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1.
高铁高砂煤矸石合成4A沸石分子筛   总被引:2,自引:0,他引:2  
以六盘水矿区的高铁高砂煤矸石为原料合成4A沸石分子筛,将煤矸石低温焙烧、盐酸酸浸除铁、高温焙烧后再碱融活化获得了活性原料,最后采用水热晶化的方法,合成了4A沸石分子筛产品.本研究采用单因素实验的方法,考察了合成条件对4A沸石分子筛性能的影响,并运用XRD和SEM对产品进行了表征,结果表明所得产品为4A沸石分子筛,粒度分...  相似文献   

2.
 微波辐照频率为1.2~2.0 GHz时,利用宽带天线对微型计算机主板进行微波辐照,考察了微波辐照载波频率、调制方式和调制深度对微波辐照效应的影响,得到了计算机分别处于满负荷工作、内存读写操作、磁盘读写操作和系统空闲4种工作状态下的微波辐照干扰功率阈值。实验结果表明:微波辐照的载波频率为1.47 GHz时,辐照干扰功率阈值最低,为32.7 dBm,计算机最易被干扰;瞬时功率是干扰微型计算机的关键参数,调制方式、调制频率和深度对微波辐照干扰功率阈值影响不大;处于高负荷工作状态的微型计算机更易于被微波辐射干扰;计算机启动的干扰功率阈值为32.0 dBm,小于正常工作状态时的阈值。  相似文献   

3.
XRD粉末衍射法研究微波场作用下4A分子筛的合成   总被引:1,自引:0,他引:1  
在微波场作用下合成了粒度均匀、白度和钙离子交换容量高、性能优异的4A分子筛.用XRD粉末衍射法研究了硅铝比、水钠比、微波功率和微波加热时间对微波合成4A分子筛的影响,找出了在微波场作用下合成4A分子筛的最佳条件,并用IR,SEM和DSC等方法对合成的产物进行了表征.  相似文献   

4.
基于红外热成像的微波热疗透热深度   总被引:2,自引:0,他引:2       下载免费PDF全文
 对临床上常用的2 450 MHz微波在均匀介质中的电透入深度进行了分析,基于生物组织的热波模型,研究了生物组织吸收微波能的热效应;实验采用红外热成像仪测温,以2 450 MHz的微波辐射器辐照均匀的分层仿生体模,根据实验数据对微波热疗中透热深度进行了研究,说明微波的透入深度和透热深度的区别,并给出微波辐射器的功率、辐照距离和辐照持续时间对透热深度的影响。结果表明:当采用增大功率、延长辐照时间和近距离辐照等手段,都可以提高微波在人体的透热深度,为体外微波热疗中的人体传输模型建立及热疗的无损测温与控温奠定实验基础。  相似文献   

5.
槐角中染料木素微波提取法   总被引:2,自引:0,他引:2  
以槐角为原料,甲醇为溶剂,利用微波辐射、回流、水解提取染料木素.微波辐照法从槐角中提取、纯化制备染料木素的工艺条件.在微波功率28-32W的条件下,槐角粉末(60目),液料比V/W(6:1),回流提取时间(40min×3),收率2.06%,含量92.5%.微波辐照法提取染料木素,方法简便、快速、高效.  相似文献   

6.
XRD和FTIR对沸石合成机制的光谱学解析   总被引:1,自引:0,他引:1  
Fan CH  Ma HR  Hua L 《光谱学与光谱分析》2012,32(4):1118-1122
以粉煤灰为原料,采用优化的水热晶化一步法合成沸石。比较晶化反应过程沸石产物CEC值及化学成分的变化,推断固液体系中物质转换及元素迁移方式和途径。借助XRD,SEM,FTIR等表征反应过程沸石的晶型变化及成核特性,提出可能存在的沸石生成机制。合成产物主要为NaP1型沸石,反应24h后CEC值最大为135mmol/100g。12h后,产物中初步发现NaP1沸石相特征峰和亚晶结构,48h后出现羟基方钠石的特征弱峰。沸石生成过程涉及到固液体系间的物质流动:碱熔融作用将粉煤灰组分侵蚀进入液相体系,为沸石形成提供了原料组分,而固相体系为沸石生长提供骨架结构,液相体系和固相体系分别为晶化反应的"源"和"汇",这是液相转化机制和固相转化机制的客观反映。  相似文献   

