Electron-stimulated desorption of europium atoms from the surface of oxidized tungsten: Concentration dependence of the low-energy peak

The nature of electron-stimulated desorption of europium atoms Eu⁰ at low incident electron energies E _e (～30 eV) and the specific features of the dependence of the yield of europium atoms Eu⁰ on their concentration on the surface of oxidized tungsten are discussed. The crucial stage is found to be the primary event of vacancy creation in the inner 5p shell of the europium adatom. As follows from estimates, only the first of the two possible ionization scenarios (intratomic electron transfer to the outer shell of the Eu adatom or ejection of the knocked-out electron into vacuum) results in Eu⁰ desorption. The concentration threshold of the Eu⁰ yield is determined.     

Heat capacity, root-mean-square displacements of atoms and thermal expansion coefficient of europium hexaboride

The temperature dependences of the specific heat capacity c _p(T), thermal expansion coefficient α(T) of europium hexaboride, and root-mean-square displacements of Eu and B atoms are determined in the temperature range from helium to room temperature (5–300 K).     

Elastic scattering of electrons by europium and ytterbium atoms

The method of relativistic optical potential is applied to studying elastic scattering of electrons by europium and ytterbium atoms in a wide range of collision energies up to 2 keV. The angular dependences of the scattering differential cross sections and the energy dependences of the scattering integral (total, elastic, momentum transfer, and viscosity) cross sections are calculated in both spin-polarized and spin-unpolarized approximations. It is shown that the spin-polarized approximation should be used to calculate the scattering cross sections at energies below 10 eV for a europium atom. The low-energy scattering of an electron by a europium atom is characterized by P-, D-, and F-wave shape resonances. For an ytterbium atom, the calculated cross sections are in good agreement with available experimental data and with those obtained by calculation in terms of the relativistic convergent close-coupling method.     

Electron momentum distribution in multiply-ionized neon atoms

We present momentum-space properties of multiply ionized neon atoms as a function of the degree of ionization of the atom. In particular, we have calculated the Compton profiles of all possible ionized states of neon atoms with electronic configurations 1s^m2sⁿ2p^q, m=1-2, n=0-2, q=0-6. The radial single-electron radial wave functions, obtained from the Hartree-Fock atomic model, were converted into momentum space wave functions by applying appropriate Fourier transformation. The values of the Compton profiles from the present calculation can be used to interpret experimental cross sections of variously ionized neon atoms colliding with other atoms. Compton profiles of neutral neon atoms, available in the literature, are in excellent agreement with the present calculation.     

Energy losses of fast heavy multiply charged structural ions in collisions with complex atoms

A nonperturbatve theory of energy losses of fast heavy multiply charged structural ions in collisions with neutral complex atoms is elaborated with allowance for simultaneous excitations of ionic and atomic electron shells. Formulas for the effective deceleration that are similar to the well-known Bethe-Bloch formulas are derived. By way of example, the energy lost by partially stripped U ^q+ ions (10 ≤ q ≤ 70) colliding with argon atoms and also the energy lost by Au, Pb, and Bi ions colliding with various targets are calculated. The results of calculation are compared with experimental data.     

Adsorption stage in the formation of Eu-Si(111) thin-film structures

The adsorption stage in the formation of the Eu-Si(111) interface has been studied within a broad temperature range by thermal and isothermal desorption spectroscopy, low-energy-electron diffraction, Auger electron spectroscopy, and the contact potential difference method. It is shown that the ordering of an adsorbed europium film is accompanied by silicon surface reconstruction throughout the coverage range studied, 0<θ≤1.8. This self-organized process is also shown to be thermally activated. Ordered adsorbed europium layers have been found to be made up of 2D islands, whose structure depends on the amount of the metal deposited on the surface. The energy required to remove atoms from an island to vacuum has been determined. This energy decreases with decreasing 2D lattice constant of the islands. This pattern of its variation is accounted for, in the final count, by the decrease of the number of the Si surface atoms not bound directly to Eu atoms.     

