石墨烯的声子热学性质研究

声子是石墨烯导热过程中的主要载体,而声子的弛豫时间又是其中最基本、最重要的物理量.本文采用简正模式分解法研究了石墨烯声子的弛豫时间,并且借此分析了不同声子在导热过程中的贡献.该方法通过平衡分子动力学模拟实现,首先通过模拟得到单个声子的能量自相关函数衰减曲线,并进一步采用拟合和积分两种方法得到单个声子的弛豫时间.然后,研究了弛豫时间与波矢、频率和温度的关系.结果发现,弛豫时间随波矢的变化与对应的色散关系相近,弛豫时间与频率和温度的关系符合理论模型:1/τ=νnTm,其中声学支的n为1.56,而光学支结果较为发散,指数m对于不同声子支结果略有不同.最后,还研究了不同频率声子对导热的贡献,发现低频声子在态密度上占有绝对优势,并且其弛豫时间整体高于高频声子,所以低频声子对导热的贡献占据主导地位.     

气泡体积分数对沙质沉积物低频声学特性的影响

由于有机物质分解等原因,实际的海底沉积物中存在气泡,气泡的存在会显著影响沉积物低频段的声学特性,因此研究气泡对沉积物低频段声速的影响机理具有重要意义.考虑到外场环境的不可控性,在室内水池中搭建了大尺度含气非饱和沙质沉积物声学特性获取平台,在有界空间中应用多水听器反演方法首次获取了含气非饱和沙质沉积物300—3000 Hz频段内的声速数据(79—142 m/s),并同时利用双水听器法获取了同一频段的数据(112—121 m/s).在声波频率远低于沉积物中最大气泡的共振频率时,根据等效介质理论,将孔隙水和气泡等效为一种均匀流体,改进了水饱和等效密度流体近似模型.模型揭示了气泡对沉积物低频段声学特性的影响规律,理论上解释了沉积物中声速的降低.通过分析模型预报声速对模型参数的敏感性,根据测量得到的声速分布反演得到了沉积物不同区域的气泡体积分数,气泡体积分数从1.07%变化到2.81%.改进的模型为沉积物中气泡体积分数估计提供了一种新方法.     

可激发气体振动弛豫时间的两频点声测量重建算法

振动弛豫时间是可激发气体分子内外自由度能量转移速率的宏观体现,它决定了声吸收谱峰值点对应的弛豫频率.本文给出了等温、绝热定压和绝热定容三种不同热力学过程下振动弛豫时间的相互关系;基于Petculescu和Lueptow[2005 Phys.Rev.Lett.94 238301]的弛豫过程合成算法,推导了单一压强下两频点声测量值的弛豫时间重建算法.该算法可应用于等温、绝热定压、绝热定容弛豫时间和弛豫频率的重建测量,并避免了弛豫时间传统声测量方法需要不断改变气体腔体压强的问题.仿真结果表明,对于室温下CO_2,CH_4,Cl_2,N_2和O_2组成的多种气体,重建的弛豫时间和弛豫频率与实验数据相符.     

射频等离子体鞘层动力学模型

在流体力学方程的基础上建立了一种自洽的无碰撞射频等离子体鞘层动力学模型.这种自洽性包含两个方面:一方面,由于考虑了瞬时鞘层电场对离子运动的影响,因此该模型适用于描述任意频率段的射频鞘层演化过程;另一方面,在模型中采用等效电路方法来自洽地确定极板上的瞬时电位与瞬时鞘层厚度之间的关系.采用数值方法模拟出鞘层的瞬时厚度及极板的瞬时电位变化、鞘层内离子密度和电场强度等物理量的时空变化.结果表明,当射频场的频率小于或等于离子等离子体频率时,离子流密度明显地随时间变化 关键词： 射频 离子 鞘层 流体力学     

交流磁场振幅和频率对J_c不均匀超导体谐波的影响

本文采用Jc不均匀超导体模型来研究多晶超导体的磁性质,运用非线性磁通蠕动模型,通过数值模拟得到交流磁化率基波及谐波随温度的变化关系.系统分析了交流磁场振幅和频率改变对Jc不均匀超导体交流磁化率基波及谐波的影响.结果表明,交流磁场振幅和频率的变化对交流磁化率的影响存在显著差异,并归因为交流磁场振幅和频率的改变引起的磁弛豫时间的改变不同所致.上述结果为分析Jc不均匀超导体交流磁化率的实验现象提供了相关依据.     