7.
胶原蛋白的三股螺旋结构是其不同于其他蛋白质的特殊结构,也是其具有特殊功能的基础,然而,胶原的三股螺旋结构易在外界条件的影响下被破坏。目前微波已被越来越多的应用于胶原蛋白的提取和改性过程,但是关于微波辐照对胶原蛋白结构影响的研究还相对较少。首先从牛跟腱中提取胶原蛋白,然后采用0.5 mg·mL-1的胶原蛋白溶液在30 ℃下以微波辐照保温为实验样,水浴加热和未经加热处理为对比样,最后采用紫外-可见光谱、傅里叶变换红外光谱、圆二色谱以及荧光发射光谱等方法,对不同加热方法中胶原蛋白的三股螺旋结构和超分子结构进行表征,研究了微波辐照对胶原蛋白结构的影响。实验结果表明,在低于胶原变性温度的条件下,无论是微波辐照还是水浴加热都不会破坏胶原蛋白的三股螺旋结构,也不会使胶原蛋白变性。但是,与水浴加热相比,微波辐照会对胶原蛋白的聚集行为产生抑制作用。微波辐照对胶原蛋白的作用既有与常规加热相同的热效应,又有常规加热过程中不存在的非热效应,非热效应表现为抑制胶原蛋白的聚集行为。研究结果可为微波场中胶原蛋白结构和性质的变化提供科学依据。  相似文献   

8.
采用微波辐射技术结合酸、碱、盐分别对沸石进行活化改性处理,用分光光度法分析改性沸石对Fe2+的吸附性能及影响因素。结果表明:NaOH改性沸石对Fe2+的去除效果优于NaCl、HCl改性沸石,当微波功率为640W,微波时间为5min,NaOH浓度为0.8mol/L时,Fe2+去除率可达98.56%。经过对改性沸石再生,NaOH浸泡过的改性沸石再生性较好。  相似文献   

9.
双折射晶体YVO4原料的合成与表征   总被引:2,自引:0,他引:2  
本文采用液相法研究了双折射晶体YVO4 原料的合成工艺 ,着重讨论了溶液的pH值等合成条件对原料合成纯度与洁白度的影响。并采用红外光谱、X射线粉末衍射、紫外光谱等方法对合成的原料和生长单晶进行了纯度与质量的表征 ,确定了原料合成的最佳方案 ,结果表明原料的纯度对单晶生长起决定性的作用。所合成高纯原料通过Czochralski(CZ)技术可生长出尺寸为4 0× 4 0× 5 0mm3的无缺陷单晶。  相似文献   

10.
无线电引信的超宽谱辐照效应及其防护   总被引:6,自引:3,他引:6       下载免费PDF全文
 探讨了超宽谱高功率微波对无线电引信的辐照效应、耦合机理和防护方法。利用超宽谱高功率微波辐照源对多姿态的无线电引信进行了辐照实验并对结果进行了分析,实验表明当引信和弹体的轴向与超宽谱高功率微波的电场极化方向一致时,引信最容易被引爆,辐照效应最明显。通过理论分析和辐照实验找出超宽谱高功率微波能量耦合机理为:引信和弹体上感应的瞬变电压通过引信电源电路传递到执行电路,瞬变电压上升率超过了电路中晶闸管的断态电压临界上升率,使晶闸管意外导通,导致引信误动作。在不影响引信工作特性前提下,采取增加防护器件和替换敏感器件的加固方法,可以提高引信抗干扰能力。采用综合防护加固方法可使引信在超宽谱高功率微波辐照下不再产生误动作,达到了防护加固的目的。  相似文献   

