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1.
E. Yang Zhao‐Ji Li Jian Zhang Yu‐Biao Chen Yuan‐Gen Yao 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(9):m457-m459
The reaction of cadmium chloride with pyridine‐2,6‐dicarboxylic acid (PDA) and 98% H2SO4 in ethanol led to the formation of the title compound, bis[μ‐6‐(ethoxycarbonyl)pyridine‐2‐carboxylato]‐1:2κ4O6,N,O2:O2;1:2κ4O2:O2,N,O6‐bis[diaquachlorocadmium(II)] dihydrate, [Cd2(C9H8NO4)2Cl2(H2O)4]·2H2O. PDA is esterified to monoethyl pyridine‐2,6‐dicarboxylate (MEPD) by the catalysis of H2SO4 during the reaction. The dinuclear CdII complex lies about an inversion centre and the unique Cd atom has a pentagonal–bipyramidal geometry. The two Cd atoms are bridged by two carboxylate O atoms, forming a planar Cd2O2 unit. Stair‐like chains are formed via O—H⋯Cl hydrogen bonds and these are further arranged into two‐dimensional layers via hydrogen bonds involving solvate water molecules. 相似文献
2.
Nobuo Okabe Naomi Oya 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(12):1416-1417
In the structure of the title compound, [Mn2(C7H3NO4)2(H2O)6]·2C7H5NO4, a centrosymmetric dinuclear complex, hexaaaquabis(pyridine‐2,6‐dicarboxylato)dimanganese(II) and free pyridine‐2,6‐dicarboxylic acid are present in a 1:2 ratio. In the complex, each Mn2+ ion is coordinated by three O atoms and one N atom from the pyridine‐2,6‐dicarboxylate ligands and by three water O atoms, resulting in a distorted pentagonal bipyramidal coordination. Within the centrosymmetric dinuclear complex, two Mn2+ ions are bridged by two carboxylate O atoms. The crystal structure is stabilized by hydrogen bonds involving all the H atoms of the water ligands. 相似文献
3.
Chun‐Bo Liu Guang‐Bo Che Chuan‐Bi Li Yun‐Cheng Cui 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(4):m153-m155
An in situ reaction under hydrothermal conditions leads to the formation of the title compound, diaqua(pyridine‐2‐carboxylato)(pyridine‐2,6‐dicarboxylato)indium(II) trihydrate, [In(C6H4NO2)(C7H3NO4)(H2O)2]·3H2O, in which the central InIII atom is seven‐coordinated by one pyridine‐2,6‐dicarboxylate ligand, one pyridine‐2‐carboxylate ligand and two water molecules in a pentagonal–bipyramidal coordination environment. An indium(III)–water chain based on an unusual water pentamer is observed. 相似文献
4.
Annegret K. Hall Jack M. Harrowfield Brian W. Skelton Allan H. White 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(4):407-411
The sodium salt of a complex anion formed between gadolinium(III) and three variously deprotonated chelidamic acid (4‐hydroxypyridine‐2,6‐dicarboxylic acid) ligand moieties, assigned as Na5[Gd(C7H2NO5)2(C7H3NO5)]·16H2O, i.e. pentasodium (4‐hydroxypyridine‐2,6‐dicarboxylate)bis(4‐oxidopyridine‐2,6‐dicarboxylate)gadolinium(III) hexadecahydrate, forms as colourless monoclinic crystals upon vapour diffusion of ethanol into its aqueous solution. The ligand moieties, assigned as two trianionic and one dianionic chelidamate species, are all tridentate in the complex anion of tricapped trigonal prismatic donor‐atom geometry. The geometry of the ligands and that of the primary coordination sphere is very similar to that of the analogous anionic tris(ligand)–rare earth complexes of the pyridine‐2,6‐dicarboxylate (dipicolinate) dianion. 相似文献
5.
Ying‐Quan Zou Xia Li Yan Li Huai‐Ming Hu 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(9):1048-1050
The title compound, tetrakis(μ‐2,3‐dimethoxybenzoato)‐κ4O:O′;κ6O,O′:O′‐bis[(2,2′‐bipyridine‐N,N′)(2,3‐dimethoxybenzoato‐O,O′)lanthanum(III)], [La2(2,3‐DMOBA)6(2,2′‐bpy)2], where 2,3‐DMOBA is 2,3‐dimethoxybenzoate (C9H9O4) and 2,2′‐bpy is 2,2′‐bipyridine (C10H8N2), is a dimer with a centre of inversion between the La atoms bridged by four carboxylate ligands. The central La atom is ennea‐coordinated and has a distorted monocapped square‐antiprism geometry. 相似文献
6.