电子弛豫过程对重复频率高功率微波大气击穿的影响

 研究了重复频率高功率微波脉冲作用下的大气击穿。分析了重复频率脉冲作用下电子的弛豫过程,对脉冲间隔时间内电子温度和自由电子密度的变化规律进行了研究,得出了电子温度弛豫时间远小于电子密度弛豫时间的结论。分析了电子弛豫过程的附着效应和复合效应,给出了高功率微波重复频率脉冲作用下发生大气击穿的条件和重复频率高功率微波大气击穿的电子数密度方程。     

基于多带解调分析和瞬时频率估计的耳语音话者识别

为了改善耳语音话者识别的稳健性,提出了一种基于调幅-调频(AM-FM)模型的耳语音特征参数,瞬时频率估计(IFE)。根据语音产生的共振峰调制理论,采用多带解调分析(MDA)获得语音的瞬时包络和频率;然后根据包络幅度和频率的加权估计,得到语音的特征IFE来描绘语音的频率结构。将该特征用于耳语话者识别并和传统的Mel倒谱系数(MFCC)进行了比较。实验结果表明,随着测试人数的增加,IFE的识别效果略好于MFCC;在测试信道改变的情况下,与MFCC相比IFE的稳健性得到了有效的提高。      

多元可激发气体声弛豫频率的环境影响分析

推导多元可激发气体中声弛豫频率和环境温度、压强的解析关系.理论分析和仿真计算表明：声弛豫频率线性反比于主弛豫过程的弛豫时间,正比于主弛豫过程的振动耦合热容,反比于外自由度热容;温度升高导致振动耦合热容增加、内外自由度能量转移速率增大引起弛豫时间减少,进而造成声弛豫频率正比于环境温度;压强增加使得分子碰撞速率增加引起弛豫时间减少,进而使得声弛豫频率线性正比于环境压强.     

太赫兹波段石墨烯等离子体的增益特性

基于麦克斯韦方程组和物质本构方程对石墨烯表面等离子体进行了研究.从理论上探索了石墨烯表面等离子体激元在太赫兹波段的增益特性曲线,并且讨论了石墨烯表面等离子体增益与石墨烯中载流子浓度、石墨烯所处温度以及载流子动量弛豫时间的关系.研究结果表明:在太赫兹波段增益峰值随着石墨烯载流子浓度的增加而发生蓝移,并且在所讨论的温度范围内,由于增益峰所对应的频率都大于1 THz,因此温度的变化对增益峰值以及相应频率的影响不大,即在不同的温度下,相同载流子浓度所对应的增益曲线上峰值的位置和强度几乎相同;增益与石墨烯载流子动量弛豫时间相关,随着载流子动量弛豫时间的增加,使得激发态激励的电子增加,从而导致石墨烯表面等离子体增益变得更大,但这种动量弛豫时间的增加却因弛豫时间对受激辐射频率影响较小而并未对增益峰值位置产生影响.     

用高斯分布法计算非晶态聚合物聚氯乙烯主转变过程中的动态力学弛豫时间谱分布

对非晶态聚合物聚氯乙烯PVC进行不同频率升温扫描的动态力学弛豫谱测量,发现主转变内耗峰(α峰)峰形及其他峰参数均随频率变化。本文根据连续分布谱的理论讨论PVC主转变内耗峰弛豫时间τ的分布情况,并通过高斯分布时方法,计算出PVC主转变弛豫过程中弛豫时间常数τ₀和激活能△H对弛豫时间τ的贡献权重。指出τ₀和△H在PVC主转变过程中都有明显的分布。     

Relaxation processes in harmonic glasses?

A relaxation process, with the associated phenomenology of sound attenuation and sound velocity dispersion, is found in a simulated harmonic Lennard-Jones glass. We propose to identify this process with the so-called microscopic (or, instantaneous) relaxation process observed in real glasses and supercooled liquids. A model based on the memory function approach accounts for the observation and allows one to relate to each other (1) the characteristic time and strength of this process, (2) the low frequency limit of the dynamic structure factor of the glass, and (3) the high frequency sound attenuation coefficient, with its observed quadratic dependence on the momentum transfer.     

