A Cud-d excitation model for the pairing in the high-T c cuprates

A new model for the pairing mechanism in the ceramic superconductors is presented. Like the magnetic models, we assume the limit of large correlation energies for the Cud electrons. We postulate that the pairing of the Op conduction holes occurs viad–d orbital excitations within thee _g manifold of thed hole of Cu⁺⁺, which is split because of tetragonal or lower symmetry at the Cu sites. This valence conserving charge degree of freedom has been ignored in the magnetic pairing models. Thed–d excitation model may provide a simple qualitative understanding of many experimental results.     

Calculation of the Knight shift in palladium

The direct and the exchange core polarization (ECP) contributions of the conduction electrons to the Knight shift of palladium are evaluated. To obtain the wave functions for the conduction electrons and the partial densities of states at the Fermi surface a KKR energy band calculation was performed. The contributions of the core electrons to the Knight shift were determined by using the moment perturbation method (MP). Electron-electron interactions are taken into account by individual enhancement factors for thed ands electrons. The agreement between the theoretical results and the available experimental data is quite satisfactory.     

Extended electron and nonlocal electromagnetic interaction: The perturbation theory

The nonlocal interaction between electrons and electromagnetic fields is considered. It is shown that different contraction forms of interacting fields are equivalent to different nonlocal theories where nonlocality is connected to either the photon field or the electron field, or to both these fields simultaneously. The nonlocal theory where the electron carries nonlocality is studied in detail. The gauge invariance of this model is achieved by using thed-operation applying the perturbation theory. Primitive Feynman diagrams of the nonlocal theory are investigated and a restriction on the “size”l of the electron is obtained. From low-energy experimental data from tests of local quantum electrodynamics it follows thatl≦10⁻¹⁵ cm.     

Lattice dynamics of FCC transition metals: A pseudopotential approach

Simple pseudopotential model for the binding energy of transition metals is proposed. The contribution of thes-like electrons is calculated in the second-order perturbation theory for the local model pseudopotential while that of thed-like electrons is taken into account by introduction of repulsive short-range interatomic potential. Model parameters were determined for ten fcc transitions metals (Cu, Ni, Fe, Co, Ag, Pd, Rh, Au, Pt, and Ir). This model was used for the calculation of the phonon dispersion and the density of states, as well as for the elastic constants and their pressure derivatives. Good agreement with experimental data was achieved for the overall shape of phonon spectra and even for the position of the Kohn anomalies in Pd and Pt. Existence of such anomalies is also stated for predicted phonon spectra of rhodium and iridium.     

Equation of state and thermodynamics of fcc transition metals: A pseudopotential approach

A simple pseudopotential model is used for the calculation of the phonon spectra at the equilibrium volume and under pressure. The model is based on the secondorder perturbation theory with the local pseudopotential acting on thes electrons while thed electrons contribution is simulated by the repulsive Born-Mayer interatomic potential. Pressure influence on the lattice properties was studied for small compressions (mode Grüneisen parameters) as well as for ultrahigh pressure (equation of state up to 1 TPa). Results of the lattice dynamics calculations were used for determining temperature dependence of the lattice heat capacity and of the macroscopic Grüneisen parameter. The Kohn anomaly at the small wave vectors obtained previously in palladium, platinum and rhodium affects strongly the temperature dependence at low temperature.     

Electronic structure of cubic uranium compounds

Self-consistent cellular multiple scattering techniques and photoemission energy distribution curves obtained at 20<hv<80 eV are used to study the density of states of UN and US. The calculations are based on a model using a finite cluster of atoms in a condensed-matter-like boundary potential. The main results refer to the mixing of thes, p, d, andf-states of uranium into a valence and a conduction band. Thef-states form orbitals with the ligands, within the valence and conduction bands. In the nitride the amount off character in the valence band is only 0.3 electrons and thef electrons are in two resonant levels (of each spin) in the conduction band. Only the first of these levels is occupied for the local, alternate from atom to atom, majority spin. In the sulfide the amount off character in the valence band is 0.59 electrons and the rest of thef-levels are in a resonance state (of majority spin) at the beginning of the conduction band. The conduction band is mainly of localized uranium 6d character. The theoretical results compare favorably with the photoemission data reported here.     

Electronic charge distributions and correlations in highT c superconducting compounds

Calculations on negatively charged planar Cu _n O _m clusters are reported. Starting from a self-consistent field calculation within a good Gaussian-type orbital basis set, correlations are included by using the Local Ansatz. A charge analysis reveals that the Cu 3d occupation is 9.5, in close agreement with Local Spin Density calculations. The electrons in the formal ((CuO₂)^2–) _n entities are delocalized between Cu and O sites and strongly correlated. Our findings do not agree with the assumption of localized Cu²⁺ spins which lead to thet-J model. Spin correlations indicate strong short-range antiferromagnetic order even when additional electrons are removed. For them, there is no difference between O and Cu sites.     

