An investigation on near wall transport characteristics in an adiabatic upward gas–liquid two-phase slug flow

The near-wall transport characteristics, inclusive of mass transfer coefficient and wall shear stress, which have a great effect on gas–liquid two-phase flow induced internal corrosion of low alloy pipelines in vertical upward oil and gas mixing transport, have been both mechanistically and experimentally investigated in this paper. Based on the analyses on the hydrodynamic characteristics of an upward slug unit, the mass transfer in the near wall can be divided into four zones, Taylor bubble nose zone, falling liquid film zone, Taylor bubble wake zone and the remaining liquid slug zone; the wall shear stress can be divided into two zones, the positive wall shear stress zone associated with the falling liquid film and the negative wall shear stress zone associated with the liquid slug. Based on the conventional mass transfer and wall shear stress characteristics formulas of single phase liquid full-pipe turbulent flow, corrected normalized mass transfer coefficient formula and wall shear stress formula are proposed. The calculated results are in good agreement with the experimental data. The shear stress and the mass transfer coefficient in the near wall zone are increased with the increase of superficial gas velocity and decreased with the increase of superficial liquid velocity. The mass transfer coefficients in the falling liquid film zone and the wake zone of leading Taylor bubble are lager than those in the Taylor bubble nose zone and the remaining liquid slug zone, and the wall shear stress associated falling liquid film is larger than that associated the liquid slug. The mass transfer coefficient is within 10⁻³ m/s, and the wall shear stress below 10³ Pa. It can be concluded that the alternate wall shear stress due to upward gas–liquid slug flow is considered to be the major cause of the corrosion production film fatigue cracking.     

Experimental study on hydrodynamic characteristics of upward gas–liquid slug flow

To clarify the impacts of the hydrodynamic boundary layer and the diffusion boundary layer in the near wall zone on gas–liquid two-phase flow induced corrosion in pipelines, the hydrodynamic characteristics of fully developed gas–liquid slug flow in an upward tube are investigated with limiting diffusion current probes, conductivity probes and digital high-speed video system. The Taylor bubble and the falling liquid film characteristics are studied, the effects of various factors are examined, and the experimental results are compared with the data and models available in literature. The length of Taylor bubble, the local void fraction of the slug unit and the liquid slug, the shear stress and mass transfer coefficient in the near wall zone, are all increased with the increase of superficial gas velocity and decreased with the increase of superficial liquid velocity, whereas the length of liquid slug and the liquid slug frequency are changed contrarily. The alternate wall shear stress due to upward gas–liquid slug flow is considered to be one of the major causes for the corrosion production film fatigue cracking. A normalized formula for mass transfer coefficient is obtained based on the experimental data.     

Hydrodynamic and mass transfer characteristics of slug flow in a vertical pipe with and without dispersed small bubbles

In this work, we present a numerical study to investigate the hydrodynamic characteristics of slug flow and the mechanism of slug flow induced CO₂ corrosion with and without dispersed small bubbles. The simulations are performed using the coupled model put forward by the authors in previous paper, which can deal with the multiphase flow with the gas–liquid interfaces of different length scales. A quasi slug flow, where two hypotheses are imposed, is built to approximate real slug flow. In the region ahead of the Taylor bubble and the liquid film region, the presence of dispersed small bubbles has less impacts on velocity field, because there are no non-regular intensive disturbance forces or centrifugal forces breaking the balance of the liquid and the dispersed small bubbles. In the liquid slug region, the strong centrifugal forces generated by the recirculation below the Taylor bubble lead to the effect of heterogeneity, which makes the profile of the radial liquid velocity component sharper with higher volume fraction of dispersed small bubbles. The volume fraction has a maximum value in the range of r/R = 0.5–0.6. Meanwhile, it is usually higher than 0.35, which means that larger dispersed bubbles can be formed by coalescences in this region. These calculated results are in good agreement with experimental results. The wall shear stress and the mass transfer coefficient with dispersed small bubbles are higher than those without dispersed small bubbles due to enhanced fluctuations. For short Taylor bubble length, the average mass transfer coefficient is increased when the gas or liquid superficial velocity is increased. However, there may be an inflection point at low mixture superficial velocities. For the slug with dispersed small bubbles, the product scales still cannot be damaged directly despite higher wall shear stress. In fact, the alternate wall shear stress and the pressure fluctuations perpendicular to the pipe wall with high frequency are the main cause for breaking the product scales.     

