Determination of permeability tensors for two-phase flow in homogeneous porous media: Theory

In this paper we continue previous studies of the closure problem for two-phase flow in homogeneous porous media, and we show how the closure problem can be transformed to a pair of Stokes-like boundary-value problems in terms of pressures that have units of length and velocities that have units of length squared. These are essentially geometrical boundary value problems that are used to calculate the four permeability tensors that appear in the volume averaged Stokes' equations. To determine the geometry associated with the closure problem, one needs to solve the physical problem; however, the closure problem can be solved using the same algorithm used to solve the physical problem, thus the entire procedure can be accomplished with a single numerical code.Nomenclature a a vector that maps V onto , m^-1. - A a tensor that maps V onto . - A area of the - interface contained within the macroscopic region, m². - A area of the -phase entrances and exits contained within the macroscopic region, m². - A area of the - interface contained within the averaging volume, m². - A area of the -phase entrances and exits contained within the averaging volume, m². - Bo Bond number (= (=(–)g²/). - Ca capillary number (= v/). - g gravitational acceleration, m/s². - H mean curvature, m^-1. - I unit tensor. - permeability tensor for the -phase, m². - viscous drag tensor that maps V onto V. - ^* dominant permeability tensor that maps onto v , m². - ^* coupling permeability tensor that maps onto v , m². - characteristic length scale for the -phase, m. - l characteristic length scale representing both and , m. - L characteristic length scale for volume averaged quantities, m. - n unit normal vector directed from the -phase toward the -phase. - n unit normal vector representing both n and n . - n unit normal vector representing both n and n . - P pressure in the -phase, N/m². - p superficial average pressure in the -phase, N/m². - p intrinsic average pressure in the -phase, N/m². - p –p , spatial deviation pressure for the -phase, N/m². - r ₀ radius of the averaging volume, m. - r position vector, m. - t time, s. - v fluid velocity in the -phase, m/s. - v superficial average velocity in the -phase, m/s. - v intrinsic average velocity in the -phase, m/s. - v –v , spatial deviation velocity in the -phase, m/s. - V volume of the -phase contained within the averaging volmue, m³. - averaging volume, m³. Greek Symbols V /, volume fraction of the -phase. - viscosity of the -phase, Ns/m². - density of the -phase, kg/m³. - surface tension, N/m. - (v +v ^T ), viscous stress tensor for the -phase, N/m².     

A rotating hot-wire technique for spatial sampling of disturbed and manipulated duct flows

The documentation and control of flow disturbances downstream of various open inlet contractions was the primary focus with which to evaluate a spatial sampling technique. An X-wire probe was rotated about the center of a cylindrical test section at a radius equal to one-half that of the test section. This provided quasi-instantaneous multi-point measurements of the streamwise and azimuthal components of the velocity to investigate the temporal and spatial characteristics of the flowfield downstream of various contractions. The extent to which a particular contraction is effective in controlling ingested flow disturbances was investigated by artificially introducing disturbances upstream of the contractions. Spatial as well as temporal mappings of various quantities are presented for the streamwise and azimuthal components of the velocity. It was found that the control of upstream disturbances is highly dependent on the inlet contraction; for example, reduction of blade passing frequency noise in the ground testing of jet engines should be achieved with the proper choice of inlet configurations.List of symbols K _uv correlation coefficient= - P percentage of time that an azimuthal fluctuating velocity derivative dv/d is found - U streamwise velocity component U=U (, t) - V azimuthal or tangential velocity component due to flow and probe rotation V=V (, t) - mean value of streamwise velocity component - U _m resultant velocity from and - mean value of azimuthal velocity component induced by rotation - u fluctuating streamwise component of velocity u=u(, t) - v fluctuating azimuthal component of velocity v = v (, t) - u phase-averaged fluctuating streamwise component of velocity u=u(0) - v phase-averaged fluctuating azimuthal component of velocity v=v() - û average of phase-averaged fluctuating streamwise component of velocity (u()) over cases I-1, II-1 and III-1 û = û() - average of phase-averaged fluctuating azimuthal component of velocity (v()) over cases I-1, II-1 and III-1 - u fluctuating streamwise component of velocity corrected for non-uniformity of probe rotation and/or phase-related vibration u = u(0, t) - v fluctuating azimuthal component of velocity corrected for non-uniformity or probe rotation and/or phase-related vibration v=v (, t) - u ² rms value of corrected fluctuating streamwise component of velocity - rms value of corrected fluctuating azimuthal component of velocity - phase or azimuthal position of X-probe     

