PREDICTION OF THE VISCOELASTIC PROPERTIES OF THE EQUIVALENT PARTICLE FOR THE INTERCALATED MULTI-LAYER STACK OF NANOPLASTICS

The aim of this paper is to apply the asymptotic homogenization method to deter- mining analytically and numerically the transversely isotropic viscoelastic relaxation moduli of the equivalent particle for the intercalated multi-layer stack of intercalated type nanoplastics.A two-phase multilayered material containing n layers is considered.The matrix is assumed to be an isotropic viscoelastic standard linear body and the reinforcement is assumed to be an isotropic elastic body.Final explicit analytical formulae for the effective elastic moduli of the multilay- ered material are derived first;and then the correspondence principle is employed to obtain the homogenized relaxation moduli of the equivalent intercalated particle.A numerical example is given.Final explicit analytical formulae in the time domain derived here make it convenient to estimate the influence of all the particle parameters of micro-structural details on the effective properties of the equivalent intercalated particle.The results of this paper can also be applied to multi-layer composites.     

Effective properties of a linear viscoelastic composite

The relaxation moduli of a composite are determined. The relaxation of its components is described by various few-parameter kernels: Mittag-Leffler functions of different orders and Rzhanitsyn kernel. It is assumed that the composite components are made of model materials with volume relaxation. The Laplace transform and fractional rational approximation are used to develop an algorithm for reducing the relaxation functions of the composite to one class (series of decreasing exponents or exponents of fractional order). The relaxation moduli of a unidirectionally reinforced composite are determined as an example     

Modeling of anisotropic polydispersed composites by progressive micromechanical approach

A progressive micromechanical method is presented in order to predict the elastic constants of polydispersed composites including multi-directional or randomly oriented reinforcement particles. Heterogeneities of various types are introduced into the matrices in a gradual manner. At each step, the Mori-Tanaka method is used to obtain the stiffness tensor of the intermediate medium used as a matrix of the following step. The proposed method is capable of introducing any kind of heterogeneities based on their dimensions, orientations, mechanical properties, and volume fractions to the matrix. Furthermore, suitable probability density functions can be defined for physical and structural parameters of the composite, including the level of the filler-matrix interfacial bonding, the aspect ratio, and the orientation of reinforcement particles. The efficiency of the iterative approach and the convergence of the solution are studied by computing the stiffness tensors of unidirectional and bidirectional particulate composites. The results of the present study are also compared with the literature data for a randomly oriented particulate composite.     

A Method for Determining the Viscoelastic Characteristics of Composites

An efficient method for determining the deformation function of a composite is discussed. The method is based on a fractional exponential representation of the deformation functions of the composite components. The viscoelastic solution is obtained using the Volterra principle. The deformation function is represented as a function of a base operator. Thus, the problem is solved by approximating the deformation function by a continued fraction and applying the method of operator continued fractions. A computational procedure is detailed and illustrated using data on longitudinal relaxation of polymethylmethacrylate. As an example, the deformation of a polymethylmethacrylate-based fibrous composite with viscoelastic properties is analyzed__________Translated from Prikladnaya Mekhanika,Vol. 41, No. 5, pp. 9–21, May 2005.     

Vibration analysis of linear coupled thermoviscoelastic thin plates by a variational approach

According to the integral type constitutive relation of linear coupled thermoviscoelasticity, a mathematical model of thin plates is set up by the introduction of “structural functions” and “thermal functions” in the sense of the Kirchhoff’s hypothesis. The corresponding integral type variational formulations are presented by means of modern convolution bilinear forms as well as classical Cartesian bilinear forms. The Ritz method in the spatial domain and the differentiating method in the temporal domain are used to approximate the mathematical model in a system of rectangular Cartesian coordinates. By properties of inequality and parabola, the structure of dynamic solution to vibration of a thermoviscoelastic thin plate under a harmonic thermal load is studied in the space splayed by material parameter and loading parameter. The influences of thermal excitation frequency, mechanical relaxation time and thermal relaxation time on amplitude and phase difference of steady-state vibration of a square plate are investigated by amplitude-frequency analysis and phase-frequency analysis. Double-peak resonance vibration of thermoviscoelastic plates exists for given parameters.     

