Dynamical enhanced electron emission and discharges at contaminated surfaces

Broad-area electrodes show electron emission already at electric field strengthsF≈10⁷ V/m. This enhanced field emission (EFE) occurs only for contaminated surfaces. EFE is accompanied by photon emission and gas desorption yielding finally discharges. EFE is caused by dust and contaminants initiating the following effects:

an electron is stochastically emitted in a trigger zone

the electron gains energyΔE?eΔxF ^*

which excites electronic states

which relax by the emission of electrons, photons, and atoms

where the positive charges left behind enhanceF ^*=βF (β?1) initiating so an electron avalanche, i.e., a high conductivity channel. Because of charge migration and neutralization, this avalanche has a life time. This pulsating EFE is accompanied by light emission and gas desorption yielding finally a gas cloud and a discharge.

The pulsating, self-sustained EFE has the same root as:

the enhanced secondary emission found first by Malter

the conductivity switching exhibited by thin (≈ 1 μm) layers of semiconductors or insulators

the normal cathode fall and

the firing-wave instability in neurodynamics.

     

Small-angle X-ray scattering on spinodal,nucleotic or coarsening processes in two-phase systems containing spherical,fibrillar or lamellar inhomogeneities

We study the effects of some of the most important and typical structural changes in two-phase systems on selected structural parameters obtained from small-angle x-ray scattering (SAXS) measurements. To limit the present study, it was assumed that the Phase, 1, embedded in the matrix

1. is monodispersed and homogeneous,
2. possesses one of the three most extreme shapes (spherical, fibrillar or lamellar) and
3. changes its behaviour

1. through type change (spinodal or nucleotic or coarsening), without changing the shape,
2. through a change of the shape only, or
3. through a) (type change) and b) (shape change) simultaneously.

To find the type of change for three basically different shapes of Phase 1 and to calculate its intensity (amount of the change) the following three SAXS parameters must be compared before and after the treatment of the system:

1. chord lengthl ₁ (and/or radius of gyrationR),
2. volume partw ₁ of the Phase 1, and
3. relative inner surfaceS _v of the system.

It is shown by this comparison that by the pure type change in the case of

1. spinodal change, all three SAXRS parameters are increasing or decreasing simultaneously and proportional to a power of the intensity of the change,
2. nucleotic change,l ₁ (and/orR) is unchanged, the other two (w ₁ andS _v ) are increasing or decreasing simultaneously and directly proportional to the intensity,
3. coarsening change,w ₁ is unchanged and anincreasing ofl ₁ is always accompanied by adecreasing ofS _v and vice versa.

In addition to this type change, the cases of mere changes of the shape (“shape change”) and finally of simultaneous type and/or shape change are studied. For the case of pure shape change the alteration of the dimensions (chord lengthl ₁ and/or radius of gyrationR) must be followed. The limitations of the analyses of the simultaneous type and/or shape change are discussed in detail.     

The moment of inertia at the saddle point of low energy fission of even-even nuclei

We use the molecular model of low energy fission, which describes the nucleus by two interacting fragments, to calculate the moment of inertia for U²³⁶ in the cranking approximation including BCS theory. We show that the moment of inertia at the saddle point:

1. depends almost linearly on the fragment distance.
2. is influenced only very weakly by the pairing constant and by the fragment deformations.
3. shows, as a function of the distribution of mass between the two fragments (A ₁ ,A ₂ ), a minimum near the magic configurationA ₁=132,Z ₁=50 and depends in this mass region strongly on the term structure near the Fermi energy.
4. is approximately that of a rigid body.

     

An investigation of the axial mode behaviour of a helical TEA-CO2 laser

The frequency behaviour of axial modes was investigated during the initial phase of mode competition in case of a helical TEA-CO₂ laser. With the help of a homodyne technique single-shot and multi-shot beat spectra were measured. Analysing these under various aspects and combining the results of an earlier investigation it was found that

1. inferior modes exist only for 100–200 ns.
2. their spectral width is less than 1 MHz and is determined by lifetime broadening, with the dominant mode narrower than 0.77 MHz,
3. in the average over many shots the spectral envelope of modes does not follow a Lorentzian shape as expected for the Lorentzian gain curve,
4. the beat powers change widely from shot to shot, whereas the total laser power remains constant,
5. no specific phase structures are likely to govern the laser emission, although the maximum emission principle appears to be obeyed with every individual shot. In an appendix relations are derived and summarized which are required for the evaluation of beat mode spectra and for the determination of line width as they apply to the actual time dependence of the laser emission.

