Peristaltic blood flow with gold nanoparticles as a third grade nanofluid in catheter: Application of cancer therapy

Cancer is dangerous and deadly to most of its patients. Recent studies have shown that gold nanoparticles can cure and overcome it, because these particles have a high atomic number which produce the heat and leads to treatment of malignancy tumors. A motivation of this article is to study the effect of heat transfer with the blood flow (non-Newtonian model) containing gold nanoparticles in a gap between two coaxial tubes, the outer tube has a sinusoidal wave traveling down its wall and the inner tube is rigid. The governing equations of third-grade fluid along with total mass, thermal energy and nanoparticles are simplified by using the assumption of long wavelength. Exact solutions have been evaluated for temperature distribution and nanoparticles concentration, while approximate analytical solutions are found for the velocity distribution using the regular perturbation method with a small third grade parameter. Influence of the physical parameters such as third grade parameter, Brownian motion parameter and thermophoresis parameter on the velocity profile, temperature distribution and nanoparticles concentration are considered. The results pointed to that the gold nanoparticles are effective for drug carrying and drug delivery systems because they control the velocity through the Brownian motion parameter $N_b$ and thermophoresis parameter $N_t$. Gold nanoparticles also increases the temperature distribution, making it able to destroy cancer cells.     

Analysis of peristaltic flow of Jeffrey six constant nano fluid in a vertical non-uniform tube

Peristaltic flow of non-Newtonian nano fluid through a non-uniform surface has been investigated in this paper. The fluid motion along the wall of the surface is caused by the sinusoidal wave traveling with constant speed. The governing equations are converted into cylindrical coordinate system and assuming low Reynolds number and long wave length partial differential equations are simplified. Analytically solutions of the problem are obtained by utilizing the homotopy perturbation method (HPM). In order to insight the impact of embedded parameters on temperature, concentration and velocity some graphs are plotted for different peristaltic waves. At the end, some observations were made from the graphical presentation that velocity, pressure rise and nano particle concentration are increasing function of thermophoresis parameter N_t while temperature and frictional forces show opposite trend.     

Meta-analysis on thermo-migration of tiny/nano-sized particles in the motion of various fluids

The importance of thermophoresis and its essential role in particle migration have led to many published reports (i.e. aim and objectives). However, there exists no report on thermo-migration of tiny/nano-sized particles in the motion of various fluids. A meta-analysis on the significance of either nano or tiny particles exposed to thermophoretic force owing to temperature gradient during the dynamics of liquid substances is deliberated upon in this report. The method of slope linear regression through the data point was adopted to scrutinize sixty (60) published reports in which the effects of thermophoresis (thermodiffusion) is deliberated upon. The outcome of the study shows that different responses to the force of a temperature gradient are sufficient enough to enhance the temperature distribution and the concentration of non-Newtonian fluid due to an increase in thermophoresis. Thermophoretic effect increases the concentration of fluids in which the relationship between the shear stress and shear strain is non-linear. Skin friction coefficients is a decreasing function of thermophoresis. Increase in thermophoretic deposition is achievable due to an increase in thermophoresis. The effect of haphazard motion of nanoparticles should be investigated when it increases negligibly and considerably large. Thermal radiation strongly influences the significance of thermo-migration of tiny particles on fluid flow.     

Rapid communication: Transverse spin with coupled plasmons

The steady two-dimensional flow and heat transfer of a non-Newtonian power-law nanofluid over a stretching surface under convective boundary conditions and temperature-dependent fluid viscosity has been numerically investigated. The power-law rheology is adopted to describe non-Newtonian characteristics of the flow. Four different types of nanoparticles, namely copper (Cu), silver (Ag), alumina (Al ₂ O ₃) and titanium oxide (TiO ₂) are considered by using sodium alginate (SA) as the base non-Newtonian fluid. Lie symmetry group transformations are used to convert the boundary layer equations into non-linear ordinary differential equations. The transformed equations are solved numerically by using a shooting method with fourth-order Runge–Kutta integration scheme. The results show that the effect of viscosity on the heat transfer rate is remarkable only for relatively strong convective heating. Moreover, the skin friction coefficient and the rate of heat transfer increase with an increase in Biot number.     

