Wavelength modulation spectra of GaSe,GaS, and alloys

Recently electroreflectance (at 300 K) and thermoreflectanee (at 77 K) of the layer compound GaSe have been reported. For comparison we have measured the wavelength modulation spectra (1/R) dR/dE of GaSe, GaS, GaSe_0.2S_0.8, and GaSe_0.8S_0.2 at 5, 77, and 300 K between 2 and 6 eV. A large number of new structures are reported.     

Analyzing in-plane magnetic anisotropy from surface morphology for amorphous films

A method is developed to analyze the in-plane magnetic anisotropy from surface morphology for amorphous films. The lateral sizes along radial direction (R_RD) and tangent direction (R_TD) of rotational substrate, which are extracted from the surface morphology of Co_66.3Zr_33.7 amorphous films, are used to calculate stress anisotropy energy E_σ. It is found that E_σ is consistent with the magnetic anisotropy energy K_μ for the samples deposited on Si (1 0 0) substrate and then a relationship K_μ ∝ 1/R_RD − 1/R_TD can be obtained. This method is sensitive to the initial state of substrate so its application range is discussed.     

Orbital quantization in a system of edge Dirac fermions in nanoperforated graphene

The dependence of the electric resistance R of nanoperforated graphene samples on the position of the Fermi level E _F, which is varied by the gate voltage V _g, has been studied. Nanoperforation has been performed by irradiating graphene samples on a Si/SiO₂ substrate by heavy (xenon) or light (helium) ions. A series of regular peaks have been revealed on the R(V _g) dependence at low temperatures in zero magnetic field. These peaks are attributed to the passage of E _F through an equidistant set of levels formed by orbitally quantized states of edge Dirac fermions rotating around each nanohole. The results are in agreement with the theory of edge states for massless Dirac fermions.     

Optical spectra of CsI,CsBr, ZuGeP2, and SbSI

We report here the study of the normal reflectivity spectra R and the corresponding derivative spectra (1/R) dR/dE of SbSI between 2 and 6 eV. The spectra show very strong anisotropy. We have also tried to use the change of the wavelength modulation spectrum to monitor the change in the band structure of SbSI due to the phase transition at 292 °C (D_2h¹⁶→C_2v⁹). Careful examination of the spectra at various temperatures around T_c shows no observable change. We report also the wavelength-modulated reflectivity spectra of the chalcopyrite crystal ZnGeP₂ at 5 K between 2 and 6 eV, for E∥ C and E⊥ C. The experimental results are compared with the theoretical band structure calculation by de Alvarez and Cohen. We also present measurements on CsBr, CsI in the vacuum uv (between 5 and 8 eV) at 1.8K, showing noticeable difference with previous reflectivity measurements at 77 K.     

High pressure tuning of optical transitions in Mg[Pt(CN)4]·7H2O

Mg[Pt(CN)₄]·7H₂O belongs to the class of tetracyanoplatinates(II) which crystallize in columnar structures. In different M_x[Pt(CN)₄]·yH₂O (MCP) single crystals the in-chain Pt-Pt-distance R varies between 3.67 Å (NaCP) and 3.15 Å (MgCP). Two optical transitions can be observed in polarized emission with the electric field vector E either parallel or perpendicular to the columnar (c)-axis. Polarized emission spectra of MgCP are recorded under hydrostatic pressure up to p ≈ 18 kbar (at 295 K). The transition energy v?₆ can be tuned from 17,600 cm^-1 to about 12,000 cm^-1 (2.18-1.48 eV). The pressure induced red shift for the two transitions is: E 6 c: dv?₆/dp = -320±20 cm^-1/kbar, E ⊥ c: dv?_⊥/dp = -270±20 cm^-1/kbar. These values are discussed in the context of the known functional relationship (for ambient conditions) between v? and R.     

Quantizing a classically ergodic system: Sinai's billiard and the KKR method

Sinai's “billiards on a torus,” i.e., free motion of a particle in a plane amongst reflecting discs of radius R centred on points of the unit square lattice, is a classically ergodic system with two freedoms, parametrized by R. Quantal energy levels E_n are given by the vanishing of the Korringa-Kohn-Rostoker (KKR) determinant of solid state theory. This gives a rapid computational scheme for computing E_n as functions of R. Except for the integrable case R = 0, no degeneracies are found, illustrating the theorem that two parameters, not one, are required to make levels cross in a generic system. The same theorem leads to the prediction that the probability distribution of the spacings S of neighbouring levels is $\text{O}$(S) as S → 0, in good agreement with computation. The KKR determinant is transformed analytically to give the level density d(E) semiclassically (i.e., as ? → 0) as the sum of a steady contribution $\text{d}\text{?}\text{(E)}$ and an oscillatory contribution d_osc(E). $\text{d}\text{?}$ is $\text{O}$(?^?2) and is given by the Weyl “area” formula plus “edge,” “corner” and “curvature” corrections, in excellent agreement with computation. d_osc is given by a sum over classical closed orbits (all unstable). Nonisolated closed orbits (not hitting discs) contribute terms with $\text{O}$$\text{(?}{}^{\mathrm{<mtext>?3</mtext><mtext>2</mtext><mtext>)</mtext>}}$ to d_osc, while isolated closed orbits (bouncing between discs) contribute terms with $\text{O}$(?^?1) to d_osc. The isolated orbits are vastly more numerous than the nonisolated orbits and their contributions cannot be neglected. As a means of calculating the individual E_n (rather than the smoothed spectrum), the KKR method is much more efficient than the classical path sum.     

