influence of determined chaos on the photometry and fluctuations of regular and chaotic collection are considered. The photometric relationships generalizing the formula of the integrating sphere as applied to chaotic collection are obtained. A universal law for noise in the regular light collection is predicted and found to be in good agreement with the available experimental data. The relationships studied can find use in the elaboration of a new-design detectors, light guides, light-emitting diodes, etc., for the enhancement of their efficiency and the reduction of noise.     

Simultaneous multicolor photometry of fast-moving objects using the 1-meter telescope at Xinglong Observatory

Simultaneous multicolor photometry of fast-moving objects is discussed in this paper. In conventional astronomical photometry, the accuracy of flux and color indices of fast-moving objects is affected by the variations of the targets and weather conditions in space and time domains. We optimize related techniques and methods of observation and data reduction, including image calibration, background fitting, targets detection and location, isophotal photometry, and flux calibration by using background stars from different fields. We consider that simultaneous multicolor data acquisition and differential flux calibration are critical for improving photometric accuracy of fast-moving objects. Our results show the photometric accuracy is better than 5% based on the observations carried out by a 1-meter telescope under ordinary, non-photometric conditions.     

《三度学及其测量》课程建设的探索与实践

辐射度学、光度学和色度学(以下简称"三度学")是现代光电信息转换、传输、存储、显示、测量和计量的基础,随着光电信息技术、图像技术的发展和应用的扩展,"三度学"及其测量技术已成为光电工程领域科研和应用人员必备的专业基础知识和技术,在国内还没有完全类似的教材和课程设置。以往教学中仅在某些课程中部分涉及辐射度学和光度学的概念,难以使学生全面地掌握和应用相关的知识,至于色度学则更少涉及,系统讲授的课程大多安排在研究生阶段,但也较少涉及相关的实验仪器和技术的讲授。从光电信息科学与工程类专业知识体系结构的角度出发,总结了多年教学科研的经验,探索了以"三度学"作为教学内容,通过配合相关测量的实验,开展了"三度学"课程建设的探索。     

基于相关分析的LED路灯光强分布测试步距角优化研究

优化LED路灯光强分布测试系统的测试步距角可以较大程度地提高LED路灯测试的效率。选择不同的测试步距角对LED路灯的光强分布进行测试,将1°测试步距角所测得的路灯光强分布视为真值,采用相关分析的方法研究在较大步距角下所测得的路灯光强分布与真值之间的近似程度。研究结果显示,当相关系数要求在98%左右时,可以选择15°测试步距角对LED路灯的光强分布进行测试,相对于真值测试,在此步距下LED路灯的测试时间减少了98%以上,极大地提高了测试效率。     

High-temperature measurement techniques for the application in photometry,radiometry and thermometry

Well characterised sources of thermal radiation are essential for photometry, radiometry, and thermometry. They serve as reference radiators for the calibration of detectors and radiance sources. Thermal radiation sources are advantageous for this purpose compared to other radiance sources such as lamps or LEDs because they possess a continuous spectrum of the emitted spectral radiance, which, for blackbody sources, can be calculated analytically using Planck’s law of radiation.For application in thermometry, blackbody sources starting from temperatures near absolute zero to temperatures up to 3000 ^°C are needed for the calibration of radiation thermometers. For application in photometry and radiometry high intensity sources of radiation in the visible and UV region of the optical spectrum were required. This latter requirement is met by blackbody sources at temperatures well above 2000 ^°C. An ideal reference source should always emit the same amount of radiation at any time of use. This is realised by fixed-point radiators. Such radiators are based on a phase transition of a substance, at high temperatures the melting and freezing points of metals. However, current metal fixed-points are limited to relatively low temperatures. In the present work innovative techniques necessary for research into high-temperature thermal radiation sources are developed and thoroughly described. Starting with variable temperature blackbody sources the techniques required are: Precise apertures determination and detailed characterisation of the applied optical detectors.The described techniques are then used to undertake research into the development of high-temperature fixed-points above the copper fixed-point for application in photometry, radiometry, and thermometry. Applying these sophisticated techniques it was shown that these new high-temperature fixed-points are reproducible and repeatable to better than 100 mK at temperatures up to nearly 3200 K. Finally, a forward look is given that shows the potential of such fixed-points for improving traceability and accuracy in photometry, radiometry, and thermometry. This work forms the foundation for accurate and practical applications of high-temperature fixed-point sources and sets the international benchmark for measurement techniques in photometry, radiometry, and thermometry. This work will open the use of the novel high-temperature fixed-points in an improved International Temperature Scale and will significantly improve and ease the realisation and dissemination of the SI base unit candela, significantly reducing the uncertainty for industrial measurements in these fields.     

Integrated BVRIJHK photometry of galactic globular clusters

Summary We present preliminary BVRI photometric data of 22 galactic globular clusters of the Southern hemisphere. The observations were carried out at the ESO Observatory, during two observing runs in August 1988 (VRI) and March 1989 (BVRI). In both periods half of the total number of nights was used to perform near-infrared (JHK) photometry of the same clusters: the goal of this quasi-contemporary photometry was to obtain a homogeneus sample of galactic clusters photometric observations, on a wavelength range as wide as possible. Paper presented at the V Cosmic Physics National Conference, S. Miniato, November 27–30, 1990.     

H0323+022天体的光变特性和黑洞质量研究

从大量文献资料中，收集了BL Lac天体H0323+022光学V波段的大量观测数据，获得了H0323+ 022从1982年至2003年的长期光变曲线.给出了从2000年至2003年，使用云南天文台1米望远 镜和上海天文台的156米望远镜，对H0323+022进行光学波段近4年的监测数据，观测发现 了H0323+022在光学R波段有7min的短时标光变.色指数B—V与V波段的星等值有较强的相关性 ，对H0323+022 CCD测光的结果与Bai（1998）观测的结果ΔR=063 ΔI=081是 一致的.由观测所发现的短时标光变，推算出了BL Lac天体H0323+022的中心黑洞质量和辐射 区域. 关键词： BL Lac天体 光变曲线 短时标光变 辐射区域 中心黑洞质量