不同氧含量Bi2Sr2CaCu2O８+δ单晶电阻率的各向异性

精确测量了在不同氧压下退火的单晶Bi₂Sr₂CaCu₂O_8+δ(Bi2212)样品的Cu-O面内和Cu-O面外的电阻率ρ_c(T)和ρ_ab(T).发现ρ_c(T)和各向异性比(ρ_c(T)/ρ_ab(T))随着载流子浓度增加而迅速下降.在过掺杂样品中,高于120K时,ρ_c随温度线性下降,而各向异性 关键词：     

Bi2Sr2CaCu2O8超导单晶中的电阻反常行为

测量了Bi₂Sr₂CaCu₂O₈单晶的ab面和c轴方 向电阻,在其超导转变温度附近发现了反常的电阻峰出现.其随外磁场(>100Gs)和电流的增 加而逐渐消失.文章认为这个反常的电阻峰是由于单晶中超导相的不均匀分布而导致的准再 进入行为. 关键词： 2Sr₂CaCu₂O₈单晶')" href="#">Bi₂Sr₂CaCu₂O₈单晶 反常电阻峰 准再入行为     

Bi2Sr2CaCu2O8的晶体结构与超导性能

本文研究了Bi-Sr-Ca-Cu-O体系中理想成份为Bi₂Sr₂CaCu₂O₈化合物的超导性能和晶体结构。名义成份为BiSrCaCu₂O_5.5零电阻超导转变温度T_c(0)=81.5K。用X射线粉末衍射方法测定了Bi₂Sr₂CaCu₂O₈的晶体结构,其基本结构属体心四方晶系,空间群为D_4h¹⁷-l4/mmm,点阵常数a=3.825?,c=30.82?。每单胞化合式单位为2.2Ca占据2(a)等效点系,4Sr,4Bi和4Cu占据三组4(e)位置,其原子参数z分别为0.110,0.302和0.445,16O分别占据8(g),z=0.445和二组4(e),z=0.210和0.380。Bi₂Sr₂CaCu₂O₈晶体结构可认为是阳离子沿z轴的(00z)和((1/2)(1/2)z)交错排列,由Aurivillius相导生出来的。讨论了在Bi-Sr-Ca-Cu-O体系中可能存在的其它沿z轴不同堆垛层数的超导相。 关键词：     

Bi2Sr2CaCu2O8单晶中的反常尖锋效应

使用牛津震动样品磁强计(VSM)研究了Bi₂Sr₂CaCu₂O₈单晶的磁滞回线.在20到40K温度之间发现了反常的尖锋效应,随样品O含量的增加,发生尖锋效应的外场也相应提高.可以认为在尖峰效应处发生了由涡漩物质的有序固态到无序固态的相变,在有少量点缺陷存在的BSCCO单晶相图上,B_sp线终止于20K温度处,在20K以下温区没有发生准格子到涡漩玻璃的相变,涡漩固相始终以准格子形式存在;可以认为尖峰效 关键词： 2Sr₂CaCu₂O₈单晶')" href="#">Bi₂Sr₂CaCu₂O₈单晶 磁滞回线 尖锋效应 相变     

Anisotropy of Electronic Spin Texture in the High-Temperature Cuprate Superconductor Bi2Sr2CaCu2O8+δ

Seeking new order parameters and the related broken symmetry and studying their relationship with phase transition have been important topics in condensed matter physics. Here, by using spin-and angle-resolved photoemission spectroscopy, we confirm the helical spin texture caused by spin-layer locking in the nodal region in the cuprate superconductor Bi₂Sr₂CaCu₂O_8+δ and discover the anisotropy of spin polarizations at nodes along Γ –X and Γ –Y directio...     

Y1-xCaxBa2Cu3-xMxO7-δ (M=Fe,Ni)体系的超导电性

本文报道,通过对Y_1-xCa_xBa₂Cu_3-xMxO_7-δ(M=Fe,Ni)体系样品的晶体结构、氧含量、正常态电阻率与温度的关系,以及超导转变温度等测量,并与YBa₂Cu_3-xMxO_7-δ(M=Fe,Ni)体系进行比较,发现Y_1-xCa_xBa₂Cu_3-xFe_xO_7-δ体系的T_c显著地高于相应x值的YBa₂Cu_3-xFe_xO_7-δ体系,而Y_1-xCa_xBa₂Cu_3-xNi_xO_7-δ体系则相反,T_c低于仅Ni替代的体系,表明Ca和Fe同时替代时两者引起的载流子浓度(n_H)变化相互补偿,抑制了仅Fe替代时引起的n_H和T_c急剧下降;而作Ca和Ni同时替代时主要的不是两者引起载流子浓度变化的相互补偿,Ca和Ni替代效应之间的关联较弱。作者认为,对Y_1-xCa_xBa₂Cu_3-xFe_xO_7-δ体系属于CuO₂平面外的元素替代,这时载流子浓度是决定Tc的主要因素;而对Y_1-xCa_xBa₂Cu_3-xNi_xO_7-δ体系,由于Ni²⁺离子主要占据Cu(Ⅱ)位,它导致磁拆对效应,Ni²⁺离子的拆对效应是引起T_c下降的直接原因。 关键词：     

