Hyperbolic phenomena in a strongly degenerate parabolic equation

We consider the equation u _t =((u) (u _x )) _x , where >0 and where is a strictly increasing function with lim _s = <. We solve the associated Cauchy problem for an increasing initial function, and discuss to what extent the solution behaves qualitatively like solutions of the first-order conservation law u _t = ((u)) _x . Equations of this type arise, for example, in the theory of phase transitions where the corresponding free-energy functional has a linear growth rate with respect to the gradient.     

Some remarks on differential equations of quadratic type

In this paper we study differential equations of the formx(t) + x(t)=f(x(t)), x(0)=x ₀ C HereC is a closed, bounded convex subset of a Banach spaceX,f(C) C, and it is often assumed thatf(x) is a quadratic map. We study the differential equation by using the general theory of nonexpansive maps and nonexpansive, non-linear semigroups, and we obtain sharp results in a number of cases of interest. We give a formula for the Lipschitz constant off: C C, and we derive a precise explicit formula for the Lipschitz constant whenf is quadratic,C is the unit simplex inR ⁿ, and thel ₁ norm is used. We give a new proof of a theorem about nonexpansive semigroups; and we show that if the Lipschitz constant off: CC is less than or equal to one, then lim_tf(x(t))–x(t)=0 and, if {x(t):t 0} is precompact, then lim_tx(t) exists. Iff¦C=L¦C, whereL is a bounded linear operator, we apply the nonlinear theory to prove that (under mild further conditions on C) lim_t f(x(t))–x(t)=0 and that lim_t x(t) exists if {x(t):t 0} is precompact. However, forn 3 we give examples of quadratic mapsf of the unit simplex ofR ⁿ into itself such that lim_t x(t) fails to exist for mostx ₀ C andx(t) may be periodic. Our theorems answer several questions recently raised by J. Herod in connection with so-called model Boltzmann equations.     

On the closure problem for Darcy's law

In a previous derivation of Darcy's law, the closure problem was presented in terms of an integro-differential equation for a second-order tensor. In this paper, we show that the closure problem can be transformed to a set of Stokes-like equations and we compare solutions of these equations with experimental data. The computational advantages of the transformed closure problem are considerable.Roman Letters A interfacial area of the- interface contained within the macroscopic system, m² - A _e area of entrances and exits for the-phase contained within the macroscopic system, m² - A interfacial area of the- interface contained within the averaging volume, m² - A _e area of entrances and exits for the-phase contained within the averaging volume, m² - B second-order tensor used to respresent the velocity deviation - b vector used to represent the pressure deviation, m^–1 - C second-order tensor related to the permeability tensor, m^–2 - D second-order tensor used to represent the velocity deviation, m² - d vector used to represent the pressure deviation, m - g gravity vector, m/s² - I unit tensor - K C ^–1,–D, Darcy's law permeability tensor, m² - L characteristic length scale for volume averaged quantities, m - characteristic length scale for the-phase, m - l _i i=1, 2, 3, lattice vectors, m - n unit normal vector pointing from the-phase toward the-phase - n _e outwardly directed unit normal vector at the entrances and exits of the-phase - p pressure in the-phase, N/m ² - p intrinsic phase average pressure, N/m² - p –p , spatial deviation of the pressure in the-phase, N/m² - r position vector locating points in the-phase, m - r ₀ radius of the averaging volume, m - t time, s - v velocity vector in the-phase, m/s - v intrinsic phase average velocity in the-phase, m/s - v phase average or Darcy velocity in the \-phase, m/s - v –v , spatial deviation of the velocity in the-phase m/s - V averaging volume, m³ - V volume of the-phase contained in the averaging volume, m³ Greek Letters V /V volume fraction of the-phase - mass density of the-phase, kg/m³ - viscosity of the-phase, Nt/m²     

A Strongly Degenerate Quasilinear Equation: the Parabolic Case

We prove the existence and uniqueness of entropy solutions of the Neumann problem for the quasilinear parabolic equation u_t=÷ a(u, Du), where a(z,)=f(z,), and f is a convex function of with linear growth as ||||, satisfying other additional assumptions. In particular, this class includes the case where f(z,)=(z)(), >0, and is a convex function with linear growth as ||||.     

