Antifriction and mechanical properties of polymer compositions based on silicone adhesives

A comparative investigation has been made of the antifriction and mechanical properties of polymer compositions based on K-400 silicone adhesive and fillers in the form of finely dispersed powdered polymers (tetrafluoroethylene, Kapron, polyethylene), graphite, sawdust, B-83 babbitt, and a lubricant^–US-2 grease. The antifriction properties of these materials are not inferior to those of some common nonferrous metals (B-83 babbitt, TsAM9-1.5 zinc alloy, OTsS5-5-5 bronze). The rational range of application of the compositions investigated is indicated.Rostov-on-Don Institute of Railroad Transport Engineers. Translated from Mekhanika Polimerov, No. 5, pp. 937–940, September–October, 1969.     

Statistical analysis of some characteristics of cylindrical glass-fiber-reinforced plastic materials

The results are given of a statistical treatment of experimental data on several characteristics of glass-fiber-reinforced plastic cylindrical shells, prepared from glass fabric TS8/3-250 and epoxide binder IF-ÉD-6 (TU-26-59) at the "Électroizolit" factory by winding an impregnated fabric cloth on a mandrel. The experim ental data on the mechanical properties of the glass-fiber-reinforced plastic material were obtained in tests on representative samples cut from the margin of the cylindrical shells. The results of the statistical analysis can be used to evaluate the mechanical reliability of structures made of glass-fiber-reinforced plastic material of the above type.Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 906–910, September–October, 1973.     

Effect of fillers on the structure and properties of cured resins

The elastic (modulus of elasticity and equilibrium high-elastic modulus) and thermal (volume coefficients of thermal expansion below and above the glass transition temperature) properties of compositions based on ÉD-5 epoxy resin cured with polyethylenepolyamine have been investigated. Quartz powder and aluminoborosilicate glass powder were employed as fillers at concentrations from 0 to 0.413. The thermal expansion coefficients of the compositions were studied in a dilatometer, in which the specimen is free of mechanical loads. The Young's modulus at 25°C and the equilibrium high-elastic modulus at 125°C of the compositions were determined in the compression regime in an instrument based on the IZV-2 optical length gage. The thermal expansion coefficients of the polymer matrix were calculated with allowance for the elastic properties of the resin and the filler. It is shown that, as the filler concentration increases, the thermal and elastic properties of the resin in the filled system change. This can be interpreted as a change in the properties of the resin as it approaches the surface of the filler particles. Increased interaction between the filler surface and the epoxy resin tends to stiffen the polymer network.Scientific Research Institute of Precision Technology, Moscow. Translated from Mekhanika Polimerov, No. 6, pp. 1018–1022, November–December, 1969.     

Statistical characteristics of the mechanical properties of glass-reinforced plastics

A statistical analysis has been made of experimental data on the mechanical properties of a glass-reinforced plastic based on T₁ glass fabric (Soviet standard GOST 8481-61) and IF-ÉD-6 epoxy resin (Elektroizolit Plant, tech. spec. TU 26-59) obtained by testing specimens cut from the waste of wound cylindrical shells. The data obtained can be used for estimating the mechanical reliability of products composed of glass-reinforced plastics of this type.Moscow. Translated from Mekhanika Polimerov, No. 1, pp. 131–134, January–February, 1971.     

Progressive increase in the displacements of a glass-reinforced plastic helicopter blade under the influence of its own weight

The question of the progressive increase in the displacements of a glass-reinforced plastic helicopter blade under its own weight is examined. Integral operators, expressed in terms of fractional-exponential functions, are used for solving the flexural creep problem. The creep curve parameters for simple deformation (tension and torsion) are found for ÉF-32-301 glass-reinforced textolite.K. É. Tsiolkovskii Moscow Aviation Engineering Institute. Translated from Mekhanika Polimerov, No. 5, pp. 943–946, September–October, 1975.     