Material functions generated by the complex viscosity

Based on the complex viscosity model various steady-state and transient material functions have been completed. The model is investigated in terms of a corotational frame reference. Also, BKZ-type integral constitutive equations have been studied. Some relations between material functions have been derived. C ^–1 Finger tensor - F[], (F ^–1[]) Fourier (inverse) transform - rate of deformation tensor in corotating frame - h(I, II) Wagner's damping function - J (x) Bessel function - m parameter inh (I, II) - m(s) memory function - m _k, n_k integers (powers in complex viscosity model) - P principal value of the integral - parameter in the complex viscosity model - rate of deformation tensor - shear rates - [], [] incomplete gamma function - (a) gamma function - steady-shear viscosity - ^* complex viscosity - , real and imaginary parts of ^* - ₀ zero shear viscosity - ⁺, ₁ ⁺ stress growth functions - ^–, ₁ ^- stress relaxation functions - (s) relaxation modulus - ₁(s) primary normal-stress coefficient - ø(a, b; z) degenerate hypergeometric function - ₁, ₂ time constants (parameters of ^*) - frequency - extra stress tensor     

Flow in porous media II: The governing equations for immiscible,two-phase flow

The Stokes flow of two immiscible fluids through a rigid porous medium is analyzed using the method of volume averaging. The volume-averaged momentum equations, in terms of averaged quantities and spatial deviations, are identical in form to that obtained for single phase flow; however, the solution of the closure problem gives rise to additional terms not found in the traditional treatment of two-phase flow. Qualitative arguments suggest that the nontraditional terms may be important when / is of order one, and order of magnitude analysis indicates that they may be significant in terms of the motion of a fluid at very low volume fractions. The theory contains features that could give rise to hysteresis effects, but in the present form it is restricted to static contact line phenomena.Roman Letters (, = , , and ) A interfacial area of the- interface contained within the macroscopic system, m² - A _e area of entrances and exits for the -phase contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A ^* interfacial area of the- interface contained within a unit cell, m² - A _e ^* area of entrances and exits for the-phase contained within a unit cell, m² - g gravity vector, m²/s - H mean curvature of the- interface, m^–1 - H area average of the mean curvature, m^–1 - H – H , deviation of the mean curvature, m^–1 - I unit tensor - K Darcy's law permeability tensor, m² - K permeability tensor for the-phase, m² - K viscous drag tensor for the-phase equation of motion - K viscous drag tensor for the-phase equation of motion - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the-phase, m - n unit normal vector pointing from the-phase toward the-phase (n = –n ) - p _c p – P , capillary pressure, N/m² - p pressure in the-phase, N/m² - p intrinsic phase average pressure for the-phase, N/m² - p – p , spatial deviation of the pressure in the-phase, N/m² - r ₀ radius of the averaging volume, m - t time, s - v velocity vector for the-phase, m/s - v phase average velocity vector for the-phase, m/s - v intrinsic phase average velocity vector for the-phase, m/s - v – v , spatial deviation of the velocity vector for the-phase, m/s - V averaging volume, m³ - V volume of the-phase contained within the averaging volume, m³ Greek Letters V /V, volume fraction of the-phase - mass density of the-phase, kg/m³ - viscosity of the-phase, Nt/m² - surface tension of the- interface, N/m - viscous stress tensor for the-phase, N/m² - / kinematic viscosity, m²/s     

A class of hypo-elastic non-elastic materials and their thermodynamics

Thermodynamics is developed for a class of thermo-hypo-elastic materials. It is shown that materials of this class obey the laws of thermodynamics, but are not elastic.