Modelling of heat transfer by conduction in a transition region between a porous medium and an external fluid

We study the modelling of purely conductive heat transfer between a porous medium and an external fluid within the framework of the volume averaging method. When the temperature field for such a system is classically determined by coupling the macroscopic heat conduction equation in the porous medium domain to the heat conduction equation in the external fluid domain, it is shown that the phase average temperature cannot be predicted without a generally negligible error due to the fact that the boundary conditions at the interface between the two media are specified at the macroscopic level.Afterwards, it is presented an alternative modelling by means of a single equation involving an effective thermal conductivity which is a function of point inside the interfacial region.The theoretical results are illustrated by means of some numerical simulations for a model porous medium. In particular, temperature fields at the microscopic level are presented.Roman Letters _sf interfacial area of thes-f interface contained within the macroscopic system m² - A _sf interfacial area of thes-f interface contained within the averaging volume m² - C _p mass fraction weighted heat capacity, kcal/kg/K - g vector that maps to _s , m - h vector that maps to _f , m - K _eff effective thermal conductivity tensor, kcal/m s K - l _s,l _f microscopic characteristic length m - L macroscopic characteristic length, m - n _fs outwardly directed unit normal vector for thef-phase at thef-s interface - n outwardly directed unit normal vector at the dividing surface. - R ₀ REV characteristic length, m - T _i macroscopic temperature at the interface, K - error on the external fluid temperature due to the macroscopic boundary condition, K - T ^* macroscopic temperature field obtained by solving the macroscopic Equation (3), K - V averaging volume, m³ - V _s,V _f volume of the considered phase within the averaging volume, m³. - _mp volume of the porous medium domain, m³ - _ex volume of the external fluid domain, m³ - _s , _f volume of the considered phase within the volume of the macroscopic system, m³ - dividing surface, m² - x, z spatial coordinates Greek Letters _s, _f volume fraction - ratio of the effective thermal conductivity to the external fluid thermal conductivity - ^* macroscopic thermal conductivity (single equation model) kcal/m s K - _s, _f microscopic thermal conductivities, kcal/m s K - spatial average density, kg/m³ - microscopic temperature, K - ^* microscopic temperature corresponding toT ^*, K - spatial deviation temperature K - error in the temperature due to the macroscopic boundary conditions, K - ^* _i macroscopic temperature at the interface given by the single equation model, K - spatial average - ^s , ^f intrinsic phase average.     

Heat transfer from laminar flow in ducts with elliptic cross-section

Summary The cooling of a hot fluid in laminar Newtonian flow through cooled elliptic tubes has been calculated theoretically. Numerical data have been computed for the two values 1.25 and 4 of the axial ratio of the elliptic cross-section . For =1.25 the influence of non-zero thermal resistance between outmost fluid layer and isothermal surroundings has also been investigated. Special attention has been given to the distribution of heat flux around the perimeter; when increases the flux varies more with the position at the circumference. This positional dependence becomes less pronounced, however, as the (position-independent) thermal resistance of the wall increases.Flattening of the conduit, while maintaining its cross-sectional area constant, improves the cooling. Comparison with rectangular pipes shows that this improvement is not as marked with elliptic as with rectangular pipes.Nomenclature A _k =A _{m, n} coefficients of expansion (6) - a, b half-axes of ellipse, b<a - a _p =a _{r, s} coefficients of representation (V) - D hydraulic diameter, = 4S/P; S = cross-sectional area, P = perimeter - D _e equivalent diameter, according to (13) - n coordinate (outward) normal to the tube wall - T temperature of fluid - T _i temperature of fluid at the inlet - T _s temperature of surroundings - v ₀ mean velocity of fluid - v _z longitudinal velocity of fluid - x, y carthesian coordinates coinciding with axes of ellipse - z coordinate in flow direction - , dimensionless half-axes of ellipse, =a/D and =b/D - _t heat transfer coefficient from fluid at bulk temperature to surroundings; equation (11) - _w heat transfer coefficient at the wall; equation (3) - axial ratio of ellipse, = a/b = / - , , , dimensionless coordinates; =x/D, =y/D, =z/D, =n/D - dimensionless temperature, = (T–T _s)/(T _i–T _s) - ₀ cup-mixing mean value of ; equation (10) - thermal conductivity of fluid - _m,n = _k eigenvalue - c volumetric heat capacity of fluid - _{m, n} = _k = _k eigenfunction; equations (6) and (I) - Nu total Nusselt number, = _t D/ - Nusselt number at large distance from the inlet - Nu _w wall Nusselt number, = _w D/, based on _w - Pé Péclet number, = ₀ Dc/     