Behavior of antifrictional self-lubricating plastics at elevated temperatures in the friction process

Conclusions 1. The process of friction of antifrictional self-lubricating plastics based on F-1 polyarylate and various fillers has been studied. It has been shown that a distinctive feature of this process is the formation of a film of the same composition as that of the antifrictional plastic on the steel surface.2. It has been shown that during the process of friction of antifrictional self-lubricating plastics both structural changes in the mobybdenum disulfide and also tribochemical transformations of molybdenum disulfide and copper, plus reaction of these with the counterbody material, take place in the surface films.3. It has been found that the nature of the tribochemical transformations depends on the chemical composition of the antifrictional self-lubricating plastic and affects the temperature limits of the friction zones.Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 4, pp. 649–657, July–August, 1976.     

Structure and Properties of Teflon Composites with Natural Diamond Powders

The results of experimental investigations of the structure and properties of composites based on polytetrafluorethylene (PTFE) containing natural diamond powders (NDP) of different dispersity are presented. To obtain diamond-containing compositions for antifrictional applications, we used a preliminary mechanical treatment of NDP (40 m) in a planetary mill. It was stated that the formation of the maximum ordered small-spherulite structure of PTFE after injection of NDP significantly increased the wear resistance and deformational and strength characteristics of the polymer composite materials. To produce abrasive materials, PTFE was filled with NDP having a larger graininess (from 40 to 125 m). It was found that the injection of NDP did not cause evident morphological changes in the binder — the bonds between diamond grains and the polymer are created by physicomechanical forces. To strengthen the adhesion interaction at the interface between the binder and diamond grains and to raise the wear resistance of the material, a complex modification of the polymer with inorganic and organic fillers was carried out. It is shown that the injection of the complex filler significantly improves the tribotechnical and operational properties of the diamond-containing composite material. The general laws of the influence of NDP on the formation of the supermolecular structure of PTFE are revealed. It is shown that, by varying the degree of dispersity and the content of NDP in PTFE, and by applying different methods of their injection into the polymer matrix, it is possible to control the operational properties of the composites and to produce materials of different functional application, from antifrictional to abrasive ones.     

Antifrictional properties of compositions in the polyamide - copper system

Conclusion 1. The antifrictional properties of metallopolymer compositions made up by a thermal method in an air atmosphere (method A) and in a hydrogen atmosphere (method B), and also made up by mechanical mixing of P610 polyamide powders and PM grade copper (method C) have been investigated.2. It has been shown that the metallopolymer obtained by the thermal method in a hydrogen medium, at a degree of filling of 30% or more by wt., has less wear of the composition as compared with compositions made up by method C which are similar in degree of filling.3. Compositions made up by method A have a loosened structure and are comparable in wear resistance with the unfilled polymer.4. The coefficient of friction of the metallopolymer obtained in a hydrogen medium is less at the selected slippage regime than the coefficient of friction of the pure polyamide by a factor of 1.5, and is 20% less than that of the metal-filled composition made up by mechanical mixing in accordance with method C.5. It has been shown that the temperature on the friction surface of the metallopolymer made up by method B is less than that of the pure polyamide or the metal-filled composition made up by method C, by 40°C and by 20°C, respectively.Lenin Young Communist League. Riga Institute of Civil Aviation Engineers. Translated from Mekhanika Polimerov, No. 6, pp. 1043–1048, November–December, 1978.     

Numerical identification of properties of particle-reinforced composite materials

The paper deals with numerical identification of the average elastic properties of particle-reinforced composite materials. The finite element method for the determination of deformation energy of the characteristic volume element was used. In earlier analytical investigations, an approximation function of the averaged elastic properties of the composite was derived. An identification procedure allows the estimation of the unknown approximation parameters from numerical experiments. The obtained functions describe precisely the numerical data for any relationships between constituents of the material.Presented at the 10th International Conference on the Mechanics of Composite Materials (Riga, April 20–23, 1998).Institute of Computer Analysis of Structures, Riga Technical University, Riga PDP-1658, Latvia. Institute of Materials Science, Department of Materials Science, Martin-Luther-University Halle-Wittenberg, D-06099 Halle, Germany. Published in Mekhanika Kompozitnykh Materialov, Vol. 34, No. 3, pp. 383–390, May–June, 1998.     