Table of Symbols

Latin Letters A _ijkl tensor-valued function of t _ij appearing in hypo-elastic constitutive relation - B _ijkl another tensor-valued function. See equation (4.2) - B the square of - d _ij rate of deformation tensor - d _ij deviator of rate of deformation - f, k functions of pressure, p - g, h functions of the invariant - p pressure - q _i heat flux vector - s _ij stress deviator - _ij co-rotational derivative of stress deviator - t time - t ₁ t ₂ specific values of time - t _ij stress tensor - t _ij ⁰ a specific value of stress - T Temperature - T ₀ a specific value of temperature - u _i velocity - V(t) a material volume as a function of time, t - V ₀ a material volume at a reference configuration - W work (W = work done in a deformation—section 5) Sript Letters Specific internal energy - Specific Helmholtz free energy - G Specific Gibbs function Greek Letters an invariant of the stress deviator—see eq. (2.4) - _ij kroneker delta - (W = work done in a deformation—section 5) - specific entropy - hypo-elastic potential - hypo-elastic potential - mass density - ₀ mass density in a reference configuration - specific volume = 1/ - a function of p - _ijkl a constant tensor—see eq. (2.5) - –G/ - _ij rate of rotation tensor This work is dedicated to Jerald L. Ericksen, without whose influence it would not have been possible     

Maximum density effects on thermal instability of horizontal laminar boundary layers

Linear stability theory is used to investigate the onset of longitudinal vortices in laminar boundary layers along horizontal semi-infinite flat plates heated or cooled isothermally from below by considering the density inversion effect for water using a cubic temperature-density relationship. The analysis employs non-parallel flow model incorporating the variation of the basic flow and temperature fields with the streamwise coordinate as well as the transverse velocity component in the disturbance equations. Numerical results for the critical Grashof number Gr _L ^* =Gr _X ^* /Re _X< ^{Emphasis>/3/2} are presented for thermal conditions corresponding to –0.5 ₁–2.0 and –0.8 ₂1.2.Nomenclature a wavenumber, 2/ - D operator, d/d - F (f–f)/2 - f dimensionless stream function - g gravitational acceleration - G eigenvalue, Gr _L/Re_L - Gr _L Grashof number based on L - Gr _X Grashof number based on X - L characteristic length, (X/U)^1/2 - M number of divisions in y direction - P pressure - Pr Prandtl number, / - p dimensionless pressure, P/( ² /Re _L) - Re _L, Re_X Reynolds numbers, (U L/)=Re _X< ^1/2 and (U), respectively - T temperature - U, V, W velocity components in X, Y, Z directions - u, v, w dimensionless perturbation velocities, (U, V, W)/U - X, Y, Z rectangular coordinates - x, y, z dimensionless coordinates, (X, Y, Z)/L - thermal diffusivity - coefficient of thermal expansion - ₁, ₂ temperature coefficients for density-temperature relationship - similarity variable, Y/L=y - dimensionless temperature disturbance, /T - dimensionless wavelength of vortex rolls, 2/a - ₁, ₂ thermal parameters defined by equation (12) - kinematic viscosity - density - dimensionless basic temperature, (T _b T )/T - –1 - T temperature difference, (T _w–T ) - * critical value or dimensionless disturbance amplitude - prime, disturbance quantity or differentiation with respect to - b basic flow quantity - max value at a density maximum - w value at wall - free stream condition     

The third-normal stress difference in entangled melts: Quantitative stress-optical measurements in oscillatory shear

Stress-optical measurements are used to quantitatively determine the third-normal stress difference (N ₃ = N ₁ + N ₂) in three entangled polymer melts during small amplitude (<15%) oscillatory shear over a wide dynamic range. The results are presented in terms of the three material functions that describe N ₃ in oscillatory shear: the real and imaginary parts of its complex amplitude ₃ ^* = ₃ - i ₃ , and its displacement ₃ ^d . The results confirm that these functions are related to the dynamic modulus by ² ₃ ^* ()=(1-)[G ^*())– G ^*(2)] and ² ₃ ^d ()=(1- )G() as predicted by many constitutive equations, where = –N ₂/N ₁. The value of (1-) is found to be 0.69±0.07 for poly(ethylene-propylene) and 0.76±0.07 for polyisoprene. This corresponds to –N ₂/N ₁ = 0.31 and 0.24±0.07, close to the prediction of the reptation model when the independent alignment approximation is used, i.e., –N ₂/N ₁ = 2/7 – 0.28.     

