Spectroscopic investigation of the plasma of a high-current diffuse discharge in He/Ar/CF2Cl2(CCl4) mixtures

Survey emission spectra in the region of 190–600 nm and time and service-life characteristics of a transverse nanosecond discharge in He/Ar/CF₂Cl₂(CCl₄) mixtures at a pressure of 10–100 kPa are investigated. In the emission spectra, excited products of the decomposition of freons—C₂(A−X), CN(B−X), Cl ₂ ^* , C^*, Cl^*, and Cl^+*— and the emission of ArF at λ=193 nm are revealed. The emissions of Cl ₂ ^* at λ=258 nm and ArF at λ=193 nm were the most intense. The discharge in the He/Ar/CF₂Cl₂ mixture is a multiwave emission source with λ=258 nm Cl ₂ ^* 193 nm ArF, and probably, 175 nm Arcl. It is of interest for applications in UV-VUV-range pulse photometry. The duration of the emission on Cl ₂ ^* , ArF, ArI, ClI, and ClII transitions in the discharge in the Ar/CF₂Cl₂ mixture (P=10–20 kPa) was 200–300 nsec. With adding He and increasing pressure to 100 kPa the duration of the emission decreased by a factor of 1.5–2. The basic mechanisms of the formation of Cl₂, ArF, and CN(B) molecules in the transverse-discharge plasma are considered. Uzhgorod State University, 46, Pidgirna Str., Uzhgorod, 294000, Ukraine. Translated from Zhurnal. Prikladnoi Spektroskopii, Vol. 66, No. 2, pp. 241–246, March–April, 1999.     

Optical magnetometer with submicron spatial resolution based on Rb vapors

It is shown experimentally that use of fluorescence and transmission spectra obtained from nanocells with the thickness of column of rubidium atomic vapor L = λ/2 and L = λ, respectively (λ = 794 nm is the wavelength of laser radiation close to resonance with D ₁-line transition of Rb atoms), by means of a narrowband diode laser allows spectral separation and study of variations of probabilities of atomic transitions between ground and excited states of hfs of D ₁ lines of ⁸⁵Rb and ⁸⁷Rb atoms in the range of magnetic fields from 10 to 5000 G. Small thickness of atomic vapor column (∼390 nm and ∼794 nm) allows applying permanent magnets simplifying essentially creation of strong magnetic fields. Advantages of this technique are discussed as compared with the technique of saturated absorption. The obtained results show that a nanocell with submicrom thickness of vapor column may serve as a basis for designing a magnetometer with submicron local spatial resolution which is important in case of measuring strongly inhomogeneous magnetic fields. Experimental data are in good agreement with the theoretical results.     

Non-steady-state photo-EMF in nanostructured GaN and polypyrrole within porous matrices

We report an experimental investigation of the non-steady-state photoelectromotive force in nanostructured GaN within porous glass and polypyrrole within chrysotile asbestos. The samples are illuminated by an oscillating interference pattern created by two coherent light beams and the alternating current is detected as a response of the material. Dependences of the signal amplitude versus temporal and spatial frequencies, light intensity, and temperature are studied for two wavelengths λ=442 and 532 nm. The conductivity of the GaN composite is measured: σ=(1.1–1.6)×10⁻¹⁰ Ω⁻¹ cm⁻¹ (λ=442 nm, I ₀=0.045–0.19 W/cm², T=293 K) and σ=(3.5–4.6)×10⁻¹⁰ Ω⁻¹ cm⁻¹ (λ=532 nm, I ₀=2.3 W/cm², T=249–388 K). The diffusion length of photocarriers in polypyrrole nanowires is also estimated: L _D=0.18 μm.     