Effect of fillers on the sensitivity of epoxide compositions to stress concentrations in the glassy state

The results are presented of a study of the effect of mica and annealed and unannealed quartz on the strength characteristics of epoxide compositions and on their sensitivity to stress concentrations in the glassy state. It was established that the positive effect of the fillers on the properties of the polymeric compositions in the glassy state becomes apparent in a reduction of the sensitivity of these materials to stress concentrations.Institute of Physical Chemistry, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 929–931, September–October, 1973.     

Effect of fiber tension on the unwinding resistance of hardening layers of glass-reinforced plastic

The shear fracture toughness characteristics of glass-reinforced plastics used for strengthening metal pressure vessels have been determined by testing metal-GRP rings. The shear fracture toughness characteristics are statistically estimated for a unidirectional GRP as a function of the winding tension.K. É. Tsiolkovskii Moscow Aviation Engineering Institute. Translated from Mekhanika Polimerov, No. 5, pp. 935–938, September–October, 1975.     

Investigation of the anisotropy of the properties of glass-reinforced plastic shells

The load-carrying capacity and deformation of cylindrical and conical glass-reinforced plastic (ÉDT-10 resin) shells loaded in axial compression have been investigated experimentally in relation to the orientation of the fabric reinforcement. The results of the tests are compared with the relations of the theory of elasticity of an orthotropic body.Zhukovskii Central Aerohydrodynamics Institute, Moscow Region; Scientific Research Institute of Production Technology and Organization, Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 814–818, September–October, 1969.     

Theory of compositions

A survey of papers on the theory of compositions and their application to the investigation of manifolds in spaces with fundamental groups is presented.Translated from Itogi Nauki i Tekhniki. Problemy Geometrii, Vol. 10, pp. 117–145, 1978.I thank Érnst Gergardovich Neifel'd, whose paper [12] stimulated much of this survey, and who, moreover, showed me inestimable help in the formulation of my paper. In particular, he wrote Sec. 17.     

Properties of multicomponent polymers systems

In order to design materials having different mechanical properties combined with a permittivity of 2.2–2.6 and tg =2·10^–4-4.10^–4 at 20±1° C and 10⁶ Hz, it is possible to use compositions consisting of polystyrene, polyisobutylene and polyethylene. Projections of the three-dimensional triangular composition-property diagrams are presented for selecting the composition corresponding to spcified properties (hardness at 20 and 50° C and breaking stress and elongation).Central Scientific-Research Institute of Communications, Moscow. Moscow Krupskaya Regional Pedagogical Institute. Translated from Mekhanika Polimerov, Vol. 4, No. 6, pp. 133–1135, November–December, 1968.     

Mathematical simulation of failure processes of composite materials reinforced with brittle fibers

Conclusions 1. It is concluded on the basis of an analysis of experimental data and also from theoretical investigations with respect to stress redistribution upon the breaking of fibers that the successive breaking of a number of fibers, caused by the overload from the breaking of individual fibers, is one of the principal mechanisms according to which the complete failure of a material reinforced with brittle fibers takes place.2. A discrete model of a composite material has been worked out. A random fiber strength distribution over the surfaces of the cross sections of the composite material is produced on the computer by the application of Monte Carlo methods.3. A program was written for the computer which simulates the testing of composite materials, permitting the investigation of the statistical accumulation of damage in failure processes as well as the avalanchetype processes of the complete failure of a material.4. The effect of the statistical distribution of the strength of the reinforcing fibers, the ratio of properties, and the volume fractions of composites on the failure processes of composite materials is investigated. Deformation diagrams of a D-16 aluminum alloy-boron fiber composite material, constructed on the basis of an anlysis of the simulated process of fiber breaking in a composite, agree well with the experimental relations.5. The opinion is expressed that the development of cybernetic simulation of failure processes will permit giving an answer to a number of actual questions in the study of materials and the mechanics of failure.Baikov Institute of Metallurgy, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 800–808, September–October, 1976.     

