Multiple light scattering from a moving layer of Brownian particles: comparison with a rigid phase screen

The temporal fluctuations in the intensity of light scattered by a moving layer of emulsions and suspensions containing Brownian particles are investigated experimentally, and a comparison is made with light scattered by a translating phase screen. The intensity fluctuations of the scattered light are detected through an imaging system, which collects the light emanating only from a limited volume in the medium. The effect of translational motion of the particle layer on the decay rate of the autocorrelation function of intensity fluctuations depends on the illuminating form of a laser beam and on the point spread function of the imaging system. The Brownian motion of the particles causes the scattered light to fluctuate more rapidly than that arising from the translating phase screen. In the multiple-scattering regime, the influence of this diffusional motion increases with an increase of the particle concentration in the layer.     

A direct method of particle sizing based on the statistical processing of scattered photons from particles executing Brownian motion

A direct method of determining the mean diameter of particles executing Brownian motion is presented. The temporal coherence of the scattered field from submicroscopic particles illuminated by laser light is a function of both the integration time and the particle diameter. The temporal degree of coherence of the time-averaged scattered intensity decreases as the integration time increases. Statistical processing of the scattered photons leads to a method of particle sizing (average diameter), which circumvents the need for digital autocor-relation or power spectral estimation.     

Light scattering from colloids

This paper presents a review of light scattering results on static and dynamic properties of ordered colloidal suspensions of charged polystyrene particles and fractal colloidal aggregates. Our studies on static structure factor,S(Q), of ordered monodisperse colloidal suspensions and binary mixtures of particles with different particle diameters, measured by angle-resolved Rayleigh scattering will be discussed. This will include determination of bulk modulus using gravitational compression and observation of colloidal glass (inferred from splitting of the second peak inS(Q)). Dynamic light scattering, with real time analysis of scattered intensity fluctuations, is used to get information about Brownian dynamics of the particles. Recent advances in the field of light scattering from colloidal aggregates which show fractal geometry will also be discussed.     

Resolving Concentrated Particle Size Mixtures Using Dynamic Light Scattering

Dynamic light scattering (DLS) is a technique used for measuring the size of molecules and particles undergoing Brownian motion by observing time‐dependent fluctuations in the intensity of scattered light. The measurement of samples using conventional DLS instrumentation is limited to low concentrations due to the onset of a phenomenon called multiple scattering. The problems of multiple scattering have been addressed in a light scattering instrument incorporating non‐ invasive backscatter optics (NIBS). This novel optic arrangement maximizes the detection of scattered light while maintaining signal quality and allows for measurements of turbid samples. This paper discusses the ability of backscatter detection to accurately determine particle sizes at 1 %w/v sample concentrations and demonstrates the correct resolution of different size populations using a series of latex standard mixtures with known volume ratios. The concentration of 1 %w/v is much higher than can be measured on conventional dynamic light scattering instruments.     

Radiation force exerted on nanometer size non-resonant Kerr particle by a tightly focused Gaussian beam

We calculate the radiation force that is exerted by a focused continuous-wave Gaussian beam of wavelength λ on a non-absorbing nonlinear particle of radius a ? 50λ/π. The refractive index of the mechanically-rigid particle is proportional to the incident intensity according to the electro-optic Kerr effect. The force consists of two components representing the contributions of the electromagnetic field gradient and the light scattered by the Kerr particle. The focused intensity distribution is determined using expressions for the six electromagnetic components that are corrected to the fifth order in the numerical aperture (NA) of the focusing objective lens. We found that for particles with a < λ/21.28, the trapping force is dominated by the gradient force and the axial trapping force is symmetric about the geometrical focus. The two contributions are comparable with larger particles and the axial trapping force becomes asymmetric with its zero location displaced away from the focus and towards the beam propagation direction. We study the trapping force behavior versus incident beam power, NA, λ, and relative refractive index between the surrounding liquid and the particle. We also examine the confinement of a Kerr particle that exhibits Brownian motion in a focused beam. Numerical results show that the Kerr effect increases the trapping force strength and significantly improves the confinement of Brownian particles.     

Fluctuation characteristics of singly scattered light intensity

The correlation function and variance of the intensity fluctuations of singly scattered light are computed for a system of independent scatterers subjected to Brownian motion and illuminated by a light beam. The computation is carried out taking account of space and time averaging by the detector. The results obtained agree with available test data.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 120–124, May, 1973.     

Fourth moments of acoustic waves forward scattered by a rough ocean surface

Abstract

Three types of statistical fourth moments of acoustic waves forward scattered by a randomly rough ocean surface are derived and numerically evaluated. The first one is related to the scintillation index which characterizes intensity fluctuations. The second one is the two-position intensity correlation function which describes the spatial correlation of wave intensity. The third is the fourth-moment two-position coherence function which carries information on the phase fluctuations of the scattered wave. In the range of weak scattering, the ratio of the absolute value of the fourth-moment two-position coherence function over the two-position intensity correlation exactly describes the mean-square fluctuation of the relative phase between the two positions. The acoustic frequency is high so that the Kirchhoff approximation can be used. Two types of spectral functions for surface-height fluctuations are considered: a Gaussian spectrum and the Donelan-Pierson spectrum. The latter is obtained from a model for the fluctuations of the ocean surface height which are controlled by the wind speed at the ocean surface.     