Band diagram for chemical vapor deposition diamond surface conductive layer: Presence of downward band bending due to shallow acceptors

The properties of surface conductivity (SC) of impurity-non-doped CVD diamond (001) samples were studied by various methods of sheet-resistance (R_S) measurement, Hall-effect measurement, XPS, UPS, SES, SR-PES, PEEM and 1D band simulation taking into account special emphases on deriving the information about the surface band diagram (SBD). The R_S values in UHV conditions were determined after no-annealing or 200 ～ 300 °C annealing in UHV. C 1 s XPS profiles were measured in detail in bulk-sensitive and surface-sensitive modes of photoelectron detection. The energy positions of valence band top (E_V) relative to the Fermi level (E_F) in UHV conditions after no-annealing or 200 ～ 300 °C annealing in UHV were determined. One of the samples was subjected to SR-PES, PEEM measurements. The SBDs were simulated by a band simulator from the determined R_S and E_V ? E_F values for three samples based on the two models of surface conductivity, namely, so-called surface transfer doping (STD) model and downward band bending with shallow acceptor (DBB/SA) model. For the DBB/SA model, there appeared downward bends of SBDs toward the surface at a depth range of ～ 1 nm. C 1 s XPS profiles were then simulated from the simulated SBDs. Comparison of simulated C 1 s XPS profiles to the experimental ones showed that DBB/SA model reproduces the C 1 s XPS profiles properly. PEEM observation of a sample can be explained by the SBD based on the DBB/SA model. Mechanism of SC of CVD diamonds is discussed on the basis of these findings. It is suggested that the STD model combined with SBD of DBB/SA model explains the surface conductivity change due to environmental changes in actual cases of CVD diamond SC with the presence of surface E_F controlling defects.     

A relaxation phenomenon observed in fine gold wire

Two modulation techniques were used to determine the heat capacity of 1 mil gold wire as a function of temperature. A frequency effect was observed at high temperature in the directly measured parameter C_p/(1/R_m) (dR/dT)T_m where C_p is the specific heat at constant pressure and R_m is the resistance of the specimen at temperature T_m. It is believed that the vacancy defect is responsible for this frequency effect. The relaxation phenomenon observed suggests the surface of the wire as the source of the vacancies.     

Hopping conductivity of carbynes modified under high pressures and temperatures: Galvanomagnetic and thermoelectric properties

The conductivity, thermopower, and magnetoresistance of carbynes structurally modified by heating under a high pressure are investigated in the temperature range 1.8–300 K in a magnetic field up to 70 kOe. It is shown that an increase in the synthesis temperature under pressure leads to a transition from 1D hopping conductivity to 2D and then to 3D hopping conductivity. An analysis of transport data at T ≤ 40 K makes it possible to determine the localization radius a ～ (56?140) Å of the wave function and to estimate the density of localized states _g(E _F) for various dimensions d of space: _g(E _F) ≈ 5.8 × 10⁷ eV^?1 cm^?1 (d=1), _g(E _F) ≈5×10¹⁴ eV^?1 cm ^?2 (d=2), and _g(E _F)≈1.1×10²¹ eV^?1 cm_?3 (d=3). A model for hopping conductivity and structure of carbynes is proposed on the basis of clusterization of sp ² bonds in the carbyne matrix on the nanometer scale.     

On the nature of energy bands in tetracyanoplatinates

Optical data and band calculations are presented for a series of tetracyanoplatinates with varying Pt—Pt-distance R. The band gap energies decrease according to R^-3 with decreasing R. The energy bands which determine the optical and electrical properties for E6 c originate from (Pt5d_z², 6s) and (Pt6p_z, CNπ¹) hybrid molecular states.     

