Influence of Phase Transition on Spalling Behavior in FeMnNi alloy

通过逆向加载和等厚对称碰撞实验相结合的方法,确定了FeMnNi合金完整的加卸载物理过程和相变层裂特征。采用修正的Boettger模型与非平衡两相相变理论模型,成功模拟再现了实验过程,解释了冲击相变、卸载逆相变及稀疏冲击波形成的物理机理。实验和数值模拟相结合,从应力波相互作用的角度定量分析了层裂发生的原因,指出层裂发生的机制正是由于受载样品发生了冲击相变和卸载逆相变。     

斜波压缩下锡的相变和层裂行为

获取不同热力学路径下锡的动态响应实验数据,是深入研究其相变和损伤物理过程的基础.利用小型磁驱装置CQ-4完成了金属锡的斜波加载实验,获取了锡含有相变和层裂损伤物理信息的实验数据.实验结果显示,在加载段锡依次经历了弹塑性转变和β-γ相变两种物理过程,屈服强度约0.194 GPa,相变压力随着锡厚度的增加从7.54 GPa减小到7.14 GPa.在卸载段出现了明显的层裂损伤,层裂强度约1.1 GPa,与相同加载压力下冲击实验结果有巨大差异,层裂片厚度约0.38 mm.结合由锡的多相Helmholtz自由能计算的多相状态方程、Hayes相变动力学方程和损伤度理论,对斜波压缩实验过程进行一维流体动力学数值模拟,计算结果可以很好描述锡的弹塑性转变、相变和层裂三个物理过程.     

纯铁材料的冲击相变与"反常"层裂

采用VISAR、X射线衍射和金相处理联合测试分析技术,开展等厚对称碰撞实验,研究了纯铁材料的冲击相变与层裂行为特征。结果发现,冲击加载压力大于纯铁材料相变阈值(13 GPa)时,等厚对称碰撞样品发生反常2次层裂。结合相关文献的实验结果,从应力波相互作用的角度分析了反常层裂形成的原因,指出纯铁材料的冲击相变和卸载逆转变及引发的稀疏冲击波是导致反常2次层裂的物理机制。     

低相变阈值金属高压加载下的相变层裂特性

采用激光速度干涉仪（VISAR）和X光联合测试技术,在冲击压力远高于相变应力加载下,实验研究低相变阈值金属FeMnNi合金的相变层裂特性,结果发现等厚对称碰撞加载下FeMnNi合金出现反常的层裂行为。针对该反常的层裂行为,利用塑性波、相变波、稀疏波和逆相变引发的稀疏冲击波的相互作用过程进行分析,结果表明,该实验状态下FeMnNi合金样品存在相变和逆相变行为,逆相变引发的稀疏冲击波是导致反常层裂行为的主要因素。     

FeMnNi合金冲击加卸载历程研究

采用激光速度干涉仪(VISAR),应用逆向加载实验装置FeMnNi飞片/蓝宝石窗口和FeMnNi飞片/LiF缓冲层/LiF窗口,分别对低相变阈值金属FeMnNi合金含相变的低压和高压冲击加卸载历程进行实验研究。参阅文献[3,4]分析了实验结果。在低压加载下,FeMnNi合金样品存在α→ε相变,卸载时存在逆相变ε→α及逆相变引发的卸载稀疏冲击波;在高压加载下,FeMnNi合金样品存在α→ε相变,卸载时可能存在逆相变ε→γ和γ→ε行为及逆相变引发的卸载稀疏冲击波。     

FeMnNi合金高压相变波形测量和层裂机理分析

采用激光速度干涉仪（VISAR）测试技术,利用逆向加载装置FeMnNi飞片／LiF缓冲层／LiF窗口,对低相变阈值金属FeMnNi合金高压加卸栽历程进行实验研究,结果发现FeMnNi合金在高压加载下发生α→ε相变,在高压卸载下发生ε→γ和γ→α逆相变,并有相应的稀疏冲击波Rs1和Rs2形成。应用该结果分析FeMnNi合金等厚对称在高压加载下的“反常”层裂行为发现,逆相变γ→α引发的稀疏冲击波Rs2与中心稀疏波R的相互作用是导致该“反常”层裂的主要因素。     

HR2钢及几种铁基材料的冲击相变行为

利用双灵敏度VISAR测量了抗氢钢HR2、工业纯铁DT2和铁锰镍合金FeMnNi在一维应变冲击载荷下的自由面速度历史,结合受载样品的回收分析对其动载行为和断裂表现进行了分析。研究表明,在实验加载压力范围内DT2和FeMnNi样品的自由面速度历史呈现包括相变波在内的典型三波结构,而对HR2钢,尽管金相分析显示其加载前后样品的相组织已发生变化,但速度剖面呈现的仅是典型的弹塑性双波结构。分析认为溶质材料成分和初始相组织是无相变波的主要原因。从冲击相变和卸载逆相变角度解释了在等厚靶碰撞时DT2和FeMnNi材料中出现的多重层裂、浅表层裂现象。     

