Half-lives,neutron emission probabilities and fission yields of neutron-rich rubidium isotopes in the mass regionA=96 toA=100

Neutron-rich rubidium isotopes were produced by thermal-neutron induced fission of²³⁵U and were isolated by surface ionization and mass separation. The new isotope (51 ±17) ms¹⁰⁰Rb was identified. The half-lives of the rubidium isotopes with mass numberA=96 toA=100 were measured using neutron multiscaling or gamma multispectrum analysis. Measurements of the delayed-neutron emission probabilityP _n of⁹⁹Rb and of the fission yields of⁹⁷Rb,⁹⁸Rb, and⁹⁹Rb were performed.     

High resolution spectroscopy of84m Rb and86m Rb

Gamma radiations from^84m Rb and^86m Rb, produced by (n, 2n) reaction on⁸⁵Rb and⁸⁷Rb respectively, have been studied using a high resolution Ge(Li) spectrometer. Gamma rays of 216.3±0.25, 248.2±0.25 and 464.5±0.25 keV have been found decaying with 20 min half-life and are assigned to^84m Rb. A single gamma ray of 556.1±0.25 keV was found to decay with 62 sec half-life and has been assigned to^86m Rb. The results are incorporated into decay schemes for the two isomers.     

The N = Z nuclide 74Rb with T,Iπ = 1, 0+

Improved experimental techniques have permitted the observation of the new nuclide ⁷⁴Rb with a half-life of 64.9 ± 0.5 ms, which represents the heaviest self-conjugate nucleus detected until now. The absenceof along-lived isomer indicates that the T = 0 state of ⁷⁴Rb lies a bove the T = 1 state. An upper limit of 10^?3 relative top ⁷⁴Rb can be placed on the yield of the (unobserved) mirror nucleus ⁷³Rb, and it appears likely that the limit of particle stability has been reached. The half-life of ⁷⁵Rb is 17.0 ± 1.0 s.     

The reaction Rb(d,p)Rb near the coulomb barrier

Cross sections for the reaction ⁸⁷Rb(d, p)⁸⁸Rb induced by 4 to 6 MeV deuterons were measured to obtain spectroscopic data on levels in ⁸⁸Rb. The Q-value for the reaction to the ground state of ⁸⁸Rb was 3.837 ± 0.020 MeV. In addition twenty-three levels up to 3 MeV excitation in ⁸⁸Rb were populated. Four different deuteron optical model parameter sets, which fit our ⁸⁷Rb(d, d) elastic scattering data, were used in a DWBA analysis. Assignments of l_n, were made to nine levels on the basis of angular distribution shapes and excitation functions. Relative spectroscopic factors were determined with a maximum deviation of only 15%. However absolute spectroscopic factors were extremely sensitive to the neutron radius parameter, and hence the normalization of the bound neutron wave functions. The structure of ⁸⁸Rb is discussed.     

PräziseQ β -Wert-Messungen mit einem Intrinsic-Germanium Detektor an leichten,neutronenreichen Spaltprodukten

An intrinsic Germanium detector of 10 mm depth and 300 mm² sensitive area has been used to determineβ-endpoint energies for Rb, Sr and Y fission products. It was calibrated with monoenergetic electrons supplied by a magnetic conversion electron spectrometer for the energy range from 1.6 to 8 MeV. The energy calibration of the detector is linear with deviations less than 2 · 10^?4, and the detector was recalibrated daily using precisely known gamma rays of⁹⁰Rb. At the on-line fission product separator OSTIS at the ILL, Grenoble the endpoints ofβ-singles-spectra have been determined andQ-values deduced if possible also from beta-gamma coincidence measurements. The obtainedQ-values are:⁸⁸Rb:(5 318±4) keV,⁸⁹Rb: (4 510 ± 8) keV,⁹⁰Rb: (6 578 ± 15) keV,⁹¹Rb: (5 857 ± 8) keV,⁹¹Sr: (2 704.5 ±3) keV,⁹²Rb: (8 111 + 15) keV,⁹³Rb:(7 485 ± 15) keV,⁹⁴Rb: (10 304 ± 30) keV,⁹⁴Sr: (3 512 ± 5) keV,⁹⁴Y: (4 920 ±5)keV,⁹⁵Rb: (8 947 ±100) keV,⁹⁵Y: (4 445±5) keV,⁹⁶Rb: (11 303±250) keV,⁹⁶Sr: (5 413±20) keV,⁹⁶Y: (7 120 ±50) keV,⁹⁷Rb: (10 020 ±50) keV.     