Characterization of channel waveguides in Pr:YLiF<Subscript>4</Subscript> crystals fabricated by direct femtosecond laser writing

Single tracks and pairs of tracks are written in the volume of Pr-doped LiYF₄-crystals using tightly focused femtosecond laser radiation (λ=1045 nm, τ _p=400–500 fs, f=0.1–1 MHz). Waveguiding between the tracks is demonstrated and optimized by varying the distance between the tracks and the laser writing conditions. The stress-induced guiding mechanism is explained based on TEM, interference microscopy, near-field and far-field measurements. It is shown that the single-crystalline material is getting poly-crystalline under femtosecond laser irradiation. By measuring the lifetime of the ³P₁→³H₅ transition and the emission spectrum at excitation with λ=444 nm, no influence on these properties of the guided light is observed. This possibly enables the realization of a channel waveguide laser in the visible spectral range.     

Microwave energy channeling in plasma waveguides created by a high-power UV laser in the atmosphere

The grazing mode of microwave propagation in a hollow plasma waveguide formed by ionization of atmospheric air with a small easily ionized additive by strong UV pulses of the Garpun KrF laser (λ = 248 nm, the pulse duration and energy are ∼70 ns and ∼50 J) was experimentally demonstrated for the first time. The annular laser beam produced a hollow tube ∼10 cm in diameter with an electron density of ∼10¹² cm⁻³ in a plasma wall ∼1 cm thick, over whichmicrowave radiation with λ _mw ∼ 8 mm was transmitted to a distance of 60 m. Themicrowave signal transmitted by the waveguide was amplified by a factor of 6 in comparison with propagation in free space.     

Spectrofluorimetric Assessment of Hydrochlorothiazide Using Optical Sensor Nano-Composite Terbium Ion Doped in Sol-Gel Matrix

A new, simple, sensitive and selective spectrofluorimetric method for the determination of Hydrochlorothiazide was developed in acetonitrile at pH 6.2. The Hydrochlorothiazide can remarkably enhance the luminescence intensity of the Tb³⁺ ion doped in sol–gel matrix at λ_ex = 370 nm. The intensity of the emission band of Tb³⁺ ion doped in sol–gel matrix was increased due to the energy transfer from the triplet excited state of Hydrochlorothiazide to (⁵D₄) excited energy state of Tb³ ion. The enhancement of the emission band of Tb³⁺ ion doped in sol–gel matrix at (⁵D₄→⁷ F₅) 545 nm was directly proportion to the concentration of Hydrochlorothiazide with a dynamic ranges of 5.0 × 10⁻¹⁰—5.0 × 10⁻⁶ mol L⁻¹ and detection limit of 2.2 × 10⁻¹¹ mol L⁻¹.     

Investigation of Rb <Emphasis Type="Italic">D</Emphasis><Subscript>1</Subscript> atomic lines in strong magnetic fields by fluorescence from a half-wave-thick cell

It has been experimentally demonstrated that the use of the effect of significant narrowing of the fluorescence spectrum from a nanocell that contains a column of atomic Rb vapor with a thickness of L = 0.5λ (where λ = 794 nm is the wavelength of laser radiation, whose frequency is resonant with the atomic transition of the D ₁ line of Rb) and the application of narrowband diode lasers allow the spectral separation and investigation of changes in probabilities of optical atomic transitions between levels of the hyperfine structure of the D ₁ line of ⁸⁷Rb and ⁸⁵Rb atoms in external magnetic fields of 10–2500 Gs (for example, for one of transitions, the probability increases ∼17 times). Small column thicknesses (∼390 nm) allow the application of permanent magnets, which facilitates significantly the creation of strong magnetic fields. Experimental results are in a good agreement with the theoretical values. The advantages of this method over other existing methods are noted. The results obtained show that a magnetometer with a local spatial resolution of ∼390 nm can be created based on a nanocell with the column thickness L = 0.5λ. This result is important for mapping strongly inhomogeneous magnetic fields.     