Satyanarayan Pal Samudranil Pal 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(5):m273-m274
In the title complex, [RuCl2(C7H7NO)(C2H6OS)2], the metal ion is at the centre of a distorted octahedral NOCl2S2 coordination sphere. The neutral 2‐acetylpyridine ligand binds to the metal ion through the pyridine N and carbonyl O atoms, forming a five‐membered chelate ring. The monodentate S‐coordinating dimethyl sulfoxide molecules are mutually cis, and the two remaining positions in the coordination sphere are occupied by two mutually trans Cl? ions. 相似文献
7.
Maurice Abou Rida Joseph Saikaili Anthony K. Smith Alain Thozet 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(4):352-353
The title compound, dicarbonyl‐1κ2C‐di‐μ‐chloro‐1:2κ4Cl‐[cis,cis‐2(η4)‐1,5‐cyclooctadiene]dirhodium(I), [Rh2Cl2(C8H12)(CO)2], consists of a dichloro‐bridged dimer of rhodium, with a non‐bonded Rh?Rh distance of 3.284 (2) Å. One Rh atom is coordinated to two carbonyl ligands, while the other Rh atom is coordinated to the cyclooctadiene moiety. 相似文献
8.
Wen‐Na Zhao Jian‐Wei Zou Qing‐Shen Yu 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(9):m443-m444
The title one‐dimensional chain nickel(II)–disulfide complex, [Ni(C14H8O4S2)(C5H5N)2(H2O)]n, has each NiII cation coordinated by two N atoms from two pyridine ligands, three carboxylate O atoms from two different dithiodibenzoate ligands and one O atom from a coordinated water molecule, in a distorted octahedral coordination geometry. Each dithiodibenzoate ion links two NiII cations through its carboxylate O atoms, making the structure polymeric. Hydrogen‐bond interactions between two shoulder‐to‐shoulder chains lead to the formation of a ladder‐like structure. 相似文献
9.
Sara K. Metcalf Elizabeth M. Holt 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(10):1228-1231
Diethyl 4‐(2,5‐dimethoxyphenyl)‐2,6‐dimethyl‐1,4‐dihydropyridine‐3,5‐dicarboxylate, C21H27NO6, (I), diethyl 4‐(3,4‐dimethoxyphenyl)‐2,6‐dimethyl‐1,4‐dihydropyridine‐3,5‐dicarboxylate, C21H27NO6, (II), and diethyl 2,6‐dimethyl‐4‐(3,4,5‐trimethoxyphenyl)‐1,4‐dihydropyridine‐3,5‐dicarboxylate, C22H29NO7, (III), crystallize with hydrogen‐bonding networks involving the H atom bonded to the N atom of the 1,4‐dihydropyridine ring and carbonyl O atoms in (I) and (II). Unusually, (III) shows O atoms of methoxy groups serving as hydrogen‐bond acceptors. 相似文献
10.
Il Yoon Byeong Soon Yoo Shim Sung Lee Bong Gon Kim 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(7):758-759
The preparation and crystal structure of the title compound, cis‐dichloro[6,9‐dioxa‐3,12‐dithiabicyclo[12.4.0]octadeca‐14,‐16,18(1)‐triene‐S,S′]palladium(II), [PdCl2(C14H20O2S2)], are described. The Pd atom has a square‐planar environment, coordinated to two S atoms of the dithiadioxa macrocycle and to two Cl? ions. The non‐coordinating O atoms are oriented away from the metal coordination plane. Upon complexation, a bicyclic chelate structure, which consists of a seven‐ and an eleven‐membered ring, is formed. 相似文献
11.
Li‐Ming Wu Ling Chen Jingcao Dai Ping Lin Wen‐Xin Du Xin‐Tao Wu 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(9):e382-e382
The title compound, [Sn(C5H5NS)2(C2H4S2)2], was obtained from a 1:2 mixture of bis(ethane‐1,2‐dithiolato)tin(IV) and 2‐mercaptopyridine. The molecules are discrete monomeric trans‐octahedral units, with the SnIV atom at the centre of symmetry, planar 2‐mercaptopyridine zwitterions and SnS2C2 groups in twist–envelope conformations. The 2‐mercaptopyridine ligands are monodentate and are bonded through the S atoms. The S—Sn distances between the S atom of edt (edt is ethane‐1,2‐dithiolate) and the Sn atom are 2.473 (1) and 2.505 (1) Å, which are slightly longer than the S—Sn distance in Sn(edt)2 of 2.390 (1) Å. The bond between the 2‐mercaptopyridine S atom and the Sn atom are, remarkably, weaker than the S—Sn bond involving edt. 相似文献
12.