Numerical analysis for peristalsis of Carreau–Yasuda nanofluid in an asymmetric channel with slip and Joule heating effects

This study investigates the peristaltic transport of magnetohydrodynamic (MHD) Carreau–Yasuda nanofluid through an asymmetric channel. Viscous dissipation, Joule heating and Hall effects are also included in the analysis. Velocity, thermal and concentration slip conditions are considered. The problem is modeled subject to long wavelength and low Reynolds number assumptions. Resulting nonlinear equations are numerically solved. Impact of embedded parameters on the fluid velocity, temperature, concentration of nanoparticles and heat and mass transfer rates at the wall are examined. Graphical results show that an escalation in the strength of appliedmagnetic field and increase in the value of Hall parameter reduce the velocity of nanofluid. Brownian motion and thermophoresis effects increase the temperature of the nanofluid. The present study shows an excellent agreement with the previously available studies in the limiting case.     

Unsteady boundary layer flow of a nanofluid over a stretching sheet with variable fluid properties in the presence of thermal radiation

In this paper, we investigated numerically an unsteady boundary layer flow of a nanofluid over a stretching sheet in the presence of thermal radiation with variable fluid properties. Using a set of suitable similarity transformations, the governing partial differential equations are reduced into a set of nonlinear ordinary differential equations. System of the nonlinear ordinary differential equations are then solved by the Keller-box method. The physical parameters taken into consideration for the present study are: Prandtl number Pr, Lewis number Le, Brownian motion parameter N _b, thermophoresis parameter N _t, radiation parameter N _r, unsteady parameter M. In addition to these parameters, two more new parameters namely variable thermophoretic diffusion coefficient parameter e and variable Brownian motion diffusion coefficient parameter β have been introduced in the present study. Effects of these parameters on temperature, volume fraction of the nanoparticles, surface heat and mass transfer rates are presented graphically and discussed briefly. To validate our method, we have compared the present results with some previously reported results in the literature. The results are found to be in a very good agreement.     

Synthesis and characterization of Ni-Zn ferrite nanoparticles

Nickel zinc ferrite nanoparticles Ni_xZn_1−xFe₂O₄ (x=0.1, 0.3, 0.5) have been synthesized by a chemical co-precipitation method. The samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, electron paramagnetic resonance, dc magnetization and ac susceptibility measurements. The X-ray diffraction patterns confirm the synthesis of single crystalline Ni_xZn_1−xFe₂O₄ nanoparticles. The lattice parameter decreases with increase in Ni content resulting in a reduction in lattice strain. Similarly crystallite size increases with the concentration of Ni. The magnetic measurements show the superparamagnetic nature of the samples for x=0.1 and 0.3 whereas for x=0.5 the material is ferromagnetic. The saturation magnetization is 23.95 emu/g and increases with increase in Ni content. The superparamagnetic nature of the samples is supported by the EPR and ac susceptibility measurement studies. The blocking temperature increases with Ni concentration. The increase in blocking temperature is explained by the redistribution of the cations on tetrahedral (A) and octahedral (B) sites.     

Effects of surface roughness on mixed convective nanofluid flow past an exponentially stretching permeable surface

A numerical study is carried out to display the effects of surface roughness on mixed convective nanofluid flow along an exponentially stretching surface in presence of suction/injection. The dimensional coupled nonlinear partial differential equations are transformed into dimensionless form by using suitable non-similar transformations. The resulting equations are solved by utilizing the Quasilinearization technique as well as the implicit finite difference scheme. The influence of several non-dimensional parameters on various profiles and gradients is examined. The results are presented graphically, which are analyzed to depict the effects of various physical parameters, for example, Brownian diffusion parameter Nb, thermophoresis parameter Nt, suction/blowing parameter A and Lewis number Le. In order to analyse the influence of surface roughness on mixed convective nanofluid flow, the major part of this research paper is devoted to investigate the effects of the small parameter α and frequency parameter n over the gradients defined at the wall. The results reveal that an increase in the values of Nb and Nt, enhances the velocity and temperature of the fluid. The increasing value of suction parameter (A > 0) reduces the velocity of the fluid. Further, the increasing values of Nb and Le decrease the nanoparticle volume fraction profile. The sinusoidal variations are observed in the skin-friction coefficient, Nusselt number as well as the nanoparticle Sherwood number. Moreover, with the addition of nanoparticles, the magnitude of the skin-friction coefficient increases, while the magnitude of heat transfer rate decreases, significantly.     

