Flow structure and bubble dynamics in supercritical water fluidized bed and gas fluidized bed: A comparative study

Supercritical water (SCW) fluidized bed is a new reactor concept for hydrogen production from biomass or coal gasification. In this paper, a comparative study on flow structure and bubble dynamics in a supercritical water fluidized bed and a gas fluidized bed was carried out using the discrete element method (DEM). The results show that supercritical water condition reduces the incipient fluidization velocity, changes regime transitions, i.e. a homogeneous fluidization was observed when the superficial velocity is in the range of the minimum fluidization velocity and minimum bubbling velocity even the solids behave as Geldart B powders in the gas fluidized bed. Bubbling fluidization in the supercritical water fluidized bed was formed after superficial velocity exceeds the minimum bubbling velocity, as in the gas fluidized bed. Bubble is one of the most important features in fluidized bed, which is also the emphasis in this paper. Bubble growth was effectively suppressed in the supercritical water fluidized bed, which resulted in a more uniform flow structure. By analyzing a large number of bubbles, bubble dynamic characteristics such as diameter distribution, frequency, rising path and so on, were obtained. It is found that bubble dynamic characteristics in the supercritical water fluidized bed differ a lot from that in the gas fluidized bed, and there is a better fluidization quality induced by the bubble dynamics in the supercritical water fluidized bed.     

Insights in hydrodynamics of bubbling fluidized beds at elevated pressure by DEM–CFD approach

A numerical simulation was conducted to study the effect of pressure on bubble dynamics in a gas–solid fluidized bed. The gas flow was modeled using the continuum theory and the solid phase, by the discrete element method (DEM). To validate the simulation results, calculated local pressure fluctuations were compared with corresponding experimental data of 1-mm polyethylene particles. It was shown that the model successfully predicts the hydrodynamic features of the fluidized bed as observed in the experiments. Influence of pressure on bubble rise characteristics such as bubble rise path, bubble stability, average bubbles diameter and bubble velocity through the bed was investigated. The simulation results are in conformity with current hydrodynamic theories and concepts for fluidized beds at high pressures. The results show further that elevated pressure reduces bubble growth, velocity and stability and enhances bubble gyration through the bed, leading to change in bed flow structure.     

Hydrodynamics of a bubble-induced inverse fluidized bed reactor with a nanobubble tray

This paper reports on the hydrodynamics of a bubble-induced inverse fluidized bed reactor, using a nanobubble tray gas distributor, where solid particles are fluidized only by an upward gas flow. Increasing the gas velocity, the fixed layer of particles initially packed at the top of the liquid starts to move downwards, due to the rise of bubbles in this system, and then gradually expands downwards until fully suspended. The axial local pressure drops and standard deviation were examined to delineate the flow regime comprehensively under different superficial gas velocities. Four flow regimes (fixed bed regime, initial fluidization regime, expanded regime, and post-homogeneous regime) were observed and three transitional gas velocities (the initial fluidization velocity, minimum fluidization velocity, and homogeneous fluidization velocity) were identified to demarcate the flow regime. Three correlations were developed for the three transitional velocities. As the fine bubbles generated from the nanobubble tray gas distributor are well distributed in the entire column, the bed expansion process of the particles is relatively steady.     

Hydrodynamic characteristics of a rectangular gas-driven inverse liquid-solid fluidized bed

The hydrodynamic characteristics of a rectangular gas-driven inverse liquid-solid fluidized bed (GDFB) using particles of different diameters and densities were investigated in detail. Rising gas bubbles cause a liquid upflow in the riser portion, enabling a liquid downflow that causes an inverse fluidization in the downer portion. Four flow regimes (fixed bed regime, initial fluidization regime, complete fluidization regime, and circulating fluidization regime) and three transition gas velocities (initial fluidization gas velocity, minimum fluidization gas velocity, and circulating fluidization gas velocity) were identified via visual observation and by monitoring the variations in the pressure drop. The axial local bed voidage (ε) of the downer first decreases and then increases with the increase of the gas velocity. Both the liquid circulation velocity and the average particle velocity inside the downer increase with the increase of the gas velocity in the riser, but decrease with the particle loading. An empirical formula was proposed to successfully predict the Richardson-Zaki index “n”, and the predicted ε obtained from this formula has a ±5% relative error when compared with the experimental ε.     

