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应用拉曼光谱法并结合聚类分析对44种不同型号的汽车前保险杠进行了深入的检验研究。采用显微激光拉曼光谱分析技术分别对样品进行检测,得到532nm激光光源的拉曼光谱可构建具有高鉴别能力的聚类分析模型,采集光谱数据将其定量化,选择平均组间距离定义类间距离,采用平方欧氏距离作为度量区间表征样品之间的亲疏程度,进行系统聚类分析,通过验证衡量聚类效果,成功将44种汽车前保险杠样本分为了19类,分类正确率达94.8%,分类结果理想,实现了基于全波段光谱信息结合系统聚类分析建立的模型用于准确鉴定汽车前保险杠种类的目的,为现场物证的检验提供了一定的理论依据。 相似文献
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拉曼光谱法已被广泛应用于印文油墨成分的检验,且具有快速准确、无损检材的优势。本文利用显微拉曼光谱,检验7种不同品牌和型号的印油所形成的印文样本,并对其在纸张上的扩散过程进行分析。通过获取印文样本在不同扩散距离、扩散时间下所对应的拉曼光谱变化,为分析印油在纸张上的扩散行为提供依据。实验结果表明,印油在短时间内即能达到一个较为稳定的状态,同时扩散过程会受到印油种类、纸张种类等因素的影响。 相似文献
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本文利用拉曼光谱对不同种类的毒品进行检验,利用拉曼光谱对同分异构体氯胺酮和羟亚胺、同系物合成大麻素JWH-018和JWH-073进行区分,并结合R软件,对成分未知的摇头丸样品中各组分的含量进行分析;并且利用拉曼光谱成像技术,对油汗混合指纹、护手霜油脂指纹、502熏显指纹上的毒品颗粒进行了检验。实验结果表明,拉曼光谱是分析各类毒品的有效手段,以其快速、无损、无需样品前处理的优势,实现对分子结构相似的样品的区分;结合拉曼光谱成像技术,可以获得毒品颗粒在指纹上的分布情况,在物证的现场检验中有良好的应用前景。 相似文献
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静电复印纸的鉴别是法庭科学物证检验中的一项重要工作。建立显微共聚焦拉曼光谱技术结合化学计量学检验、鉴别不同品牌、型号静电复印纸的分析方法,以实现对静电复印纸的无损检验和准确鉴别。收集不同品牌、不同型号的静电复印纸共计20种,利用激光波长为785 nm的半导体激光器,采集不同纸张样品的拉曼光谱数据,分析每种纸张样品中的主要特征峰及对应的物质成分;将光谱数据使用沃尔德系统聚类分析法进行分类,并采用主成分分析法评价聚类分析的鉴别结果。研究发现,不同纸张样品的主要特征峰集中在900~1 700 cm-1范围内,分别位于714, 892, 1 092, 1 119, 1 143, 1 343, 1 385, 1 470, 1 510和1 600 cm-1附近,主要成分为纤维素、木素和碳酸钙;各纸张样品的光谱曲线虽然相互交叠,但峰强度和峰面积存在一定差异,可利用化学计量学中的聚类分析和主成分分析对纸张样品的光谱数据进行分类鉴别。根据系统聚类分析的树状图和按计划表绘制的散点图可将20种不同品牌、不同型号的静电复印纸样品分为四类,其中第Ⅰ类中包含10份样品,... 相似文献
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本文开展了多波长纳秒脉冲拉曼激光对行间转移CCD相机的损伤实验。分别研究了496 nm、574 nm、630 nm单波长拉曼激光与混合输出的多波长拉曼激光对CCD的点损伤、线损伤和面损伤情况,测量了不同波长拉曼激光的损伤阈值区间,并根据损伤情况统计拟合,获得了不同波长拉曼激光能量与损伤概率的关系曲线。实验结果表明:混合波长拉曼激光对CCD的损伤阈值低于单波长拉曼激光的损伤阈值,不同波长拉曼激光对于CCD的损伤阈值也存在区别,其中630 nm拉曼激光的损伤阈值低于496 nm激光,574 nm激光的损伤阈值介于496 nm和630 nm拉曼激光之间。在此基础上,通过分析CCD不同损伤情况的显微图像,以及受损伤CCD的电子学特性,对拉曼激光损伤CCD的机理进行了探讨。 相似文献
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癌症患者血清的激光拉曼光谱 总被引:13,自引:0,他引:13
按正常人和不同种类癌症患者进行分类,用激光拉曼光谱分别对正常人,鼻咽癌患者、肝癌患者和慢性白血病患者四类受试者的血清在0-2000cm^-1范围内进行测试。结果表明,同类患者中不同受试者血清的激光拉曼光谱特征峰值大小虽然不同,但光谱图特征基本一致;不同种类癌症患者血清的激光拉曼光谱图存在较大差异;在各类癌症患者血清的激光拉曼光谱图特征峰附近,正常人血清均没有拉曼光谱特征峰。 相似文献
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A review of schemes for multiple access in fiber optic networks shows that a hybrid of wavelength and code division multiple access (WCDMA) combines the best features of both. In particular, the hybrid scheme retains the large information carrying capacity of wavelength division multiple access (WDMA) and flexibility of code division multiple access (CDMA). In this paper WDMA, optical CDMA (OCDMA), and WCDMA networks are discussed. In OCDMA networks, concept of incoherent and coherent coding including inverse decoding and matched filter is introduced. The delay performance of both WDMA and WCDMA networks, under the simple suboptimum access protocols based on cyclic search, is computed. It has been shown quantitatively that tuning delay significantly affects the delay performance of both WDMA and WCDMA networks. Futhermore, delay performance of WCDMA networks is always better than the WDMA networks for the same tuning delay, load, and number of users. 相似文献
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Guided-Wave Two-Dimensional Acousto-Optic Scanner Using Proton-Exchanged Lithium Niobate Waveguide 总被引:1,自引:0,他引:1
Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs. 相似文献
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A simple technique of pulse compression, based on the linear chirp compensation of self-phase modulation (SPM) spectra in dispersion shifted fibers, is demonstrated. The optimization procedure is carried out, for a short span of a single-mode fiber, using a parabolic law, which describes the behavior of the squared output pulse width versus the pump peak power in the case of Gaussian pulses. The experimental results give a minimum pulse duration of 233 fs, which is in good agreement with the model. Shorter and coherent pulses, down to 90 fs, have been obtained by inserting an interference filter at the optical output. 相似文献
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S. G. Nedel’ko M. A. Krysyuk A. L. Apanasenko L. N. Lymarenko Z. T. Moroz 《Journal of Applied Spectroscopy》1997,64(1):55-61
Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped
with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly
described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation
(5.5·104 Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum
cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics
of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure
crystals is analyzed (preliminarily).
