Propagation of electromagnetic waves in a medium with nonlinear magnetic susceptibility

The interaction of electromagnetic waves in a medium with nonlinear magnetic susceptibility is investigated. On the basis of Tinkham's measurements an antiferromagnet showing a resonance in the submillimeter region is considered as a nonlinear medium. The solution of both the Landau-Lifshitz and Maxwell equations leads to the RHS wave equation. Its solution with boundary conditions shows that the amplitude of the reflected wave from the nonlinear medium on a combined frequency can be non-zero.     

Rossby waves in the magnetic fluid dynamics of a rotating plasma in the shallow-water approximation

We have studied rotating magnetohydrodynamic flows of a thin layer of astrophysical plasma with a free boundary in the β-plane. Nonlinear interactions of the Rossby waves have been analyzed in the shallow-water approximation based on the averaging of the initial equations of the magnetic fluid dynamics of the plasma over the depth. The shallow-water magnetohydrodynamic equations have been generalized to the case of a plasma layer in an external vertical magnetic field. We have considered two types of the flow, viz., the flow in an external vertical magnetic field and the flow in the presence of a horizontal magnetic field. Qualitative analysis of the dispersion curves shows the presence of three-wave nonlinear interactions of the magnetic Rossby waves in both cases. In the particular case of zero external magnetic field, the wave dynamics in the layer of a plasma is analogous to the wave dynamics in a neutral fluid. The asymptotic method of multiscale expansions has been used for deriving the nonlinear equations of interaction in an external vertical magnetic field for slowly varying amplitudes, which describe three-wave interactions in a vertical external magnetic field as well as three-wave interactions of waves in a horizontal magnetic field. It is shown that decay instabilities and parametric wave amplification mechanisms exist in each case under investigation. The instability increments and the parametric gain coefficients have been determined for the relevant processes.     

Linear and nonlinear waves in crystals with charged dislocations

Based on the principle, a set of equations describing ultrasonic wave propagation in a dielectric crystal with charged dislocations has been derived. The linear dispersion relation has been derived, and the ultrasonic wave velocity and absorbance have been determined. In the case of the nonlinear ultrasonic wave, equations for its amplitude damping and phase variation have been obtained.     

Analysis of the tuning and operation of reflection resonator EPR spectrometers

This paper investigates basic characteristics of the electron paramagnetic resonance (EPR) signal obtained from spectrometers employing reflection resonators. General equations are presented which reveal the phase and amplitude dependence on instrumental parameters of both components of the continuous wave (CW) EPR signal (absorption and dispersion). New phase vector diagrams derived from these general equations are presented for the analysis of the EPR response. The dependence of the phase and absolute value of the CW EPR signal on the local oscillator (LO) phase and on resonator offset and coupling is presented and analyzed. The EPR spectrometer tuning procedures for both balanced and unbalanced heterodyne receivers are analyzed in detail using the new phase diagrams. Extraneous signals at the RF input of the microwave receiver (resulting from circulator leakage and reflections in the resonator transmission line) have been taken into account and analyzed. It is shown that a final tuning condition that corresponds to an extremum of the receiver output as a function of the resonator frequency is necessary and sufficient for the acquisition of pure absorption signal. This condition is universal: it applies to all spectrometer configurations in all frequency ranges. High Frequency EPR spectrometer (130 GHz) data are used to generate experimental phase diagrams that illustrate the theoretical concepts presented in the paper. Conditions are presented under which the absorption signal can be measured with complete suppression of the dispersion, independent of the mutual frequency offset between the microwave source and the EPR sample resonator. Equations describing the approximate relationship between changes of the resonator properties (Q-factor and frequency) and paramagnetic susceptibility are derived and analyzed.     

Acoustic activity effect for picosecond soliton-like pulses

A theoretical analysis is made of the acoustic activity for interfering picosecond acoustic soliton-like pulses of down to a single oscillation period. An analysis is made of the case where these pulses propagate parallel to an external magnetic field and one of the acoustic axes in a cubic crystal containing paramagnetic impurities having effective spin S = 1. Allowance is made for natural, magnetic (Faraday), and cross acoustic activity. This cross activity is caused by the significant spatial nonlocality of the spin-phonon interaction for such short pulses in crystals having no center of inversion in the presence of paramagnetic impurities. A system of nonlinear equations is obtained for the transverse and longitudinal components of the strain in the form of a coupling between the “differentiated” nonlinear Schrödinger equation (with nonlinearity after the derivative sign) and the Korteweg-de Vries equation which generalizes the known systems of long-short-wavelength resonance to the case where the slowly varying envelope approximation is not valid. An approximate solution of this system is used to study the structure of an elastic soliton-like pulse whose transverse component has a rotating plane of polarization, which propagates under conditions of nonlinear coupling with the longitudinal strain.     