One-way coupled fluid–structure interaction of gas–liquid slug flow in a horizontal pipe: Experiments and simulations

Pipelines conveying a multiphase mixture must withstand the cyclic induced stresses that occur due to the alternating motion of gas pockets and liquid slugs. Few previous studies have considered gas–liquid slug flow and the associated fluid–structure interaction problems. In this study, experimental and numerical techniques were adopted to simulate and analyze the two-phase slug flow and the associated stresses in the pipe structure. In the numerical simulation, a one-way coupled fluid–structure framework was developed to explore the slug flow interaction with a horizontal pipe assembly under various superficial gas and liquid velocities. A modified Volume of Fluid and finite element methods were utilized to model the fluid and structure domains. The file-based coupling technique was adopted to execute the coupling mechanism. By contrast, slug characteristics were measured experimentally, while Bi-axial strain gauges were used to capture time-varying strain signals. Excellent agreements between the predicted and measured stress results were achieved with a maximum error of 10.2 %. It was found that at constant superficial liquid velocity, the maximum induced stresses on the pipe wall increased with increasing the slug length and slug velocity. While for the slug frequency, the maximum principal stresses decreased with increasing the slug frequency.     

Study of local hydrodynamic characteristics of upward slug flow

Results of an experimental study of local velocity, fluctuation and void fraction profiles in liquid plugs of an upward vertical gas-liquid flow as well as of wall shear stress distribution both under gas slugs and in liquid plugs, are presented. The conditional sampling technique allowed to obtain instantaneous profiles of the above hydrodynamical quantities, which illuminated the real physical picture of the flow in a liquid plug. The toroidal vortex adjacent to the bottom of a gas slug is shown to determine significantly the development of the flow in a liquid plug. The intensity of this vortex is determined only by the relative velocity of the gas bubble with respect to the liquid.     

Gas–liquid mass transfer in the gas–liquid–solid mini fluidized beds

The gas–liquid–solid mini fluidized bed (GLSMFB) combines the advantages of fluidized bed and micro-reactor, and meets the requirements for safety and efficiency of green development of process industry. However, there are few studies on its flow performance and no studies on its mass and heat transfer performance. In this paper, the characteristics of gas–liquid mass transfer in a GLSMFB were studied in order to provide basic guidance for the study of GLSMFB reaction performance and application. Using CO₂ absorption by NaOH as the model process, the gas–liquid mass transfer performance of GLSMFB was investigated. The results show that the liquid volumetric mass transfer coefficient and the gas–liquid interfacial area both increase with the increase of the superficial gas velocity within the experimental parameter range under the same given superficial liquid velocity. At the same ratio of superficial gas to liquid velocity, the liquid volumetric mass transfer coefficient increases with the increase of the superficial liquid velocity. Fluidized solid particles strengthen the liquid mass transfer process, and the liquid volumetric mass transfer coefficient is about 13% higher than that of gas–liquid mini bubble column.     