Nature of conduction via impurities in uncompensated silicon

The static conductivity σ(E) and photoconductivity (PC) at radiation frequencies ħω=10 and 15 meV in Si doped with shallow impurities (density N=10¹⁶−6×10¹⁶ cm⁻³, ionization energy ε₁≃45 meV) with compensation K=10⁻⁴−10⁻⁵ in electric fields E=10–250 V/cm are measured at liquid-helium temperatures T. Special measures are taken to prevent the high-frequency part of the background radiation (ħω>16 meV) from striking the sample. It is found that the conductivity σ(E) is due to carrier motion along the D ⁻ band, which is filled with carriers under the influence of the field E. In fields E<E _q (E _q ≃100–200 V/cm) the carrier motion consists of hops along localized D ⁻ states in a 10–15 meV energy band below the bottom of the free band (energy ε=ε₁); for E>E _q carriers drift along localized D ⁻ states with energy ε∞ε₁−10 meV. An explanation is proposed for the threshold behavior of the field dependence of the photo-and static conductivities. Pis’ma Zh. éksp. Teor. Fiz. 66, No. 4, 232–236 (25 August 1997)     

Two-photon resonant four-wave mixing processes in atomic barium

By means of a N₂-laser pumped dye-laser (P _L ≈20kW, Δv _L < 10 GHZ) different two-photon resonant four-wave coupling processes in Ba vapour (n _Ba≈10¹⁶ cm⁻³) using the Ba states 6s8s ¹ S _o and 7s5d ¹ D ₂ were investigated. Coherent line radiation with conversion rates up to 10⁻³ was generated within the range of λ=190–200 nm by sumfrequency mixingv _UV=2v ₁+v ₂ of 3 laser photons and within the range of λ=250–380 nm by couplingv _UV=2v ₁±v _IR of 2 laser photons with one photonv _IR stimulated emitted in laser-induced Ba transitions. For the second coupling type the various nonlinear processes contributing to the formation of the coupling components are discussed. The power of the UV-component as function of inensity and resonance detuning of the laser as well as on the phase-mismatch was calculated on the basis of the small signal theory and compared to the experimental data.     

Beat frequency intercomparisons of127I2 stabilized ion lasers at 514.5 nm

International comparisons of I₂ stabilized ion lasers operated at 514.5 nm have shown a laser frequency reproducibility of 2·10⁻¹⁰ v to 5·10⁻¹² v. These results encouraged the international acceptance of the wavelength value λ_vac=514.673467 for thea ₃ hyperfine component of the¹²⁷I₂ line 43-0P(13).     

ESR study of exchange coupled pairs in copper diethyldithiocarbamate

ESR investigations on exchange coupled pairs of Cu ions in single crystals of Cu(dtc)₂, isomorphously diluted with the corresponding diamagnetic zinc salt, are reported. The spin Hamiltonian parameters for the coupled species (S=1) are:g _‖=2.1025,g ₊=2.031,A=75.1×10⁻⁴ cm⁻¹,B=14.8×10⁻⁴,D=276.0×10⁻⁴ cm⁻¹ andE=46.7×10⁻⁴ cm⁻¹. While theg andA tensors show tetragonal symmetry, the zeor-field splitting tensor is rhombic and has principal axes different from those of theg andA tensors. Intensity measurements made down to 4.2 K indicate that the exchange is ferromagnetic with |FFF| ∼ 10 cm⁻¹. Direct dipole-dipole interaction appears to be the major contribution to the zero-field splitting. A calculation on the distributed point dipole model shows that dipolar interaction is considerably modified by the high covalency of the Cu-S bond and accounts for the rhombic nature of the tensor. The possible exchange mechanisms in Cu(dtc)₂—direct exchange and superexchange through the bridging sulphurs—are discussed.     