     

The possibility of using a semiconductor thermal probe to investigate the power flow distribution in waveguides

Conclusions

1. The temperature profile of an absorbing film for a given microwave power flux distribution has been considered.
2. The conditions under which agreement is found between the temperature relief and the flux distribution has been clarified.
3. An experimental investigation has been carried out of the temperature profile in a matched film for the TE₁₀ mode.
4. The possibility of using a semiconductor thermal probe to investigate the microwave power flux distribution has been demonstrated.

     

SIMS and flash desorption studies of nickel oxygen interaction

O₂ exposure of polycrystalline nickel at 300 K results in characteristics changes of secondary ion emission. These can be described by a model which is in good agreement with corresponding LEED, AES, XPS, and ΔΦ results of other authors. According to this model, oxygen can be bonded on Ni in at least five different phases:

1. chemisorption, indicated by a rapid increase of Ni⁺, Ni ₂ ⁺ , and Ni₂O⁺ (≦5 L);
2. a rearranged chemisorption layer, characterized by a drastic decrease of Ni⁺, Ni ₂ ⁺ , and Ni₂O⁺ (5–15 L);
3. nickel oxide (NiO) responsible for a strong NiO^?- and NiO ₂ ^? -emission (≦40 L);
4. oxygen on top of this NiO layer, producing a final increase of Ni⁺ and NiO⁺ and a O₂-flash signal at 400 K (>40 L);
5. bulk dissolved oxygen in thermal equilibrium with a chemisorption layer (after several exposure/heating cycles).

During ion bombardment of a 100 L O₂ exposed Ni surface these different binding states occur in a reversed order of succession. O₂-flash signals at 400 and 1100 K, related to drastic changes in secondary ion emission at 400, 700, and 1100 K, reflect the disappearance of various oxygen binding states. The exchange between different oxygen phases was studied by¹⁶O₂/¹⁸O₂ isotope experiments.     

A proof of the unitarity ofS-matrix in a nonlocal quantum field theory

Using the formfactors which are entire analytic functions in a momentum space, nonlocality is introduced for a wide class of interaction Lagrangians in the quantum theory of one-component scalar field φ(x). We point out a regularization procedure which possesses the following features:

1. The regularizedS ^δ matrix is defined and there exists the limit $$\mathop {\lim }\limits_{\delta \to 0} S^\delta = S.$$
2. The Green positive-frequency functions which determine the operation of multiplication in \(S \cdot S^ + \mathop = \limits_{Df} S \circledast S^ + \) can be also regularized ?^δ and there exists the limit $$\mathop {\lim }\limits_{\delta \to 0} \circledast ^\delta = \circledast \equiv .$$
3. The operator \(J(\delta _1 ,\delta _2 ,\delta _3 ) = S^{\delta _1 } \circledast ^{\delta _2 } S^{\delta _3 + } \) is continuous at the point δ₁=δ₂=δ₃=0.
4. $$S^\delta \circledast ^\delta S^{\delta + } \equiv 1at\delta > 0.$$ Consequently, theS-matrix is unitary, i.e. $$S \circledast S^ + = S \cdot S^ + = 1.$$

     

Spin-order and magnetic properties of BaZn2Fe16O27 (Zn2-W) hexagonal ferrite

We have observed large peaks in the ultrasonic attenuation of a pure and two doped LaAl₂ crystals in the temperature region of about 45 K which are possibly of the Bordoni type. Their most interesting characteristics are:

1. There is only one peak in each sample.
2. The peaks are so narrow that they can be described by the original Seeger model with only one actication energy and one attempt frequency.

     

Magnetostriction measurement by means of strain modulated ferromagnetic resonance (SMFMR)

A novel method for measuring magnetostriction constants is presented. A strain, periodic in time, applied to the sample, causes a modulation of the ferromagnetic resonance line position. The height of the signal obtained after phase-sensitive detection is proportional to the strain modulation depth. The appropriate magnetostriction constant λ is obtained by comparing the height of the SMFMR signal with that of the FMR line, as recorded by means of magnetic field modulation. Features of the new technique are:

1. high sensitivity: λ_min? 10_?9 forM=100 Oe and linewidth ΔH _d=1 Oe;
2. λ's belonging to distinct precession modes are separately determined;
3. applicable to thin layers for which strain gauge techniques cannot be used;
4. wide temperature range: 1.2 K<T<300 K;
5. uniform stress.