Transient laminar free convection in horizontal cylinders

A numerical study of laminar natural convection inside uniformly heated, partially or fully filled horizontal cylinders is made. A coordinate transformation which simplifies the discretization of the equations of motion and energy is utilized. The resulting system of partial differential equations with their boundary conditions is solved using central differences for various Prandtl and Grashof numbers for two different grid sizes. The flow in completely filled cylinders for which experimental data are available is predicted. Close agreement between steady-state predictions and experiments is obtained for temperature and velocity profiles as well as for the streamline contours and isotherms. The technique is further demonstrated by solving the transient natural convection flow inside a partially filled horizontal cylinder with an adiabatic free surface and subjected to uniform wall heating.

---

Laminare freie Konvektion in horizontalen Zylindern

Zusammenfassung Es wurde eine numerische Berechnung der laminaren, freien Konvektion in gleichmäßig beheizten, teilweise oder ganz gefüllten, horizontalen Zylindern durchgeführt. Dabei wird eine Koordinatentransformation benützt, welche die Diskretisierung der Bewegungs- und der Energiegleichung vereinfacht. Das so resultierende System von partiellen Differentialgleichungen wird, zusammen mit seinen Randbedingungen, unter Verwendung einer Differenzenmethode für verschiedene Prandtl und Grashof-Zahlen sowie für zwei verschiedene Gittergrößen gelöst. Für den vollständig gefüllten Zylinder, für den experimentelle Daten verfügbar sind, wird die Strömung vorhergesagt. Dabei wird für stationäre Zustände gute Übereinstimmung zwischen Rechnung und Experiment erzielt. Dies gilt sowohl für den Verlauf der Stromlinien als auch für den der Isothermen. Das Verfahren wird weiterhin am Beispiel der Berechnung instationärer, freier Konvektion in einem partiell gefüllten, horizontalen Zylinder demonstriert, wobei eine adiabate, freie Oberfläche und gleichmäßige Beheizung der Wand angenommen sind.

---

Nomenclature g acceleration due to gravity, m/s² - Gr _R ^* modified Grashof number =gqR⁴/kv² - Gr _R Grashof number =gTR³/v² - H heat function vector, dimensionless - k thermal conductivity, W/mK - L(Y) cord length associated with coordinateY, dimensionless - Pr Prandtl number=v/ - q wall heat flux, W/m² - R radius, m - r(X, Y,Z) distance of a boundary point from the reference axis, dimensionless - S vector derived from the flow field solution, dimensionless - T temperature, K - T _w wall temperature, K - T reference temperature, K - t time, s - u, v velocity components inx, y directions, m/s - U, V dimensionless velocity components inX- and Y-direction normalized withU - U reference velocity=gqR²/k or gTR, m/s - V velocity vector, dimensionless - W vorticity vector, dimensionless - W vorticity, dimensionless - x, y, z cartesian coordinates, m - X, Y, Z cartesian coordinates normalized with a reference length, dimensionless Greek letters thermal diffusivity, m²/s - coefficient of thermal expansion, K^–1 - ,,, non-dimensional coordinates in the transformed domain - non-dimensional temperature =(T–T)_k/q^R or T–T/T_w–T - v kinematic viscosity, m²/s - non-dimensional time=v/R² Gr_Rt or v/R² G _R ^* t - angle measured from the bottom of the cylinder, rads - ^* angle measured from the axis on (– ) plane, rads - heat potential, dimensionless - angle of incidence of the heat flux vector, rads - non-dimensional stream function - vector potential, dimensionless - grid size, dimensionless - ² Laplacian operator - gradient vector     

Zur Bestimmung rheologischer Parameter viskoelastischer Flüssigkeiten mit Hilfe eines Kugel-Kugel-Rheometers

Zusammenfassung Wird eine viskoelastische Flüssigkeit in einem konzentrischen Kugel-Kugel-Raum durch Rotation einer Kugel beansprucht, so ermöglicht eine Analyse der Antriebsmoment- und Druckverteilungskennlinie die Bestimmung rheologischer Parameter. Insbesondere zeigen die Ergebnisse, daß der in den konventionellen Meßapparaten nur ungenau dargestellte Bereich der Anfangsbeanspruchung durch geeignete Wahl von Spaltweite und Durchmesserverhältnis erfaßt werden kann.