Experimental and theoretical radiative properties of odd-parity highly excited levels in Mo II

Investigations are made for the collective spontaneous emission of a Bose-Einstein condensate consisting of N two-level atoms when s atoms are initially excited in a multi-photon q-deformed Dicke model. The model is based on the generalized deformed oscillator algebra in which the field radiation operators are deformed by an operator-valued function $f\left( {\hat n} \right)$ of the photon number operator $\hat n$ . The time evolution of the expectation value of the atomic inversion is calculated for s = 1, s = 2 and s = 3. When s = 3 its spectra are characterized by nonequidistant eigenvalues, and the phenomenon of the quantum collapse and revival is demonstrated. In particular, the influences of photon multiplicity and q-deformation on the spontaneous emission of the system are discussed. The results show that the nonlinearities due to the photon multiplicity and q-deformation may lead to the inhibition of collective spontaneous emission.     

On the interaction of an electron with a nonspherical atom

A three-stage scheme for the excitation of the autoionization state of europium atoms is realized, and the corresponding ionization cross section is determined: σ=6.5×10^?10 cm². Analytical signals from europium atoms are recorded in standard and waste water solutions used in mining noble metals and in the diagnostics of rare-earth elements.     

Ionization function of magnesium for electron impact

Ionization cross sections for electron impact are measured with crossed beams of Mg atoms and pulsed electrons. Total numbers of particles are determined by the light emission of excited atoms. The ionization cross section obtained for electron energies from 7 eV to 60 eV has its maximum valueq _i (max)=7.8 · 10^?16 cm² at 12 eV electron energy.     

An ESCA investigation of some dithiooxalato complexes

A series of dithiooxalato complex ions have been investigated as their tetraphenyl-phosphonium and potassium salts. Core-electron binding energies (E_b) of S, C, and O were determined, as well as those of the metals. From the first-mentioned data, effective charge values (q) were estimated for the atoms of the ligands. For this purpose linear relations (E_b = k · q + E_bO) were used that had been previously derived within a scheme using C ls (phenyl) as the internal standard. From the data thus obtained the effective charge on the metal atoms could be estimated. The data is used to test if analogous linear relations also hold for the heavy elements; for example, we have found E_b(Pt) = 3.17 · q_pt + 71.1 eV.     

Ionization of Rydberg atoms by the kicks of half-cycle pulses

We present a quantum mechanical model to study the ionization of quasione-dimensional Rydberg atoms interacting with half-cycle pulses (HCPs) and use it to demonstrate the inadequacy of semiclassical approaches to calculate ionization probabilities of such atoms subject to the impact of more than one HCP. For a single-kicked atom both models correctly reproduce the experimentally observed ‘s-curve’ as can be seen by plotting the ionization probability P as a function of momentum transfer q₁. We demonstrate that for a twice-kicked atom, the semiclassical model yields numbers for P which are not physically realizable. For fixed values of momentum transfers q₁ and q₂, in a twice-kicked atom, the ionization probability as a function of time delay between the kicks exhibits periodic decay and revival. The results of the semiclassical approach appear to agree with the quantum mechanical values at the times of revival of P, else these show considerable deviation. We attempt to provide a physical explanation for the limitation of the semiclassical approach.     

Charge state effect on K-shell ionization of aluminum by 600–3400 keV xenonq+ (12 < q < 29) ion collisions

