Atomic O and H exposure of C-covered and oxidized d-metal surfaces

Carbon coverage, oxidation and reduction of Au, Pt, Pd, Rh, Cu, Ru, Ni and Co layers of 1.5 nm thickness on Mo have been characterized with ARPES and desorption spectroscopy upon exposure to thermal H and O radicals. We observe that only part of the carbon species is chemically eroded by atomic H exposure, yielding hydrocarbon desorption. Exposure to atomic O yields complete carbon erosion and CO₂ and H₂O desorption. A dramatic increase in metallic and non-metallic oxide is observed for especially Ni and Co surfaces, while for Au and Cu, the sub-surface Mo layer is much more oxidized. Although volatile oxides exist for some of the d-metals, there is no indication of d-metal erosion. Subsequent atomic H exposure reduces the clean oxides to a metallic state under desorption of H₂O. Due to its adequacy, we propose the atomic oxygen and subsequent atomic hydrogen sequence as a candidate for contamination removal in practical applications like photolithography at 13.5 nm radiation.     

Laser cladding of copper with molybdenum for wear resistance enhancement in electrical contacts

Laser cladding of Mo on Cu has been attempted with the aim of enhancing the wear resistance and hence increasing the service life of electrical contacts made of Cu. In order to overcome the difficulties arising from the large difference in thermal properties and the low mutual solubility between Cu and Mo, Ni was introduced as an intermediate layer between Mo and Cu. The Ni and Mo layers were laser clad one after the other to form a sandwich layer of Mo/Ni/Cu. Excellent bonding between the clad layer and the Cu substrate was ensured by strong metallurgical bonding. The hardness of the surface of the clad layer is seven times higher than that of the Cu substrate. Pin-on-disc wear tests consistently showed that the abrasive wear resistance of the clad layer was also improved by a factor of seven as compared with untreated Cu substrate. The specific electrical contact resistance of the clad surface was about 5.6 × 10⁻⁷ Ω cm².     

Hyperfine structure of highly charged ions

¹⁹⁷Au Mössbauer spectra from Au/TM (TM = Fe, Co, Ni) multilayers consist mainly of two components. One component shows a large hyperfine magnetic field due to the hybridization at the interface between Au and ferromagnetic layers. The other component is nonmagnetic arising from the middle part of the Au layers. From the fractional area of the magnetic components in each spectrum, the Au atoms in 0.4 nm Au layers are perturbed by the Fe and Ni layers, and Co layers perturb 0.3 nm Au layers at the interface.     

A rutherford scattering study of the diffusion of heavy metal impurities in silicon to ion-damaged surface layers

Rutherford backscattering of 1.75 and 2 MeV ⁴He⁺ ions has been utilized to study the high temperature gettering of Fe, Co, Ni, Cu and Au from silicon by ion-damaged surface layers. In a typical experiment a metal film was evaporated onto one side of a silicon wafer (125 microm thick) which had received ion implantation damage (10¹⁶/cm² Si⁺ ions at 100 keV) on the opposite side; the wafer was then annealed at 900°C, usually for 30 min. The results of such experiments show that the metals studied may be divided into two classes, those which are gettered slowly - Fe, Co, and Au, and those gettered rapidly - Cu and Ni. Fe, Co, and Au were found at levels of 1×10¹³?1×10¹⁴/cm² in the damaged layer, whereas Cu and Ni appeared at levels of 6×10¹⁴ to 5 ×10¹⁶cm². The gettered level of Au, one of the “slow” group, was increased ten-fold by an equal increase in the anneal time to 300 min. The gettered Cu and Au exhibited double peaks in the scattered ion spectra, corresponding to metal concentrated at the most heavily damaged region (end of range for Si implant) and also at the outer surface, with a separation of ~ 1300 Å. A simple model is proposed to explain the slow and fast gettering, based on published interstitial diffusivities and solubilities of the five elements studied.Rutherford scattering has proven to be well suited for the quantitative identification of low levels of impurities on Si surfaces and for impurities gettered at damaged layers close to the surface.     

