共查询到20条相似文献,搜索用时 15 毫秒
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Krohn K Cludius-Brandt S Schulz B Sreelekha M Shafi PM 《Natural product communications》2011,6(11):1595-1596
Several biologically active alkaloids (1-4, 6), including a new quinazoline-6-carboxylic acid (1), were isolated from the medicinal plant Zanthoxylum rhetsa, an evergreen tree, native to subtropical areas. Whereas the pharmacological properties of the plant extract and single constituents have been widely tested, we now show that all of the metabolites have antialgal activities, all but 6 are antibacterial, and 6 and the reduction product 5 (derived from 4) are also antifungal. 相似文献
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From the roots of Baill. an unsymmetrical dimeric alkaloid has been isolated and called sungucine. Its original structure has been established by X-Ray diffraction; UV, IR, MS and NMR data are also given. 相似文献
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A new carboline alkaloid, 1-(7-methoxy-quinolinyl-4′-yl)-3,4-dihydro-β-carboline (1), was isolated from the leaves and twigs of Trigonostemon lii Y.T. Chang, together with three known ones, trigonostemonines C and D (2 and 3), and trigonoliimine A (4). Their structures were elucidated by spectroscopic analyses, including 2D-NMR techniques. 相似文献
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A new lycodine alkaloid, N-methylhydroxypropyllycodine (1), was isolated from the club moss Lycopodium japonicum Thunb, together with five known compounds, N-methyllycodine (2), huperzinine (3), β-obscurine (4), α-obscurine (5) and des-N-methyl-α-obscurine (6). Their structures were elucidated by spectroscopic analyses, including 2D NMR techniques. 相似文献
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A securinega-type alkaloid epibubbialine was isolated from Phyllanthus niruri Linn. Its structure was established by spectroscopic methods and X-ray single-crystal diffraction analysis. Its crystal structure is reported herein for the first time. 相似文献
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Di YT He HP Wang YS Li LB Lu Y Gong JB Fang X Kong NC Li SL Zhu HJ Hao XJ 《Organic letters》2007,9(7):1355-1358
[structure: see text]. A new hexacyclic alkaloid, calydaphninone (1), containing a 4-azatricyclo[5.2.2.0(1,4)]undecan ring system, has been isolated from the leaves and twigs of Daphniphyllum calycillum (Daphniphyllaceae). Its structure was elucidated by spectral and crystallographic means. Furthermore, conformations of calydaphninone (1) in solution are discussed on the basis of NMR spectral analysis and computational (B3LYP/6-31G*) results. 相似文献
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The aerial part of Nauplius aquaticus afforded a new sesquiterpene lactone with a humulanolide skeleton, 6,7,9,10-tetrahydroasteriscunolide (1), in addition to the known asteriscunolides A (2) and D (3). Their structures were established principally by two-dimensional NMR spectroscopy. 相似文献
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Anna Palumbo Marco dIschia Giovanna Misuraca Giuseppe Prota 《Tetrahedron letters》1982,23(31):3207-3208
Unfertilized sea urchin eggs (Paracentrotus lividus) contain, in addition to glutathione, a new low molecular weight thiol, 1-methyl-5-thiol-l-histidine () which was isolated and characterized as the disulphide by spectral and chemical evidence. 相似文献
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Isolation, synthesis and photochemical properties of almazolone, a new indole alkaloid from a red alga of Senegal 总被引:1,自引:0,他引:1
An indole alkaloid bearing an oxazolone ring, christened almazolone, has been isolated from a new collection of Haraldiophyllum sp. from Dakar (Senegal), as an 88:12 mixture of (Z)/(E) stereoisomers. The relative ratio could be modified under controlled photochemical and thermal processes. The product (Z)-3-indolyl-2-(phenyl-propionylamino)-acrylic acid obtained by oxazolone ring opening has also been observed. Its formation has been confirmed by alkaline hydrolysis of (Z)-almazolone available from synthesis, where condensation of indole-3-carboxaldehyde with (3-phenylpropionylamino)-acetic acid represents the key step. 相似文献
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Chun-Mei Sai Ning-Bo Qin Cui-Cui Jia Da-Hong Li Kai-Bo Wang Yue-Hu Pei Jiao Bai Zhan-Lin Li Hui-Ming Hua 《中国化学快报》2016,27(11):1717-1720
Macleayine (1),a new natural occurring alkaloid with a unique spiro[furanone-piperidinedione] framework,was isolated from the aerial parts of Macleaya cordata.Its unusual structure was established by extensive spectroscopic analyses,computer-assisted structure elucidation software (ACD/Structure Elucidator),quantum chemistry calculations and ECD calculation.The result of virtual molecular docking predicted the compound can enhance the effects of insulin,and may be used to treat type II diabetes. 相似文献
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《中国化学快报》2016,(11)
Macleayine(1),a new natural occurring alkaloid with a unique spiro[furanone-piperidinedione]framework,was isolated from the aerial parts of Madeaya cordata.Its unusual structure was established by extensive spectroscopic analyses,computer-assisted structure elucidation software(ACD/Structure Elucidator),quantum chemistry calculations and ECD calculation.The result of virtual molecular docking predicted the compound can enhance the effects of insulin,and may be used to treat type II diabetes. 相似文献
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Staerk D Larsen J Larsen LA Olafsdottir ES Witt M Jaroszewski JW 《Natural product research》2004,18(3):197-203
A new natural product, named selagoline, and two known alkaloids, huperzine A and serratidine, were isolated from Huperzia selago (Lycopodiaceae) collected in Iceland. Their structures were determined using 600 and 800MHz one- and two-dimensional NMR methods supported by Fourier-transform mass spectrometry. Possible role of selagoline as a precursor of 5,15-oxidolycopodane, a component of the classical alkaloids L28 and L31, is discussed. 相似文献