Stabilitätsrechnung der Rohrströmung einer inkompressiblen viskoelastischen Flüssigkeit zweiter Ordnung

Zusammenfassung Für die Durchsatzströmung im Rohr wird mit Hilfe der klassischen hydrodynamischen Stabilitätstheorie gezeigt, daß die inkompressible Flüssigkeit zweiter Ordnungs = –pI + 2(d + 2t ₁ d ² –t ₀ d) stabil ist gegenüber kleinen rotationssymmetrischen Störungen.

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Summary For Poiseuille pipe flow it is shown by means of the classical theory of hydrodynamic stability, that the incompressible second-order fluids = –pI + 2(d + 2t ₁ d ² –t ₀ d) is stable with respect to small disturbances of rotational symmetry.

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Nomenklatur a _n Koeffizienten der Reihenentwicklung - c = /k komplexe Wellengeschwindigkeit - d Deformationsgeschwindigkeitstensor - D, D dimensionsloser Deformationsgeschwindigkeitstensor (Grund- und Störtensor) - e _i kovariante Basis - g Vektor der Erdbeschleunigung - I Einheitstensor - k Wellenzahl - M, O, S, Q, T Funktion vonk, Re, ₀ - p, P, p Gesamt-, Grund-, Stördruck - r, (r, , z) dimensionsloser Ortsvektor (Zylinderkoordinaten) - R Rohrradius - Re =U _M R/ Reynoldszahl - s(s ^*=s*pI) Spannungstensor (Isotroper Anteil des ) - t ₀,t ₁ Stoffzeiten, Parameter der Flüssigkeit zweiter Ordnung - t Zeit - u, U, u Vektor der Gesamt-, Grund-, Störgeschwindigkeit - U _M Maximale Grundgeschwindigkeit - v, V, v Vektor der dimensionslosen Gesamt-, Grund-, Störgeschwindigkeit - w Rotationsgeschwindigkeitstensor - W, W Rotationsgeschwindigkeitstensor, dimensionslos (Grund-, Störtensor) - x (x _r ,x ,x _z ) Ortsvektor (Zylinderkoordinaten) - Viskosität - ₀, ₁ dimensionslose Stoffzeiten - dimensionsloser Druck - Dichte - dimensionslose Zeit - Stromfunktion, dimensionslos - komplexe Frequenz, dimensionslos - = e ⁱ /x _i Nablaoperator (e ⁱ kontravariante Basis) - _* Nablaoperator, dimensionslos - R, I Real-, Imaginärteil Mit 4 Abbildungen     

Existence theorem for a minimum problem with free discontinuity set

We study the variational problem Where is an open set in ⁿ ,n2gL ^q () L (), 1q<+, O<, <+ andH _n–1 is the (n–1)-dimensional Hausdorff Measure.     

Shock-induced chemical processes and ‘molecular rocket reaction’ in metallocenes and their cyclodextrin inclusion compounds

Shock-induced yield enhancement has been observed in implantation of recoil atoms into metallocene and its-cyclodextrin (CD) inclusion compounds, as in the case of metal-diketonate compounds previously studied. The enhancement, however, occurs at much lower energy compared with that in metal-diketonates. In acetylruthenocene and benzoylruthenocene--CD inclusion compounds, various aspects of molecular rocket reaction have been discussed.This article was processed by the author using Springer-Verlag T_EX PJour2g macro package version 1.     