Brownian motion and thermophoresis effects on unsteady stagnation point flow of Eyring-Powell nanofluid: a Galerkin approach

This article concerns the analysis of an unsteady stagnation point flow of Eyring-Powell nanofluid over a stretching sheet. The influence of thermophoresis and Brownian motion is also considered in transport equations. The nonlinear ODE set is obtained from the governing nonlinear equations via suitable transformations. The numerical experiments are performed using the Galerkin scheme. A tabular form comparison analysis of outcomes attained via the Galerkin approach and numerical scheme (RK-4) is available to show the credibility of the Galerkin method. The numerical exploration is carried out for various governing parameters, namely, Brownian motion, steadiness, thermophoresis, stretching ratio, velocity slip, concentration slip, thermal slip, and fluid parameters, and Hartmann, Prandtl and Schmidt numbers. The velocity of fluid enhances with an increase in fluid and magnetic parameters for the case of opposing, but the behavior is reversed for assisting cases. The Brownian motion and thermophoresis parameters cause an increase in temperature for both cases (assisting and opposing). The Brownian motion parameter provides a drop-in concentration while an increase is noticed for the thermophoresis parameter. All the outcomes and the behavior of emerging parameters are illustrated graphically. The comparison analysis and graphical plots endorse the appropriateness of the Galerkin method. It is concluded that said method could be extended to other problems of a complex nature.     

Modeling of the blocking temperature of a system of core/shell nanoparticles

A theoretical study was conducted on the size dependence of the blocking temperature T_b of a system of interacting core/shell nanoparticles. A method for estimating the blocking temperature of interacting core/shell nanoparticles is presented, which allows T_b to be calculated more precisely than using the “Neel relation”. It was shown that with an increase in the intensity of the magnetostatic interaction (concentration of nanoparticles), the blocking temperature increases, while the growth of the external magnetic field leads to the opposite effect. Moreover, the T_b of large nanoparticles changes more significantly. Comparing different approaches, we identify a precise method for determining the blocking temperature from ZFC and FC magnetization curves.     

Reduced conductivity and enhancement of Debye orientational polarization in lanthanum doped cobalt ferrite nanoparticles

In this work we have investigated the conductivity and dielectric properties of CoLa_xFe_2−xO₄ (x=0.0, 0.03, 0.05, and 0.07) nanoparticles synthesized by chemical co-precipitation route. X-ray diffraction analysis confirms the inverse spinal structure of nanoparticles with slight increase in the lattice constant as La concentration increases. Transmission electron microscopy shows spherical nanoparticles with sizes of ∼20 nm. Impedance spectroscopy of the samples was performed in the frequency range 20 Hz-2 MHz at room temperature. The resistance of the grains and grain boundaries was found to increase with lanthanum concentration while the AC conductivity of the samples was observed to decrease with increasing La concentration. Dipolar orientational polarization was found to play an important role in determining dielectric properties of the samples.     

Electron magnetic resonance spectra of Fe1−x Mnx amorphous nanoparticles

Nanoparticles of Fe_1?x Mn_x (0.07 < x < 0.20) alloys are studied using electron magnetic resonance in the temperature range 295–500 K. It is found that the temperature and manganese concentration in the nanoparticles have a noticeable effect on their electron magnetic resonance spectra. It is suggested that the Fe_1?x Mn_x nanoparticles contain phases with different magnetic properties and that the relative content of the phases depends on the manganese concentration in the nanoparticles. The magnetic transition temperature lies above 500 K for one of these phases and in the temperature range 350–375 K for another.     

Anomalous states of the crystal structure of (Rb0.1(NH4)0.9)2SO4 solid solutions in the temperature range 4.2–300 K

Crystals of (Rb_0.1(NH₄)_0.9)₂SO₄ solid solutions are studied using x-ray diffractometry. It is revealed that the temperature dependence of the lattice parameter a exhibits an anomalous behavior, namely, the “invar effect” at temperatures above the ferroelectric phase transition point T _c and an anomalous increase in the temperature range from T _c to the liquid-helium temperature. An anomalous increase in the lattice parameter a and an increase in the intensity of Bragg reflections with a decrease in the temperature are interpreted within the model of the coexistence of two sublattices hypothetically responsible for the ferroelectric phase transition. A series of superstructure reflections observed along the basis axes corresponds to a sublattice formed in the matrix of the host structure. Analysis of the ratio between the lattice parameters of these structures allows the inference that, in the temperature range 4.2–300 K, the structure of the crystal under investigation can be considered an incommensurate single-crystal composite.     