The use of polymers for model investigations based on dynamic photoelasticity

The possibility of taking the inelastic characteristics of polymeric and nonpolymeric materials into account in the photoelastic modeling of dynamical problems has been investigated. The proposed method is an approximate one based on the use of the Kelvin-Voigt model for both types of materials. The results of comparative experimental investigations of certain plane dynamical problems are presented and the experimental and theoretical data are compared.B. E Vedeneev All-Union Scientific-Research Institute of Hydraulic Engineering, Leningrad. Translated from Mekhanika Polimerov, No. 3, pp. 456–465, May–June, 1972.     

Modification of glass-filled polyamide 66 by reactive oligoorganosilane

Properties of glass-filled polyamide 66 modified by reactive oligoorganosilane were investigated. It was found that modification led to the improvement of the rheological properties of polyamide. The addition of the modifier decreased the glass transition temperature T_g of the polyamide from 60 to 50–59°C, without affecting the melting point. Composites modified by oligoorganosilane are characterized by higher (10–40°C) temperatures of onset and 50% weight loss as compared to the initial composite. It was found that chemical reaction of oligoorganosilane with polyamide and glass fibers took place during coextrusion of the modifier and polyamide, which formed firm chemical bonds between the polyamide and filler and thus favored a considerable improvement in the physicomechanical properties of the composite. The change in the structure and properties of the polyamide observed during modification by oligoorganosilane significantly affected its behavior during friction. The modification made it possible to increase the wear resistance of the composite 1.5 to 2 times and to decrease its friction coefficient from 0.38 to 0.27–0.33. It was also found that the ability of oligoorganosilane to react during its processing with water in the polyamide allowed for a significant decrease in the intensity of hydrolytic processes in the polymer. Because of this, the physicomechanical, rheological, and antifrictional properties of modified composites with an increased content of moisture (up to 3%) in the initial polyamide surpass similar characteristics of the composites containing no modifier, with not only enhanced but also optimum (0.2%) humidity of polymer granules.Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia. Translated from Mekhanika Kompozitnykh Materialov, Vol. 34, No. 4, pp. 545–553, July–August, 1998.     

Distribution of integral points on certain two-sheeted hyperboloids

Yu. V. Linnik's investigations [Vestn. Leningr. Univ., No. 2, 3–23; No. 5, 3–32; No. 8, 15–27 (1955)] are refined and generalized to indefinite ternary quadratic forms of a sufficiently general form (to forms contained in the form x₁x₃—x ₂ ² ]. The method of investigation is improved. The presentation is substantially simplified.Translated from Zapiski Nauchnykh Seminarov Leningradskogo Otdeleniya Matematicheskogo Instituta im. V. A. Steklova AN SSSR, Vol. 93, pp. 87–141, 1980.     

Friction and wear of polymer-based composites

Polymeric materials containing different fillers and/or reinforcements are frequently used for applications in which friction and wear are critical issues. This overview describes how to design high temperature-resistant thermoplastics, e.g., filled with carbon fibers and internal lubricants, for operation under low friction and wear at elevated temperatures as sliding elements in, e.g., textile drying machines. Further information will be given on the systematic development of continuous fiber/polymer composites with high wear resistance, and on attempts for the prediction of their load-bearing capacity using a finite element approach. Finally, the application of such composites in thermoplastic filament-wound journal-bearings is discussed.Presented at the 10th International Conference on the Mechanics of Composite Materials (Riga, April 20–23, 1998).Institute of Composite Materials (IVW), University of Kaiserslautern, D-67663 Kaiserslautern, Germany. Published in Mekhanika Kompozitnykh Materialov, Vol. 34, No. 6, pp. 717–732, November–December, 1998.     

Relaxation characteristics of glass-reinforced plastics

A study was made of the relaxation properties of glass-reinforced plastics KAST-V, ÉDF, SVAM, and Textolite. The article gives experimental and theoretical values of the pliabilities and tables of the values of the relaxation properties required for the solution of boundary value problems in viscoelasticity.M. V. Lomonosov State University, Moscow. Translated from Mekhanika Polimerov, No. 3, pp. 560–562, May–June, 1970.