An illustrative example (YIG layer on GGG substrate) is given.     

Infrared and conductivity studies on blends of PMMA/PEO based polymer electrolytes

Poly(methylmetacrylate)/poly(ethylene oxide) (PMMA/PEO) based polymer electrolytes were synthesized using the solution cast technique. Four systems of PMMA/PEO blends based polymer electrolytes films were investigated:

1. PMMA/PEO system,
2. PMMA/PEO + ethylene carbonate (EC) system,
3. PMMA/PEO + lithium hexafluorophosphate (LiPF₆) system and
4. PMMA/PEO + EC + LiPF₆ system.

The polymer electrolytes films were characterized by Impedance Spectroscopy and Fourier Transform Infrared Spectroscopy (FTIR). The FTIR spectra show the complexation occurring between the polymers, plasticizer and lithium salt. The FTIR results give further insight in the conductivity enhancement of PMMA/PEO blends based polymer electrolytes.     

Construction of Euclidean (QED)2 via lattice gauge theory

Let ν=det_ren(1+K _g ) be the renormalized Matthews-Salam determinant of (QED)₂, where \(K_g = ieA_{g,} S = \left( {\sum {\gamma _\mu \partial } _\mu + m} \right)^{ - 1} \) is euclidean fermion propagator of one of the following boundary conditions: (1) free, (2) periodic at ?Λ, Λ=[?L/2;L/2]², (3) anti-periodic at ?Λ, and \(A_g (x) = (\sum \gamma _\mu A_\mu (x))g(x)\) . Hereg(x)=1 ifxεΛ₀=[?r/2,r/2]² с Λ and 0 otherwise. Then we show

1. νεL ^p (dμ(A)), p>0. Further we prove a new determinant inequality which holds for the QED, QCD-type models containing fermions. This enables us to prove:
2. Z(Λ₀)=∫νdμ(A)≦exp[c|Λ₀|]. Similar volume dependence is shown for the Schwinger functions.

     

Bounds on the number of eigenvalues of the Schrödinger operator

Inequalities on eigenvalues of the Schrödinger operator are re-examined in the case of spherically symmetric potentials. In particular, we obtain:

1. A connection between the moments of order (n ? 1)/2 of the eigenvalues of a one-dimensional problem and the total number of bound statesN _n, inn space dimensions;
2. optimal bounds on the total number of bound states below a given energy in one dimension;
3. alower bound onN ₂;
4. a self-contained proof of the inequality for α ≧ 0,n ≧ 3, leading to the optimalC ₀₄,C ₃;
5. solutions of non-linear variation equations which lead, forn ≧ 7, to counter examples to the conjecture thatC _0n is given either by the one-bound state case or by the classic limit; at the same time a conjecture on the nodal structure of the wave functions is disproved.

     

Magnetische und kalorische Eigenschaften von Alkali-Hyperoxid-Kristallen

The phase transitions of Alkali-Hyperoxide crystals (NaO₂, KO₂, RbO₂, and CsO₂) grown in liquid ammonia have been investigated by means of the following measurements:

1. magnetic susceptibility
2. differential magnetic susceptibility as magnetic field
3. magnetization curve in static and pulsed fields
4. specific heat.

The anomalies of the specific heat could be correlated with the magnetic properties and structural changes. Several new phase transitions were found. The magnetic behaviour of NaO₂ indicates magnetic order (of as yet unknown nature) at low temperatures. The magnetic and caloric behaviour of KO₂ at low temperatures is compatible with a Néel point at 7 K. A metamagnetic transition can be induced at temperatures below 12 K with fields of about 70 kOe. This transition is connected with structural changes. RbsO₂ and CO₂ are probably antiferromagnetic with Néel temperatures of 15 K and 9.6 K, respectively.     

Nachwirkungsmechanismen in Ferriten

In ferrites a large number of after-effects are found, with time constants between nano-seconds and years. In this review the after-effects due to ion-and electron motion will be treated. One finds:

1. single-ion effects in combination with lattice deformations, e.g. Mn³⁺;
2. ion effects caused by mobile vacancies, e.g. Co²⁺;
3. effects due to electron transfer:
4. Co²⁺?Co³⁺
5. Me²⁺?Fe³⁺, in combination with Me⁴⁺ and vacancies.
6. Me⁴⁺?Fe²⁺, with Me=Si, Ti (photomagnetic effect).