Effect of the spatial distribution of probe beam on the results of measurements of the disperse composition of nanoparticles by dynamic light scattering method

The model of dynamic scattering on a finite ensemble of Brownian particles in liquid is considered. It is shown that an artifact characteristic relaxation time appears in the autocorrelation function of the scattered light intensity, which is much longer than the correlation time controlled by particle diffusion in the scattering volume.     

Active Brownian motion tunable by light

Active Brownian particles are capable of taking up energy from their environment and converting it into directed motion; examples range from chemotactic cells and bacteria to artificial micro-swimmers. We have recently demonstrated that Janus particles, i.e.?gold-capped colloidal spheres, suspended in a critical binary liquid mixture perform active Brownian motion when illuminated by light. In this paper, we investigate in more detail their swimming mechanism, leading to active Brownian motion. We show that the illumination-borne heating induces a local asymmetric demixing of the binary mixture, generating a spatial chemical concentration gradient which is responsible for the particle's self-diffusiophoretic motion. We study this effect as a function of the functionalization of the gold cap, the particle size and the illumination intensity: the functionalization determines what component of the binary mixture is preferentially adsorbed at the cap and the swimming direction (towards or away from the cap); the particle size determines the rotational diffusion and, therefore, the random reorientation of the particle; and the intensity tunes the strength of the heating and, therefore, of the motion. Finally, we harness this dependence of the swimming strength on the illumination intensity to investigate the behavior of a micro-swimmer in a spatial light gradient, where its swimming properties are space-dependent.     

A gas of Brownian particles in statistical dynamics

We consider a large number of particles on a one-dimensional latticel Z in interaction with a heat particle; the latter is located on the bond linking the position of the particle to the point to which it jumps. The energy of a single particle is given by a potentialV(x), x∈Z. In the continuum limit, the classical version leads to Brownian motion with drift. A quantum version leads to a local drift velocity which is independent of the applied force. Both these models obey Einstein's relation between drift, diffusion, and applied force. The system obeys the first and second laws of thermodynamics, with the time evolution given by a pair of coupled non linear heat equations, one for the density of the Brownian particles and one for the heat occupation number; the equation for a tagged Brownian particle can be written as a stochastic differential equation.     

Using dynamic low-coherence interferometry to image Brownian motion within highly scattering media

Dynamic low-coherence interferometry was used to measure Brownian motion of submicrometer particles within highly scattering media. Strong rejection of multiply scattered light was obtained by combination of a coherence gate with a confocal microscope, thus allowing particle characterization methods generally reserved for optically dilute materials to be applied to optically concentrated suspensions. The Brownian diffusion coefficient of highly scattering media was determined with an accuracy better than 5%. Furthermore, we show that spatial variations in the Brownian diffusion coefficient can be imaged with an axial resolution determined by the coherence length of the light source (~30 mum) . The experiments also show broadening of the power spectrum as a function of depth into the sample, most likely as a result of detecting multiply scattered light.     

Experimental measurements of non-Gaussian scattering by a fractal diffuser

We report measurements of the statistics of intensity scintillations of 10.6 μm CO₂ radiation scattered by a two-dimensional fractal phase screen. The surface profile of the phase screen is measured and shown to have a Hausdorff-Besicovitch dimension of approximately 1.4. Measurements of the on-axis intensity fluctuations as a function of illuminated spot size in both the Fresnel and Fraunhofer region are presented. This fractal scatterer does not produce the high contrast values found in speckle patterns of smoothlyvarying surfaces. Both direct and heterodyne detection results are reported. Measurements of the average intensity as a function of angle are also presented, and illustrate the failure of theoretical models which assume a Gaussian phase autocorrelation function.     

Focussing by a random phase screen

We present experimental measurements of the statistics of intensity scintillations in light scattered by a random phase screen. The phase screen was produced in the laboratory by turbulent mixing of hot and cold air; the parameters of this screen were such that geometrical focussing effects could be studied near the screen and speckle effects were clearly visible in the far field. Results are given for the propagation of both laser light and white light through the turbulent region. We compare experimental results with the theory for a phase screen with a gaussian phase correlation function. New theoretical work which allows comparison for mean-square phase fluctuation $\text{φ}{}^2$ å 1 is also outlined.     

Application of integral transforms to a description of the Brownian motion by a non-Markovian random process

The one-dimensional Brownian motion and the Brownian motion of a spherical particle in an infinite medium are described by the conventional methods and integral transforms considering the entrainment of surrounding particles of the medium by the Brownian particle. It is demonstrated that fluctuations of the Brownian particle velocity represent a non-Markovian random process. A harmonic oscillator in a viscous medium is also considered within the framework of the examined model. It is demonstrated that for rheological models, random dynamic processes are also non-Markovian in character. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 66–74, February, 2009.     