多原子分子气体中声波弛豫衰减谱的重建算法

提出了一种宽频率范围的弛豫衰减谱重建算法,并采用基于SSH理论的方法和基于实验数据的方法估计气体的有效弛豫时间.通过该算法得到了包括氮气、甲烷、氧气、二氧化碳和水蒸气在内的多种多原子分子混合气体的声衰减谱,研究的声波频率范围从1Hz到10GHz.与预测弛豫衰减的DL模型的结果比较表明,该算法获得的弛豫衰减谱结果与之相符,其预测精度取决于对分子弛豫过程的正确认识.另外该算法还被用于几种混合气体中水蒸气和二氧化碳含量的分析,其结果表明弛豫衰减谱可被用于定量分析多原子分子气体的成分组成,这使得实现高灵敏度地检测气体成分的智能声气体传感技术成为可能. 关键词： 声弛豫衰减 有效弛豫时间 重建算法 声气体传感器     

Phase change measurement,and speed of sound and attenuation determination,from underwater acoustic panel tests

A technique for measuring the change in phase produced by the insertion of a panel between a projector and receiver is described. Presented also is a procedure for determining the phase speed and attenuation of the panel material. Although the methods were developed over the frequency decade 10-100 kHz, they are not limited to that band. It was observed that a "settling time" of approximately 20 min is required to obtain reproducible phase measurements if the experiment is disturbed even slightly. For example, rotating the panel 10 degrees, then immediately returning to the original position, causes the observed phases to differ by up to 10 deg from those obtained prior to the disturbance. These differences are distributed randomly across frequency. Temperature stabilization within the medium as well as the material is also required before measurements can take place. After the stated 20 min settling time, however, the phases return to the values obtained prior to rotation, or after temperature stabilization, to within +/- 1/2 deg. The sound speed and attenuation determination technique employs least-squares fitting of a causal model to the measurements. Four (or fewer) adjusted parameters accommodate the measurements over the stated frequency decade, even for samples that exhibit significant dispersion. The sound speed is typically determined to an accuracy of +/- 30 m/s, as judged from a propagation-of-error calculation. This model assumes single-layered panels.     

Synthesizing primary molecular relaxation processes in excitable gases using a two-frequency reconstructive algorithm

Identifying molecular relaxation processes in excitable gases remains challenging. An algorithm that reconstructs the primary relaxation processes is presented. Based on measurements of acoustic attenuation and sound speed at two frequencies, it synthesizes the entire frequency dependence of the complex effective specific heat of the gas, which is the macroscopic "footprint" of relaxation effects. The algorithm is based on the fact that for a simple relaxation process, such as occurs in many polyatomic gases at temperatures around 300 K, the effective specific heat traces a semicircle in the complex plane as a function of frequency. Knowing the high-frequency or instantaneous value of the specific heat provides the capability to not only sense the presence, but also infer the nature and, for mixtures of unlike-symmetry molecules, the concentration of foreign molecules leaking in a host gas.     

Frequency dependence of acoustic properties of aqueous glucose solutions in the VHF/UHF range

The bioultrasonic spectroscopy system was employed for measurements of velocity and attenuation coefficient of glucose solutions in the VHF/UHF range. The relation between the slope of the square of velocity and the relaxation parameters, and the relation between the frequency exponent on attenuation coefficient and the relaxation parameters are investigated. In order to carry out numerical calculations, a model for a single relaxation process is employed, wherein the attenuation coefficient is expressed as (A/( 1 + (f/falpha)2) + B)f2 where falpha is the attenuation relaxation frequency, and A and B are constants. The numerical calculations show that the slope of the square of the velocity is determined uniquely by the velocity relaxation frequency fv and v(infinity)2 - v(0)2 where v0 is the zero-frequency velocity and v(infinity) is the infinite-frequency velocity, and that the frequency exponent on the attenuation coefficient is determined uniquely by falpha and A/B. For experimental considerations, the velocities and the attenuation coefficients of 5, 15, and 25% concentration aqueous solutions of glucose were measured in the frequency range 20 to 700 MHz. The data for the 5 and 15% aqueous solutions can be explained using the single relaxation model. However, the data for the 25% aqueous solution suggest the existence of multirelaxation processes.     

千周和兆周范围的马氏体相变内耗以及预马氏体相变内耗

在千周和兆周两个频段分别测量了含Cd为46.1at％,47.5at％,50.0at％和52.5at％的AuCd合金中与马氏体转变有关的内耗和杨氏模量。实验结果表明,在千周范围,由于马氏体转变引起的Q^-1(内耗)是静滞后型的。Q^-1峰的形成可以用弹性软化及界面位错的静滞后阻尼机制来解释。而兆周范围的超声衰减是与频率有关的,表明尚有共振型及弛豫型阻尼的成份。此外,实验还观察到AuCd合金的等温马氏体转变Q^-1峰以及预马氏体相变Q^-1峰。 关键词：     

How we can interpret the T1 dispersion of MC, HPMC and HPC polymers above glass temperature?

