共查询到19条相似文献,搜索用时 125 毫秒
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苯基荧光酮在混合表面活性剂体系中铜、铝的分光光度法同时测定 总被引:3,自引:1,他引:2
本文对在溴代十六烷基三甲铵和吐温80混合表面活性剂中苯基荧光酮分光光度法同时测定铜和铝进行了研究。实验表明,在磷酸介质中,pH=6.8-7.4范围内,苯基荧光酮与铜、铝形成稳定的络合物。铜络合物最大吸收波长为600nm,εCu600=6.63×104L·mol-1·cm-1,线性范围为0—5μg/25mL;铝络合物最大吸收波长为564nm,εAl564=1.01×105L·mol-1·cm-1,线性范围0—6μg/25mL。方法灵敏度高,选择性好,用于水及健康人体冻干血浆中铜、铝回收率的测定,结果满意。 相似文献
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分光光度法测定烟叶中镁的研究 总被引:3,自引:1,他引:2
在pH= 7.0 NH4Ac 缓冲介质中,苦氨酸偶氮-H-酸(PHA)与镁反应生成2∶1 蓝紫色络合物,λm ax=630nm ,ε= 1.16×104L·m ol- 1·cm - 1,镁的含量在0.5- 40μg/25m L内符合比尔定律,本方法用于烟草样品中镁的测定,结果令人满意。 相似文献
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报道了光学外差法测量表面起伏精度及横向分辨精度达到0.11nm及4μm。本文采用的是完全共光路外差干涉系统,阐述了它的原理、构造及噪声的影响,并将测量结果与其它商品仪器测量结果作了比较。 相似文献
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苯基荧光酮分光光度法测定煤矸石中钛 总被引:4,自引:1,他引:3
本文研究和比较了几种表面活性剂存在下,苯基荧光酮(PF)与钛的显色反应。试验表明,在0.03-0.05mol·L-1的硫酸介质中,钛与PF形成蓝紫色配合物,最大吸收峰在595nm处,表观摩尔吸光系数ε=6.3×104L·mol-1·cm-1。钛量在0-15μg/25mL范围内服从比耳定律。方法灵敏度高,选择性好,抗干扰能力强,体系稳定,测定煤矸石中钛,结果满意。 相似文献
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新试剂2-(4-安替比林偶氮)-5-二乙氨基苯胺与钯显色反应的研究及应用 总被引:1,自引:0,他引:1
在pH=5.0HAc-NaAc缓冲介质中,吐温-80存在下,2-(4-安替比林偶氮)-5-二乙氨基苯胺(ADEA)与钯生成2∶1红色络合物,λmax=530nm,ε=6.15×104L·mol-1·cm-1,钯的含量在0—20μg/25mL内符合比耳定律,本方法用于钯催化剂中痕量钯的测定,结果令人满意。 相似文献
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提出一种新的具有高空间分辨力的整形环形光式差动共焦测量方法。该方法通过整形环形光式共焦测量法和锐化爱里斑主瓣,改善系统横向分辨力;通过差动共焦测量法改善系统的轴向分辨力,最终达到提高系统空间分辨能力的目的。理论分析和实验表明:整形环形光内孔归一化半径ε越大,横向分辨力改善越明显,量程扩展范围越宽;当入射光波长λ=632.8nm,物镜数值孔径取NA=0.85,ε=0.5时,该系统的横向分辨力优于0.2μm,轴向分辨力优于2nm。该方法为光触针测量系统空间分辨力的提高提供了1种新的方法,可广泛应用于超精密三维微细结构工件的超精密测量。 相似文献
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Based on a set of microoptics the output radiation from a continuous wave (CW) linear laser diode array is coupled into a multi-mode optical fiber of 400 μm diameter.The CW linear laser diode array is a 1 cm laser diode bar with 19 stripes with 100 μm aperture spaced on 500 μm centers.The coupling system contains packaged laser diode bar,fast axis collimator,slow axis collimation array,beam transformation system and focusing system.The high brightness,high power density and single fiber output of a laser diode bar is achieved.The coupling efficiency is 65% and the power density is up to 1.03×104 W/cm2. 相似文献
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WANG Xiaowei XIAO Jianwei MA Xiaoyu WANG Zhongming FANG Gaozhan 《Chinese Journal of Lasers》2002,11(3):205-207
1 Introduction Laserdiodearray (LDA )thathasmultipleemittingregionsisaperfectdevicetoachievehigherpoweroutputswithanincreasedbrightness.ThehighCW power ,highbrightnessandfiberoutputofalaserdiodebarcanbeappliedinmedicine ,materialsprocessing ,solid statelas… 相似文献
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In modern semiconductor and optics industries, there is a strong demand for a highly sensitive and non-contact surface profilometer. This paper describes a practical heterodyne surface profiling interferometer for on-line non-contact measurement which has been developed recently. The essential feature of the profilometer is a newly designed common-path configuration to minimize the effects caused by vibration, air turbulence and other environmental variations. A single-mode frequency-stabilized laser diode (780 nm) serves as the light source to make the whole system compact (total volume 250L×200W×100H mm). A powerful signal processing scheme is also developed, which includes three parts: automatic voltage control, phase measurement with wide range and automatic focusing control. All these make the repeatability and stability of the profiling interferometer greatly improved. The system has vertical resolution of 0.39 nm and lateral resolution of 0.73 μm. During approximately an hour, the stability is within 1.95 nm(3σ). 相似文献