Nonlinear waves in gas-fluidized beds

A mathematical model for gas-fluidized beds is examined which treats both the particles and gas as continua by volume averaging. The system is then considered as two interlocking one-phase fluids. For small perturbations to the uniform state, these equations have been shown by Crighton (1991) to reduce to the Burgers-KdV equation and under certain criteria, we have instability. We consider the unstable situation when the amplification effects are a perturbation to the KdV equation and take an initial condition of a single KdV soliton. The growth of this soliton is followed through several regions in which the unstable Burgers-KdV equation is no longer appropriate, but KdV remains the leading order equation. Eventually, there is a fundamental change in the solution and the new governing equations are fully nonlinear and O(1). These admit a solitary wave solution which matches back onto the KdV soliton. Thus, we can follow the formation of a bubble from a small amplitude perturbation to the uniform state.University of Cambridge, Cambridge, United Kingdom. Published in Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 36, No. 8, pp. 797–800, August, 1993.     

Instability of Fabry-Perot interferometer with a multilayered paramagnetic filling

The results of the analysis of the stability of stationary solutions of wave equations discribing a behavior of the nonlinear Fabry-Perot interferometer with a saturated paramagnetic filling are presented in this paper. The cases when paramagnetic medium is characterized by a homogeneously and nonhomogeneously broadened line of the magnetic resonance have been considered. Areas of unstable behavior of these characteristics of the resonance structure have been found.     

Time-Resolved EPR Spectra of Photoexcited Copper Porphyrin

Photoinduced spin-polarized transient electron paramagnetic resonance (EPR) spectra of copper 5,10,15,20-tetrakis(3-pyridyl)porphyrin (3PyNCu) in the frozen solution have been observed in the X-band. The time evolution and the temperature dependence of the spectra have been studied. The effect of molecular oxygen in the frozen solution on the polarization pattern has also been examined. The magnetic resonance parameters of the ground state of 3PyNCu have been obtained by comparing the experimental continuous-wave and echo-detected EPR spectra with the numerical computations. The magnetic resonance parameters of the excited states and the photoinduced polarizations have been investigated by time-resolved EPR (TREPR) spectroscopy and numerical analysis. The experimental spectra have been considered as a sum of the polarized spectra of the ground and excited states. Our analysis confirmed that the TREPR spectra consisted of two main patterns: the enhanced signal from the ground state and the multiplet contribution belonging to the excited quartet state.     

Nonlinear waves guided by a dielectric slab

An exact solution of Maxwell's equations is found for TM-polarized nonlinear guided waves which are guided by a linear dielectric slab embedded between two nonlinear uniaxial media. Additional waves in comparison with the linear case arise. Some of these waves have no counterpart in linear systems. Similarities and differences with respect to TE-polarized nonlinear guided waves are pointed out.     

Nonlinear waves and shocks in a rigid acoustical guide

A model is developed for the propagation of finite amplitude acoustical waves and weak shocks in a straight duct of arbitrary cross section. It generalizes the linear modal solution, assuming mode amplitudes slowly vary along the guide axis under the influence of nonlinearities. Using orthogonality properties, the model finally reduces to a set of ordinary differential equations for each mode at each of the harmonics of the input frequency. The theory is then applied to a two-dimensional waveguide. Dispersion relations indicate that there can be two types of nonlinear interactions either called "resonant" or "non-resonant." Resonant interactions occur dominantly for modes propagating at a rather large angle with respect to the axis and involve mostly modes propagating with the same phase velocity. In this case, guided propagation is similar to nonlinear plane wave propagation, with the progressive steepening up to shock formation of the two waves that constitute the mode and reflect onto the guide walls. Non-resonant interactions can be observed as the input modes propagate at a small angle, in which case, nonlinear interactions involve many adjacent modes having close phase velocities. Grazing propagation can also lead to more complex phenomena such as wavefront curvature and irregular reflection.     