Excess 1/f noise in systems with an exponentially wide spectrum of resistances and dual universality of the percolation-like noise exponent

The excess 1/f noise in a random lattice with bond resistances r∼exp(−λx), where x is a random variable and λ≪1, is studied theoretically. It is shown that if the correlation function {δr ²}∼r r ^θ+2, then the relative spectral density of the noise in the system is expressed as C _e∼λ^m exp(−λ(1−p _c)), where p _c is the percolation threshold and m=νd (ν is the critical exponent of the correlation length and d is the dimensionality of the problem). It is hypothesized that the exponent m possesses a dual universality: It is independent of 1) the geometry of the lattice and 2) the θ-mechanism responsible for the generation of the local noise. Numerical modeling in a three-dimensional lattice gives m=52.3 for θ=1 and θ=0, in agreement with the hypothesis. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 8, 614–618 (25 April 1996)     

Theoretical optimization of metalp–n silicon Schottky barrier solar cell

The theoretical optimization of the design parametersN _A ,N _D andW _P has been done for efficient operation of Au-p-n Si solar cell including thermionic field emission, dependence of lifetime and mobility on impurity concentrations, dependence of absorption coefficient on wavelength, variation of barrier height and hence the optimum thickness ofp region with illumination. The optimized design parametersN _D =5×10²⁰ m⁻³,N _A =3×10²⁴ m⁻³ andW _P =11.8 nm yield efficiencyη=17.1% (AM0) andη=19.6% (AM1). These are reduced to 14.9% and 17.1% respectively if the metal layer series resistance and transmittance with ZnS antireflection coating are included. A practical value ofW _P =97.0 nm gives an efficiency of 12.2% (AM1).     

Spectral properties of backward stimulated scattering in liquid carbon disulfide

The spectral structure of backward stimulated scattering from a 10 cm-long CS₂-liquid cell is investigated by using Q-switched 10-ns and 532-nm laser pulses with different spectral linewidths. Under a narrow spectral line (∼0.1 cm⁻¹) pump condition, very strong sharp lines near the pump wavelength (λ ₀) position and the first-order stimulated Raman scattering (λ _s1) position can be observed. However, under a wide line (≈1 cm⁻¹) pump condition, only a strong and superbroadening spectral band can be observed mainly in the red-shift side of the pump wavelength. The different spectral features under these two conditions can be explained by a competition between stimulated Brillouin, Raman, and Rayleigh-Kerr scattering. Under both pump conditions, the broadening spectral distributions are not consistent with the predictions given by stimulated Rayleigh-wing scattering theories, but can be interpreted well utilizing the theoretical model of stimulated Rayleigh-Kerr scattering. Zh. éksp. Teor. Fiz. 112, 1563–1573 (November 1997) Published in English in the original Russian journal. Reproduced here with stylistic changes by the Translation Editor.     

Optical characteristics of a transverse discharge in neon at atmospheric pressure

We present the results of investigation into radiation of a pulsed transverse discharge in neon at a pressure of 10–200 kPa. Survey spectra of plasma radiation, time characteristics of radiation, and the effect of small impurities of water vapors and air on the optical characteristics of a neon plasma were studied. We show that at a pressure of residual gases at a level of 10 Pa intense OH*, NO*, and N _* ² bands are observed in radiation of the plasma of a nanosecond transverse discharge in Ne against the background of continuous plasma radiation, and in the spectral region with λ>400 nm radiation was observed on the H_β 486.1 nm and NeI 585.3 nm lines, and (when P≥100 kPa) on the line at the 3s–3p-transitions of a Ne atom. The radiation intensity of the third continuum of neon increases with pressure and with energy contribution to plasma, with its maximum being located in the VUV spectral region (λ _max <200 nm). To whom correspondence should be adressed. Uzhgorod State University, 46, Pidgirna St., Uzhgorod, Ukraine. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 66, No. 1, pp. 5–10, January–February, 1999.     

Terbium Sensitized Luminescence for the Determination of Ketoprofen in Pharmaceutical Formulations