Micro Raman,Mossbauer and magnetic studies of manganese substituted zinc ferrite nanoparticles: Role of Mn

A series of Mn–Zn Ferrite nanoparticles (<15 nm) with formula Mn_xZn_1−xFe₂O₄ (where x=0.00, 0.35, 0.50, 0.65) were successfully prepared by citrate-gel method at low temperature (400 °C). X-ray diffraction analysis confirmed the formation of single cubic spinel phase in these nanoparticles. The FESEM and TEM micrographs revealed the nanoparticles to be nearly spherical in shape and of fairly uniform size. The fractions of Mn²⁺, Zn²⁺ and Fe³⁺ cations occupying tetrahedral sites along with Fe occupying octahedral sites within the unit cell of different ferrite samples are estimated by room temperature micro-Raman spectroscopy. Low temperature Mossbauer measurement on Mn_0.5Zn_0.5Fe₂O₄ has reconfirmed the mixed spinel phase of these nanoparticles. Room temperature magnetization studies (PPMS) of Mn substituted samples showed superparamagnetic behavior. Manganese substitution for Zn in the ferrite caused the magnetization to increase from 04 to18 emu/g and Lande's g factor (estimated from ferromagnetic resonance measurement) from 2.02 to 2.12 when x was increased up to 0.50. The FMR has shown that higher Mn cationic substitution leads to increase in dipolar interaction and decrease in super exchange interaction. Thermomagnetic (M–T) and magnetization (M–H) measurements have shown that the increase in Mn concentration (up to x=0.50) enhances the spin ordering temperature up to 150 K (blocking temperature). Magnetocrystalline anisotropy in the nanoparticles was established by Mossbauer, ferromagnetic resonance and thermomagnetic measurements. The optimized substitution of manganese for zinc improves the magnetic properties and makes these nanoparticles a potential candidate for their applications in microwave region and biomedical field.     

EPR spectroscopy and imaging of TEMPO-labeled magnetite nanoparticles

The article presents results of a study of TEMPO-labeled polymer coated superparamagnetic iron(II,III) oxide nanoparticles using both Electron Paramagnetic Resonance (EPR) spectroscopy and Electron Paramagnetic Resonance imaging technique (EPRI). The X-band (9.4 GHz) EPR spectroscopy was used to investigate the behavior of TEMPO-labeled polymer coated magnetite nanoparticles in different conditions (temperature and orientation in magnetic field). The broad line, which comes from the core of Fe₃O₄ nanoparticles, shows anisotropy. This signal broadens with decreasing temperature, its intensity increases with increasing temperature and the g factor decreases with increasing temperature. The shape of the signal from nitroxide radical strongly depends on temperature. When temperature is higher than 200 K, a narrow triplet appears, but when it is lower than 200 K the signal consists of broad asymmetric lines. Analysis of the signal allowed characterization of the motion of the spin label attached to nanoparticles. Values of anisotropy parameter ɛ and rotational correlation time τ_c were calculated for TEMPO in the fast rotation regime.The ability of TEMPO-labeled PEG coated magnetite nanoparticles to diffuse within the hydrogel medium was also investigated. The EPR imaging of nanoparticles diffusion in hydrogel was made at room temperature using an EPR L-band (1 GHz) spectrometer. EPRI has been proved effective for evaluation of changes in the spatial distribution of nanoparticles in the sample.     

Electron spin resonance properties of semiconductor/granular film heterostructures with cobalt nanoparticles in millimeter waveband

Ferromagnetic resonance spectra (FMR) on heterostructures of amorphous silicon dioxide films containing cobalt nanoparticles, (SiO₂)_100−xCo_x, grown on GaAs and Si substrates have been investigated over a frequency range of 37–41 GHz at room temperature. The FMR linewidth and saturation magnetization dependencies on the cobalt concentration have been analyzed. The impact of the semiconductor type on the FMR linewidth ΔH and a sharp increase in ΔH with a decreasing concentration of cobalt nanoparticles have been noted. The effect of considerable FMR linewidth broadening has been accounted for by the spin-polarized relaxation mechanism.     