The electron transfer is found to be related to electrical effects. In analogy to the photoelectric effect, one has found that illumination produces changes in magnetic properties. Generally speaking, one has in ferrites as many problems with donors and acceptors as in other semiconductors. Information from magnetic measurements helps to elucidate their nature.     

Spatial representation of groups of automorphisms of von Neumann algebras with properly infinite commutant

Theorem. Let a topological groupG be represented (a→φ _a ) by *-automorphisms of a von Neumann algebraR acting on a separable Hilbert spaceH. Suppose that

1. G is locally compact and separable,
2. R′ is properly infinite,
3. for anyT∈R,x,y∈H the function

$$a \to \left\langle {\phi _a (T)x,y} \right\rangle _H $$ is measurable onG. Then there exists a strongly continuous unitary representation ofG onH,a→U _a , such that forT∈R,a∈G, $$\phi _\alpha (T) = U_a TU_a *.$$ .     

Absence of singular continuous spectrum for certain self-adjoint operators

We give a sufficient condition for a self-adjoint operator to have the following properties in a neighborhood of a pointE of its spectrum:

1. its point spectrum is finite;
2. its singular continuous spectrum is empty;
3. its resolvent satisfies a class of a priori estimates.

     

Versuche zum toroidalen Einschluß von Hoch-Beta-Plasmen mit Hilfe von helischen Multipolfeldern

Helical multipole fields with multiplicities of 1 to 3 and up to 16 field cycles around the circumference of the torus are superposed on a toroidal theta pinch. The vacuum fields of the configurations are calculated and regions of closed flux surfaces are found. The experimental results are:

1. Equilibria of High-Beta plasmas also exist, if the vacuum field has no absolute minimum, provided that the region of closed flux surfaces in the vacuum field has a greater diameter than the plasma, and that the helical multipole fields do not periodically increase and decrease the gradient of the toroidal main field. These equilibria are possibly unstable.
2. If the helical multipole fields periodically increase and decrease the gradient of the theta pinch field along the circumference of the torus there is no equilibrium, even if the helical curvature of the field lines is great.
3. The main cause of the losses is the escape of particles along the field lines.

     

New developments and trends in NMR-ON

New developments and new trends in NMR-ON are presented, especially in the context of precise measurements of nuclear magnetic moments and electric quadrupole moments of short-lived nuclei far off stability with on-line nuclear orientation techniques. The main emphasis is put on the following items:

1. Quadrupole-interaction-resolved NMR-ON (QI-NMR-ON): It is shown that hcp-Co is an ideal matrix for precise measurements of electric quadrupole moments of radioactive nuclei in the region Hg, Au, Pt, Ir, Os. Recently, the first on-line experiment was performed successfully at NICOLE/ISOLDE-CERN and the very interesting quadrupole moment of¹⁸⁶Au could be determined precisely.
2. General problems with lattice location and NMR-ON line widths in long decay chains, such as “lattice-site conservation” by implantation of a suitable precursor.
3. β-decay-induced lattice site change. In the context of integral nuclear orientation measurements on nuclei far off stability, where the β-decay energies become large, lattice site changes may occur, which make the interpretation of γ-anisotropies measured by integral and even time-differential techniques difficult or even impossible. A pilot experiment is described, in which such a β-decay-induced lattice site change has been identified by a double-resonance NMR-ON measurement.

     

Polarization effects of picosecond CARS in liquids

Coherent Raman scattering of delayed probing pulses after ultrafast excitation is investigated under generalized polarization conditions. Three factors are shown to contribute to the scattering signal:

1. scattering off the isotropic part of the resonant material excitation via the isotropic component of the Raman polarizability
2. scattering via the anisotropic part of the Raman polarizability from a second, oriented component of the resonant material excitation
3. four-wave mixing via the non-resonant part χ_NR of the third-order susceptibility. We demonstrate theoretically and experimentally that different polarization conditions lead to drastic changes of the signal transients in liquids. For the ring breathing mode of C₆H₅Br the ratio of non-resonant to resonant contributions is measured to be χ_NR/χ_res=0.037±0.015.