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Cover Picture: Structurally Defined Molecular Hypervalent Iodine Catalysts for Intermolecular Enantioselective Reactions (Angew. Chem. Int. Ed. 1/2016) 下载免费PDF全文
Dr. Stefan Haubenreisser Dr. Thorsten H. Wöste Dr. Claudio Martínez Prof. Dr. Kazuaki Ishihara Prof. Dr. Kilian Muñiz 《Angewandte Chemie (International ed. in English)》2016,55(1):1-1
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Dr. Michael Brown Dr. Ravi Kumar Dr. Julia Rehbein Prof. Dr. Thomas Wirth 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(12):4030-4035
A stereoselective hypervalent iodine‐promoted oxidative rearrangement of 1,1‐disubstituted alkenes has been developed. This practically simple protocol provides access to enantioenriched α‐arylated ketones without the use of transition metals from readily accessible alkenes. 相似文献
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Dr. Alejandro Parra Dr. Silvia Reboredo 《Chemistry (Weinheim an der Bergstrasse, Germany)》2013,19(51):17244-17260
Chiral hypervalent iodine chemistry has been steadily increasing in importance in recent years. This review catalogues enantioselective transformations triggered by chiral hypervalent iodine(III/V) reagents, in stoichiometric or catalytic quantities, highlighting the different reactivities in terms of yield and enantioselectivity. Moreover, the synthesis of the most remarkable and successful catalysts has been illustrated in detail. 相似文献
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