11.
目前浮选提高重晶石品位的方法通常采用新型浮选药剂从低品位重晶石矿中进行分选,采用微波加热预处理矿物可提高浮选回收率,但微波对浮选药剂与矿物的作用机理还不清楚。微波加热技术近年来用于矿物加工、冶金与材料制备等领域,具有反应速度快、产品指标高等优点。以油酸钠为捕收剂,对微波预处理后的重晶石纯矿物进行浮选,并对不同微波作用时间下的重晶石浮选样品进行红外光谱检测,通过红外拟合平滑光谱和二阶导数光谱计算分析,研究微波对重晶石浮选的影响机理。浮选试验结果表明,未经微波预处理的重晶石,在油酸钠用量为55 mg·L-1、pH值为8.0的条件下,浮选指标最佳,回收率为91.41%;而对比之下,经微波作用后的重晶石进行浮选,随着微波处理时间的增加浮选指标逐渐提高,且在微波作用60s时的回收率最高,达95.27%。基于浮选试验的红外光谱分析表明,重晶石未经微波预处理进行浮选,与油酸钠作用,在波数为3 004 cm-1处-CH2-的对称伸缩振动峰、2 953 cm-1处-CH3的反对称伸缩振动峰、1 119和1 077 cm-1处SO2-4的非对称伸缩振动峰均发生了红移,说明油酸钠在重晶石表面发生化学吸附;而经微波预处理后的重晶石浮选时,在波数为2 853 cm-1处-CH2-对称伸缩振动峰、2 923 cm-1处-CH2-反对称伸缩振动峰、2 958 cm-1处-CH3反对称伸缩振动峰、1 181,1 122和1 086 cm-1处SO2-4非对称伸缩振动峰、982 cm-1处SO2-4对称伸缩振动峰、635和610 cm-1处SO2-4弯曲振动峰,其峰位并未发生红移,但峰强随着微波作用时间的增加明显加强,且微波作用60 s时其峰强增加最明显;对微波处理后的红外光谱进行拟合平滑光谱和二阶导数光谱计算发现,在波数为2 958,2 923,2 853,1 181,1 122,1 086,982,635和610 cm-1处峰面积均有不同程度的增加,且在微波作用60s时峰面积分别增加了1.84%,259.12%,761.15%,235.72%,145.61%,198.50%,641.16%,549.67%和744.97%,表明微波预处理并未诱发重晶石表面发生化学反应,但强化了捕收剂油酸钠与重晶石矿之间的化学吸附,使其与重晶石表面的化学吸附更加致密,吸附量增加,因此重晶石回收率增加,浮选指标提高。  相似文献   

12.
Here, we present physical–chemical properties of Linde type A (LTA) zeolite crystals synthesized via conventional hydrothermal and microwave heating methods. Both heating methods produced LTA crystals that were sub-micron in size, highly negatively charged, super-hydrophilic, and stable when dispersed in water. However, microwave heating produced relatively narrow crystal size distributions, required much shorter heating times, and did not significantly change composition, crystallinity, or surface chemistry. Moreover, microwave heating allowed systematic variation of crystal size by varying heating temperature and time during the crystallization reaction, thus producing a continuous gradient of crystal sizes ranging from about 90 to 300 nm. In ion-exchange studies, colloidal zeolites exhibited excellent sorption kinetics and capacity for divalent metal ions, suggesting their potential for use in water softening, scale inhibition, and scavenging of toxic metal ions from water.  相似文献   

13.
化学浸提法研究中药赤石脂中活性铝的溶出及形态分布   总被引:3,自引:0,他引:3  
利用KCl,NH_4Ac,HCl,NaOH4种化学浸提液将中药赤石脂中活性铝溶出,根据不同的溶出机理,得到赤石脂中铝的不同化学形态,采用分光光度法进行定量测定,得到中药赤石脂中活性铝的形态分布,并对影响铝溶出的若干因子进行了探讨。  相似文献   