A study of the121,123Sb(p,d) reactions

Levels of^120,122Sb have been observed using the^121,123Sb(p, d) reactions atE _p = 26.2 MeV. Thirty-two levels of¹²⁰Sb and thirty-four levels of¹²²Sb are observed below 2.0 MeV excitation with an energy resolution better than 25 keV FWHM. Experimental angular distributions were compared to DWBA calculations in order to extractl-transfers and spectroscopic factors. Strong mixing between the 3s _1/2, 2d _3/2, 2d _5/2, and 1g _7/2 neutron orbitals is observed in both nuclei. Nuclear Reactions:^121,123Sb(p, d),E=26.2 MeV; measuredσ(E _d ,θ).^120,122Sb deduced levels,l,J,π, spectroscopic factors. Enriched targets, magnetic spectrometer.     

Spin-0 and spin-1/2 particles in a constant scalar-curvature background

We study the Klein-Gordon and Dirac equations in the presence of a background metric ds²=−dt²+dx²+e^−2gx(dy²+dz²) in a semi-infinite lab (x>0). This metric has a constant scalar-curvature R=6g² and is produced by a perfect fluid with equation of state p=−ρ/3. The eigenfunctions of spin-0 and spin-1/2 particles are obtained exactly, and the quantized energy eigenvalues are compared. It is shown that both of these particles must have nonzero transverse momentum in this background. We show that there is a minimum energy E²_min=m²c⁴+g²c²?² for bosons (E_KG>E_min), while the fermions have no specific ground state (E_Dirac>mc²).     

Fundamental reflectivity spectra of Hg1−xMnxTe mixed crystals in the 1.7 to 3.5 eV energy range

The room temperature reflectivity coefficient R(E) for the mixed crystals Hg_1?xMn_xTe (x up to 0.57) in the energy range 1.7 to 3.5 eV was investigated. Two distinct maxima E₁ and E₁ + Δ₁ connected with the transitions in the critical points on the [111] direction of the Brillouin zone for the samples with x up to 0.3 and the more diffused structure of R(E) for the samples with x > 0.3 was observed. A quadratic dependence of E₁ and E₁ + Δ₁ transition energy vs alloy composition with x up to 0.3 was found, with bowing coefficient c = 1.21 ± 0.02 and 1.06 ± 0.02 respectively. The energy variation of an additional shoulder probably connected with the e₁ transitions at L point of the Brillouin zone is also reported.     

Transverse voltage in superconductors at zero applied magnetic field

A systematic study of the transverse voltage at zero magnetic field in the superconducting state is reported. The effects of warming rate, temperature, applied magnetic field, and electrical current on the transversal resistance (R_XY) of polycrystalline superconducting sample are taken into account. At zero magnetic field two peaks are observed in R_XY(T) curves which are related to the double superconducting transition in the R_XX(T) component. In the superconducting (R_XX = zero) and normal states no transverse voltage has been detected at zero magnetic field as expected. The results are discussed within the framework of the motion of Abrikosov and Josephson vortices and anti-vortices. A new scaling relation between transverse and longitudinal components given by R_XY ～ dR_XX/dT has been confirmed.     

On the separation of initial and final state effects in photoelectron spectroscopy using an extension of the auger-parameter concept

First, we show that the quantity Δβ(i) = ΔE_A(kii) + 2ΔE_B(i) — ΔE_B(k) is directly related to the final state relaxation contribution ΔE_R(i) of the binding energy shift ΔE_B(i). ΔE_A(kii) is the kinetic energy shift of the Auger transition which corresponds to the decay of a hole state with a hole in level k into a final state with two holes in level i. The shift parameter Δβ(i), which is based on information on two binding energies, is conceptually similar to Wagner's Auger parameter. To establish the relation between Δβ(i) and ΔR(i) one needs, however, less drastic approximations than in the case of Auger parameter shifts. The only approximation necessary is the assumption that ΔR(i) is determined by coulomb contributions.Secondly, we use Δβ (i) to analyse the experimental data of eighteen gaseous phosphorus-containing compounds obtained by Sodhi and Cavell¹. It is shown that ΔR(P_2p) is strongly related to changes in the polarizability of the ligands. The initial state effects derived from our study deviate from those expected on the basis of simple electronegativity considerations.     

Effect of an electric field on the I–V curves of DyBa2Cu3−x Oy/1 wt % Pt HTSC ceramics