Transferred hyperfine field of Rb2CoCl4 single crystals in the ferroelectric-incommensurate-normal phase by Rb NMR

The molecular susceptibility and paramagnetic shift of Rb₂CoCl₄ single crystals grown using the slow evaporation method were measured, and from these experimental results we obtained the transferred hyperfine interaction due to the transfer of spin density from Co²⁺ ions to Rb⁺ ions. The transferred hyperfine field was obtained for the ferroelectric, incommensurate, and normal phases. In the case of Rb(I), the transferred hyperfine interaction decreases with increasing temperature in the incommensurate phase, and increases with increasing temperature in the normal phase. The value of H_hf in the incommensurate and normal phases increases abruptly with increasing temperature in the case of Rb(II). These results indicate that the effects due to the transfer of spin density from Co²⁺ ions to the Rb(I) and Rb(II) ions are large above T_i. In particular, the effect due to the transfer of spin density to Rb(II) ions in the normal phase is very large; the variations with temperature of the transferred hyperfine interactions of the Rb(I) and Rb(II) nuclei are more or less continuous in T_c1 and T_i, and are not affected by the ferroelectric-incommensurate-normal phase transitions.     

Die Konversion des86mRb

^86mRb was produced by irradiation of natural Rb and Rb enriched in⁸⁷Rb (99.2%) with fast neutrons. The half-life ofT _1/2=(61.2±1.0) sec and the energy ofE _ρ=(556.03±0.25) keV were remeasured. The experimental conversion coefficients α_tot=0.0184±0.0015 andα _K =0.0158±0.0015 yield the multipolarity of E4 for the isomeric transition. The spin of 6^? was assigned to the isomeric state. It is proposed that the spin 6^? is formed by coupling ap _3/2-proton and ag _9/2-neutron according to Nordheim's “weak” rule.     

Atomic resonance behavior in laser-induced Rb atom desorption—the effect of ambient gas atoms and molecules

We report an observation that in a typical optical pumping cell containing Rb metal and 150 Torr N₂ gas, a cw laser beam of a few tens of mW and beam size 5.5 mm² can desorb Rb films on cell surfaces when the laser is tuned to the Rb D₁ line. The frequency dependence of the Rb desorption rate displays atomic resonance behavior. The desorption is suggested to be mediated by the ambient gas atoms (Rb) and molecules (N₂). The phenomenon was used to provide evidence for the existence of thin Rb films on seemingly clear cell surfaces.     

Hyperfine structure,g j factors and lifetimes of excited2 P 1/2 states of Rb

The hyperfine structure of the 6² P _1/2 and 7² P _1/2 state of⁸⁵Rb and⁸⁷Rb and of the 6² P _3/2 state of⁸⁷Rb has been investigated with optical double resonance at intermediate magnetic fields. The magnetic interaction constants,g _j factors and lifetimes are: $$\begin{gathered} 6^2 P_{1/2} state: A\left( {^{85} Rb} \right) = 39.11\left( 3 \right) MHz,A\left( {^{87} Rb} \right) = 132.56 \left( 3 \right)MHz, \hfill \\ g_j = 0.6659\left( 3 \right), \tau = 1.14\left( {13} \right) \cdot 10^{ - 7} \sec , \hfill \\ 7^2 P_{1/2} state: A\left( {^{85} Rb} \right) = 17.68\left( 8 \right)MHz,A\left( {^{87} Rb} \right) = 59.92\left( 9 \right)MHz, \hfill \\ g_j = 0.6655\left( 5 \right), \hfill \\ 6^2 P_{3/2} state: g_j = 1.3337\left( {10} \right), \tau = 1.12\left( 8 \right) \cdot 10^{ - 7} \sec for ^{87} Rb. \hfill \\ \end{gathered} $$ From the hfs coupling constants of then ² P multiplets a 11.5% core polarization contribution to the magnetic hfs of then ² P _3/2 states is obtained, which is found to be independent from the main quantum numbern. The expectation values <r ^?3> _j for thenp valence electrons corrected for core polarization are compared with those derived from the² P fine structure separation. Good agreement is achieved for allnp levels with the choice ofZ _i =Z?3=34 for the effective nuclear charge number. The nuclear quadrupole moments of⁸⁵Rb and⁸⁷Rb are rederived on the basis of this more improved treatment for thep-electron-nucleus interaction yielding $$\begin{gathered} Q_N \left( {^{85} Rb} \right) = + 0.274\left( 2 \right) \cdot 10^{ - 24} cm^2 \hfill \\ Q_N \left( {^{85} Rb} \right) = + 0.132\left( 1 \right) \cdot 10^{ - 24} cm^2 \hfill \\ \end{gathered} $$ where the error does not include the remaining theoretical uncertainty of about 10%.     