---

Summary Visco-elastic liquids will be stressed in a concentric space between a sphere and a hollow sphere by rotation of one of the spheres. By analysis of the torque- and wall-pressure-characteristics it is possible to determine rheological parameters. In this paper it is shown how to measure the dynamic viscosity and the relaxation times in the range of initial shear-strain in a sphere-sphere-rheometer.

---

a isotroper Druckanteil - f _i () Geometriefunktionen - g Erdbeschleunigung - h _i , _i Normalspannungsparameter - k, m Fließkurvenparameter des Potenzgesetzes - n Drehfrequenz der Innenkugel - p _w Wanddruck - reduzierter Wanddruck - p ₀ Außendruck - r, , Kugelkoordinaten - t ₀,t _0i Anfangsrelaxationszeiten - v Geschwindigkeitsvektor - A, C Fließkurvenparameter des Polynomgesetzes - M Antriebsmoment - M _i Drehmomentanteile - R Radius der Innenkugel - R _G Radius der Hohlkugel - _i Stoffkonstanten der rheologischen Zustandsfunktion - Schergradient - RadienverhältnisR/R _G - variable dynamische Viskosität - ₀ Anfangsviskosität - Proportionalitätsfaktor - Dichte - _I , _II , Viskosimeterfunktionen - Kreisfrequenz der Innenkugel - D Deformationsgeschwindigkeitstensor - I Einheitstensor - W Rotationstensor - Spannungstensor - korotationale zeitliche Ableitung des Deformationsgeschwindigkeitstensors (n-te Ableitung) - Nablaoperator Vorgetragen auf der Jahrestagung der Deutschen Rheologen vom 28.–30. April 1975 in Berlin.Mit 4 Abbildungen und 1 Tabelle     

Anlaufkorrektur und Elastizität bei der Kapillarströmung von Lösungen

Zusammenfassung Aus der Anlaufkorrektur kann man nach einer Rechnung vonFromm, die auf dem Maxwellschen Modell basiert, eine Relaxationszeit und eine korrigierte Viskosität _c ermitteln. Der Quotient _c/ stellt einen Schermodul dar. Diese Größe wird für Lösungen von Cellulosetrinitrat in Butylacetat, Polyvinylacetat in Dioxan, Polystyrol in Toluol, Polyacrylamid in Wasser, und Viskose, in Abhängigkeit von der Konzentrationc und dem SchergefälleD ermittelt. Es zeigt sich, daß _c/ etwa im Wendepunkt der Fließkurven eine Art Plateau oder ein flaches Maximum zeigt und in diesem Plateaubereich eine lineare Abhängigkeit von der Konzentration. Die absolute Größe von _c/ ist jedoch um Größenordnungen geringer, als sie nach der Formel vonRouse bzw.Bueche für die erste Relaxationszeit eines Verhängungsnetzwerkes zu erwarten wäre. Das wird so gedeutet, daß bei dem hohen Schergefälle, das bei den Messungen herrschte (D etwa 10⁴ sec^–1), ein Teil der Verhängungen zerstört ist, wodurch die Relaxationszeit vergrößert und der Schermodul verkleinert wird.

---

Summary From the end-correction, according to a calculation byFromm based upon theMaxwell-model, a relaxation time and a corrected viscosity _c can be obtained. The quotient _c/ represents a shear modulus. Its value is determined for solutions of cellulosetrinitrate in butylacetate, polyvinylacetate in dioxane, polystyrene in toluene, polyacryloamide in water, and viscose, in dependence of concentrationc and shear rateD. It is found, that _c/ shows a plateau or a flat maximum at the inflection point of the flow curves. In this range, a linear dependence on concentration is found too. The absolute value of _c/, however, is smaller by orders of magnitude than that to be expected for the first relaxation time of an entanglement network according to the formulas byRouse resp.Bueche. This is explained by a partial disruption of entanglements in the high shear rate prevailing at the experiments (D about 10⁴ sec^–1), which effects an increase of the relaxation time and a decrease of the shear modulus.