Planar dynamics of inclined curved flexible riser carrying slug liquid–gas flows

Flexible risers transporting hydrocarbon liquid–gas flows may be subject to internal dynamic fluctuations of multiphase densities, velocities and pressure changes. Previous studies have mostly focused on single-phase flows in oscillating pipes or multiphase flows in static pipes whereas understanding of multiphase flow effects on oscillating pipes with variable curvatures is still lacking. The present study aims to numerically investigate fundamental planar dynamics of a long flexible catenary riser carrying slug liquid–gas flows and to analyse the mechanical effects of slug flow characteristics including the slug unit length, translational velocity and fluctuation frequencies leading to resonances. A two-dimensional continuum model, describing the coupled horizontal and vertical motions of an inclined flexible/extensible curved riser subject to the space–time varying fluid weights, flow centrifugal momenta and Coriolis effects, is presented. Steady slug flows are considered and modelled by accounting for the mass–momentum balances of liquid–gas phases within an idealized slug unit cell comprising the slug liquid (containing small gas bubbles) and elongated gas bubble (interfacing with the liquid film) parts. A nonlinear hydrodynamic film profile is described, depending on the pipe diameter, inclination, liquid–gas phase properties, superficial velocities and empirical correlations. These enable the approximation of phase fractions, local velocities and pressure variations which are employed as the time-varying, distributed parameters leading to the slug flow-induced vibration (SIV) of catenary riser. Several key SIV features are numerically investigated, highlighting the slug flow-induced transient drifts due to the travelling masses, amplified mean displacements due to the combined slug weights and flow momenta, extensibility or tension changes due to a reconfiguration of pipe equilibrium, oscillation amplitudes and resonant frequencies. Single- and multi-modal patterns of riser dynamic profiles are determined, enabling the evaluation of associated bending/axial stresses. Parametric studies reveal the individual effect of the slug unit length and the translational velocity on SIV response regardless of the slug characteristic frequency being a function of these two parameters. This key observation is practically useful for the identification of critical maximum response.     

Investigation on two-phase flow-induced vibrations of a piping structure with an elbow

The dynamic behaviors of a horizontal piping structure with an elbow due to the two-phase flow excitation are experimentally investigated. The effects of flow patterns and superficial velocities on the pressure pulsations and vibration responses are evaluated in detail. A strong partition coupling algorithm is used to calculate the flow-induced vibration (FIV) responses of the pipe, and the theoretical values agree well with the experimental results. It is found that the lateral and axial vibration responses of the bend pipe are related to the momentum flux of the two-phase flow, and the vibration amplitudes of the pipe increase with an increase in the liquid mass flux. The vertical vibration responses are strongly affected by the flow pattern, and the maximum response occurs in the transition region from the slug flow to the bubbly flow. Moreover, the standard deviation (STD) amplitudes of the pipe vibration in three directions increase with an increase in the gas flux for both the slug and bubbly flows. The blockage of liquid slugs at the elbow section is found to strengthen the vibration amplitude of the bend pipe, and the water-blocking phenomenon disappears as the superficial gas velocity increases.     

Experimental study of “laminar” bubbly flows in a vertical pipe

Measurement of bubbly two-phase flow parameters in a vertical pipe were performed. To keep the pipe Reynolds number below that for single-phase turbulent transition, a water-glycerin solution was used as the test liquid. Local void fraction and liquid velocity profiles along with the wall shear stress were measured by an electrochemical method. Experiments were made with bubbles of two different sizes. As the gas flow rate was increased, a gradual development of the liquid velocity profile from the parabolic Poiseuille flow to a flattened two-phase profile was observed. The evolution of the wall shear stress and of the velocity fluctuations were also quantified.Centre National de la Recherche Scientifique. Université Joseph Fourier, Institut National Polytechnique de Grenoble.     

Perturbation of a downward liquid flow by a stationary gas slug

The effect of a stationary gas slug on the hydrodynamics of a downward liquid flow in a pipe is investigated. The electro-diffusion technique is used to measure the mean and fluctuating viscous stresses on the wall below the gas slug and in the liquid behind the slug base. It is shown that at a constant liquid velocity the friction beneath the slug is determined by the distance from its nose. The flow structure perturbation due to a single slug is recorded at distances greater than 25 pipe diameters from the slug base.     