Experimental attempt to detect stimulated “diffusion” scattering by particles in liquid

The change in the shape of the correlation function of the intensity of light scattered by particles in liquid, i.e., the appearance of a cosine component, with increasing excitation radiation intensity, is observed. The amplitude of this component increases with the intensity of exciting radiation. A quadratic component appears in the dependence of the scattering intensity on the exciting radiation intensity. These results point to the appearance of stimulated “diffusion” scattering by particle concentration fluctuations.     

Spherical particle Brownian motion in viscous medium as non-Markovian random process

The Brownian motion of a spherical particle in an infinite medium is described by the conventional methods and integral transforms considering the entrainment of surrounding particles of the medium by the Brownian particle. It is demonstrated that fluctuations of the Brownian particle velocity represent a non-Markovian random process. The features of Brownian motion in short time intervals and in small displacements are considered.     

Low-Concentration Photon Correlation Spectroscopy

Photon correlation spectroscopy (PCS) is a technique to measure rapidly particle size in the sub-micrometre region. The use of PCS is, however, limited by concentration. The upper limit is due to multiple scattering of the incident light and the lower limit is determined by the fact that fluctuations of the number of particles in the measuring zone have a significant influence on the apparent diffusion coefficient. In this paper a signal processing method is described which differentiates this influence. With this system the lower limit is no longer limited to about 100 particles in the measuring volume corresponding to a concentration of 10⁹ particles/cm³. The limitation is now the intensity of the scattered light, which becomes too weak at a concentration of about 50 particles/cm³. As a consequence of this work, a revision to the basic theory of PCS may be necessary. Moreover, the new processing method also permits the measurement of the particle concentration in the sample.     

Dynamic Light Scattering Measurement of Nanometer Particles in Liquids

Dynamic light scattering (DLS) techniques for studying sizes and shapes of nanoparticles in liquids are reviewed. In photon correlation spectroscopy (PCS), the time fluctuations in the intensity of light scattered by the particle dispersion are monitored. For dilute dispersions of spherical nanoparticles, the decay rate of the time autocorrelation function of these intensity fluctuations is used to directly measure the particle translational diffusion coefficient, which is in turn related to the particle hydrodynamic radius. For a spherical particle, the hydrodynamic radius is essentially the same as the geometric particle radius (including any possible solvation layers). PCS is one of the most commonly used methods for measuring radii of submicron size particles in liquid dispersions. Depolarized Fabry-Perot interferometry (FPI) is a less common dynamic light scattering technique that is applicable to optically anisotropic nanoparticles. In FPI the frequency broadening of laser light scattered by the particles is analyzed. This broadening is proportional to the particle rotational diffusion coefficient, which is in turn related to the particle dimensions. The translational diffusion coefficient measured by PCS and the rotational diffusion coefficient measured by depolarized FPI may be combined to obtain the dimensions of non-spherical particles. DLS studies of liquid dispersions of nanometer-sized oligonucleotides in a water-based buffer are used as examples.     

Light scattering studies of Brownian motion in confined geometries

Summary Dynamic light scattering can be a useful tool to determine the confinement of Brownian particles whose motion is restricted to dimensions comparable to the wavelength of the light. The theoretical form of the correlation function of the electric field scattered from such trapped particles has been derived and compared with the signal obtained both in a simulated experiment and in a real experiment where the particles are trapped in a glass wedge. This new result can be of relevance for particles trapped in various media such as a porous (transparent) media, a gel, a suspension of lamellar phases or even a concentrated colloidal suspension where a particle is ?trapped? by its neighbours. Paper presented at the I International Conference on Scaling Concepts and Complex Fluids, Copanello, Italy, July 4–8, 1994.     

Truncated Lévy flights and generalized Cauchy processes

A continuous Markovian model for truncated Lévy flights is proposed. It generalizes the approach developed previously by Lubashevsky et al. [Phys. Rev. E 79, 011110 (2009); Phys. Rev. E 80, 031148 (2009), Eur. Phys. J. B 78, 207 (2010)] and allows for nonlinear friction in wandering particle motion as well as saturation of the noise intensity depending on the particle velocity. Both the effects have own reason to be considered and, as shown in the paper, individually give rise to a cutoff in the generated random walks meeting the Lévy type statistics on intermediate scales. The nonlinear Langevin equation governing the particle motion was solved numerically using an order 1.5 strong stochastic Runge-Kutta method. The obtained numerical data were employed to analyze the statistics of the particle displacement during a given time interval, namely, to calculate the geometric mean of this random variable and to construct its distribution function. It is demonstrated that the time dependence of the geometric mean comprises three fragments following one another as the time scale increases that can be categorized as the ballistic regime, the Lévy type regime (superballistic, quasiballistic, or superdiffusive one), and the standard motion of Brownian particles. For the intermediate Lévy type part the distribution of the particle displacement is found to be of the generalized Cauchy form with cutoff. Besides, the properties of the random walks at hand are shown to be determined mainly by a certain ratio of the friction coefficient and the noise intensity rather than their characteristics individually.