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1.
WO3在γ-Al2O3表面的分散状态和最大分散量 总被引:2,自引:0,他引:2
应用X光衍射法(XRD)测定了WO2/γ-Al2O3体系的物相组成和平均晶粒度,以及该体系的孔容和比表面:应用XRD相定量外推法和光电子能谱(XPS)峰强度比(Iw4f/IA12s)法定量测定了WO3在γ-Al2O3表面的最大分散量,测值分别为0.21和0.20gWO3/100m[2]γ-Al2O3,与按照WO3在γ-Al2O3表面作密置单层排布模型的计算值0.189WO3/100m[2],即4.9x10[18]W原子/m[2])相近,对WO3/γ-Al2O3体系与MoO3/γ-Al2O3体系比较和讨论。 相似文献
2.
Synthesis,Crystal Structure and Antitumor Activity in Vitro of a New Benzoate Binuclear Cupper( Ⅱ) Complex 总被引:3,自引:0,他引:3
The title compound, [Cu2(C7H5O2)4(C2H6O)2], was synthesized by the reaction of benzoic acid, copper acetate and ethanol in an aqueous solution. Trypan blue dye exclusion method was used in experiment. X-ray single-crystal analysis has revealed that compound 1 (C32H32Cu2O10) crystallizes in the monoclinic system, space group C2/c, Mr = 703.66, a = 47.340(5), b = 6.6613(4), c = 22.028(2)A,β = 113.284(4)°, V = 6380.6(10) A^3, Z = 8, Dc= 1.465 g/cm^3, F(000) = 2896,μ = 1.388 mm^-11, the final R = 0.0515 and wR = 0.1172 for 5712 observed reflections with I 〉 2σ(I). X-ray crystal structure analysis suggests that compound [CH2(C7H5O2)4(C2H6O)2] has a binuclear structure with two Cu(II) atoms coordinated by four benzoate groups and two ethanol molecules. The crystal packing is stabilized by intermolecular O-H...O hydrogen bonds. The compound inhibits the proliferation of K562 cells (chronic myeloid leukemic cells) significantly and dose-dependently in 48 h, and IC50 of K562 is 17.3μg/mL by trypan blue dye exclusion method. 相似文献
3.
Three rare-earth-containing heteropolyoxometalates with different sizes, Na9[Eu(W5O18)2],K13[Eu(SiW11O39)2], and K17[Eu(P2W17O61)2], have been incorporated by self-assembly into the interlayer of synthetic multibilayer films of dimethyldioctadecylammonium chloride and exhibited different orientations. 相似文献
4.
2,4,6-三硝基间苯二酚钡一水化合物的热分解动力学(英) 总被引:1,自引:0,他引:1
0IntroductionBarium2,4,6鄄trinitroresorecinatemonohydrate,Ba(TNR)·H2O,hasgooddetonatingpropertiesandissensitivetoflame.Itcanbeusedasinitiatingagent,igniterpowderordelaypowder.Itspreparation[1],pro鄄perties[1],crystalstructure[1]andthermalbehavior[2]haveb… 相似文献
5.
1 INTRODUCTION The tris(ethylenediamine) cobalt (Ⅲ) complex in which there are L and D configurations is one of the very interest cations due to the chirality among research complexes and the characterization of reaction on the ion-pair charge-transfer transitions. It has been mentioned in a lot of examples on the chirality and the structure, such as [L-Co(en)3]- [?Co(edta)]2Cl?0H2O[1], [(+)DCo(en)3]Cl3稨2O[2], [(+)-Co(en)3?-)-Cr(en)3]Cl?.1H2O[3], [()-Co(en)3] (SCN)3[4], [(+)D… 相似文献
6.
由于聚氧酸盐在催化、制药和阳离子电极等方面具有潜在的应用价值[1~3], 因此一直是无机化学研究的热点[4~8], 自1993年具有双螺旋结构的化合物[(CH3)2NH2]K4[V10O10(H2O)2(OH)4(PO4)7]*4H2O[9]被合成以来, 更多的关注集中在聚氧酸盐的合成及结构研究中. 相似文献
7.
铁取代钨硅酸盐位置异构体的合成、表征及电化学性质 总被引:5,自引:0,他引:5
取代型杂多酸盐( HPC)具有金属卟啉的类似结构 ,它可以代替金属卟啉在很多反应中作催化剂 [1],被称为无机金属卟啉。 Hill[2],Neumann[3]分别报道了过渡元素单取代的杂多阴离子 [PW11M(H2O)O39]n-, [SiW11Ru(H2O)O39]n-对烯烃环氧化反应具有催化活性。目前,在单取代的杂多配合物中,β异构体的报道很少,我们发现,某些单取代金属衍生物中,β异构体具有良好的催化活性,具有明显的应用前景。继过去的工作 [4],我们又研究了过渡元素取代的 11-系列杂多阴离子的某些性质。有关α-XW11Fe(H2O)O39n-( X=Si, P, Ge, As… 相似文献
8.