This paper explores an ultra-sensitive luminescence method for the determination of Ketoprofen (KP) in pharmaceutical formulations. The technique is indirect and exploits the luminescence enhancement of terbium (Tb³⁺) by complexation with KP (Tb³⁺–KP), which was monitored at respective excitation and emission wavelengths of λ _ex = 258 nm and λ _em = 549 nm. The effect of varying the Tb³⁺ concentration and using multiple solvents was examined to determine optimal experimental conditions. Maximum sensitization was accomplished in the presence of methanol where the most favourable condition for the formation of the complex was recorded at a level of 1.0 × 10⁻⁵ M of Tb³⁺. Under these optimum experimental conditions, linear calibration curve was obtained in the range of 2.8 × 10⁻⁷–3.1 × 10⁻⁶ M with a detection limit of 8.7 × 10⁻⁸ M. The technique was validated with ‘working’ reference standards and produced relative standard deviations < 2% indicating that the reproducibility was highly acceptable. The proposed method was successfully applied to assays of KP in pharmaceutical formulations with average recoveries of 92–98%. The results were found to be in good agreement with those obtained by HPLC. The method is highly suited for general applications of this nature.     

Kinetics of the formation of gas bubbles during polarization of copper and graphite electrodes in electrolytic aqueous solutions

The adsorption and kinetic processes of the formation of gas bubbles passivating the surface during polarization of copper and graphite electrodes in 1% aqueous solution of sulfuric acid have been investigated. Three stages of the process related to the recharging of the double electric layer—adsorption accumulation of the gas escaping from the surface, the critical nucleation of the gas bubbles, and their subsequent growth—have been revealed, distinguished, and quantitatively estimated. It has been shown that potential leveling at the steady-state value specified by the Tafel equation is unambiguously associated with achievement of the limiting surface area screened by the gas bubbles for each particular current density. The surface diffusion constants D _H = (1.5–4.4) × 10⁻⁴ and (0.1–3.8) × 10⁻⁵ cm²/s of hydrogen on copper and graphite, respectively, and D _O = (1.8–4.5) × 10⁻⁷ cm²/s of oxygen on graphite during the motion toward the drain (the gas bubbles) have been calculated.     

Glow-discharge-pumped broadband ultraviolet lamp

The optical characteristics of a UV broadband lamp that was excited by a longitudinal glow discharge and operated on Kr—Br₂—I₂, Xe—Br₂—I₂, and Kr—Xe—Br₂—I₂ mixtures are investigated. The interelectrode spacing in the lamp is 10 cm, the inner diameter of a discharge tube being 14 mm. The current-voltage characteristics, the emission spectra of the plasma, and the dependence of the intensity of spectral lines (the amplitude of radiation bands) on the power that was pumped into the plasma based on mixtures of various compositions and pressures, as well as the radiation power in the spectral range from 200 to 390 nm, are studied. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 72, No. 6, pp. 840–842, November–December, 2005.     

Radiative characteristics and kinetics of processes in low-pressure gas-discharge lamps based on a mixture of helium and iodine vapors

The UV radiation of glow- and capacitive-discharge lamps based on mixtures of inert gases with iodine vapors are optimized in the spectral range of 175–360 nm, in which working helium-iodine mixtures of different compositions are used. The most intense spectral lines in the bactericidal region of the spectrum were the atomic lines of iodine (183.0, 206.2 nm), and in the region of 320–360 nm, emission of the spectral band of an iodine molecule prevailed with a maximum at λ = 342 nm. For a capacitive lamp with a casing opaque in the spectral range λ < 250 nm, the main part of the plasma emission power is concentrated in the A′-D′ band of an iodine molecule with a maximum at 342 nm. The emission brightness of this lamp is optimized in iodine molecule transitions depending on the partial helium pressure. We present the results of simulating the kinetics of processes in a glow-discharge plasma in mixtures of He, Xe, and iodine vapors. We establish the dependence of the main part of the emission intensity of the 206.2 nm spectral line of an iodine atom and the 342 nm band of an iodine molecule on the helium pressure in a glow-discharge lamp operating on a He-I₂ mixture.     

Multi-Hamiltonian structure of kdv hierarchy by Drienfeld-Sokolov formalism

Conserved quantities and the multi-Hamiltonian structure for the integrable coupled kdv system which is associated with the isospectral flow [(∑ _i=0 ^N−1 ε _i λ ⁱ )∂² + ∑ _i=0 ^N−l V ₁λ ⁱ ]φ=λ ^N φ are deduced by the Drienfeld-Sokolov formalism.