K-shell X-ray spectra of Al were measured by the interaction of 600–3400 keV Xe ^q+ (q = 12–29) ions with Al surface. The X-ray yields per incident ion were deduced and the K-shell ionization cross-sections were obtained from the experimental yield data. With the same incident energy, the K-shell ionization cross-sections of Al excited by Xe ^q+ (q < 26) ions were of the same order of magnitude, while for q = 26 and 29 Xe ion collisions, they were, respectively, about two and ten times larger. Taking into account the binding-energy-modification and the recoil effect of target atoms, the binary encounter approximation (BEA) theory was consistent with the experimental data for q < 26 Xe ion collisions, but it underestimated those excited by q = 26 and 29 Xe ions. This indicates that the K-shell ionization of target induced by Xe ^q+(q < 26) ions was mainly due to the direct Coulomb excitation. However for q = 26 and 29 Xe ions collisions, the transfer of 3d vacancies of projectile to the 1s orbital of target via rotational coupling of the 3dπ, δ-3dσ molecular orbitals, which were formed in the ion-atom quasi-molecule, may cause a considerable contribution to the enhancement of ionization. In addition to the well known Auger and X-ray transition, our experiments proved that the molecular orbital transition (“side-feeding”) mechanism is also a significant channel for de-excitation of hollow atoms formed below the surface.     

Effect of secondary electrons on the yield of electron-stimulated desorption of neutral atoms under differently localized core-level excitations in a substrate

This paper reports on the results of a comparative analysis of the changes in the electron-stimulated desorption (ESD) yield of neutral particles from layers of alkali metal and Ba atoms deposited on the surface of a metal atop an oxygen (O/W, O/Mo) or germanium (Ge/W) film as a function of the incident electron beam energy E. The atomic yield q(E) is compared with the ionization cross sections of the core levels whose ionization potentials coincide with the ESD yield thresholds of the atoms. Three types of dependences q(E) are discussed, and the role of the secondary electrons generated in the electron-bombarded substrate for each type of the dependence of the ESD yield on E is elucidated. The analysis is based on the experimental studies performed by the authors in the recent years, starting from 1991. It is shown that the actual type of dependence q(E) is determined both by the actual localization of the atom excited by the electron beam and by the extent of localization of the core excitation resulting in ESD.     

Compton profiles of multiply ionized oxygen atoms

We have calculated Compton profiles of multiply ionized oxygen atoms with electronic configurations 1s^m2sⁿ2p^q, m=1−2,n=0−2,q=0−4. The values of the Compton profiles from the present calculation can be used to determine the doubly differential electron production cross sections in recent ion-atom collision experiments with oxygen ions in the rest frame of the target atoms. The calculations have been performed in impulse approximation using numerical Hartree-Fock wave functions. Compton profiles of neutral oxygen atoms, available in the literature, are in excellent agreement with the present calculation. The variation of Compton profile with the degree of ionization is investigated.     

Hyperfine interactions of tin atoms in samarium

The hyperfine interactions of ¹¹⁹Sn impurity atoms in samarium at temperatures from 5 to 70 K are investigated by Mössbauer spectroscopy. The distributions P of magnetic hyperfine fields B _hf for tin atoms at sites of the hexagonal [P _h(B _hf)] and cubic [P _c(B _hf)] samarium sublattices are determined from the experimental absorption spectra. Ion ordering in pairs of magnetic centers located in layers of the cubic sublattice is observed by Mössbauer spectroscopy for the first time. Each magnetic center involves ordered ions at the nearest neighbor sites of the tin atom replacing the samarium ion at the hexagonal lattice site. The quadrupole coupling constant e ² q _hQ=0.59±0.12 mm/s is determined for tin atoms at the hexagonal sublattice sites of samarium. The quadrupole interaction of tin atoms in heavy rare-earth metals (from Tb to Er) with a hexagonal close-packed structure is discussed.     

Atom-phonon interaction at a surface

The interaction between an atom and a phonon is evaluated at a surface. The basic assumption is that the total potential energy of the atom V(r) can be written as the sum of pair interactions w(r?r_i with individual substrate atoms. The result is an expansion in phonon wavevector q, with coefficients expressed in terms of the equilibrium adsorption potential. The coupling can be utilized in calculations of kinetic and equilibrium properties of adsorbed atoms.     