HU Qiao-ling WU Jia CHEN Fu-ping SHEN Jia-cong 《高等学校化学研究》2006,22(6):792-796
IntroductionMagnetite (Fe3O4) is widespread in the environ-ment although it is thermodynamically unstable with re-spect to hematite(α-Fe2O3) in the presence of oxygen.It has been widely used for targeted delivery ofdrugs[1], in MRI reagents[2], hyperther… 相似文献
9.
10.
Behnaz Afzalian Joel T. Mague Maryam Mohamadi S. Yousef Ebrahimipour Behjat Pour amiri Esmat Tavakolinejad Kermani 《催化学报》2015,(7):1101-1108
Three complexes containing 2-pyrazinecarboxylate (pzca–), including [Ni(pzca)2(H2O)2], [Co(pzca)2(H2O)2], and [Cu(pzca)2(H2O)2], have been synthesized and characterized using physico-chemical and spectroscopic methods. Furthermore, the structure of each complex was determined by single-crystal X-ray diffraction. All three complexes have an octahedral geometry, where the metal ion chelated by two carboxylate oxygens, two nitrogen atoms belonging to pyrazinic acid molecules, and two oxygen atoms of two water molecules. The catalytic activities of these complex-es were also investigated in the green synthesis of 2H-indazolo[2,1-b]phthalazine-triones by the reaction of hydrazine hydrate with an arylaldehyde, phthalic anhydride, and dimedone in acetic acid. 相似文献
11.
Solid-state nuclear magnetic resonance is used to study the thermal decomposition of lithium tetrahydroaluminate into metallic aluminum, hydrogen and trilithium hexahydroaluminate. Aluminum sites in LiAlH4 and Li3AlH6 were characterized using static, magic angle spinning (MAS) and multiple-quantum MAS NMR. By applying the in situ NMR method, it has been demonstrated that melting is not a prerequisite for the decomposition of LiAlH4. Based on the observed data, a decomposition path has been established that is consistent with the concentrations of observed Al species at various stages of the thermally induced reaction. 相似文献
12.
K. Muraleedharan M. P. Kannan T. Ganga Devi 《Journal of Thermal Analysis and Calorimetry》2011,103(3):943-955
The thermal decomposition of potassium iodate (KIO3) has been studied by both non-isothermal and isothermal thermogravimetry (TG). The non-isothermal simultaneous TG–differential
thermal analysis (DTA) of the thermal decomposition of KIO3 was carried out in nitrogen atmosphere at different heating rates. The isothermal decomposition of KIO3 was studied using TG at different temperatures in the range 790–805 K in nitrogen atmosphere. The theoretical and experimental
mass loss data are in good agreement for the thermal decomposition of KIO3. The non-isothermal decomposition of KIO3 was subjected to kinetic analyses by model-free approach, which is based on the isoconversional principle. The isothermal
decomposition of KIO3 was subjected to both conventional (model fitting) and model-free (isoconversional) methods. It has been observed that the
activation energy values obtained from all these methods agree well. Isothermal model fitting analysis shows that the thermal
decomposition kinetics of KIO3 can be best described by the contracting cube equation. 相似文献
13.
Decomposition of hydrogen peroxide in high-purity water has been measured at temperatures ranging 100 to 280°C in a laboratory test loop. A first-order decomposition kinetics has been observed in all cases, but the decomposition rates were found to vary widely, depending on the material used in the reaction chamber. In a 4 mm ID stainless steel tubing, the decomposition rate constant is determined to be k = 2 × 105 exp(?14800/RT). This decomposition rate is approximately 100 times faster than that observed in a Teflon tubing. The variation of decomposition rate in different reaction chambers is attributed to the heterogeneous catalytic effects. There is no evidence of reaction between H2 and H2O2 in the highpurity water at temperatures up to 280°C. 相似文献
14.
A. Kozak K. Wieczorek-Ciurowa K. Pielichowski 《Journal of Thermal Analysis and Calorimetry》1995,45(5):1245-1253
The adduct of Al(NO3)3·6CO(NH2)2 has been prepared and characterized by means of chemical analysis, IR spectroscopy, X-ray patterns and microscopy. A thermoanalytical study of Al(NO3)3·6CO(NH2)2 as well as urea, for comparison purposes, under conventional dynamic and quasi-isothermal—quasi-isobaric conditions in air has been carried out. It has been found that the adduct is thermally stable up to about 200°C, i.e. up to higher temperature than the decomposition temperature of the constituent compounds. The thermal decomposition mechanism of the adduct is complex, thus infrared spectroscopy and X-ray diffraction techniques have been used to determine the intermediate products. Aluminium oxide(III) is the final decomposition product. 相似文献
15.
The isothermal decomposition of zinc hydroxy azides, Zn(OH)2-x(N3)x: follows deceleratory kinetics throughout the temperature range studied. The initial part of the decomposition fits into
unimolecular decay law, log (1-a) = -kt. The contracting volume law satisfactorily describes the data at higher degrees of decomposition. The maximum value ofa upto which the slow decomposition could be recorded was 0.75. The aged form of zinc hydroxy azide decomposes with much lower
rates and slightly different topochemical characteristics. The decrease in the rate of decomposition on ageing has been attributed
to the formation of carbonate on the surface of the compound during storage. The change in topochemical behaviour is traced
to the reported layer structure of zinc hydroxy azide. The effect of pre-heating on subsequent thermal decomposition has also
been discussed. 相似文献
16.