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In order to further improve the performance of a confocal microscope (CM) used for measurement of surface profiles and 3D microstructures, a shaped annular beam heterodyne confocal measurement method based on annular pupil filter technique and reflection confocal microscopy, is proposed to expand the measurement range and to improve the defocused property of CM. The approach proposed uses a confocal dual-receiving light path arrangement and a heterodyne subtraction of two signals received from detectors with axial offset to enable CM to be used for bipolar absolute measurement and to improve the defocused property of CM, and it uses the annular pupil filter technique to produce a binary optical shaped annular beam, which expands the measurement range by expanding the full-width at half-maximum of intensity curve received from two detectors in a heterodyne confocal microscopy system. Theoretical analyses and experimental results indicate that a shaped annular beam heterodyne microscope has a measurement range expanded from 4 to 14 μm, achieved an axial resolution of 2 nm and improved the defocused property, when ε=0.5 and NA=0.65. It can be therefore concluded that the shaped annular beam heterodyne confocal measuring method proposed is a new approach to ultraprecision measurement of surface profiles and 3D microstructures. 相似文献
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This paper proposes an optical method for measuring small displacements using the surface plasmon resonance (SPR) heterodyne interferometry. A heterodyne light beam reflected by a mirror passes through a hemisphere glass and then enters into a surface plasmon resonance apparatus at the resonant angle. A small displacement of the mirror will introduce a phase-difference variation between p- and s-polarizations of the light emerging from the SPR apparatus. The phase-difference variation can be precisely measured with the heterodyne interferometric technique, and the associated displacement can be estimated. The feasibility of this method was verified by experiment, and the displacement measurement resolution of about 1.4 nm over a traveling range of 6 μm was achieved. Our method of measurement has the merits of both common-path interferometry and heterodyne interferometry. 相似文献
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An optical measurement system has been developed for the simultaneous detection for five degree-of-freedom (DOF) deviations of the object. The measuring system designed bases on laser holographic technique, laser alignment technique, laser drift compensation technique and magneto-optic modulating technique where a single laser beam is used as datum line. This measuring system is applied to multiple degree-of-freedom alignment and measurement of fine deviation, and it carries out the automatic testing in a deformation of machine tool, or the loaded axon in a strain wind tunnel balance. Through actual calibration and measurement, the resolution of the system is estimated to be 4 μm for linear displacement error measurement and better than 2″ for angular error measurement with a 1 m offset between laser and a photoelectric receiving target. 相似文献