Reconstruction of the first-derivative EPR spectrum from multiple harmonics of the field-modulated continuous wave signal

Selection of the amplitude of magnetic field modulation for continuous wave electron paramagnetic resonance (EPR) often is a trade-off between sensitivity and resolution. Increasing the modulation amplitude improves the signal-to-noise ratio, S/N, at the expense of broadening the signal. Combining information from multiple harmonics of the field-modulated signal is proposed as a method to obtain the first derivative spectrum with minimal broadening and improved signal-to-noise. The harmonics are obtained by digital phase-sensitive detection of the signal at the modulation frequency and its integer multiples. Reconstruction of the first-derivative EPR line is done in the Fourier conjugate domain where each harmonic can be represented as the product of the Fourier transform of the 1st derivative signal with an analytical function. The analytical function for each harmonic can be viewed as a filter. The Fourier transform of the 1st derivative spectrum can be calculated from all available harmonics by solving an optimization problem with the goal of maximizing the S/N. Inverse Fourier transformation of the result produces the 1st derivative EPR line in the magnetic field domain. The use of modulation amplitude greater than linewidth improves the S/N, but does not broaden the reconstructed spectrum. The method works for an arbitrary EPR line shape, but is limited to the case when magnetization instantaneously follows the modulation field, which is known as the adiabatic approximation.     

Solitary waves in the Madelung's fluid: Connection between the nonlinear Schrödinger equation and the Korteweg-de Vries equation

An investigation to deepen the connection between the family of nonlinear Schr?dinger equations and the one of Korteweg-de Vries equations is carried out within the context of the Madelung's fluid picture. In particular, under suitable hypothesis for the current velocity, it is proven that the cubic nonlinear Schr?dinger equation, whose solution is a complex wave function, can be put in correspondence with the standard Korteweg-de Vries equation, is such a way that the soliton solutions of the latter are the squared modulus of the envelope soliton solution of the former. Under suitable physical hypothesis for the current velocity, this correspondence allows us to find envelope soliton solutions of the cubic nonlinear Schr?dinger equation, starting from the soliton solutions of the associated Korteweg-de Vries equation. In particular, in the case of constant current velocities, the solitary waves have the amplitude independent of the envelope velocity (which coincides with the constant current velocity). They are bright or dark envelope solitons and have a phase linearly depending both on space and on time coordinates. In the case of an arbitrarily large stationary-profile perturbation of the current velocity, envelope solitons are grey or dark and they relate the velocity u₀ with the amplitude; in fact, they exist for a limited range of velocities and have a phase nonlinearly depending on the combined variable x-u_{0 s} (s being a time-like variable). This novel method in solving the nonlinear Schr?dinger equation starting from the Korteweg-de Vries equation give new insights and represents an alternative key of reading of the dark/grey envelope solitons based on the fluid language. Moreover, a comparison between the solutions found in the present paper and the ones already known in literature is also presented. Received 20 February 2002 and Received in final form 22 April 2002 Published online 6 June 2002     

The reverse shift of the EPR line of paramagnetic centers coupled to species with a fast paramagnetic relaxation

The EPR spectrum of the spin 1/2 paramagnetic centers with a relatively slow relaxation is considered in the case when they are coupled via the Heisenberg exchange interaction to partners which have short times of the longitudinal and transverse paramagnetic relaxation. Under these conditions only the EPR line of paramagnetic centers with a relatively slow relaxation is detectable in experiment. The shape of this line is analyzed by solving numerically kinetic equations for the spin density matrix for simple model systems. Depending on a ratio between the exchange integral and the paramagnetic relaxation rates of partner spins, the EPR line shifts in opposite directions. For moderate relaxation rates, as the relaxation rates decrease, the EPR line shifts toward the gravity center of the total EPR spectrum. In the case of extremely fast relaxation, as the relaxation rates decrease, the reverse shift of the EPR line is expected, the line shifts away from the gravity center of the total EPR spectrum. This type of the non-monotonous line shift was experimentally observed for the monocrystal of [CuNd₂(C₄O₄)₄(H₂O)₁₆] · 2H₂O when relaxation rates were changed by temperature variation.     

Nonlinear spiral waves in a galactic disk

An analytical solution of the nonlinear dynamic equations for a galactic disk is found. This solution describes the spiral design of spiral galaxies. The logarithmic profile of the spiral design and relatively larger density fluctuations as compared to velocity-field fluctuations are explained. Breaking of the obtained solution takes place for a certain critical amplitude. This can be a mechanism for the formation of galactic shocks and narrow star formation regions.     

Scattering of ultrasonic shock waves in suspensions of silica nanoparticles

Experiments are carried out to assess, for the first time, the validity of a generalized Burgers' equation, introduced first by Davidson [J. Acoust. Soc. Am. 54, 1331-1342 (1973)] to compute the nonlinear propagation of finite amplitude acoustical waves in suspensions of "rigid" particles. Silica nanoparticles of two sizes (33 and 69 nm) have been synthesized in a water-ethanol mixture and precisely characterized via electron microscopy. An acoustical beam of high amplitude is generated at 1 MHz inside a water tank, leading to the formation of acoustical shock waves through nonlinear steepening. The signal is then measured after propagation in a cylinder containing either a reference solution or suspensions of nanoparticles. In this way, a "nonlinear attenuation" is obtained and compared to the numerical solution of a generalized Burgers' equation adapted to the case of hydrosols. An excellent agreement (corresponding to an error on the particles size estimation of 3 nm) is achieved in the frequency range from 1 to 40 MHz. Both visco-inertial and thermal scattering are significant in the present case, whereas thermal effects can generally be neglected for most hydrosols. This is due to the value of the specific heat ratio of water-ethanol mixture which significantly differs from unity.     