The thermal decomposition of rare-earth trioxalatocobaltates LnCo(C2O4)3 · x H2O, where Ln La, Pr, Nd, has been studied in flowing atmospheres of air/oxygen, argon/ nitrogen, carbon dioxide and a vacuum. The compounds decompose through three major steps, viz. dehydration, decomposition of the oxalate to an intermediate carbonate, which further decomposes to yield rare-earth cobaltite as the final product. The formation of the final product is influenced by the surrounding gas atmosphere. Studies on the thermal decomposition of photodecomposed lanthanum trioxalatocobaltate and a mechanical mixture of lanthanum oxalate and cobalt oxalate in 1 : 2 molar ratio reveal that the decomposition behaviour of the two samples is different. The drawbacks of the decomposition scheme proposed earlier have been pointed out, and logical schemes based on results obtained by TG, DTA, DTG, supplemented by various physico-chemical techniques such as gas and chemical analyses, IR and mass spectroscopy, surface area and magnetic susceptibility measurements and X-ray powder diffraction methods, have been proposed for the decomposition in air of rare-earth trioxalatocobaltates as well as for the photoreduced lanthanum salt and a mechanical mixture of lanthanum and cobalt oxalates. 相似文献
17.
Different ammonium fluoroferrates (NH4)xFeF2x (2≤x≤3) have been investigated. The thermal decomposition of the compounds obtained can be interpreted by their identical crystal structures (cryolite type). The decomposition products of all ammonium fluoroferrates formed in initial stage are isostructural of NH4FeF4. The decomposition is accompanied by the partial reduction of Fe(III) to Fe(II) by ammonium isolated. The end product of the thermal decomposition is FeF2 and FeF3 mixture. 相似文献
18.
The thermal decomposition of ammonium uranate in air has been studied using TG, DTG, surface area measurements, chemical and X-ray analyses. The effect of washing and calcination at different temperatures is discussed. The optimum conditions for preparing β-UO3 are chosen to be via ammonium uranate washed by distilled water and calcined at 500°C.The kinetics of the thermal decomposition are studied using Kissinger's shape index method. The thermal decomposition includes dehydration reaction, complicated reactions to form UO3 and thermal decomposition of UO3 to U3O8. The order of reaction is calculated for each stage. 相似文献
19.
Ingo G. M. Riccucci C. Bultrini G. Chiozzini G. 《Journal of Thermal Analysis and Calorimetry》2001,66(1):27-35
By means of the combined use of scanning electron microscopy+energy dispersive spectrometry(SEM+EDS), X-ray photoelectron
spectroscopy (XPS), X-ray diffraction (XRD), differential thermal analysis (DTA) and thermogravimetry (TG), the thermal decomposition
of gypsum and gypsum bonded investment used for casting jewellery products has been studied in order to gain a further insight
into the origin of the gas porosity in gold-based alloys produced via lost wax casting. The occurrence of the defect is related
to the thermal decomposition of CaSO4 that constitutes with silica the investment material and the decomposition of which takes place at a temperature very close
to the casting temperature of some typical gold alloys. The decrease of the thermal decomposition temperature of gypsum is
induced by the presence of silica and is related to the surface acid-base interaction between SiO2 and CaSO4. On the base of these results, the solid state thermal decomposition of calcium sulphate in the presence of other metal oxides
characterised by different acid-base nature has been investigated and a correlation between the surface acid-base properties
measured as isoelectric point of the solid surface (IEPS) and via XPS analysis and the temperature of CaSO4 thermal decomposition is observed.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
20.
Ray L. Frost Sara J. Palmer János Kristóf Erzsébet Horváth 《Journal of Thermal Analysis and Calorimetry》2010,101(1):73-79
Dynamic and controlled rate thermal analysis has been used to characterise synthesised jarosites of formula [M(Fe)3(SO4)2(OH)6] where M is Pb, Ag or Pb–Ag mixtures. Thermal decomposition occurs in a series of steps. (a) dehydration, (b) well defined
dehydroxylation and (c) desulphation. CRTA offers a better resolution and a more detailed interpretation of water formation
processes via approaching equilibrium conditions of decomposition through the elimination of the slow transfer of heat to
the sample as a controlling parameter on the process of decomposition. Constant-rate decomposition processes of water formation
reveal the subtle nature of dehydration and dehydroxylation. CRTA offers a better resolution and a more detailed interpretation
of the decomposition processes via approaching equilibrium conditions of decomposition through the elimination of the slow
transfer of heat to the sample as a controlling parameter on the process of decomposition. Constant-rate decomposition processes
of non-isothermal nature reveal separation of the dehydroxylation steps, since in these cases a higher energy (higher temperature)
is needed to drive out gaseous decomposition products through a decreasing space at a constant, pre-set rate. 相似文献