Bottom bed regimes in a circulating fluidized bed boiler

This paper extends previous work on the fluidization regimes of the bottom bed of circulating flyidized bed (CFB) boilers. Pressure measurements were performed to obtain the time-average bottom bed voidage and to study the bed pressure fluctuations. The measurements were carried out in a 12 MW_th CFB boiler operated at 850°C and also under ambient conditions (40°C). Two bubbling regimes were identified: a “single bubble regime” with large single bubbles present at low fluidization velocities, and, at high fluidization velocities, an “exploding bubble regime” with bubbles often stretching all the way from the air distributor to the surface of the bottom bed. The exploding bubble regime results in a high through-flow of gas, indirectly seen from the low average voidage of the bottom bed, which is similar to that of a stationary fluidized bed boiler, despite the higher gas velocities in the CFB boiler. Methods to determine the fluidization velocity at the transition from the single to the exploding bubble regime are proposed and discussed. The transition velocity increases with an increase in particle size and bed height.     

Fluidization and bubbling behavior of potash particles in a deep fluidized bed

Most existing models for predicting bubble size and bubble frequency have been developed for freely bubbling fluidized beds. Accurate prediction of bubbling behavior in deep fluidized beds, however, has been a challenge due to the higher degree of bubble coalescence and break up, high probability of the slugging regime, partial fluidization, and chaotic behavior in the bubbling regime. In this work, the bubbling and fluidization behavior of potash particles was investigated in a deep fluidized bed employing a twin-plane electrical capacitance tomography (ECT) system. Solid volume fraction, average bubble velocity, average bubble diameter, and bubble frequency in both bubbling and slugging regimes were measured at two different bed height ratios (H/D = 3.5 and H/D = 3.78). This work is the first to illustrate a sequential view of bubbles at different superficial gas velocities in a fluidized bed. The results show that both the bubble diameter and rising velocity increased with increasing the superficial gas velocity for the two bed heights, with larger values observed in the deeper bed compared to the shallower one. Predicted values for bubble diameter, bubble rise velocity and bubble frequency from different models are compared with the experimental data obtained from the ECT system in this work. Good agreement has been achieved between the values predicted by the previous models and the experimental data for the bubble diameter and bubble rise velocity with an average absolute deviation of 16% and 15% for the bed height of 49 cm and 13% and 8% for the bed height of 53 cm, respectively.     

CFD-DEM investigation into flow characteristics in mixed pulsed fluidized bed under electrostatic effects

Static electricity has an important effect on gas–solid fluidized bed reactor fluidization performance. In the process of fluidization, electrostatic interaction between particles will obviously accelerate particle agglomerate formation, which consequently reduces the fluidization performance. Pulsed gas flow injection is an efficient method to enhance particle mixing, thereby weakening the occurrence of particle agglomerate. In this study, the two-dimensional hybrid pulsed fluidized bed is established. The flow characteristics are studied by using the coupled CFD-DEM numerical simulation model considering electrostatic effects. Influences of different pulsed frequencies and gas flow ratios on fluidized bed fluidization performance are investigated to obtain the optimal pulsed gas flow condition. Results show that in the presence of static electricity, the bubble generation position is lower, which is conducive to the particle flow. Pulsed gas flow can increase the particle velocity and improve the diffusion ability. The bubble generation time is different at different frequencies, and the frequency of 2.5 Hz has the most obvious effect on the flow characteristics. Different gas flow ratios have significant impacts on the particle movement amplitude. When the pulse gas flow accounts for a large ratio, the particle agglomerate tends to be larger. Therefore, in order to improve the fluidization effect, the ratio of pulsed gas flow to stable gas flow should be appropriately reduced to 0.5 or less.     