The dynamic performance of the Weissenberg rheogoniometer III. Large amplitude oscillatory shearing — harmonic analysis

The harmonic content of the nonlinear dynamic behaviour of 1% polyacrylamide in 50% glycerol/water was studied using a standard Model R 18 Weissenberg Rheogoniometer. The Fourier analysis of the Oscillation Input and Torsion Head motions was performed using a Digital Transfer Function Analyser.In the absence of fluid inertia effects and when the amplitude of the (fundamental) Oscillation Input motion _I is much greater than the amplitudes of the Fourier components of the Torsion Head motion _Tn empirical nonlinear dynamic rheological propertiesG _n (, ⁰),G _n (, ⁰) and/or _n (, ⁰), _n (, ⁰) may be evaluated without a-priori-knowledge of a rheological constitutive equation. A detailed derivation of the basic equations involved is presented.Cone and plate data for the third harmonic storage modulus (dynamic rigidity)G ₃ (, ⁰), loss modulusG ₃ (, ⁰) and loss angle ₃ (, ⁰) are presented for the frequency range 3.14 × 10^–2 1.25 × 10² rad/s at two strain amplitudes, _CP ⁰ = 2.27 and 4.03. Composite cone and plate and parallel plates data for both the third and fifth harmonic dynamic viscosities ₃ (, ⁰), _S (, ⁰) and dynamic rigiditiesG ₃ (, ⁰),G ₅ (, ⁰) are presented for strain amplitudes in the ranges 1.10 _CP ⁰ 4.03 and 1.80 _PP ⁰ 36 for a single frequency, = 3.14 × 10^–1 rad/s. Good agreement was obtained between the results from both geometries and the absence of significant fluid inertia effects was confirmed by the superposition of the data for different gap widths.     

Approximate solutions for drag coefficient of bubbles moving in shear-thinning elastic fluids

The drag coefficient for bubbles with mobile or immobile interface rising in shear-thinning elastic fluids described by an Ellis or a Carreau model is discussed. Approximate solutions based on linearization of the equations of motion are presented for the highly elastic region of flow. These solutions are in reasonably good agreement with the theoretical predictions based on variational principles and with published experimental data. C _D Drag coefficient - E ^* Differential operator [E ^{* 2} = ²/² + (sin/ ²)/(1/sin /)] - El Ellis number - F _D Drag force - K Consistency index in the power-law model for non-Newtonian fluid - n Flow behaviour index in the Carreau and power-law models - P Dimensionless pressure [=(p – p ₀)/₀ (U /R)] - p Pressure - R Bubble radius - Re ₀ Reynolds number [= 2R U /₀] - Re Reynolds number defined for the power-law fluid [= (2R) ⁿ U ^2–n /K] - r Spherical coordinate - t Time - U Terminal velocity of a bubble - u Velocity - Wi Weissenberg number - Ellis model parameter - Rate of deformation - Apparent viscosity - ₀ Zero shear rate viscosity - Infinite shear rate viscosity - Spherical coordinate - Parameter in the Carreau model - ^* Dimensionless time [=/(U /R)] - Dimensionless length [=r/R] - Second invariant of rate of deformation tensors - ^* Dimensionless second invariant of rate of deformation tensors [=/(U /R)²] - Second invariant of stress tensors - ^* Dimensionless second invariant of second invariant of stress tensor [= / ₀ ² (U /R)²] - Fluid density - Shear stress - ^* Dimensionless shear stress [=/ ₀ (U /R)] - _1/2 Ellis model parameter - ₁ ^2/* Dimensionless Ellis model parameter [= _1/2/ ₀(U /R)] - Stream function - ^* Dimensionless stream function [=/U R ²]     

A class of nonlinear,completely integrable abstract wave equations

IfL is a positive self-adjoint operator on a Hubert spaceH, with compact inverse, the second-order evolution equation int,u+Lu+u _H ² u=0 has an infinite number of first integrals, pairwise in involution. It follows from this that no nontrivial solution tends weakly to 0 inH ast. Under an additional separation assumption on the eigenvalues ofL, all trajectories (u,u) are relatively compact inD(L ^1/2)×H. Finally, if all the eigenvalues are simple, the set of initial values of quasi-periodic solutions is dense in the ball B=(u ₀,u ₀ )D(L ^1/2)×H; L^1/2 u _{0 H} ² +u ² < for sufficiently small.     