The effect of velocity and dimension of solid nanoparticles on heat transfer in non-Newtonian nanofluid

In this investigation, the behavior of non-Newtonian nanofluid hydrodynamic and heat transfer are simulated. In this study, we numerically simulated a laminar forced non-Newtonian nanofluid flow containing a 0.5 wt% carboxy methyl cellulose (CMC) solutionin water as the base fluid with alumina at volume fractions of 0.5 and 1.5 as the solid nanoparticle. Numerical solution was modelled in Cartesian coordinate system in a two-dimensional microchannel in Reynolds number range of 10≤Re≤1000. The analyzed geometrical space here was a rectangular part of whose upper and bottom walls was influenced by a constant temperature. The effect of volume fraction of the nanoparticles, Reynolds number and non-Newtonian nanofluids was studied. In this research, the changes pressure drop, the Nusselt number, dimensionless temperature and heat transfer coefficient, caused by the motion of non-Newtonian nanofluids are described. The results indicated that the increase of the volume fraction of the solid nanoparticles and a reduction in the diameter of the nanoparticles would improve heat transfer which is more significant in Reynolds number. The results of the introduced parameters in the form of graphs drawing and for different parameters are compared.     

Particle size effect on phase and magnetic properties of polymer-coated magnetic nanoparticles

Polymer-coated magnetic nanoparticles are hi-tech materials with ample applications in the field of biomedicine for the treatment of cancer and targeted drug delivery. In this study, magnetic nanoparticles were synthesized by chemical reduction of FeCl₂ solution with sodium borohydride and coated with amine-terminated polyethylene glycol (aPEG). By varying the concentration of the reactants, the particle size and the crystallinity of the particles were varied. The particle size was found to increase from 6 to 20 nm and the structure becomes amorphous-like with increase in the molar concentration of the reactant. The magnetization at 1 T field (M_1T) for all samples is > 45 emu/g while the coercivity is in the range of 100-350 Oe. When the ethanol-suspended particles are subjected to an alternating magnetic field of 4 Oe at 500 kHz, the temperature is increased to a maximum normalized temperature (3.8 °C/mg) with decreasing particle size.     

Effect of vanadium doping on structural, magnetic and optical properties of ZnO nanoparticles

V-doped ZnO nanoparticles were synthesized by heating metal acetates in organic solvent. All synthesized samples were annealed in air and reducing gas atmosphere at 600 °C for 8 h. The XRD patterns of both samples annealed in air and reducing atmosphere indicate that samples have polycrystalline wurtzite structure with increase in lattice constant with increase in V-doping. The particle sizes were calculated by using Scherrer's equation which lies in the range of 25-30 nm. The SEM images show that particles annealed in air and under reducing environment are spherical in nature. The EDX results reveal that samples contain V, Zn, and O contents only. The TPR results indicate that the system contains isolated VO_x, ZnO_x and bimetallic Zn: V (O_x) sites and indication of electronically excited bimetal sites. There is no signature of ferromagnetism in all samples annealed in air while room temperature ferromagnetism has been observed only under reducing atmosphere annealing. There is monotonically increase in saturation magnetization with V-doping concentration. UV-vis spectroscopy study shows that there is a linear increase in band gap energy with increase in V-doping, a direct evidence of change in magnetic properties due to V-doping and under reducing environment.     

Observation of room temperature ferromagnetism in pure La2O3 nanoparticles

In this paper, we report the observation of intrinsic room temperature ferromagnetism in pure La₂O₃ nanoparticles. Magnetism measurement indicates that all of the samples exhibit room temperature ferromagnetism and the saturation magnetization for the samples decreases with the increase in annealing temperature from 700 to 1,000 °C. X-ray photoelectron spectroscopy identifies the presence of oxygen vacancies in the La₂O₃ nanoparticles. The fitting results of the O 1s spectrum indicate that the variation of the oxygen vacancy concentration is in complete agreement with the change of the saturation magnetization. It is also found that the saturation magnetization of the La₂O₃ nanoparticles can be tuned by post-annealing in argon or oxygen atmosphere. These results suggest that the oxygen vacancies are largely responsible for the room temperature ferromagnetism in pure La₂O₃ nanoparticles.