Dual characters of interaction between particles and fluid

The unique characteristics of gas-solids two-phase flow and fluidization in terms of the flow structures and the apparent behavior of particles and fluid-particle interactions are closely linked to physical properties of the particles, operating conditions and bed configurations. Fluidized beds behave quite differently when solid properties, gas velocities or vessel geometries are varied. An understanding of hydrodynamic changes and how they, in turn, influence the transfer and reaction characteristics of chemical and thermal operations by variations in gas-solid contact, residence time, solid circulation and mixing and gas distribution is very important for the proper design and scale-up of fluidized bed reactors. In this paper, rather than attempting a comprehensive survey, we concentrate on examining some important positive and negative impacts of particle sizes, bubbles, clusters and column walls on the physical and chemical aspects of chemical reactor performance from the engineering application point of view with the aim of forming an adequate concept for guiding the design of multiphase fluidized bed chemical reactors.One unique phenomenon associated with particle size is that fluidized bed behavior does not always vary monotonically with changing the average particle size. Different behaviors of particles with difference sizes can be well understood by analyzing the relationship between particle size and various forces. For both fine and coarse particles, too narrow a distribution is generally not favorable for smooth fluidization. A too wide size distribution, on the other hand, may lead to particle segregation and high particle elutriation. Good fluidization performance can be established with a proper size distribution in which inter-particle cohesive forces are reduced by the lubricating effect of fine particles on coarse particles for Type A, B and D particles or by the spacing effect of coarse particles or aggregates for Type C powders.Much emphasis has been paid to the negative impacts of bubbles, such as gas bypassing through bubbles, poor bubble-to-dense phase heat & mass transfer, bubble-induced large pressure fluctuations, process instabilities, catalyst attrition and equipment erosion, and high entrainment of particles induced by erupting bubbles at the bed surface. However, it should be noted that bubble motion and gas circulation through bubbles, together with the motion of particles in bubble wakes and clouds, contribute to good gas and solids mixing. The formation of clusters can be attributed to the movement of trailing particles into the low-pressure wake region of leading particles or clusters. On one hand, the existence of down-flowing clusters induces strong solid back-mixing and non-uniform radial distributions of particle velocities and holdups, which is undesirable for chemical reactions. On the other hand, the formation of clusters creates high solids holdups in the riser by inducing internal solids circulations, which are usually beneficial for increasing concentrations of solid catalysts or solid reactants.Wall effects have widely been blamed for complicating the scale-up and design of fluidized-bed reactors. The decrease in wall friction with increasing the column diameter can significantly change the flow patterns and other important characteristics even under identical operating conditions with the same gas and particles. However, internals, which can be considered as a special wall, have been used to improve the fluidized bed reactor performance.Generally, desirable and undesirable dual characteristics of interaction between particles and fluid are one of the important natures of multiphase flow. It is shown that there exists a critical balance between those positive and negative impacts. Good fluidization quality can always be achieved with a proper choice of right combinations of particle size and size distribution, bubble size and wall design to alleviate the negative impacts.     

Bubble chains in large diameter gas fluidized beds

Using statistically based measuring methods for the determination of local bubble size distributions and local average bubble shapes in gas fluidized beds, bubble characteristics have been measured in a fluidized bed column of 1 m diameter where quartz sand (minimum fluidizing velocity 0.0135 m/sec) was fluidized with air at velocities ranging from 0.05 to 0.30 m/sec. The results present experimental evidence that bubbles within large diameter fluidized beds do not rise completely randomly distributed in space but rather in the form of bubble chains which is in agreement with industrial operating experience in large scale fluid bed systems. Since the formation of bubble chains considerably reduces the residence time of the bubble gas this finding is of significance for the performance of fluidized bed reactors. The influence of the operating parameters on the extent of the bubble chain formation has been investigated and possible consequences of these results are discussed.     

A model of bubbles rising in a fluidized bed

A model for a single fully developed bubble moving in an unbounded fluidized bed is presented. The model allows bubble growth or shrinkage during the rise inside the bed, as well as dependence of the rise velocity upon specified bed parameters. Limiting cases of nearly spherical bubbles and of sufficiently large bubbles whose form resembles that of a spherical segment are considered in more detail. The form of bubbles rising in either fluidized beds or one-phase liquids, and its dependence on the effective “surface tension” acting on the bubble boundary are discussed.     

Bubbling behavior of cohesive particles in a two-dimensional fluidized bed with immersed tubes

Fluidization hydrodynamics are greatly influenced by inter-particle cohesive forces. This paper studies the fluidization of large cohesive particles in a two-dimensional fluidized bed with immersed tubes using “polymer coating” to introduce cohesive force, to gain better understanding of bubbling behavior when particles become cohesive and its effect on chemical processes. The results show that the cohesive force promotes bubble splitting in the tube bank region, thereby causing an increase in the number and a decline in the aspect ratio of the bubbles. As the cohesive force increases within a low level, the bubble number increases and the bubble diameter decreases, while the aspect ratio exhibits different trends at different fluidization gas velocities. The difference in the evolution of bubble size under various cohesive forces mainly takes place in the region without tubes. When the cohesive force is large enough to generate stable agglomerates on the side walls of the bed, the bubble number and the bed expansion sharply decrease. The tubes serve as a framework that promotes the agglomeration, thus accelerating defluidization. Finally, the bubble profile around tubes was studied and found to greatly depend both on the cohesive forces and the location of tubes.     