Andrew Bond William Jones 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(4):436-437
The title compound, [Mg(C5H4NOS)2(H2O)2]·C10H8N2O2S2, is a two‐component host–guest material. The 2,2′‐dithiobis(pyridine N‐oxide) molecule has crystallographic twofold symmetry. The metal complex lies on an inversion centre and associates via C—H?S interactions into chains which thread the 2,2′‐dithiobis(pyridine N‐oxide) lattice in perpendicular directions. Hydrogen bonds exist between the water molecules of the diaquamagnesium units and the N—O groups of the host lattice. 相似文献
13.
Uwe‐Christoph Knig Michael Berkei Frank Neikes Hans Preut Terence Nigel Mitchell 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(3):324-326
The single‐crystal X‐ray structure determinations of the title complexes, cis‐dichloro‐trans‐dimethyl‐cis‐bis(N‐methylpyrrolidin‐2‐one‐O)tin(IV), [Sn(CH3)2Cl2(C5H9NO)2], cis‐dibromo‐trans‐dimethyl‐cis‐bis(N‐methylpyrrolidin‐2‐one‐O)tin(IV), [SnBr2(CH3)2(C5H9NO)2], and cis‐diiodo‐trans‐dimethyl‐cis‐bis(N‐methylpyrrolidin‐2‐one‐O)tin(IV), [Sn(CH3)2I2(C5H9NO)2], show that those tin complexes in which coordination of the lactam ligand to SnIV is realized via oxygen exhibit a distorted octahedral geometry. 相似文献
14.
Jason Shearer Werner Kaminsky Julie A. Kovacs 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(9):m379-m380
A trimeric compound containing CoII is described, namely tris{μ‐2‐[3‐(dimethylamino)propylimino]propane‐1‐thiolato}tricobalt(II) chloride bis(hexafluorophosphate), [Co3(C10H21N2S)3]Cl(PF6)2. Each Co atom is ligated by one 2‐[3‐(dimethylamino)propylimino]propane‐1‐thiolate ligand, an amine group and an imine group. The thiolate groups bridge the Co atoms, forming a six‐membered ring that encloses the chloride ion in a well defined binding pocket. 相似文献
15.
Ramis Rao Subramanian Shanmuga S. Anandan Kuan Hiang Kwek Kum Sang Low S. Shanmuga Sundara Raj Hoong‐Kun Fun Ibrahim Abdul Razak John V. Hanna Seik Weng Ng 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(7):e292-e294
The monoclinic cell of dicyclohexylammonium 2,4‐dichlorophenoxyacetate contains four C12H24N+·C5H8Cl2O3? ion pairs. The ammonium N atom is hydrogen bonded to the oxygen ends of two carboxyl groups to form a 12‐membered O—C—O?HNH?O—C—O?HNH ring. In (2,4‐dichlorophenoxylacetato)bis(triphenylphosphine)silver(I), [Ag(C8H5Cl2O3)(C18H15P)2], the carboxyl CO2 unit chelates to the Ag atom in an anisobidentate manner [Ag—O = 2.436 (2) and 2.517 (2) Å]; the Ag atom shows distorted tetrahedral geometry. 相似文献
16.
Kai Liang Yi‐Zhi Li He‐Gen Zheng Xin‐Quan Xin 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(8):m310-m312
In the title compound, [1,4‐bis(diphenylphosphino)butane‐2κ2P,P′]di‐μ‐thio‐1:2κ4S‐dithio‐1κ2S‐palladium(II)tungsten(VI) N,N′‐dimethylformamide hemisolvate hemihydrate, [PdWS4(C28H28P2)]·0.5C3H7NO·0.5H2O, the Pd atom is coordinated by two S atoms from the distorted‐tetrahedral [WS4]2− anion and two P atoms from the dppb molecule [dppb is 1,4‐bis(diphenylphosphino)butane] in an approximately square‐planar configuration. A puckered seven‐membered ring is formed by the Pd atom and the dppb ligand. 相似文献
17.