Bipolaronic superconductivity in antiferromagnets

As a model of the cuprate superconductors, we have studied thep hole motion in a planar antiferromagnetic (AFM) background and ac-axis boson field. The indirect coupling between thed spins through thep holes is considered. In a range of the hole concentration, the indirect Cu–Cu interaction enhances the planar AFM coupling though it destroys the weakc-axis AFM order. At higher concentrations, the compensation of thed spins by thep holes occurs. For the strongp-d exchange coupling, thep holes can pair to form small magnetic bipolarons in the enhanced planar AFM background. The in-plane motion of the bipolarons is independent of thec-axis motion assisted by bosons. The superconducting properties of the cuprate superconductors are determined by a 2+1 dimensional bipolaron Hamiltonian. The results obtained from our model are consistent with the observations on the cuprate superconductors.     

On quark matter in a strong magnetic field

The effect of strong magnetic field on the bulk properties of quark matter is reinvestigated takingu, d ands-quarks as well as electrons in the presence of magnetic field. Here the bag pressure is chosen such that in the absence of magnetic field and at zero temperature the binding energy of theuds-system is <930 MeV while that ofud-system is greater than 940 MeV. It is observed that the equation of state changes significantly in a strong magnetic field. At finite temperature the electron chemical potential varies between 6 and 50 MeV. Thus the expansion of thermodynamical quantities in powers ofT/(Μ _i ² -M _v ⁽ⁱ⁾² )^1/2 is valid only up to few MeV. For high temperatures ∼40 MeV the exact integral expressions are to be taken.     

Constraints and field equations for ten dimensional super Yang-Mills theory

We give a complete proof of the equivalence between constraint equations and field equations for thed=10,N=1 supersymmetric Yang-Mills theory, a result proposed and partially proved recently by Witten [1]. Our approach explicitly reconstructs the superconnection satisfying the constraints from the on shell component fields. A key ingredient of the method is the choice of a suitable family of gauges, effectively eliminating all gauge dependence on anti-commuting co-ordinates. As a corollary, obtained by dimensional reduction, we also deduce the equivalence of constraints and field equations for thed=4,N=4 theory, as well as ford=6,N=2.Research supported in part by the National Science and Engineering Research Council of Canada and the Israel Ministry of ScienceOn leave of absence from: Department of Pure and Applied Mathematics, Stevens Institute of Technology, Hoboken NJ 07030, USA     

Spin polarization in the photoemission from the 5d-core levels of a thallium film

A thick unordered Tl film has been deposited on Pt(111). Photoemission with photon energies between 20 eV and 27 eV reveals two peaks due to emission from the 5d _3/2-and the 5d _5/2-levels of Tl. The measurements are performed with circularly polarized radiation. Spin analysis allows separation of the photoelectron intensityI into its partsI ₊ with spin polarization vector parallel andI _– antiparallel to the photonspin. For thed _3/2-and thed _5/2-level the ratioI ₊/I _– turns out to be approximately 31 and 11.8 respectively. These values are close to the values expected ford-level photoionization of free atoms if spin orbit interaction in the final states is neglected. A slight crystal field splitting of 0.2 eV is observed for thed _5/2-level. The data are compared with results for the photoemission from Pb films [1] and data for the photoionization from thed-levels of Hg [2].     

Paraconductivity for a d-wave superconductor in short-wavelength fluctuation regime

A theoretical study of the fluctuation conductivity above T_c (paraconductivity) is reported for a d-wave superconductor with resonant scattering impurities. A d-wave system is modeled by tight-binding electrons in the two-dimensional squared lattice, and the impurity scattering is treated in the T-matrix approximation in a unitary limit. In calculating the Aslamazov–Larkin (AL) and the Maki–Thompson (MT) terms, we also consider effects of a short-wavelength cutoff in the fluctuation spectrum. The d-wave character in the AL and MT terms manifests itself to renormalization effects on the fluctuation amplitude and reduced temperature, whereas an anomalous-MT term is absent. The present calculations can describe fairly well experiments on the paraconductivity in zinc-doped cuprate superconductors provided that effects of a total-energy cutoff are taken into account.     

High-sensitivity read-write volume holographic storage in reduced KNbO3 crystals

Reduced KNbO₃ is a photoconductive ferroelectric in which holograms can be recorded by the photorefractive effect. Read-write volume hologram storage and erase sensitivities ofS ⁻¹=100 J/cm² andS ⁻¹=84 J/cm² (S=d(Δn)/d(I₀t)‖_t=0) have been measured at zero applied electric field, where the charge transport is shown to be due to diffusion of photoexcited electrons. By applying an electric field along thec-axis, the migration length of the photoexcited electrons becomes comparable to the holographic grating spacing. This leads to storage sensitivities comparable to high-resolution photographic plates. Experimental data on storage and erase sensitivity as a function of the grating spacing, applied electric field, writing light intensity and temperature are reported and interpreted on the basis of the theoretical results of Young et al. and Amodei. Changes of the intensity ratio of the writing beams by self diffraction (beam coupling), reflections from surfaces and the residual dark conductivity are assumed to cause experimental results which deviate from the theoretical models. It is shown, that in reduced KNbO₃ and other ferroelectric photoconductors having photocarrier transport lengths much larger than the unit cell dimension, photovoltaic currents do not contribute significantly to the build-up of space-charges leading to the photorefractive effect.     