Positive frictional pressure gradient in vertical gas-high viscosity oil slug flow

The present study describes the wall shear stress and the falling liquid film behavior in upward vertical slug flow of air and high viscosity oil. The frictional pressure gradient is directly related to the wall shear stress, and it is usually negative (opposite to the overall flow direction). However, in vertical slug flow, the average total wall shear stress of a slug unit may be negative (in the same direction of the overall flow), resulting in a positive frictional pressure gradient. However, this does not mean, by any way, generation of additional energy or violation of the second law of thermodynamics.The positive frictional pressure gradient phenomenon, reasons and required conditions were explained in this paper. A simplified model was developed and validated against recent experimental data of air-high viscosity oil slug flow in a 50.8 mm ID vertical pipe. The oil viscosity was in the range of 127 mPa s to 580 mPa s. Positive frictional pressure gradient appears when the liquid film wall shear stress supersede the wall shear stress in the slug body. The rate of increase of both wall shear stresses (with respect to the mixture Reynolds number) depend, not only, on the mixture Reynolds number but also, highly, on the liquid viscosity.     

Three-dimensional numerical analysis of heat and mass transfer in heat pipes

A three-dimensional finite-element numerical model is presented for simulation of the steady-state performance characteristics of heat pipes. The mass, momentum and energy conservation equations are solved for the liquid and vapor flow in the entire heat pipe domain. The calculated outer wall temperature profiles are in good agreement with the experimental data. The estimations of the liquid and vapor pressure distributions and velocity profiles are also presented and discussed. It is shown that the vapor flow field remains nearly symmetrical about the heat pipe centerline, even under a non-uniform heat load. The analytical method used to predict the heat pipe capillary limit is found to be conservative.     

Slug and bubble flows in a flat sheet ultrafiltration module: Experiments and numerical simulation

In this paper, the effect of gas bubbling including slug and bubble flows on enhancing shear force in an ultrafiltration (UF) process in a flat sheet module is investigated experimentally by image processing and numerically using the OpenFOAM software. In order to study characteristics of bubbles in the slug and bubble flows, the flat sheet module is analyzed by a video system facilitated with a high speed camera. The experimental results show that the average diameter of the slug flow is much larger than that of the bubble flow. The permeate flux for the slug and bubble flows is increased by 78% and 30%, respectively, compared to the case with no gas bubbling. The numerical results are shown to be in good agreement with those of the measurements both qualitatively and quantitatively. The results of simulations also demonstrate that although both flow patterns increase the shear stress by increasing the velocity gradient and/or vorticity, the shear stress induced by the slug flow is considerably larger. Therefore, the slug flow with a higher induced shear stress is more effective on the enhancement of the permeate flux in a UF process.     

Visualization of flow boiling of liquid nitrogen in a vertical mini-tube

The flow boiling patterns of liquid nitrogen in a vertical mini-tube with an inner diameter of 1.931 mm are visualized with a high-speed digital camera. The superficial gas and liquid velocities are in the ranges of 0.01–26.5 m/s and 0.01–1.2 m/s, respectively. Four typical flow patterns, namely, bubbly, slug, churn and annular flow are observed. Some interesting scenes about the entrainment and liquid droplet deposition in the churn and annular flow, and the flow reversal with the indication of negative pressure drop, are also presented. Based on the visualization, the two-phase flow regime maps are obtained. Compared with the flow regime maps for gas–water flow in tubes with similar hydraulic diameters, the region of slug flow in the present study reduces significantly. Correspondingly, the transition boundary from the bubbly flow to slug flow shifts to higher superficial gas velocity, and that of churn to annular flow moves to lower superficial gas velocity. Moreover, time-averaged void fraction is calculated by quantitative image-digitizing technique and compared with various prediction models. Finally, three kinds of oscillations with long-period and large-amplitude are found, possible explanation for the oscillations is given by comparing the instantaneous flow images with the data of pressure, mass flux and temperature recorded synchronously.     

Local characteristics of upward gas-liquid flows

The results of two-phase flow structure measurements in an upward gas-liquid flow in a 86.4 mm i.d. tube by the electrochemical and conductivity techniques are presented. Measurements were made in bubble and slug flow regimes at liquid flow rates ranging from 0.2 to 2 m/s.The flow instability and ambiguity in a bubble regime at low velocities is shown to exist. Great discrepancy between measured wall shear stress values and those predicted by the Lockhart-Martinelli model are due to the nonuniform distribution of gas over the tube cross section. Measurements of intensity of wall shear stress and liquid velocity fluctuations in a two-phase flow are presented.     