Transport in ordered and disordered porous media I: The cellular average and the use of weighting functions

In this work we consider transport in ordered and disordered porous media using singlephase flow in rigid porous mediaas an example. We defineorder anddisorder in terms of geometrical integrals that arise naturally in the method of volume averaging, and we show that dependent variables for ordered media must generally be defined in terms of thecellular average. The cellular average can be constructed by means of a weighting function, thus transport processes in both ordered and disordered media can be treated with a single theory based on weighted averages. Part I provides some basic ideas associated with ordered and disordered media, weighted averages, and the theory of distributions. In Part II a generalized averaging procedure is presented and in Part III the closure problem is developed and the theory is compared with experiment. Parts IV and V provide some geometrical results for computer generated porous media.Roman Letters A interfacial area of the- interface contained within the macroscopic region, m² - A_e area of entrances and exits for the-phase contained within the macroscopic system, m² - g gravity vector, m/s² - I unit tensor - K traditional Darcy's law permeability tensor, m² - L general characteristic length for volume averaged quantities, m - characteristic length (pore scale) for the-phase - (y) weighting function - m(–y) (y), convolution product weighting function - _v special weighting function associated with the traditional averaging volume - N unit normal vector pointing from the-phase toward the-phase - p pressure in the-phase, N/m² - p0 reference pressure in the-phase, N/m² - p traditional intrinsic volume averaged pressure, N/m² - r0 radius of a spherical averaging volume, m - r position vector, m - r position vector locating points in the-phase, m - averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ - V _cell volume of a unit cell, m³ - v velocity vector in the-phase, m/s - v traditional superficial volume averaged velocity, m/s - x position vector locating the centroid of the averaging volume or the convolution product weighting function, m - y position vector relative to the centroid, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters indicator function for the-phase - Dirac distribution associated with the- interface - V/V, volume average porosity - mass density of the-phase, kg/m³ - viscosity of the-phase, Ns/m²     

LDA measurements in low Reynolds number turbulent boundary layer

LDA measurements of the mean velocity in a low Reynolds number turbulent boundary layer allow a direct estimate of the friction velocity U from the value of /y at the wall. The trend of the Reynolds number dependence of / is similar to the direct numerical simulations of Spalart (1988).     