Bi2Sr2CaCu2O8+y掺Na样品的超导机制

用熔融法制备了Bi₂Sr₂CaCu₂O_8+y掺Ｎａ多晶样品，转变温度Ｔ_c提高到９０Ｋ以上，最大的零电阻温度达到９２．５Ｋ。在流动氧气退火后，未掺Ｎａ样品Ｔ_c显著降低，而掺Ｎａ样品Ｔ_c几乎不变，说明二者Ｔ_c提高具有不同的机制。据此我们认为Ｎａ替代了Ｂｉ而使Ｂｉｏ层电荷失去平衡，Ｃｕｏ面上电子转移到Ｂｉｏ层而形成空穴，空穴和电子的吸引相 关键词：     

Bi2Sr2CaCu2O8单晶a-b平面热电势率的各向异性

测量了Bi₂Sr₂CaCu₂O₈单晶a方向的热电势率S_a和b方向的热电势率S_b与温度T的关系,发现在a-b平面内热电势率存在各向异性。认为S_a与S_b的差异来源于b方向的调制结构,并用扩散热电势率S_d,声子曳引热电势率S_g和相关跳跃热电势率S_h三种贡献,对实验结果进行了 关键词：     

Bi2Sr2CaCu2-xSnxO8+δ系列 超导体的XRD和XPS研究

实验研究了Bi₂Sr₂CaCu_2-xSn_xO_8+δ 的X射线衍射(XRD)和光电子能谱(XPS).实验发现随着掺杂(Sn)量的增加,晶格参数a 和c都有所变化,O1s和Cu2p芯能级谱也发生了变化.实验结果表明： 在低掺杂量时,Sn主要 呈二价态;而在高掺杂浓度时呈四价态;掺Sn对超导电性的影响与其他元素的掺杂不同.这 些实验结果支持化学环境在高温超导样品的电子结构中起着重要作用的结论. 关键词： Bi系超导体 掺杂 X射线衍射 光电子能谱     

(Bi,Pb)2Sr2Ca2Cu3Oy单相样品的超导电性与载流子浓度

对(Bi,Pb)₂Sr₂Ca₂Cu₃O_y单相样品进行不同条件下的热处理,通过X射线衍射、电阻-温度关系、交流磁化率,以及Hall系数等测量,发现样品均具有较好的单相性,随着热处理条件的变化,其超导转变中点温度(T_c)有规律地分布在100—110K之间,T_c随载流子浓度(n_H)的增加而升高。实验结果表明,热处理条件对样品的相结构、超导 关键词：     

Structure and superconducting properties of Bi2Ba2−xMxCuO6+δ

The effect of oxygen nonstoichiometry and barium cation substitution on the structure and superconducting properties of Bi₂Ba_2−xM_xCuO_{6 +δ}(M = Sr, Ru, Rh, Pd, In, Sb or Pb;xchanged from 0 to 0.2) were studied. The cation-substituted samples annealed in oxygen flow contain a superconducting phase withT_c^initnear 95 K.     

Anisotropy of the electron momentum distribution in Bi2Sr2CaCu2O8+δ superconductor studied by positron annihilation

The temperature dependent (30-300 K) Doppler broadening of the positron annihilated γ-radiation measurement has been investigated on single crystalline Bi₂Sr₂CaCu₂O_8+δ (Bi-2212) high T_c superconducting samples along two different crystallographic orientations. It has been observed that throughout the temperature range the electron momentum distribution has a larger value along the crystallographic c-axis than in the a-b plane. The temperature dependent Doppler broadened positron annihilation γ-radiation lineshape analysis shows a step like increase of S-parameter at the temperature region 92-116 K.     

掺Ba对Bi系2212相超导电性的影响

研究了掺Ｂａ对Bi₂Sr_2-xBa_xCaCu₂O_y（０≤ｘ≤０．１５，０．３）单晶和多晶样品超导电性的影响，结果表明，有少量Ｂａ^２＋离子进入了超导相，且有固溶度极限．对于２２１２相单晶，ｃ轴参数和Ｔ_c均随Ｂａ含量增加而增加；对于慢冷多晶样品，掺Ｂａ可明显提高Ｔ_c；然而对于淬大多晶样品，Ｔ_c没有明显变化，用掺Ｂａ 关键词：     

Evidence for superconductivity in the Bi-O layers and not in the cuprate planes of Bi2Sr2CaCu2O8

The superconductivity in Bi₂Sr₂CaCu₂O₈occurs in Bi-O slabs, with the CuO₂planes being insulating.     