The chain dynamics in methyl cellulose (MC), hydroxypropylmethyl cellulose (HPMC) and hydroxypropyl cellulose (HPC) were studied with the aid of field-cycling NMR relaxometry technique in the temperature range from 300 to 480 K that is above the glass transition, but below thermal degradation. The frequency dependence of proton spin-lattice relaxation time was determined between 24 kHz and 40 MHz for selected temperatures. The experimental spin-lattice relaxation dispersion data were fitted with the power law relations of T(1) proportional variant omega(gamma) predicted by the tube/reptation model. The exponent's values found from the fitting procedure for MC, HPMC and HPC almost exactly match the ones predicted in tube/reptation model for limit II (gamma=0.75) and in MC also for limit III (gamma=0.50). Remarkably, this finding concerns the polymers in networks formed of the same polymer species.     

An investigation of the measurement of broadband ultrasonic attenuation in trabecular bone

Commercial devices for the ultrasonic characterisation of bone normally report the broadband ultrasonic attenuation (BUA). This is the slope of the attenuation against frequency in some part of the frequency range 200–1000 kHz. The assumption is that the relationship is linear and hence independent of the frequency range selected. In this study the ultrasonic attenuation in the frequency range 200 to 800 kHz was measured with a variety of transducers in ten trabecular heel bone samples from elderly cadavers, assumed to be osteoporotic.

The results indicate that the attenuation fits better to a second order polynomial function of frequency, than to the linear fit. The use of a straight line fit is only satisfactory in the higher frequency ranges (above 400 kHz). The use of lower frequencies results in a significant measurement error caused by the combination of a poor signal to noise ratio and the departure from linearity and this is greatest for samples with low attenuation. In the worst cases this can amount to a 30% discrepancy between the BUA values measured over different frequency ranges.     

沉积物中声速和衰减系数的宽带测量方法

海底沉积物作为海洋波导声传播的下边界普遍存在于大洋中,获知其特性对于准确的声传播和混响建模是十分必要的。为了能够快速而准确地测量沉积物中的声速和衰减系数,提出一种基于脉冲压缩技术的测量方法,对接收信号进行压缩来提取透射波,根据不同厚度样品的透射波来计算沉积物中的声速和衰减系数。该方法不仅可以克服实验过程中经常遇到的多途干扰,而且测量过程简单,可以同时获得测量频带内所有频点的声速和衰减系数,即实现了对声速和衰减系数的宽带测量。在实验室环境条件下,90~170kHz的测量频带内,测得沙样品中的声速为1710~1713m/s,衰减系数在56~70dB/m之间。通过窄带和宽带测量结果的比较可以看出,声速的宽带测量结果与窄带测量结果吻合得较好,而衰减系数在频带后半部分存在较大的起伏。      

The effect of signal duration on the underwater detection thresholds of a harbor porpoise (Phocoena phocoena) for single frequency-modulated tonal signals between 0.25 and 160 kHz

The underwater hearing sensitivity of a young male harbor porpoise for tonal signals of various signal durations was quantified by using a behavioral psychophysical technique. The animal was trained to respond only when it detected an acoustic signal. Fifty percent detection thresholds were obtained for tonal signals (15 frequencies between 0.25-160 kHz, durations 0.5-5000 ms depending on the frequency; 134 frequency-duration combinations in total). Detection thresholds were quantified by varying signal amplitude by the 1-up 1-down staircase method. The hearing thresholds increased when the signal duration fell below the time constant of integration. The time constants, derived from an exponential model of integration [Plomp and Bouman, J. Acoust. Soc. Am. 31, 749-758 (1959)], varied from 629 ms at 2 kHz to 39 ms at 64 kHz. The integration times of the porpoises were similar to those of other mammals including humans, even though the porpoise is a marine mammal and a hearing specialist. The results enable more accurate estimations of the distances at which porpoises can detect short-duration environmental tonal signals. The audiogram thresholds presented by Kastelein et al. [J. Acoust. Soc. Am. 112, 334-344 (2002)], after correction for the frequency bandwidth of the FM signals, are similar to the results of the present study for signals of 1500 ms duration. Harbor porpoise hearing is more sensitive between 2 and 10 kHz, and less sensitive above 10 kHz, than formerly believed.