Mass transport and reaction in catalyst pellets

When heterogeneous chemical reactions take place in porous catalysts, mass transport can occur by bulk diffusion, Knudsen diffusion, and convective transport. Previous studies of these phenomena have been largely based on Maxwell's dusty gas model with the convective transport or Darcy flow added to the diffusive transport. This is done in order to satisfy one of the limiting conditions encountered in the study of flow in porous media. A more fundamental approach consists of the use of the method of volume averaging and the general form of the species momentum equation. For an N-component system, this leads to N independent flux relations to be used in conjunction with the volume-averaged species continuity equations.Roman Letters _A (t) surface area of a species body, m² - a _v interfacial area per unit volume, m^-1 - A _e area of entrances and exits for the -phase contained within the averaging volume, m² - A _K area of the - surface contained within the averaging volume, m² - b _A species A body force, N/kg - b mass average body force, N/kg - B inverse tortuosity tensor for bulk diffusion - c total molar concentration, moles/m³ - c _A species A molar concentration, moles/m³ - _A surface concentration of species A, moles/m² - C_A² intrinsic phase average molar concentration, moles/m³ - c _A – C_A², spatial deviation concentration, moles/m³ - c _A mean molecular speed for species A, m/s - binary diffusion coefficient, m²/s - D _A ^{K, eff} Knudsen diffusion coefficient for species A, m²/s - f vector that maps P _A into P _A , m - g gravitational vector, m/s² - G second order tensor that maps N _A into N _A for free molecule flow conditions - H inverse tortuosity tensor for Knudsen diffusion - I unit tensor - j _A c _A u _A ^* , molar diffusive flux, moles/m²s - K Darcy's Law permeability tensor, m² - L macroscopic length scale, m - L _D diffusive length, m - l characteristic length for the -phase, m - l _A mean free path for species A, m - M _A molecular weight of species A, kg/mole - n outwardly directed unit normal vector - n _K unit normal vector directed from the -phase toward the -phase - n outwardly directed unit normal vector at the entrances and exits of the -phase contained within the averaging volume - N _A c _A v _A molar flux of species A, moles/m²s - N _A intrinsic phase average of the species A molar flux, moles/m²s - \~N _A spatial deviation of the molar flux of species A, moles/m²s - p total pressure, N/m² - P p + , total pressure over and above the hydrostatic pressure, N/m² - P _A partial pressure of species A, N/m² - p _A intrinsic phase average partial pressure, N/m² - P_A – p _A, spatial deviation partial pressure, N/m² - P _A p_A + _AA partial pressure of species A over and above the hydrostatic pressure of species A, N/m² - p _ab diffusive force exerted by species B on species A, N/m³ - universal gas constant, N m/moles K - R _A molar rate of production of species A owing to homogeneous chemical reaction, moles/m³s - molar rate of production of species A owing to heterogeneous chemical reaction, moles/m²s - r _A mass rate of production of species A owing to homogeneous chemical reaction, kg/m³s - r ₀ radius of the averaging volume, m - r position vector, m - t time, s - t _A species stress vector, N/m² - T _A species stress tensor, N/m² - T total stress tensor, N/m² - T temperature, K - T spatial average temperature, K - u _A v _A – v, mass diffusion velocity, m/su _A ^* v_A – v^*, molar diffusion velocity, m/s - u _o velocity of the rigid, solid phase relative to some inertial frame, m/s - v _A species velocity, m/s - v mass average velocity, m/s - v ^* molar average velocity, m/s - v _A ^* species velocity of those molecules of species A generated by chemical reaction, m/s - _A (t) volume of a species A body, m³ - averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ - V volume of the -phase contained within the averaging volume, m³ - v phase average, mass average velocity, m/s - w arbitrary velocity vector, m/s - x _A c _A /c mole fraction of species A - X _A intrinsic phase average mole fraction - X _A – X _A , spatial deviation mole fraction Greek Letters V/V volume fraction of the -phase - _A sum of all terms in the species A momentum equation that are small compared to the diffusive force, N/m³ - viscosity of the -phase, Ns/m² - _A mass density of species A, kg/m³ - total mass density, kg/m³ - _a species viscous stress tensor, N/m² - total viscous stress tensor, N/m² - tortuosity factor - total body force potential function, Nm/kg - _a species body force potential function, Nm/kg - 3.1416 - _{a a} / mass fraction of species A     

Concentration dependence of the critical viscoelastic properties of gelatin at the gel point

Gelatin gel properties have been studied through the evolution of the storage [G()] and the loss [G()] moduli during gelation or melting near the gel point at several concentrations. The linear viscoelastic properties at the percolation threshold follow a power-law G()G() and correspond to the behavior described by a rheological constitutive equation known as the Gel Equation. The critical point is characterized by the relation: tan = G/G = cst = tan ( · /2) and it may be precisely located using the variations of tan versus the gelation or melting parameter (time or temperature) at several frequencies. The effect of concentration and of time-temperature gel history on its variations has been studied. On gelation, critical temperatures at each concentration were extrapolated to infinite gel times. On melting, critical temperatures were determined by heating step by step after a controlled period of aging. Phase diagrams [T = f(C)] were obtained for gelation and melting and the corresponding enthalpies were calculated using the Ferry-Eldridge relation. A detailed study of the variations of A with concentration and with gel history was carried out. The values of which were generally in the 0.60–0.72 range but could be as low as 0.20–0.30 in some experimental conditions, were compared with published and theoretical values.     