Strain field due to transition metal impurities in Ni and Pd

The strain field due to body centered substitutional transition metal impurities in Ni and Pd metals are investigated. The calculations are carried out in the discrete lattice model of the metal using Kanzaki lattice static method. The effective ion-ion interaction potential due to Wills and Harrison is used to evaluate dynamical matrix and the impurity-induced forces. The results for atomic displacements due to 3d, 4d and 5d impurities (Fe, Co, Cu, Nb, Mo, Pd, Pt and Au) in Ni and (Fe, Co, Cu, Ni, Nb, Mo, Pt and Au) impurities in Pd are given up to 25 NN’s of impurity and these are compared with the available experimental data. The maximum displacements of 4.6% and 3.8% of 1NN distance are found for NiNb and PdNb alloys respectively, while the minimum displacements of 0.63% and 0.23% of 1NN distance are found for NiFe and PdFe alloys respectively. Except for Cu, the atomic displacements are found to be proportional to the core radii and d state radius. The relaxation energies for 3d impurities are found less than those for 4d and 5d impurities in Ni and Pd metals. Therefore, 3d impurities may easily be solvable in these metals.     

Effects of Ni buffer layer on giant magnetoresistance in Co/Cu/Co sandwich

In order to increase the sensitivity of Co/Cu/Co sandwiches, different thickness Ni layers were used as buffer layer. It was found that in the Co 55 Å/Cu 35 Å/Co 55 Å sandwiches with different thickness Ni buffer layers, MR ratios between 3.5% and 5.6% could be obtained, and the coercive forces were about 12 Oe. Hence, the maximum field sensitivity could be enhanced to about 1%/Oe. Further investigation from the results of atomic force microscopy showed the improvement of the interfacial flatness in the sandwiches with Ni buffer layer. The microstructure observed by high-resolution electron microscope demonstrated the different structure of the two Co layers in the Ni buffered sandwich, which directly determined the small saturation field of the sandwich. This was confirmed by the magnetic behaviors of the two Co layers calculated from the experimental hysteresis loops. All these showed that the usage of a Ni buffer layer could result in interfacial improvement, different crystalline structure, and small saturation field in the Co/Cu/Co sandwich. These enhanced the electron spin scattering at the Co–Cu interfaces and finally enlarged the giant magnetoresistance and the sensitivity in the sandwich.     

CdTe太阳电池的不同背电极和背接触层的特性研究

用Ni替代Au来作为CdTe太阳电池的背电极，比较了Ni,Ni/Au,Au/Ni及Au背电极对电池性能的影响.发现Ni作为背电极和ZnTe/ZnTe:Cu复合层接触，电池的开路电压V_oc略有降低，填充因子FF有增有减，变化幅度不大，但因短路电流I_sc有较大的提高，转换效率η平均增长4％.测试了不同背电极的CdTe太阳电池的暗I-V和C-V特性，对背电极剥离后的样品进行了XPS测试分析.结果表明，Ni扩散到ZnTe/ZnTe:Cu复合层的深度比Au多，且大多呈离子态，与ZnTe/ZnTe:Cu复合层中的富Te离子形成Ni_xTe，提高了掺杂浓度，使电池性能获得改善. 关键词： 金属背电极 复合背接触层 转换效率 CdTe太阳电池     

Estimating the Critical Glass Transition Rate of Pure Metals Using Molecular Dynamic Modeling

Doklady Physics - The critical cooling rates $${{{v}}_{{\text{c}}}}$$ at which pure metals Mg, Al, Ti, Fe, Co, Ni, Cu, Zr, Mo, Pd, Ag, Ta, W, Pt, Au, and Pb transit to an amorphous state (vitrify),...     

Work function engineering and its applications in ohmic contact fabrication to II-VI semiconductors

CdTe and the associated materials are suffering from ohmic contacting problem due to their high electron affinity and consequently large function. Ni, Au, Pt and Pd have large work function and have possibility to match with CdTe. However, except Ni other materials have problems in large-scale applications. In the present paper possibility of Ni has been explored through work function engineering. Work function and bulk resistivity of Ni has been modulated with other materials like, Cu, Au, Mo, W and Co. A theoretical model has been developed to calculate the effective work function and bulk resistivity after modulation. Modulated materials have been deposited over thin film CdTe using electroless technique to evaluate the validity between the theoretical and experimental results. Results indicated about good matching between them.To the best of knowledge this is the first time applications on such type of methodology has presented in contact applications to CdTe.     