Bubble and liquid turbulence characteristics of bubbly flow in a large diameter vertical pipe

The bubble and liquid turbulence characteristics of air–water bubbly flow in a 200 mm diameter vertical pipe was experimentally investigated. The bubble characteristics were measured using a dual optical probe, while the liquid-phase turbulence was measured using hot-film anemometry. Measurements were performed at six liquid superficial velocities in the range of 0.2–0.68 m/s and gas superficial velocity from 0.005 to 0.18 m/s, corresponding to an area average void fraction from 1.2% to 15.4%. At low void fraction flow, the radial void fraction distribution showed a wall peak which changed to a core peak profile as the void fraction was increased. The liquid average velocity and the turbulence intensities were less uniform in the core region of the pipe as the void fraction profile changed from a wall to a core peak. In general, there is an increase in the turbulence intensities when the bubbles are introduced into the flow. However, a turbulence suppression was observed close to the wall at high liquid superficial velocities for low void fractions up to about 1.6%. The net radial interfacial force on the bubbles was estimated from the momentum equations using the measured profiles. The radial migration of the bubbles in the core region of the pipe, which determines the shape of the void profile, was related to the balance between the turbulent dispersion and the lift forces. The ratio between these forces was characterized by a dimensionless group that includes the area averaged Eötvös number, slip ratio, and the ratio between the apparent added kinetic energy to the actual kinetic energy of the liquid. A non-dimensional map based on this dimensionless group and the force ratio is proposed to distinguish the conditions under which a wall or core peak void profile occurs in bubbly flows.     

Slug velocity and liquid layer thickness before an abrupt contraction in horizontal gas–liquid flow

This work presents the results of an experimental investigation into the effects of an abrupt area contraction on the upstream gas-liquid intermittent flow; in particular, the slug velocity (the velocity of slugs as seen from a fixed observer) and the thickness of the liquid layer in the stratified region between two slugs were measured by means of optical probes just before the contraction, and compared with the values obtained in a straight pipe with the same inner diameter and under the same flow conditions. The superficial velocities of the liquid were from 0.6 and 0.9 m/s, while that of the gas ranged from 0.3 to 5 m/s. The results indicate that the abrupt contraction results in a substantial reduction of slug velocity, and in a growth of the liquid layer thickness.     

Gas/shear-thinning liquid flows through pipes: Modeling and experiments

In chemical and oil industry gas/shear-thinning liquid two-phase flows are frequently encountered. In this work, we investigate experimentally the flow characteristics of air/shear-thinning liquid systems in horizontal and slightly inclined smooth pipes. The experiments are performed in a 9-m-long glass pipe using air and three different carboxymethyl cellulose (CMC) solutions as test fluids. Flow pattern maps are built by visual observation using a high-speed camera. The observed flow patterns are stratified, plug, and slug flow. The effects of the pipe inclination and the rheology of the shear-thinning fluid in terms of flow pattern maps are presented. The predicted existence region of the stratified flow regime is compared with the experimental observation showing a good agreement. A mechanistic model valid for air/power-law slug flow is proposed and model predictions are compared to the experimental data showing a good agreement. Slug flow characteristics are investigated by the analysis of the signals of a capacitance probe: slug velocity, slug frequency, and slug lengths are measured. A new correlation for the slug frequency is proposed and the results are promising.     

Wall shear stress measurement in a turbulent pipe flow using ultrasound Doppler velocimetry

A turbulent boundary layer of a water flow is investigated by means of pulsed ultrasound Doppler velocimetry. The advantage of this method is the acquisition of complete velocity profiles along the sound propagation line within very short time intervals. The shear stress velocity, used for normalizing the velocity profiles, was determined by fitting the profiles to the universal profiles in a turbulent boundary layer obtained from Prandtl's mixing length theory. A coordinate transformation in the near-wall region is proposed to allocate the velocity data to "true" wall distances. From the experimental values of the wall shear stress velocity, the friction factors for a turbulent pipe flow are calculated and compared to the Blasius law. The overall error in measurement was estimated to NJ.4%.