Some remarks on differential equations of quadratic type

In this paper we study differential equations of the formx(t) + x(t)=f(x(t)), x(0)=x ₀ C HereC is a closed, bounded convex subset of a Banach spaceX,f(C) C, and it is often assumed thatf(x) is a quadratic map. We study the differential equation by using the general theory of nonexpansive maps and nonexpansive, non-linear semigroups, and we obtain sharp results in a number of cases of interest. We give a formula for the Lipschitz constant off: C C, and we derive a precise explicit formula for the Lipschitz constant whenf is quadratic,C is the unit simplex inR ⁿ, and thel ₁ norm is used. We give a new proof of a theorem about nonexpansive semigroups; and we show that if the Lipschitz constant off: CC is less than or equal to one, then lim_tf(x(t))–x(t)=0 and, if {x(t):t 0} is precompact, then lim_tx(t) exists. Iff¦C=L¦C, whereL is a bounded linear operator, we apply the nonlinear theory to prove that (under mild further conditions on C) lim_t f(x(t))–x(t)=0 and that lim_t x(t) exists if {x(t):t 0} is precompact. However, forn 3 we give examples of quadratic mapsf of the unit simplex ofR ⁿ into itself such that lim_t x(t) fails to exist for mostx ₀ C andx(t) may be periodic. Our theorems answer several questions recently raised by J. Herod in connection with so-called model Boltzmann equations.     

Testing viscometric predictions of the internal viscosity model,using dilute viscous theta solutions

A stress-symmetrized internal viscosity (I.V.) model for flexible polymer chains, proposed by Bazua and Williams, is scrutinized for its theoretical predictions of complex viscosity ^* () = – i and non-Newtonian viscosity (), where is frequency and is shear stress. Parameters varied are the number of submolecules,N (i.e., molecular weightM = NM _s ); the hydrodynamic interaction,h ^*; and/f, where andf are the I.V. and friction coefficients of the submolecule. Detailed examination is made of the eigenvalues _p (N, h ^*) and how they can be estimated by various approximations, and property predictions are made for these approximations.Comparisons are made with data from our preceding companion paper, representing intrinsic properties [], [], [] in very viscous theta solutions, so that theoretical foundations of the model are fulfilled. It is found that [ ()] data can be predicted well, but that [ ()] data cannot be matched at high. The latter deficiency is attributed in part to unrealistic predictions of coil deformation in shear.     

Free convection on an arbitrarily inclined plate with uniform surface heat flux

This paper proposed a proper inclination parameter and transformation variables for the analysis of free convection from an inclined plate with uniform surface heat flux to fluids of any Prandtl number. Very accurate numerical results and a simple correlation equation are obtained for arbitrary inclination from the horizontal to the vertical and for 0.001 Pr. Maximum deviation between the correlated and calculated data is less than 1.2%.

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Freie Konvektion an einer beliebig geneigten Platte mit erheblicher Wärmestromdichte an der Oberfläche

Zusammenfassung Für die Berechnung von freier Konvektion von Fluiden mit beliebiger Prandtl-Zahl an einer geneigten Platte mit einheitlicher Wärmestromdichte an der Oberfläche werden ein zweckmäßiger Neigungsparameter und Transformationsvariablen eingeführt. Sehr genaue numerische Ergebnisse und eine einfache Korrelationsgleichung wurden für beliebige Neigungen zwischen der Horizontalen und der Vertikalen und für 0.001Pr erhalten. Die größte Abweichung zwischen Korrelations- und berechneten Daten liegt bei weniger als 1.2%.

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Nomenclature f reduced stream function - g gravitational acceleration - h local heat transfer coefficient - k thermal conductivity - Nu local Nusselt number - p static pressure difference - Pr Prandtl number - q _w wall heat flux - Ra* modified local Rayleigh number,g(q _w x/k)x ³/ - T fluid temperature - T temperature of ambient fluid - u velocity component inx-direction - v velocity component iny-direction - x coordinate parallel to the plate - y coordinate normal to the plate Greek symbols thermal diffusivity - thermal expansion coefficient - (Ra* |sin|)^1/5/( Ra* cos)^1/6 - ( Ra* cos)^1/6+( Ra*|sin|)^1/5 - (y/x) - dimensionless temperature, (T–T )/(q _w x/k) - kinematic viscosity - [1+( Ra* cos)^1/6/( Ra*|sin|)^1/5]^–1 - density of fluid - Pr/(1+Pr) - _w wall shear stress - angle of inclination measured from the horizontal - stream function - dimensionless static pressure difference, p x ²/ ⁴