This paper reports on an experimental study of the effect of a magnetic field, B≤70 G, and an electric field, E=120 MV/m, on the critical current I _c and I–V curves of DyBa₂Cu_3?x O_y HTSC ceramics (x=0 and 0.2), both undoped and doped with 1 wt % Pt. It has been established that, in stoichiometric ceramics (x=0) at 77 K, I _c drops sharply (by more than an order of magnitude) already at very low B<1 G. In copper-deficient ceramics (x=0.2), I _c decreases with increasing B slowly, with Pt-doped samples exhibiting [on the dropping I _c (B) dependence] a peak effect, i.e., an increase rather than decrease of I _c at B≈10 G. As for the effect of an electric field on I _c and the I–V curves (the E effect), it is not observed in ceramics of a stoichiometric composition. DyBa₂Cu_2.8O _y samples acted upon by an electric field reveal a substantial increase in I _c and a decrease in the resistance R for I>I _c . In the case of DyBa₂Cu_2.8O_y/Pt, the electric field practically does not affect I _c but R decreases for I>I _c . In a sample placed in a magnetic field, the magnitude of the E effect is observed to correlate with the I _c (B) dependence. In particular, in Pt-doped samples, the E effect decreases with increasing magnetic field B not gradually but with a maximum appearing at B ≈10 G, i.e., in the region of the peak effect in the I _c (B) dependence. The data obtained suggest the conclusion that the electric-field effect in ceramics exhibiting weak links of the superconductor-insulator-superconductor (SIS) type correlates with magnetic vortex pinning.     

Mass spectrometry study of the kinetics of CdTe molecular-beam epitaxy: Part II. Cd, Te2, Te, and CdTe

The results of an in situ mass-spectrometric study of surface processes occurring during CdTe molecular beam epitaxy are presented. The measurements of kinetic parameters are performed with modulated Cd and Te₂ molecular beams with an intensity of 0.1–5.0 ML/s at a crystal temperature of 550–730 K. The experimental results are treated using a model in which condensation and evaporation proceed through adsorption and desorption steps. The desorption rates are 2–15 and 150 s^?1 for Te₂ and Cd, respectively. The activation energy of CdTe “evaporation” is found to be 1.2 eV; the desorption energies are E _d(Cd) = 1.0 eV and E _d(Te₂) = 0.3 eV. The adsobate coverage with cadmium atoms and tellurium molecules is estimated to be n(Cd) < 0.01, n(Te₂) = 0.02–0.20, and n(Te) = 0.2–1.0.     

Investigations of the spin-Hamiltonian parameters,optical absorption bands,and local structure for the tetragonal Cu2+ center in Cu2+-doped ZnCdO nanopowder

The spin-Hamiltonian (or EPR) parameters of tetragonal Cu²⁺ octahedral centers in ZnCdO nanopowders are calculated from the high-order perturbation formulas based on the cluster approach. In these formulas, the contributions to spin-Hamiltonian parameters due to the admixture between the d orbitals of dⁿ ion and the p orbitals of ligand ions via covalence effect are considered. The crystal field parameters are calculated from the superposition model and so the optical absorption bands (related to the crystal field energy levels) and local structure of Cu²⁺ octahedral centers in ZnCdO nanopowder are also studied. The calculated spin-Hamiltonian parameters and optical absorption bands are in reasonable agreement with the experimental values. The tetragonal elongation ΔR (=R_//−R_⊥) of Cu²⁺ octahedron in ZnCdO nanopowder due to Jahn–Teller effect is acquired from the calculations. The results are discussed.     

Effective surface potential method for calculating surface states

A novel formalism (the effective surface potential method) is developed for calculating surface states. Like the Green function method of Kalkstein and Soven and the transfer matrix method of Falicov and Yndurain, the technique is exact for simple tight binding Hamiltonians. As well as offering an alternative viewpoint, the present method provides a simple analytic expression describing the surface states. At each point k_s in the surface Brillouin zone the semi-infinite solid is viewed as an effective linear chain where each element of the chain is a planar layer. The solution to the linear chain problem can be expressed in terms of an effective potential h(k_s,E) at each energy E. A number of examples are presented in detail; “sp^d” Hamiltonians for a linear chain (d = 1), the honeycomb lattice (d = 2), the 111 surface of silicon (d = 3), and a dissected Bethe lattice. Various exact results are given, e.g. the extremities of surface state bands and the surface density of states of p-like (delta function) bands. The results of Kalkstein and Soven for the 100 surface of a simple cubic solid with a perturbation on the surface layer are rederived.     

Final state effect for Au 4f line from gold-nano-particles grown on oxides and HOPG supports

The effect of a positive charge left to a small metal particle immediately after photoemission, so called the final state effect is studied for Au 4f binding energy (E_B) shifts. The size and shape of Au nano-particles were determined by high-resolution medium energy ion scattering combined with scanning electron microscopy of a field emission type. The shape of Au nano-particles is well approximated by a partial sphere with diameter d and height h. It is found that the E_B shift is well expressed as number of atoms per particle (n_A) and independent of support species. The E_B shift changes dramatically at a critical n_A value of ∼70 atoms, where metal-nonmetal transition takes place. In the nonmetal region, the E_B shift increases steeply almost exponentially with decreasing n_A and in contrast, gradually decreases with increasing n_A in the metallic region. The effect of the positive charge of an Au 4f vacancy created by photoemission is expressed by the relaxation time τ and the effective charge +αe when the photoelectron just leaves the Au particle surface (e: electron charge, α < 1).