Influence of the viscoelastic properties of a composite on the stress distribution around an elliptic hole in a plate

The time variation in the stresses around an elliptic hole in a composite plate is studied. Solutions that characterize the effect of the time dependence of the relaxation moduli of the composite components on stresses are obtained. The solutions in the time domain are obtained from the elastic–viscoelastic analogy and the corresponding elastic solutions for the effective moduli of the composite and the stress field around an elliptic hole in an anisotropic plate. The inverse Laplace transformation is carried out by an effective numerical method     

Relaxation and retardation functions of the Maxwell model with fractional derivatives

A four-parameter Maxwell model is formulated with fractional derivatives of different orders of the stress and strain using the Riemann-Liouville definition. This model is used to determine the relaxation and retardation functions. The relaxation function was found in the time domain with the help of a power law series; a direct solution was used in the Laplace domain. The solution can be presented as a product of a power law term and the Mittag-Leffler function. The retardation function is determined via Laplace transformation and is solely a power law type.The investigation of the relaxation function shows that it is strongly monotonic. This explains why the model with fractional derivatives is consistent with thermodynamic principles.This type of rheological constitutive equation shows fluid behavior only in the case of a fractional derivative of the stress and a first order derivative of the strain. In all other cases the viscosity does not reach a stationary value.In a comparison with other relaxation functions like the exponential function or the Kohlrausch-Williams-Watts function, the investigated model has no terminal relaxation time. The time parameter of the fractional Maxwell model is determined by the intersection point of the short- and long-rime asymptotes of the relaxation function.     

Stresses in rotating heterogeneous viscoelastic composite cylinders with variable thickness

An analytical solution is presented for the rotation problem of a two-layer composite elastic cylinder under a plane strain assumption. The external cylinder has variable-thickness formulation, and is made of a heterogeneous orthotropic material. It contains a fiber-reinforced viscoelastic homogeneous isotropic solid core of uniform thickness. The thickness and elastic properties of the external cylinder are taken as power functions of the radial direction. By the boundary and continuity conditions, the radial displacement and stresses for the rotating composite cylinder are determined. The effective moduli and Illyushin’s approximation methods are used to obtain the viscoelastic solution to the problem. The effects of heterogeneity, thickness variation, constitutive, time parameters on the radial displacement, and stresses are investigated.     

Interacting elliptic inclusions by the method of complex potentials

An accurate series solution has been obtained for a piece-homogeneous elastic plane containing a finite array of non-overlapping elliptic inclusions of arbitrary size, aspect ratio, location and elastic properties. The method combines standard Muskhelishvili’s representation of general solution in terms of complex potentials with the superposition principle and newly derived re-expansion formulae to obtain a complete solution of the many-inclusion problem. By exact satisfaction of all the interface conditions, a primary boundary-value problem stated on a complicated heterogeneous domain has been reduced to an ordinary well-posed set of linear algebraic equations. A properly chosen form of potentials provides a remarkably simple form of solution and thus an efficient computational algorithm. The theory developed is rather general and can be applied to solve a variety of composite mechanics problems. The advanced models of composite involving up to several hundred inclusions and providing an accurate account for the microstructure statistics and fiber–fiber interactions can be considered in this way. The numerical examples are given showing high accuracy and numerical efficiency of the method developed and disclosing the way and extent to which the selected structural parameters influence the stress concentration at the matrix–inclusion interface.     