TiNi相变悬臂梁的横向冲击特性实验研究

利用改装的霍普金森压杆装置对TiNi形状记忆合金圆截面悬臂梁进行了横向冲击实验研究,并与45#钢悬臂梁的实验结果进行了对比,目的是探索相变对结构动态响应的影响。结果表明:在同样冲击条件下,TiNi悬臂梁的吸能效率优于钢悬臂梁;发现冲击过程中,TiNi试件根部内侧可能形成局部相变铰,使阻力曲线的斜率发生变化;卸载后相变铰消失,TiNi悬臂梁试件基本回复原状,钢试件则留下显著的残余变形。TiNi悬臂梁的冲击特性受热弹性马氏体相变和逆相变的支配,不同于传统的弹塑性机制。     

TiNi合金冲击相变过程中温度变化规律的实验研究

针对初始SME(shape memory effect)和PE(pseudo-elastic)状态TiNi合金试样,采用带有红外测温系统的SHPB冲击压缩装置,实时测量了冲击相变过程中两种材料试样表面瞬态温度,并根据实验结果计算了相应的温度变化。实验结果表明,冲击加载相变过程中,温度随相变应变的增大而升高,当应变最大时,温度最高;卸载过程中,对初始PE状态试样,温度降低,对初始SME状态试样,温度保持最高温度不变或降低,这同加载最高温度有关;卸载完成后,两种试样温度均高于其初始温度。计算温度结果表明,相变耗散功对加、卸载相变过程中温度变化的作用不可忽略。     

三角形波致LY12铝层裂的平板冲击实验研究

采用基于冲击波衰减动力学的实验技术,使平板碰撞层裂实验的LY12铝样品中,产生三角形冲击脉冲.采用VISAR技术记录样品自由表面历史,获得样品中发生层裂的信号.在经过高应力三角形波实验的软回收样品上,发现了两个层裂面.就样品中呈现三角形脉冲的平板冲击实验而言,样品中可以存在一些高拉伸应力区域并发生多次层裂.将该文提出的基于空穴聚集的层裂模型用于数值模拟这些特定条件的平板冲击试验,并将计算的样品自由面速度历史及样品中的损伤分布与实测的VISAR数据及软回收的样品层裂面等作了比较.研究表明,人为粘性、状态方程、本构方程以及层裂模型对于数值模拟三角形冲击脉冲引起的层裂有严重影响.     

FeMnNi合金的冲击相变和层裂特性的实验研究

对FeMnNi合金进行了轻气炮平板撞击实验研究,实验中材料发生了相变和层裂。得到的FeMnNi合金的相变阈值压力为6.3~6.9 GPa,远低于纯铁的相变阈值压力13 GPa,说明Mn、Ni合金元素的加入会极大的降低相变阈值。回收试样观测表明,当应力高于FeMnNi合金的相变阈值时,样品中可能产生二次层裂现象和浅表层裂新现象。实验结果还表明该合金相变后层裂强度没有明显的提高。     

Identification of damage mechanism and validation of a fracture model based on mesoscale approach in spalling of titanium alloy

The subject of this paper is identification of the physical mechanisms of spalling at low impact velocities for Ti–6Al–4V alloy and determination of the macroscopic stress of spalling via meso-macro approach. Spalling is a specific mode of fracture which depends on the loading history. The aspects of the initial microstructure and its evolution during plastic deformation are very important. In order to identify the spalling physical mechanisms in titanium alloy, numerous pictures by the optical microscopy of the spall surfaces created by plate impact technique have been taken. The scenario of failure observed is in complete agreement with known physical micro-mechanisms: namely nucleation, propagation and coalescence by adiabatic shearing of micro-voids. The most interesting point in spall fracture of Ti–6Al–4V alloy is the nucleation of micro-voids. A significant amount of small micro-voids in the region of the expected spall plane has been observed. It appears that microstructural effects are important due to dual α–β phase microstructure, called Widmanstätten structure. The orientation of microstructure has a direct influence on nucleation mechanism by means of distribution of nucleation sites and decohesion between the softer particles (α-phase lamellae) and the harder lattice (β-phase). According to these observations, a fracture model has been developed. This model is based on the numerous post-mortem microscopic observations of spall specimens. The goal is to determine the macroscopic stress of spalling in function of loading time and damage level via a meso-macro approach.     