Surface modification of Ni and Co metal nanowires through MeV high energy ion irradiation

Nickel (Ni) and cobalt (Co) metal nanowires were fabricated by using an electrochemical deposition method based on an anodic alumina oxide (Al₂O₃) nanoporous template. The electrolyte consisted of NiSO₄ · 6H₂O and H₃BO₃ in distilled water for the fabrication of Ni nanowires, and of CoSO₄ · 7H₂O with H₃BO₃ in distilled water for the fabrication of the Co ones. From SEM and TEM images, the diameter and length of both the Ni and Co nanowires were measured to be ∼ 200 nm and 5–10 μm, respectively. We observed the oxidation layers in nanometer scale on the surface of the Ni and Co nanowires through HR–TEM images. The 3 MeV Cl²⁺ ions were irradiated onto the Ni and Co nanowires with a dose of 1 × 10¹⁵ ions/cm². The surface morphologies of the pristine and the 3 MeV Cl²⁺ ion-irradiated Ni and Co nanowires were compared by means of SEM, AFM, and HR–TEM experiments. The atomic concentrations of the pristine and the 3 MeV Cl²⁺ ion-irradiated Ni and Co nanowires were investigated through XPS experiments. From the results of the HR–TEM and XPS experiments, we observed that the oxidation layers on the surface of the Ni and Co nanowires were reduced through 3 MeV Cl²⁺ ion irradiation.     

ESD on metal oxides and oxygen adsorption layers: Evidence for different mechanisms in electron stimulated desorption

Electron stimulated desorption (ESD) of several metal oxides (W, Mo, Ta, Fe, Ni, and Cu oxide) and oxygen adsorption layers on Ni and Fe has been investigated. ESD of O⁺ from oxides can be easily understood in terms of the Auger decay model for ESD proposed recently by Knotek and Feibelman (KF). The measured O⁺ desorption from oxygen adsorption layers on Fe and Ni however, can hardly be explained in the frame of the KF model. There is strong evidence that at least two different ESD mechanisms are operative for ionically and covalently bound oxygen, respectively.     

The role of phase separation for self-organized surface pattern formation by ion beam erosion and metal atom co-deposition

We investigate the ripple pattern formation on Si surfaces at room temperature during normal incidence ion beam erosion under simultaneous deposition of different metallic co-deposited surfactant atoms. The co-deposition of small amounts of metallic atoms, in particular Fe and Mo, is known to have a tremendous impact on the evolution of nanoscale surface patterns on Si. In previous work on ion erosion of Si during co-deposition of Fe atoms, we proposed that chemical interactions between Fe and Si atoms of the steady-state mixed Fe _x Si surface layer formed during ion beam erosion is a dominant driving force for self-organized pattern formation. In particular, we provided experimental evidence for the formation of amorphous iron disilicide. To confirm and generalize such chemical effects on the pattern formation, in particular the tendency for phase separation, we have now irradiated Si surfaces with normal incidence 5 keV Xe ions under simultaneous gracing incidence co-deposition of Fe, Ni, Cu, Mo, W, Pt, and Au surfactant atoms. The selected metals in the two groups (Fe, Ni, Cu) and (W, Pt, Au) are very similar regarding their collision cascade behavior, but strongly differ regarding their tendency to silicide formation. We find pronounced ripple pattern formation only for those co deposited metals (Fe, Mo, Ni, W, and Pt), which are prone to the formation of mono and disilicides. In contrast, for Cu and Au co-deposition the surface remains very flat, even after irradiation at high ion fluence. Because of the very different behavior of Cu compared to Fe, Ni and Au compared to W, Pt, phase separation toward amorphous metal silicide phases is seen as the relevant process for the pattern formation on Si in the case of Fe, Mo, Ni, W, and Pt co-deposition.     

天然杂质对黄铁矿的电子结构及催化活性的影响

采用密度泛函理论和平面波赝势方法对含天然杂质黄铁矿的电子结构和光学性质进行了计算,并讨论了二十种天然杂质:钴、镍、砷、硒、碲、铜、金、银、钼、锌、铊、锡、钌、钯、铂、汞、镉、铋、铅和锑,对黄铁矿催化活性的影响.结果表明在过渡金属杂质中,杂质能级主要由它们的d轨道产生,而在主族金属及非金属杂质中,杂质能级主要由它们的s或p轨道产生.含铜、钼、砷、金、银或镍的黄铁矿对氧的还原的电催化能力增强.除锌、钼、钌、砷、锑、硒和碲外,其余杂质能增强黄铁矿表面俘获电子的能力,使光生电子和空穴复合的概率减小.光学性质计算表 关键词： 天然黄铁矿 杂质 电子结构 光学性质     

Solder with discontinuous melting point in semiconductor laser arrays and stacks

High power semiconductor laser arrays must be mounted in the epitaxy-side down configuration for good heat transfer and so require a well-controlled solder. Selection of solder is very important in semiconductor laser arrays and stacks. Usually, the solder consists of two layers. The outer layer prevents In from oxidation. A new type of solder with several layers of Au between the two layers of In was made, which constitutes of multi-layer of W/Ni/Au/In/Cu. In packaging, the Au layer in the solder does not melt. Quick temperature decrease can avoid expansion of the solder. The solder cannot oxidize during packaging.     