Time-dependent thermoelastic creep analysis of rotating disk made of Al–SiC composite

Time-dependent creep stress redistribution analysis of rotating disk made of Al–SiC composite is investigated using Mendelson’s method of successive elastic solution. All mechanical and thermal properties except Poisson’s ratio are radial dependent based on volume fraction percent of SiC reinforcement. The material creep behavior is described by Sherby’s constitutive model using Pandey’s experimental results on Al–SiC composite. Loading is an inertia body force due to rotation and a distributed temperature field due to steady-state heat conduction from inner to outer surface of the disk. Using equations of equilibrium, stress strain, and strain displacement, a differential equation, containing creep strains, for displacement is obtained. History of stresses and deformations are calculated using method of successive elastic solution. It is concluded that the uniform distribution of SiC reinforcement does not considerably influence on stresses. However, the minimum and most uniform distribution of circumferential and effective thermoelastic stresses belongs to composite disk of aluminum with 0% SiC at inner surface and 40% SiC at outer surface. It has also been found that the stresses, displacement, and creep strains are changing with time at a decreasing rate so that after almost 50 years the solution approaches the steady-state condition.     

Surface tension driven oscillations of a bubble in a viscoelastic liquid

Small amplitude surface tension driven oscillations of a spherical bubble in a dilute polymer solution are considered. The rheological properties of the liquid are modelled by using a 3-constant constitutive equation of the Oldroyd type. The Laplace transform of the solution of the initial value problem is inverted numerically. As in the Newtonian fluid case, both a discrete and a continuous spectrum occurs. In addition to the non-dimensional parameters in the corresponding problem for a Newtonian fluid, the results depend on two other parameters: the ratio of the relaxation time of the polymer solution and the time scale of the flow (the Deborah number) and the product of the polymer concentration and the intrinsic viscosity. For small bubbles in an aqueous solution having a small relaxation time, significant additional damping is found even for dilute solutions.     

Nonlinear deformation of a particulate material in complex stress state

An algorithm is proposed to determine the effective deformation properties and stress-strain state of particulate composite materials with physically nonlinear components and complex stress state. The laws that govern the deformation of particulate composites are studied. A particulate composite is considered a two-component material of random structure. Its effective properties are determined by conditional averaging. The nonlinear equations that incorporate the physical nonlinearity of the components are solved by the method of successive approximations. The relationship between macrostresses and macrostrains is established. The effective deformation properties of a particulate composite as a function of the volume fractions of the components and stress state are studied __________ Translated from Prikladnaya Mekhanika, Vol. 42, No. 3, pp. 50–60, March 2006.     

Volume relaxation in polymers

Summary Volume relaxation and related phenomena in the glass transition of polymers are discussed. During volume relaxation, the molecular transport mobility changes. First, this in principle implies non-linearity of the volume relaxation process itself. The apparent contradiction of this fact with the linearity domain found experimentally byGoldbach (1) could be explained. Secondly, during volume relaxation the viscoelastic processes change their location in time scale, due to the change in molecular transport mobility. This is demonstrated by experimental results for poly(styrene). The change of mechanical properties during volume relaxation strongly increased with a decrease in frequency of the mechanical deformation. Consequently one should also be careful with mechanical measurements in the glass transition range, especially when performed at lower frequencies.A semi-automatic method to perform simultaneously a large series of isothermal volume relaxation measurements is presented.     

Overall behavior of two-dimensional periodic composites

The overall properties of a binary elastic periodic fiber-reinforced composite are studied here for a cell periodicity of square type. Exact formulae are obtained for the effective stiffnesses, which give closed-form expressions for composites with isotropic components including ones for empty and rigid fibers. The new formulae are simple and relatively easy to compute. Examples show the dependences of the stiffnesses as a function of fiber volume fraction up to the percolation limit. The specific example of glass fibers in epoxy yields new curves, which correct those displayed before by Meguid and Kalamkarov. Comparison with experimental data is very good. Bruno, Hill and Hashin's bounds are compared with the exact solution. In most cases, the latter is very close to a bound in a given interval. A useful fact to know, where the easy formula afforded by the bound is advantageous. Plots of effective properties are also given for values of the shear moduli ratio of the two media. The overall parameters in the cases of empty and rigid fibers are also shown. The exact formulae explicitly display Avellaneda and Schwarts's microstructural parameters, which have a physical meaning, and provide formulae for them. The equations easily lead to Hill's universal relations.     