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997. 相似文献
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References: 《声学学报:英文版》2008,27(1):23-33
The performance of port/starboard discrimination of dual-line array will be seriously degraded when the space between the two line arrays of the dual-line array is mismatched. The directivity function of the delay-sum and delay-subtract beamforming is deduced and the port/starboard discrimination of the delay-sum and delay-subtract beamforming is also studied both under the ideal status and the status under which the space between the two line arrays of the dual-line array is mismatched. Analysis results show the delay-subtract beamforming has better performance of port/starboard discrimination. At last, the sea trial results demonstrate the theoretical results. 相似文献
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The Shanghai Synchrotron Radiation Facility(SSRF)booster ring,a full energy injector for the storage ring,is deigned to accelerate the electron beam energy from 150MeV to 3.5GeV that demands high extraction efficiency at the extraction energy with low beam loss rate when electrons are ramping.Closed orbit distortion(COD)caused by bending magnet field uniformity errors which affects the machine performance harmfully could be effectively reduced by bending magnet location sorting.Considering the affections of random errors in measurement,both ideal sorting and realistic sorting are studied based on measured bending magnet field uniformity errors and one reasonable combination of bending magnets which can reduce the horizontal COD by a factor of 5is given as the final installation sequence of the booster bending magnets in this paper. 相似文献
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With a novel light-weight and absolutely calibrated ultraviolet (UV) spectrometer, UV skylight radiances and O3 slant column densities are measured by balloon-borne limb measurements in Xinjiang area, China. UV skylight radiances measured at the height of 31 km are compared with the results from Modtran in the wavelength range from 290 to 420 nm. O3 slant column densities are derived from radiance spectra in the Huggins bands (320 - 335 nm) using differential optical absorption spectroscopy method. And the parameter exhibits a good correlation with the same value simulated by radiative transfer model (Tracy). The O3 profile simultaneously measured by an O3 sonde is used as input in Tracy calculations. The O3 sonde is launched on the same balloon. 相似文献
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For breaking through the sensitivity limitation of conventional surface plasmon resonance (SPR) biosensors, novel highly sensitive SPR biosensors with Au nanoparticles and nanogratings enhancement have been proposed recently.But in practice, these structures have obvious disadvantages.In this study, a nanohole based sensitivity enhancement SPR biosensor is proposed and the influence of different structural parameters on the performance is investigated by using rigorous coupled wave analysis (RCWA).Electromagnetic field distributions around the nanohole are also given out to directly explain the performance difference for various structural parameters.The results indicate that significant sensitivity increase is associated with localized surface plasmons (LSPs) excitation mediated by nanoholes.Except to outcome the weakness of other LSP based biosensors, larger resonance angle shift, reflectance amplitude, and sharper SPR curves' width are obtained simultaneously under optimized structural parameters. 相似文献
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Novel polymer distributed feedback(DFB)gratings are fabricated based on photopolymerization to reduce lasing threshold of polymer lasers.A photopolymer formulation sensitive to 355-nm ultraviolet(UV)light is proposed for the fabrication of polymer gratings and it can be used to form polymer films by spin-coating process.A very low surface-relief depth ranging from 12.5 to about 1.0 nm has been demonstrated with a refractive-index modulation of about 0.012.The experimental results indicate that such polymer gratings have promising potentials for the fabrication of low-order DFB organic semiconductor lasers. 相似文献
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We propose a novel methodology based on the projector-camera (ProCam) system to address the photometric compensation issue for the projection display on the patterned screen.The patterned screen is treated as the combination of a perfect white screen and a color modulator.The perfect white screen is used to automatically and accurately characterize the ProCam system offline using the polynomial model,and the parameters of the color modulator can be efficiently recovered by employing only two gray images based on the linear reflectance model.The experimental results show that the color artifacts of the display image can be greatly improved with this methodology,which demonstrates its feasibility and validity in the photometric compensation. 相似文献