Ana María Atria Piedad Corts María Teresa Garland Ricardo Baggio 《Acta Crystallographica. Section C, Structural Chemistry》2003,59(10):m396-m398
The structures of aquadichlorobis(1H‐imidazole)cobalt(II), [CoCl2(Him)2(H2O)2] (Him is 1H‐imidazole, C3H4N2), (I), and aquadichlorobis(1H‐imidazole)nickel(II), [NiCl2(Him)2(H2O)2], (II), are isomorphous and consist of monomers with inversion symmetry. The three monodentate ligands (imidazole, chlorine and aqua), together with their symmetry equivalents, define almost perfect octahedra. Hydrogen‐bonding interactions via the imidazole and aqua H atoms lead to a three‐dimensional network. 相似文献
18.
Uwe Kolitsch 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(3):m129-m133
Rubidium chromium(III) dioxalate dihydrate [diaquabis(μ‐oxalato)chromium(III)rubidium(I)], [RbCr(C2O4)2(H2O)2], (I), and dicaesium magnesium dioxalate tetrahydrate [tetraaquabis(μ‐oxalato)magnesium(II)dicaesium(I)], [Cs2Mg(C2O4)2(H2O)4], (II), have layered structures which are new among double‐metal oxalates. In (I), the Rb and Cr atoms lie on sites with imposed 2/m symmetry and the unique water molecule lies on a mirror plane; in (II), the Mg atom lies on a twofold axis. The two non‐equivalent Cr and Mg atoms both show octahedral coordination, with a mean Cr—O distance of 1.966 Å and a mean Mg—O distance of 2.066 Å. Dirubidium copper(II) dioxalate dihydrate [diaquabis(μ‐oxalato)copper(II)dirubidium(I)], [Rb2Cu(C2O4)2(H2O)2], (III), is also layered and is isotypic with the previously described K2‐ and (NH4)2CuII(C2O4)2·2H2O compounds. The two non‐equivalent Cu atoms lie on inversion centres and are both (4+2)‐coordinated. Hydrogen bonds are medium‐strong to weak in the three compounds. The oxalate groups are slightly non‐planar only in the Cs–Mg compound, (II), and are more distinctly non‐planar in the K–Cu compound, (III). 相似文献
19.
Seik Weng Ng S. Shanmuga Sundara Raj Hoong‐Kun Fun Ibrahim Abdul Razak James M. Hook 《Acta Crystallographica. Section C, Structural Chemistry》2000,56(8):966-968
catena‐Poly[dicyclohexylammonium [tributyltin‐μ‐(4‐oxo‐4H‐pyran‐2,6‐dicarboxylato‐O2:O6)]], (C12H24N)[Sn(C7H2O6)(C4H9)3], consists of 4‐oxo‐4H‐pyran‐2,6‐dicarboxylato groups that axially link adjacent tributyltin units into a linear polyanionic chain. The ammonium counter‐ions surround the chain, and each cation forms a pair of hydrogen bonds to the double‐bond carbonyl O atoms of the same dianionic group. The chain propagates in a zigzag manner along the c axis of the monoclinic cell. In catena‐poly[methyl(phenyl)ammonium [tributyltin‐μ‐(pyridine‐2,6‐dicarboxylato‐O2:O6)]], (C7H10N)[Sn(C7H3NO4)(C4H9)3], the pyridine‐2,6‐dicarboxylato groups also link the tributyltin groups into a chain, but the hydrogen‐bonded chain propagates linearly on the ac face of the monoclinic cell. 相似文献
20.
Eleonora Freire Sergio Baggio Leopoldo Suescun Ricardo Baggio 《Acta Crystallographica. Section C, Structural Chemistry》2001,57(8):905-908
Three cis nickel–dithiocyanate (SCN) complexes with different N,N′‐bidentate bases have been prepared and their crystal structures determined: bis(2,2′‐bipyridine‐N,N′)bis(thiocyan‐ato‐N)nickel(II), [Ni(SCN)2(C10H8N2)2], bis(1,10‐phenanthroline‐N,N′)bis(thiocyanato‐N)nickel(II), [Ni(SCN)2(C12H8N2)2], and bis(2,9‐dimethyl‐1,10‐phenanthroline‐N,N′)bis(thiocyanato‐N)nickel(II) monohydrate, [Ni(SCN)2(C12H8N2)2]·H2O. Distortions due to ligand size are discussed. 相似文献