Parameters of the Edge Effect as a Function of the Mechanical Characteristics of a Composite with an Interfacial Crack

The paper studies the dependence of edge effects in a laminated composite of regular structure with a periodic system of symmetric interfacial cracks on the mechanical characteristics of the composite components. Loading the composite induces constant strain in the reinforcement direction. The problem is solved in exact formulation using the linear elastic equations for piecewise-homogeneous media and a criterion for quantitative evaluation of edge effects. An approximate solution of the problem is found by the mesh approach. A difference scheme for the mixed problem under consideration is derived. The edge-effect zones for normal stresses are constructed. The maximum values of the normal stress concentration factors are determined     

Research on the effect of cylinder particles on the turbulent properties in particulate flows

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Piezocomposite with reciprocal polarization of oriented ellipsoidal inclusions and the matrix

We consider statistically homogeneous two-phase random piezoactive structures with deterministic properties of inclusions and the matrix and with random mutual location of inclusions. We present the solution of a coupled stochastic boundary value problem of electroelasticity for the representative domain of a matrix piezocomposite with a random structure in the generalized singular approximation of the method of periodic components; the singular approximation is based on taking into account only the singular component of the second derivative of the Green function for the comparison media. We obtain an analytic solution for the tensor of effective properties of the piezocomposite in terms of the solution for the tensors of effective properties of a composite with an ideal periodic structure or with the “statistical mixture” structure and with the periodicity coefficient calculated for a given random structure with its specific characteristics taken into account. The effective properties of composites with auxiliary structures (periodic and “statistical mixture”) are also determined in the generalized singular approximation by varying the properties of the comparisonmedium. We perform numerical computations and analyze the effective properties of a quasiperiodic piezocomposite with reciprocal polarization of oriented ellipsoidal inclusions and the matrix, the layered structures with reciprocal polarization of the layers [1] of a polymer piezoelectric PVF, and find their unique properties such as a significant increase in the Young modulus along the normal to the layers and in dielectric permittivities, the appearance of negative values of the Poisson ratio under extension along the normal, and an increase in the absolute values of the basic piezomoduli.     

Computational studies on high-stiffness,high-damping SiC–InSn particulate reinforced composites

With the objective of achieving composite material systems that feature high stiffness and high mechanical damping, consideration is given here to unit cell analysis of particulate composites with high volume fraction of inclusions. Effective elastic properties of the composite are computed with computational homogenization based on unit cell analysis. The correspondence principle together with the viscoelastic properties of the indium–tin eutectic matrix are then used to compute the effective viscoelastic properties of the composite. Comparison is made with parallel experiments upon composites with an indium–tin eutectic matrix and high volume fractions of silicon-carbide reinforcement. The analytical techniques indicate that combinations of relatively high stiffness and high damping can be achieved in particulate composites with high SiC volume fractions. Based on analysis, the tradeoffs between stiffness and damping characteristics are assessed by changing the volume fraction, size, packing, and gradation of the particulate reinforcement phases. Practical considerations associated with realization of such composites based on the surface energy between the SiC and the InSn are discussed.     

泡沫铝-复合泡沫冲击韧度及黏弹性分析

泡沫铝-复合泡沫互穿相复合材料是一种新型的结构功能一体化材料,在机械、交通、建筑等领域具有重要的应用前景。本文制备了纯泡沫铝及空心玻璃微珠四种体积分数的泡沫铝-复合泡沫试件,通过摆锤冲击实验研究了其冲击韧度,讨论了其断口形貌与结构性能的关系,通过单轴压缩的应力松弛实验研究其黏弹性性能。研究表明：空心玻璃微珠体积分数为10%的泡沫铝-复合泡沫试件的冲击韧度最大,随后其冲击韧度随空心玻璃微珠体积分数的增加而减小;当空心玻璃微珠体积分数较小时,泡沫铝的结构形貌决定了冲击断口的形貌,但当其体积分数达到30%时,空心玻璃微珠的破坏是形成断口形貌的主要原因;复合材料的黏弹性性能随着玻璃微珠体积分数的增加而增大。