A theory of order-disorder transition during crystallization of binary systems2

A theory is presented describing the order-disorder transition in binary crystals growing on the condition of supersaturation from nonsolid phases. The theory applies to systems that crystallize with an almost perfectly ordered structure if exposed to conditions close to thermodynamic equilibrium. Based on a model that assumes incorporation and detachment of single atoms to occur at the kink sites of mono-atomic steps existing at an otherwise smooth crystal surface a kinetic master equation for the time dependence of configuration probabilities has been formulated. Several simplifying assumptions have been employed. Any solution for the steady-state conditions depends on a roughness parameter λ, the far-order parameter η, the incorporation frequency ω₊ and a parameter q, related to the atomic interaction energies. The solutions are discussed for conditions prevailing near equilibrium with η 1 and within the range of order-disorder transition with η 0. The analysis reveals that for different incorporation frequencies different critical values of the parameter q exist for which a transition from an ordered to a disordered phase is predicted to occur. Each of these critical values of q corresponds to a critical transition temperature T_t.     

An ESCA investigation of some thiocyanato complexes

A series of simple thiocyanato complex ions have been investigated as their tetraphenylphosphonium and potassium salts. The binding energies of N, C and S were determined as well as those of the metals. From the first-mentioned data effective charge-values were estimated for the atoms of the ligands. For this purpose linear relations E_b = kq + E_b0 were used that had been previously established within a scheme having C_1s (phenyl) as the internal standard.From the data thus obtained the effective charge on the metal atoms was estimated. For elements where we have sufficient data the same type of linear relation seems to he followed. Tentatively valid examples are E_b(Ni) = 6.74q_Ni + 848.3 eV and E_b(Pd) = 4.45q_Pd + 333.9 eV.In this interpretation the atoms of the metals are considered to be positively charged and surrounded by the negative charge of the electrons occupying the s band.It is further suggested for complexes with pronounced π backbonding (Pt(SCN)₄^2?, Pd(SCN)₄^2? and Hg(SCN)₄^2?) that the C 1s binding energy measured for the carbon atom of the SCN^? ligand is composed of the ionisation energy from the 1s level and an additional term corresponding to the intraligand π → π* transition.     

Weitere Messungen zur Anisotropie der intermolekularen Wechselwirkung durch Streuung von Molekülen in definiertem Quantenzustand

The interaction between diatomic molecules and rare gas atoms can be described by the realistic, though simplified potentialV=?[(r_m/r)¹²(1 +q₁₂P₂(cosθ))?2(r_m/r)⁶(1+q₆P₂(cosθ))] The determination of the parameters?, r _m andq ₆has been treated in the two previous parts of this series. The present final paper describes the determination of the anisotropy parameter in the repulsive part of the potential, q₁₂, for the system CsF-He. Whileq ₆ could be derived using only the dependence of the total scattering cross section on the molecular rotational state, the determination ofq ₁₂ requires, in addition, knowledge of the velocity dependence. The comparison of the experimental data for CsF in the rotational states ¦J, M〉=¦1, 1〉 and ¦1, 0〉 with cross sections calculated by means of the “high energy” approximation yields the result:q ₁₂=0.9±0.2. The validity of the “high energy” approximation in the velocity range covered by the experiment is discussed.     

Mössbauer studies of 151Eu in europium oxalate, europium bissalen ammonium and europium benzoate

Although a number of europium water insoluble chelates have been prepared for several decades, the covalent nature of these compounds has never been established in any quantitative fashion. Shifts in the I.R. bands and conductivity measurements of these salts were hitherto used to qualitatively compare their molecular nature. In this communique we have used temperature coefficients of ¹⁵¹Eu Mössbauer spectra to determine the Debye temperatures (θ _D) of three europium chelates: namely europium oxalate, europium bissalen ammonium (recently reported) and europium benzoate and compared their θ _D with the measured θ _D of the known ionic EuF₃. Additionally, the mean square amplitude (<x ²) of these four compounds was computed and plotted as a function of temperature giving in each case a reasonable linear plot. It was interesting to note that the θ _D of the most ionic EuF₃ was greatest (283 ± 10 K) followed by the oxalate (166 ± 15 K), then the europium bissalen ammonium (133 ± 5 K) and lastly the europium benzoate with a θ _D of (105 ± 5 K).