14.
在100,250和1 000 mL高压釜静态成功合成MCM-22分子筛的基础上,在2,5和200 L高压釜中进行了MCM-22分子筛的动态合成试验,对合成的样品用XRD等技术进行了表征.结果表明,在静态和动态条件下合成的样品,全部为纯相MCM-22分子筛,且结晶度较高,从100 mL到200 L的放大试验是成功的.  相似文献   

15.
The surface interaction between TiO2 and natural zeolite, clinoptilolite, has been investigated by means of transmission electron microscope (TEM), atom force microscope (AFM), X-ray diffractometer (XRD), diffuse reflectance infrared Fourier transform (DRIFT) and far Fourier transform infrared ray (FTIR) spectroscopy. And the photocatalytic degradation (PCD) rate of methyl orange (MO), a model of recalcitrant azo dye, in aqueous system has been measured to compare the photocatalytic activities of different photocatalysts. A model has been carried out to explain the incorporation between TiO2 particles and natural zeolite. The results show that the TiO2 particles loaded on zeolite are 50 nm or so, smaller than the pure one, and combine with zeolite via chemical force. Since the reserved adsorption ability and the existence of electron trapper, the TiO2-zeolite performed more efficient at low initial concentration and in the later period of PCD process, as compared with pure TiO2 nanopowders.  相似文献   

16.
In this study, highly pure magnetite nanoparticle dispersed in water and an organic solvent (n-hexane) and its powder form were prepared in laboratory scale by the fractional precipitation using ammonium hydroxide and microwave heating in the presence of linoleic acid as capping agent. In order to overcome the oxidation of Fe2+ during magnetite formation ferrous ammonium sulfate, sodium azide, and fractional precipitation technique were used. The Fe3O4 products were investigated by XRD, LLS, EDX, TEM, viscosity measurements, and chemical analysis. The effects of seven main factors on the average diameter of magnetite particles were studied by a screening design. The analysis of the samples showed that this new modified method is able to produce pure magnetite particles in the range of 1–15 nm. The most important factors on the particle size reduction of magnetite were found to be the capping agent used and the pH of solution at the end of precipitation process. Data analysis was performed using Qualitek-4 and Minitab softwares.  相似文献   

17.
We study conditions for microwave plasma-assisted chemical vapor deposition of high-quality single-crystal diamond films in a CVD reactor. These conditions are studied using the results of homoepitaxial growth of polycrystalline diamond films on diamond substrates and on the basis of numerical simulation of the microwave discharge in a CVD reactor. A high-quality single-crystal diamond layer is synthesized on a synthetic, type Ib diamond substrate. The properties of the obtained monolayer are studied by means of Raman and X-ray diffraction spectroscopy as well as optical and atomic-force microscopy.  相似文献   

18.
In this study, a reinforced silver-embedded silica matrix was designed by utilizing the interaction between the [AlO4] tetrahedral and the Ag+ in sol-gel process using sodium silicate as a silica precursor. The Ag+ mole ratio in each sample was significantly varied to examine the influence of silver concentration on the properties of the final product. Aluminium ions were added to reinforce and improve the chemical durability of silver-embedded silica. A templated sample at Al/Ag = 1 atomic ratio was also synthesized to attempt a possibility of controlling porosity of the final product. Also, a sample neither embedded with silver nor templated was synthesized and characterized to serve as reference. The material at Al/Ag = 1 was found to have a desirable properties, compared to its counterparts, before and even after calcination up to 1000 °C. The results demonstrate that materials with desirable properties can be obtained by this unprecedented method while utilizing sodium silicate, which is relatively cheap, as a silica precursor. This may significantly boost the industrial production of the silver-embedded silicas for various applications.  相似文献   

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