Beta-decay energies and masses of short-lived isotopes of rubidium,caesium, francium,and radium

Total decay energies have been measured for a number of neutron-deficient Rb and Cs isotopes, as well as for some neutron-rich isotopes of Fr and Ra. Mass separated sources were produced at the ISOLDE on-line separator at CERN. By applying two differentβ-γ coincidence methods,Q values or their lower limits were determined for^76–78Rb,⁸⁰Rb,^121–124Cs,²²²Fr,^224–226Fr,²²⁹Ra-²²⁹Ac. For many of these nuclei, the atomic mass excesses could be derived, allowing the comparison of masses of far unstable nuclei with predictions from mass formulae. The odd-odd nuclei⁷⁶Rb and⁷⁸Rb appear to be 1?1 1/2 MeV more strongly bound than expected from the systematics.     

Fast neutron scattering from rubidium

A study was made of the (n, n), (n, n′), and (n, n′ γ) reactions which occur when a natural rubidium scattering sample is exposed to mono-energetic neutron fluxes of energies ranging from 120 to 1910 keV. Total cross sections, elastic scattering angular distributions and excitation functions for inelastic scattering were measured with a neutron time-of-flight spectrometer. Results are compared with Hauser-Feshbach theory. A 40 cc Ge(Li) detector was used in the time-gated mode to measure γ-rays from the (n, n′ γ) reaction. The latter measurements were used to refine and extend the energy level schemes derived from neutron spectroscopy. Several new levels were discovered in the low-lying (below 1900 keV) energy level spectra of⁸⁵Rb and⁸⁷Rb. Gamma decay schemes and branching ratios were determined for the low-lying levels of⁸⁵Rb and⁸⁷Rb.     

Phase transition and relaxation processes by 87Rb and 39K nuclear magnetic measurements of RbKSO4 single crystals

⁸⁷Rb and ³⁹K nuclear magnetic resonance (NMR) spectra of RbKSO₄ single crystals were measured at room temperature. ⁸⁷Rb central line has the angular dependences of second-order quadrupolar shifts. From these results, the quadrupole coupling constant and the asymmetry parameter were determined at room temperature. In addition, the spin–lattice relaxation rate, 1/T₁, and the spin–spin relaxation rate, 1/T₂, were measured as a function of temperature. The values of 1/T₁ for the ⁸⁷Rb and ³⁹K nuclei were found to increase with increasing temperature, and 1/T₁ was determined to be proportional to Tⁿ. Therefore, for the ⁸⁷Rb and ³⁹K nuclei, Raman processes with n=2 are more significantly in nuclear quadrupole relaxation than direct processes.     

Half-lives and delayed neutron emission probabilities of short-lived Rb and Cs precursors

Half-lives and delayed-neutron emission probabilities (P _n ) of short-lived Rb and Cs precursors in the mass chains 94–98 and 143–147 were measured. Sources of isotope separated nuclides were obtained from the on-line mass-separator OSTIS installed at the Grenoble high-flux reactor. A newP _n -value of (25.4±3.2)% is given for the (214±30) ms¹⁴⁷Cs; theP _n -values of nine alkali precursor nuclides were redetermined: (2,730±20) ms⁹⁴Rb with (9.7±0.5)%, (377 ±6)ms⁹⁵Rb with (8.6±0.5)%, (197±5)ms⁹⁶Rb with (12.5±0.9)%, (171±4) ms⁹⁷Rb with (25.2±1.8)%, (114±13)ms⁹⁸Rb with (18.4±2.9)%, (1,765±30)ms¹⁴³Cs with (1.74 ±0.12)%, (1,000±10)ms¹⁴⁴Cs with (2.95±0.25)%, (616±20) ms¹⁴⁵Cs with (12.2±0.9)%, (325±10)ms¹⁴⁶Cs with (13.2±0.8)%. The results are compared with the existing data, and theP _n -values are discussed within some simple model predictions.     

〈S0〉Cs and 〈S0〉Rb relaxation in the presence of buffer gas and the spin exchange between Cs and Rb

〈S⁰〉_Rb and 〈S⁰〉_Cs relaxation is studied in the presence of buffer gas and spin exchange between Cs and Rb. Spin exchange collisions are found to equalize the relaxation rates of Rb and Cs polarization. This result is completely confirmed experimentally for the relaxation of the first diffusion mode.     

Study of electromagnetic transition strengths in 81Rb

High-spin states in ⁸¹Rb were excited in the fusion-evaporation reaction ⁶⁵Cu(¹⁹F, p2n)⁸¹Rb. Their lifetimes were determined by means of the recoil distance and Doppler-shift attenuation techniques. Deduced B(E2) and B(M1) transition strengths are discussed in the framework of the asymmetric rotor-plus-particle model.     