Effects of axial magnetic field and nonextensivity on small amplitude dust acoustic solitary waves in dusty plasma

The nonlinear propagation of small amplitude dust‐acoustic (DA) solitary waves in magnetized dusty plasma consisting of negatively charged mobile dust fluid, and Boltzmann‐distributed electrons and ions with two distinct temperatures following a q‐nonextensive distribution are investigated. In this article, a number of nonlinear equations, namely, the Korteweg–de‐Vries (K‐dV) equations, have been derived by employing the reductive perturbation technique that is valid for a small but finite amplitude limit. The effects of nonextensivity of ions with two distinct temperatures and dust concentration on the amplitude and width of DA solitary waves are investigated theoretically. It is observed that both the nonextensive and low‐temperatures ions significantly modify the basic properties and polarities of DA solitary waves. It is shown that both positive and negative potential DA solitons occur in this case. The implications of these results to some astrophysical environments and space plasmas (e.g., stellar polytropes, peculiar velocity distributions of galaxies, and collisionless thermal plasma), and laboratory dusty plasma systems are briefly mentioned.     

Magnetic resonance in systems with equivalent spin-1/2 nuclides. Part 1

Electron paramagnetic resonance (EPR) spectra of S=1/2 systems XL(n) with n equivalent nuclei having spin I=1/2 have been simulated for microwave frequencies in the L-, X-, and W-bands. It has been shown that for n>2 nuclei, the EPR spectra have a more complicated form than anticipated from the usual oversimplified analysis, which predicts n+1 lines with intensity ratios given by the coefficients of the binomial expansion. For the XL(n) system with n=3, the EPR spectra in fact consist of six lines. The exact solution of the spin-hamiltonian for this case has been obtained, which gives four levels in zero magnetic field. For n>2 systems, the degeneracy of the energy levels cannot be completely removed by the Zeeman electronic and nuclear interactions. For n>4, certain spin states cannot occur, consistent with the (generalized) Pauli exclusion principle. Discussion of the underlying theory, invoking exchange degeneracy and the appropriate permutation group theory, is included in some detail. Analogous considerations hold for NMR spectroscopy of non-radicals.     

Determination of differential quantum yields in solution by electron paramagnetic resonance spectroscopy

Quantitative kinetic studies on the photochemistry of paramagnetic species in solution may be carried out by electron paramagnetic resonance (EPR) spectroscopy. A cylindrical cell can be used as photochemical reactor, but the internal diameter should be less than 1.7 mm in order to achieve the resonance of an aqueous sample in an X-band (9–10 GHz) spectrometer. In this paper we present a detailed analysis of the fractions of incident light that are reflected, transmitted and absorbed by a liquid solution in a quartz cylindrical cell placed in the optical cavity of an X-band EPR spectrometer. Since the photolysis cell is irradiated perpendicularly to its axis, variable angles of incidence have been considered to calculate the transmission and reflection coefficients from Fresnel equations. Polarization of light has been also taken into account in the evaluation of the coefficients. The procedure proposed here is adequate for the evaluation of the absorbed light in the determination of quantum yields. The continuous photolysis at 366 nm of symmetric chlorine dioxide (OCIO) in aqueous solution was considered as an example. The initial differential quantum yield obtained for OCIO photodecomposition in aqueous solution was Θ₃₆₆ = 0.55 ± 0.04.     

Modulation of electromagnetic waves by time-dependent magnetic fields in a ferrite

The modulation of phase and amplitude of an electromagnetic wave in a ferrite by a longitudinal, time-dependent (sinusoidally modulated) magnetic field has been investigated. In the case of an infinite medium, an analytical expression for the amplitude envelope of the wave is obtained and it is found that the envelope differs appreciably from the sinusoidal form. In the case of a ferrite slab, the amplitude of the transmitted and the reflected components of the magnetic vector have been evaluated by an expansion method. Numerical calculations indicate, as expected, that for a uniform plane wave incident on a ferrite sheet of finite thickness, the transmitted beam is strongly amplitude modulated.