Anisotropic singlet superconductivity for systems with strongly correlated electrons

The periodic Anderson model extended by pairing interactions amongf- and conduction electrons is investigated in the context of the singlet-like superconductivity. We evaluate the transition temperatureT _c and the ratios of superconducting order parameters atT _c as functions of an effective parameter which describes the correlation off-electrons. The relative stability of thes- andd -superconductivity depends on the values of the Fermi wave vector and on the magnitude of . Due to the absence of on-site pairing forf-electrons, the increase of Coulomb correlations makes thes-like superconductivity more favourable than thed -superconductivity. This behaviour is accompanied by crossover effects: with the increase of Coulomb correlations amongf-electrons the superconductivity is taken over by conduction electrons.Supported by PAN, CPBP 01.12     

Exact density of states for lowest Landau level in white noise potential superfield representation for interacting systems

The density of states of two-dimensional electrons in a strong perpendicular magnetic field and white-noise potential is calculated exactly under the provision that only the states of the free electrons in the lowest Landau level are taken into account. It is used that the integral over the coordinates in the plane perpendicular to the magnetic field in a Feynman graph yields the inverse of the number of Euler trails through the graph, whereas the weight by which a Feynman graph contributes in this disordered system is times that of the corresponding interacting system. Thus the factors cancel which allows the reduction of thed dimensional disordered problem to a (d-2) dimensional ⁴ interaction problem. The inverse procedure and the equivalence of disordered harmonic systems with interacting systems of superfields is used to give a mapping of interacting systems withU(1) invariance ind dimensions to interacting systems with UPL(1,1) invariance in (d+2) dimensions. The partition function of the new systems is unity so that systems with quenched disorder can be treated by averaging exp(–H) without recourse to the replica trick.Supported in part by the DFG through SFB123 Stochastic Mathematical Models     

Studies of local phase transition behavior for Co2+ in CsCaCl3 crystals from EPR data

In this paper, we establish the calculation formulas ofg factorsg _∥,g _⊥ and the hyperfine structure constantsA _∥,A _⊥ for 3d⁷ ions in tetragonal octahedral field from a cluster approach. In these formulas, besides the configuration interaction, the covalency effect due to the admixture between d electrons of 3d⁷ ion and the p electrons of ligands is considered. The parameters used in these formulas (except the core polarization constantsk in the calculation ofA _i) can be obtained from optical spectra of the studied crystal. From these formulas, the local release (or elongation) factork, which is introduced to characterize the release effect of impurity-ligand bond along C₄ axis at the cubic to tetragonal phase transition, is estimated for CsCaCl₃:Co²⁺ crystal by calculating the electronic paramagnetic resonance (EPR) parametersg _i andA _i . These EPR parameters are therefore explained reasonably and the results are discussed.     

Impact ionization induced negative far-infrared photoconductivity inn-GaAs

Far-infrared photoconductivity ofn-GaAs epitaxial layers showing impact ionization breakdown has been investigated by molecular lasers at photon energies below the 1s-2p shallow donor transition energy. Negative photoconductivity was observed if a magnetic field was applied to the crystals and if impact ionization of donors by the electric bias field was the dominant electron excitation mechanism. The experimental results are qualitatively explained on the basis of the generation-recombination kinetics of electrons bound to donors. Negative photoconductivity is attributed to optically induced free to bound transitions of electrons from theN=0 Landau band to donor levels shifted by the magnetic field above the low energy edge of the conduction band.     

The temperature dependence of the quadrupole interaction of100Rh in a Zn lattice

The¹⁰⁰Pd radioactivity was implanted into a pure Zn host with the help of an isotope separator. The temperature dependence of the quadrupole interaction was studied by time-differential measurements of the 84 keVγ- 75 keVK-conversion angular correlation. We conclude that electrons contribute significantly to the electric field gradient at the Rh site, but that local effects due to the 4d electrons of Rh are probably small.     

Calculation of the Knight shift in palladium

The direct and the exchange core polarization (ECP) contributions of the conduction electrons to the Knight shift of palladium are evaluated. To obtain the wave functions for the conduction electrons and the partial densities of states at the Fermi surface a KKR energy band calculation was performed. The contributions of the core electrons to the Knight shift were determined by using the moment perturbation method (MP). Electron-electron interactions are taken into account by individual enhancement factors for thed ands electrons. The agreement between the theoretical results and the available experimental data is quite satisfactory.     

Originalarbeiten / Travaux originaux / Original Papers

An account is given of a variational calculation to estimate the amplitudes of resonance factorsɛ in a recent theory to describe the enhancement of crystalline field potentials by conduction electrons in heavy rare earth metals. It is demonstrated that the values ofɛ obtained by minimising the energy of interaction between conduction electrons and rare earth ions are consistent with those previously used to form a comparison with experiment. These latter values were obtained by maximising theA ₂ ⁰ crystal field coefficient with respect toɛ. Consistency is exhibited in both the sign and order of magnitude of the resonance amplitudes and renders the theory parameterless. The values ofɛ show an approximate linear dependence with the number of electrons in the incompletef shell of the rare earth ions.