Plasmons in monolayer Na,K and Rb films adsorbed on Ni(100)

Electronic excitations in denser monolayer Na, K and Rb films and Na duolayer films adsorbed on a Ni(100) surface have been investigated using Electron Energy Loss Spectroscopy (EELS). Lateral adatom distributions were monitored by LEED. Angular integrated EEL spectra from the ordered c(2 × 2)Na, coverage θ = 0.5, and the ordered hexagonal structures of K and Rb, θ = 0.29, show prominent losses at 3.1, 1.9 and 1.7 eV, of presumably collective nature. The loss energies shift with coverage as ∝ θ^0.4 and as ∝ θ^0.8 for the Na and K, Rb respectively. Angular resolved EEL spectra indicate an only weak dependence of the loss energies on the momentum transfer, Q. In particular the K and Rb losses seem to pass through shallow energy minima, which is predicted by the “box model”. Low energy losses observed at ?1.3 and ?1.0 eV for the c(2 × 2)Na and the hexagonal K and Rb, respectively, are tentatively identified with interband excitations. The observed interband energies yield, when introduced in the “box model”, 3.1., 2.3 and 2.4 eV for the Na, K and Rb, Q = 0 plasmon energies, which is in fair agreement with the observed plasmon loss energies.     

Microscopic aspects of identical bands in 78Sr and 78Rb

Recent investigations of the shape transition and shape coexistence phenomena dominating the structure of the even-even N ? Z nuclei in the A ? 80 mass region are extended to the odd-odd nucleus ⁷⁸Rb. Special attention is paid to the structure of some “identical” bands which have been recently identified in ⁷⁸ Sr and ⁷⁸Rb. The ground band of⁷⁸ Sr and the yrast as well as excited negative parity bands in ⁷⁸Rb are studied within the EXCITED VAMPIR approximation using complex Hartree-Fock-Bogoliubov transformations in a relatively large model space. The results are compared with the available experimental data. The emerging picture reveals the role played by the strong quadrupole deformation on the appearance of identical bands as well as the influence of the shape coexistence on their evolution. Predictions for the electromagnetic and alignment properties of the bands are presented.     

Effect of photoions on the line shape of the Förster resonance lines and microwave transitions in cold rubidium Rydberg atoms

Experiments are carried out on the spectroscopy of the Förster resonance lines Rb(37P) + Rb(37P) → Rb(37S) + Rb(38S) and microwave transitions nP → n′S, n′D between Rydberg states of cold rubidium atoms in a magneto-optical trap (MOT). Under ordinary conditions, all spectra exhibit a linewidth of 2–3 MHz irrespective of the interaction time between atoms or between atoms and microwave radiation, although the limit resonance width should be determined by the inverse interaction time. The analysis of experimental conditions has shown that the main source of line broadening is the inhomogeneous electric field of cold photoions that are generated under the excitation of initial nP Rydberg states by broadband pulsed laser radiation. The application of an additional electric-field pulse that rapidly extracts photoions produced by a laser pulse leads to a considerable narrowing of lines of microwave resonances and the Förster resonance. Various sources of line broadening in cold Rydberg atoms are analyzed.     

Nonlinear resonant polarization rotation under conditions of coherent population trapping

Nonlinear resonant optical rotation was studied over a wide range of experimental parameters at the Rb D ₁ F = 2→F′ = 1 transition in the ⁸⁷Rb vapor under conditions of coherent population trapping. The angle of rotation was found to depend nonmonotonically on the laser intensity and applied magnetic field. The effect of optical pumping out to the level F = 1 is discussed. It is demonstrated experimentally that the Faraday rotation angle increases twofold upon the compensation for pumping.     

Nuclear quadrupole moments of radioactive83Rb,84Rb and86Rb

Excited atomic² P _3/2-states of radioactive Rb isotopes have been investigated by level crossing and optical double resonance spectroscopy. The measured hyperfine structure constants yielded the nuclear moments $$\begin{gathered} \mu _I (^{84} Rb) = - 1.296(11)\mu _K Q(^{83} Rb) = + 0.27(5) \cdot 10^{ - 24} cm^2 \hfill \\ Q(^{84} Rb) = + 0.005(13) \cdot 10^{ - 24} cm^2 \hfill \\ Q(^{86} Rb) = + 0.20(3) \cdot 10^{ - 24} cm^2 \hfill \\ \end{gathered} $$ and the hyperfine anomaly₈₄Δ₈₅=+1.7(1.0) · 10^?2. The quadrupole moments of⁸³Rb to⁸⁷Rb can be explained with the unified model of vibrations.