The local structure of gas fluidized beds —I. A statistically based measuring system

A system is described for measuring the parameters characterizing the local state of fluidization in beds of arbitrary sizes. This system is based on a miniaturized capacitance probe shaped so as not to disturb the local state of fluidization. Based on a statistical analysis of the signal, the mean bubble pulse duration, the number of bubbles striking the probe per unit time and the local mean bubble rise velocity are measured. The latter is measured by using the cross-correlation technique. From these parameters, further characteristics of the local state of fluidization are derived, in particular the local mean pierced length of bubbles, the local bubble volume fraction and the local bubble gas flow.     

Vibration time series analysis of bubbling and turbulent fluidization

A non-intrusive vibration monitoring technique was used to study the hydrodynamics of a gas–solid fluidized bed. Experiments were carried out in a 15 cm diameter fluidized bed using 226, 470 and 700 μm sand particles at various gas velocities, covering both bubbling and turbulent regimes. Auto correlation function, mutual information function, Hurst exponent analysis and power spectral density function were used to analyze the fluidized bed hydrodynamics near the transition point from bubbling to turbulent fluidization regimes. The first pass of the autocorrelation function from one half and the time delay at which it becomes zero, and also the first minimum of the mutual information, occur at a higher time delay in comparison to stochastic systems, and the values of time delays were maximum at the bubbling to turbulent transition gas velocity. The maximum value of Hurst exponent of macro structure occurred at the onset of regime transition from bubbling to turbulent. Further increase in gas velocity after that regime transition velocity causes a decrease in the Hurst exponent of macro structure because of breakage of large bubbles to small ones. The results showed these methods are capable of detecting the regime transition from bubbling to turbulent fluidization conditions using vibration signals.     

Flow regime diagrams for gas-solid fluidization and upward transport

Flow regime maps are presented for gas-solids fluidized beds and gas-solids upward transport lines. For conventional gas solids fluidization, the flow regimes include the fixed bed, bubbling fluidization, slugging fluidization and turbulent fluidization. For gas solids vertical transport operation, solids flux must be incorporated in the flow regime diagrams. The flow regimes then include dilute-phase transport, fast fluidization or turbulent flow, slug/bubbly flow, bubble-free dense-phase flow and packed bed flow. In practical circulating fluidized beds and transport risers, operation below the fast fluidization regime is commonly impossible due to equipment limitations. Practical flow regime maps are proposed with the flow regimes, including homogeneous dilute-phase flow, core-annular dilute-phase flow (where there are appreciable lateral gradients but small axial gradients) and fast fluidization (where there are both lateral and axial gradients). The boundary between fast fluidization and dilute-phase pneumatic transport is set by the type A choking velocity, at which the uniform suspension collapses and particles start to accumulate in the bottom region of the transport line, while the mechanism of transition from fast fluidization to dense-phase flow depends on the column and particle diameters.     

Hydrodynamic behavior of magnetized fluidized beds with admixtures of Geldart-B magnetizable and nonmagnetizable particles

This work focuses on the hydrodynamic behavior of admixtures of Geldart-B magnetizable and nonmagnetizable particles in a magnetized fluidized bed. The applied magnetic field was axial, uniform, and steady. In operating the beds, the magnetization-LAST mode was adopted under which four distinct flow regimes exist: fixed, magnetized-bubbling, partial segregation-bubbling, and total segregation-bubbling. The operational phase diagram was drawn to display the transitions between flow regimes in an intuitive manner. Only in the magnetized-bubbling regime could the magnetic field reduce the bubble size and improve fluidization quality. In the segregation-bubbling regimes, fluidization quality deteriorated as segregation developed. The segregation of the binary mixture was quantitatively studied by observing pressure drops in the local bed. Reasons for the improvement in fluidization quality as well as the occurrence of segregation were analyzed. Furthermore, the flow regime transition under magnetization-LAST operation mode was different from that under magnetization-FIRST mode. The magnetically stabilized bed (MSB) flow regime, which could be easily created under magnetization-FIRST mode, could no longer be achieved under magnetization-LAST mode. With the admixture, the MSB was proved to be a metastable equilibrium state. Under the magnetization-LAST mode, the admixture bed reached directly the stable equilibrium state—bubbling with segregation.     