Carrier concentration dependence and impurity effects of microwave response in Bi2Sr2CaCu2O8+ y

We report the surface impedance (Z _s ) measurements in high quality single crystals of Bi₂Sr₂CaCu₂O_8+y . At relatively low oxygen content, the change of the penetration depth, Δλ(T) ≡λ(T)-λ(0), of the pure single crystals exhibits linear temperature dependence both parallel to the CuO₂ planes and in thec direction. In contrast to this behavior, by further oxygenation or 0.6% Zn substitution, theT-linear dependence is disrupted andT ² dependence of Δλ is observed. We also found that 0.9% Ni-substitution induces no pairbreaking effect. The present results suggest that the low-lying excitation spectrum of quasiparticles depends on the carrier concentration and is easily changed by a small amount of Zn substitution.     

Scanning tunneling spectroscopy of a superlattice superconductor: Bi2Sr2CaCu2O8

It is clear that many of the cuprate superconductors are truly superlattices, composed of sheets whose individual superconducting critical temperatures may approach bulk values. Such a cuprate is Bi₂Sr₂CaCu₂O₈, often referred to as BSCCO-2212. Scanning tunneling spectroscopy (vacuum tunneling) applied toa-bBiO cleavage planes ofT_c≈90 K BSCCO single crystals under liquid helium simultaneously provides topography and local dI/dVspectra (superconducting density of states: DOS). The spectra, which are similar to those obtained from angle-resolved photoemission spectroscopy, confirm a large gap parameter Δ(x,y) on the uppermost layer. The dI/dVspectra do not unequivocally select order parameter symmetry, but are probably consistent with d-wave or anisotropic s-wave states. Spatial variations of Δ on a 100 Å scale are attributed to variation in BiO metallicity, originating in oxygen stoichiometry variations. A model is presented to explain the different dI/dVspectra which are seen, and associated with different local oxygen concentrations. This model, based on the superconducting proximity effect, assumes that in some regions the BiO uppermost layer is insulating and in other regions it is metallic, in the latter case induced superconductivity by proximity to the CuO₂planes. Our STM measurements appear to sample only the uppermost half cell of the crystal, and contain no obvious superlattice features. Recent measurements have confirmed Josephson radiation from voltage biasedc-axis pillars of BSCCO. From the point of view of the present work, the superconducting systems which weakly couple along thec-direction to create Josephson junctions are probably half-cell slabs of height 15.4 Å, each containing two CuO₂and two BiO layers, which act as single composite electrodes for the Josephson junctions.     

Electrical and infrared study of Bi2Sr2Ca1Cu2O8 in semiconducting, superconducting ceramic and superconducting glass ceramic state

We have studied the electrical and infrared properties of Bi₂Sr₂Ca₁Cu₂O₈ compound in three states. Electrical and IR measurements show that the pure powder state sample is a semiconductor, the ceramic Bi₂Sr₂Ca₁Cu₂O₈ sample prepared after annealing at 820°C for 240 hours shows a T_c of 85 K, whereas Bi₂Sr₂Ca₁Cu₂O₈ sample prepared through glassy route, i.e. melting at 1250°C and annealing at 820°C for 240 hours shows a drop of T_c by 5 K. The infrared spectra of superconducting ceramic and glass ceramic states in the available frequency range of measurement reveals the presence of three phonons. Since the vibrational mode around 595 cm^–1 is due to CuO₂ layers and as the CuO₂ layers are responsible for T_c in the ceramic superconductors, any change in these layers will affect the T_c. The shifting of the 595 cm^–1 mode towards lower frequencies in the glass ceramic due to different preparation process, indicates that there is a change in CuO₂ layers resulting in a change of T_c, which is confirmed by Four probe dc measurements.     

Superconductivity and calorimetric studies of Pr1.85Ce0.15CuO4+δ under different annealing conditions

Polycrystalline samples of electron-doped Pr_1.85Ce_0.15CuO_4+δ have been prepared under different annealing conditions and investigated by means of X-ray-diffraction, oxygen content analysis, electrical resistivity, magnetic susceptibility and low temperature specific heat measurements. X-ray-diffraction patterns show that samples contain a single T′ phase. The superconducting transition temperatures T_cm taken with the onset of diamagnetism in magnetic-susceptibility measurements are 20 and 19.5 K for sample annealed in flowing Ar gas and in vacuum (∼10⁻³ torr), respectively. The data of the samples, which are annealed in flowing Ar gas, show clear evidence for an αT² term at zero magnetic field in superconducting electronic specific heat, and are consistent with d-wave superconductivity. However, this behavior is not observed in the other sample, which is annealed in vacuum. These results indicate that different heat treatments affect the oxygen content, homogeneity, superconducting transition temperature T_c, superconducting volume fraction, and the superconducting pairing symmetry of Pr_1.85Ce_0.15CuO_4+δ.