基于相变松弛法则的水下爆炸空化模型研究

水下爆炸过程中存在着大量的空化现象,空化的产生、演化及其溃灭过程对于水下冲击波传播、爆炸气泡运动以及水下结构物冲击损伤都会产生重要影响。本文基于多相可压缩流体理论模型,考虑空化发生过程中汽-液两相流体亚平衡状态下两相之间发生的热力学-化学平衡机制,分析汽-液两相介质之间的质量和热量交换,从而实现对相变过程的自动捕捉。该系统的控制方程采用分步法处理,首先利用二阶MUSCL-Hancock格式和HLLC黎曼求解器来求解齐次双曲型方程,再采用牛顿迭代法求解相变方程。数值测试结果表明,本文的计算模型对于空化相变过程具有较好的捕捉能力。最后将该模型应用到水下近水面爆炸空化的数值模拟当中,研究发现空泡的溃灭压力峰值约为冲击波压力峰值的15%,有效作用时间是冲击波载荷有效作用时间的2倍以上。本文的空化相变模型能够为水下爆炸空化现象的机理研究提供重要支撑。     

温度对冲击相变波传播的影响

冲击加载下,相界面的传播是一热力耦合过程。相变波阵面不仅是力学和物质间断面,也是温度界面。为考虑温度对相变波传播的影响,本文首先建立了相界面上的热传导方程和热力耦合的相变本构方程,然后采用一维特征线理论和有限差分数值计算相结合的方法,分析了温度界面和相变波的基本相互作用规律,进而给出了连续温度梯度下和绝热冲击下相变波传播规律。结果表明,温度对相变波传播的作用主要体现在两个方面,一方面是作为温度界面将与各类间断面相互作用,另一方面冲击相变波阵面后区域热力学状态变化影响卸载波结构。其原因在于相变方式（可逆、不可逆）和相变阈值应力具有强烈的温度相关性。     

On the structure of the Hugoniot relation for a shock-induced martensitic phase transition

The Hugoniot curve relates the pressure and volume behind a shock wave, with the temperature having been eliminated. This paper studies the Hugoniot curve behind a propagating sharp interface between two material phases for a solid in which an impact-induced phase transition has taken place. For a solid capable of existing in only one phase, compressive impact produces a shock wave moving into material, say, at rest in an unstressed state at the ambient temperature. If the specimen can exist in either of two material phases, sufficiently severe impact may produce a disturbance with a two-wave structure: a shock wave in the low-pressure phase of the material, followed by a phase boundary separating the low- and high-pressure phases. We use a theory of phase transitions in thermoelastic materials to construct the Hugoniot curve behind the phase boundary in this two-wave circumstance. The kinetic relation controlling the evolution of the phase transition is an essential ingredient in this process.      

相变柱壳的径向冲击特性

采用改进的SHPB (split Hopkinson pressure bar)装置和高速CCD (charge-coupled device)相机对TiNi合金圆柱壳进行了径向冲击实验研究,得到了动态载荷-位移曲线,并采用数字边界提取技术和纯弯曲假定对结构的动态全场变形过程进行了定量分析。结果表明,相变柱壳经受动态冲击后可以恢复,其加、卸载非线性行为与相变状态和相变铰的演化相关。同时,该结构具有良好的横向抗冲效应,对冲击加速度和冲击载荷的衰减量达到95%以上,耗能率为42.4%,可望在可重复使用的抗冲装置中得到应用。     

Phase transition and dynamics of iron under ramp wave compression

The ramp wave compression experiments of iron with different thicknesses were performed on the magnetically driven ramp loading device CQ-4. Numerical simulations of this process were done with Hayes multi-phase equation of state (H-MEOS) and dynamic equations of phase transition. The calculated results of H-MEOS are in good agreement with those of shock phase transition, but are different from those under ramp wave compression. The reason for this is that the bulk modulus of the material in the Hayes model and the wave velocity are considered constant. Shock compression is a jump from the initial state to the final state, and the sound speed is related to the slope of the Rayleigh line. However, ramp compression is a continuous process, and the bulk modulus is no longer a constant but a function of pressure and temperature. Based on Murnaghan equation of state, the first-order correction of the bulk modulus on pressure in the Hayes model was carried out. The numerical results of the corrected H-MEOS agree well with those of pure iron in both ramp and shock compression phase transition experiments. The calculated results show that the relaxation time of iron is about 30 ns and the phase transition pressure is about 13 GPa. There are obvious differences between the isentropic and adiabatic process in terms of pressure–specific volume and temperature–pressure. The fluctuation of the sound speed after 13 GPa is caused by the phase transition.