Statistical modeling and optimization of a multistage gas-solid fluidized bed for removing pollutants from flue gases

The present paper describes the statistical modeling and optimization of a multistage gas-solid fluidized bed reactor for the control of hazardous pollutants in flue gas.In this work,we study the hydrodynamics of the pressure drop and minimum fluidization velocity.The hydrodynamics of a three-stage fluidized bed are then compared with those for a single-stage unit.It is observed that the total pressure drop over all stages of the three-stage fluidized bed is less than that of an identical single-stage system.However,the minimum fluidization velocity is higher in the single-stage unit.Under identical conditions,the minimum fluidization velocity is highest in the top bed,and lowest in the bottom bed.This signifies that the behavior of solids changes from a well-mixed flow to a plug-flow,with intermediate behavior in the middle bed.     

PRESSURE FLUCTUATIONS IN GAS-SOLIDS FLUIDIZED BEDS

Pressure fluctuation data measured in a series of fluidized beds with diameters of 0.05, 0.1, 0.29, 0.60 and 1.56 m showed that the maximum amplitude or standard deviation increased with increasing the superficial gas velocity and static bed height for relatively shallow beds and became insensitive to the increase in static bed height in relatively deep beds. The amplitude appeared to be less dependent on the measurement location in the dense bed. Predictions based on bubble passage, bubble eruption at the upper bed surface and bed oscillation all failed to explain all observed trends and underestimated the amplitude of pressure fluctuations, suggesting that the global pressure fluctuations in gas-solids bubbling fluidized beds are the superposition of local pressure variations, bed oscillations and pressure waves generated from the bubble formation in the distributor region, bubble coalescence during their rise and bubble eruption at the upper bed surface.     

FLOW DYNAMICS OF GAS-SOLID FLUIDIZED BEDS WITH EVAPORATIVE LIQUID INJECTION

1. Introduction Injections of evaporative liquids into fluidized solid parti- cles are routinely practiced in industrial processes involv- ing gas-solid fluidization systems such as fluid catalytic cracking, polymerization, and plastic coating (Fan et al., 2001). In the FCC riser system, heavy oil is injected into the system to evaporate rapidly by contact with the hot catalyst particles. Simultaneously, thermal and catalytic cracking reactions take place. During a polymerization process, a …     

Fluidization behavior of graphitized glassy particles in a fluidized carbon bed cooling process for investment casting

Fluidized Carbon Bed Cooling (FCBC) is an innovative investment casting process for directional solidification of superalloy components. It takes advantage of a fluidized bed with a base of small glassy carbon beads for cooling and other low-density particles that form an insulating layer by floating to the bed surface. This so-called “Dynamic Baffle” protects the fluidized bed from the direct heat input from the high-temperature heating zone and provides the basis for an improved bed microstructure. The prerequisites for a stable casting process are stable fluidization conditions where neither collapse of the bed nor particle blow out at excessive bubble formation occur.This work aimed to investigate the fluidization behavior of spherical carbon bed material in argon and air at temperatures between 20 to 350 °C. Systematic studies at reduced pressures using the FCBC prototype device were performed to understand the stable fluidization conditions at all stages of the investment casting process. The particle shape factor and size distribution characterization and the measurement of the powder’s minimum fluidization velocity and bed voidage show that this material can be fully utilized as a cooling and buoyancy medium during the FCBC process.     

The local structure of gas fluidized beds —II. The spatial distribution of bubbles

The spatial distribution of bubbles in gas fluidized beds has been investigated with the measuring system described in Part I of this paper in beds of 0.10, 0.20, 0.45 and 1.0 m dia. The results indicate that in gas fluidized beds a characteristic flow profile of the bubble phase exists such that near the distributor a zone of increased bubble development exists in an annulus near the wall. This zone moves towards the vessel centre-line with increasing height above the distributor. The merging of the annular zone in the vessel centre-line marks the beginning of the transition of the fluidized bed to the state of slugging. The spatial flow profile of the bubble phase is shown to be responsible for the existence of characteristic solids circulation patterns in gas fluidized beds.