Finite-temperature magnetism of thin Ni films in sandwiches of Cu

The finite-temperature magnetism of thin Ni films sandwiched in Cu(001) layers, is discussed with the use of the itinerant-electron theory including the effect of spin fluctuations by means of the functional-integral method within the static and single-site approximations. The spatial- and temperature-dependent magnetization and the Curie temperature are computed by varying the Ni-film thickness from one to ten layers. The calculated results are discussed with reference to the recent experiments on Cu/Ni/Cu and Au/Ni/Au sandwiches and on compositionally modulated Ni-Cu superlattices.     

Preparation of a novel Ni/Co-based alloy gradient coating on surface of the crystallizer copper alloy by laser

A high wear-resistant gradient coating made of Ni/Co-based alloys on the surface of a Cu alloy substrate was synthesized using a YAG laser induced in situ reaction method. The coating consists of three layers: the first is a Ni-based alloy layer, the second and third are Co-based alloy layers. The microhardness increases gradually from 98 HV in the Cu alloy substrate to the highest level of 876 HV in the third layer. The main phase of the Co-based alloy layer is CoCr₂(Ni,O)₄, coexisting with the Fe₁₃Mo₂B₅, Cr(Co(Mo, and FeCr_0.29Ni_0.16C_0.06 phases. Wear tests indicate that the gradient coating has good bond strength and wear properties with a wear coefficient of 0.31 (0.50 for the Cu alloy substrate). Also, the wear loss of the coating is only 0.01 g after it has been abraded for 60 min, which is only one fifth of that of the Cu alloy of the crystallizer. Wear tests of the gradient coating reveal good adhesive friction and wear properties when sliding against steel under dry conditions. This novel technique may have good application to make an advanced coating on the surface of the Cu alloy crystallizer in a continuous casting process.     

Using elemental profiles and stable isotopes to trace the origin of green coffee beans on the global market

A broad elemental profile incorporating 54 elements (Li, Be, B, Na, Mg, Al, P, K, Ca, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Se, Rb, Sr, Y, Mo, Pd, Ag, Cd, Sn, Sb, Te, Cs, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Er, Tm, Yb, Re, Ir, Pt, Au, Hg, Tl, Pb, Bi and U) in combination with δ(2) H, δ(13) C, δ(15) N and δ(18) O was used to characterise the composition of 62 green arabica (Coffea arabica) and robusta (Coffea canephora) coffee beans grown in South and Central America, Africa and Asia, the four most internationally renowned areas of production. The δ(2) H, Mg, Fe, Co and Ni content made it possible to correctly assign 95% of green coffee beans to the appropriate variety. Canonical discriminant analysis, performed using δ(13) C, δ(15) N, δ(18) O, Li, Mg, P, K, Mn, Co, Cu, Se, Y, Mo, Cd, La and Ce correctly traced the origin of 98% of coffee beans. Copyright ? 2012 John Wiley & Sons, Ltd.     

Tailoring exchange bias by oxidizing Co film across a Cu wedge in Cu(wedge)/CoO/Co/Cu(0 0 1)

A new method was developed to control Co film oxidation in an epitaxially grown Cu(wedge)/Co/Cu(0 0 1) film. By annealing the film at 200 °C within 10⁻⁶ Torr oxygen environment, we find that the top Cu wedge controls the Co underlayer oxidation continuously as a function of the Cu film thickness. Magneto-Optic Kerr Effect measurement shows that the exchange bias of the resulting CoO/Co film exhibits a systematic variation with the Cu thickness, thus offering a new method of tailoring the exchange bias of CoO/Co films.     

A study of the infrared spectra of carbon monoxide adsorbed on metals of the copper subgroup and on cobalt,ruthenium, rhodium,and palladium

A study has been made of the infrared spectra of carbon monoxide CO, adsorbed on Cu, Ag, Au, Co, Ru, Rh and Pd at temperatures from –160° C to 200° C and pressures from 10^–5 to 1–10 mm Hg. The spectra of CO adsorbed on Cu, Ag, and Au show one absorption band, characteristic of a surface compound of carbon monoxide, with linear structure. It has been found that in the stable chemosorption of CO on Co, Ru, Rh, and Pd in the range of temperatures and pressures studied, two types of surface compound-linear and bridged-are produced.