---

---

Vorgetragen auf der Jahrestagung der Deutschen Rheologen in Bad Ems vom 18.–19. Mai 1967.     

Transport in ordered and disordered porous media V: Geometrical results for two-dimensional systems

In this paper we continue the geometrical studies of computer generated two-phase systems that were presented in Part IV. In order to reduce the computational time associated with the previous three-dimensional studies, the calculations presented in this work are restricted to two dimensions. This allows us to explore more thoroughly the influence of the size of the averaging volume and to learn something about the use of anon-representative region in the determination of averaged quantities.

Nomenclature

Roman Letters A interfacial area of the– interface associated with the local closure problem, m² - a _i i=1, 2, gaussian probability distribution used to locate the position of particles - l unit tensor - characteristic length for the-phase particles, m - ⁰ reference characteristic length for the-phase particles, m - characteristic length for the-phase, m - _i i=1,2,3 lattice vectors, m - m convolution product weighting function - m _V special convolution product weighting function associated with a unit cell - n _i i=1, 2 integers used to locate the position of particles - n unit normal vector pointing from the-phase toward the-phase - r _p position vector locating the centroid of a particle, m - r gaussian probability distribution used to determine the size of a particle, m - r ₀ characteristic length of an averaging region, m - V averaging volume, m³ - V volume of the-phase contained in the averaging volume,V, m³ - x position of the centroid of an averaging area, m - x ₀ reference position of the centroid of an averaging area, m - y position vector locating points in the-phase relative to the centroid, m Greek Letters V /V, volume average porosity - _{a i} standard deviation ofa _i - _r standard deviation ofr - intrinsic phase average of      

Nonlinear rheological behavior of a concentrated spherical silica suspension

Linear and nonlinear viscoelastic properties were examined for a 50 wt% suspension of spherical silica particles (with radius of 40 nm) in a viscous medium, 2.27/1 (wt/wt) ethylene glycol/glycerol mixture. The effective volume fraction of the particles evaluated from zero-shear viscosities of the suspension and medium was 0.53. At a quiescent state the particles had a liquid-like, isotropic spatial distribution in the medium. Dynamic moduli G^* obtained for small oscillatory strain (in the linear viscoelastic regime) exhibited a relaxation process that reflected the equilibrium Brownian motion of those particles. In the stress relaxation experiments, the linear relaxation modulus G(t) was obtained for small step strain (0.2) while the nonlinear relaxation modulus G(t, ) characterizing strong stress damping behavior was obtained for large (>0.2). G(t, ) obeyed the time-strain separability at long time scales, and the damping function h() (–G(t, )/G(t)) was determined. Steady flow measurements revealed shear-thinning of the steady state viscosity () for small shear rates (< ^–1; = linear viscoelastic relaxation time) and shear-thickening for larger (>^–1). Corresponding changes were observed also for the viscosity growth and decay functions on start up and cessation of flow, + (t, ) and _– (t, ). In the shear-thinning regime, the and dependence of ₊(t,) and _–(t,) as well as the dependence of () were well described by a BKZ-type constitutive equation using the G(t) and h() data. On the other hand, this equation completely failed in describing the behavior in the shear-thickening regime. These applicabilities of the BKZ equation were utilized to discuss the shearthinning and shear-thickening mechanisms in relation to shear effects on the structure (spatial distribution) and motion of the suspended particles.Dedicated to the memory of Prof. Dale S. Parson     

A rotating hot-wire technique for spatial sampling of disturbed and manipulated duct flows

The documentation and control of flow disturbances downstream of various open inlet contractions was the primary focus with which to evaluate a spatial sampling technique. An X-wire probe was rotated about the center of a cylindrical test section at a radius equal to one-half that of the test section. This provided quasi-instantaneous multi-point measurements of the streamwise and azimuthal components of the velocity to investigate the temporal and spatial characteristics of the flowfield downstream of various contractions. The extent to which a particular contraction is effective in controlling ingested flow disturbances was investigated by artificially introducing disturbances upstream of the contractions. Spatial as well as temporal mappings of various quantities are presented for the streamwise and azimuthal components of the velocity. It was found that the control of upstream disturbances is highly dependent on the inlet contraction; for example, reduction of blade passing frequency noise in the ground testing of jet engines should be achieved with the proper choice of inlet configurations.List of symbols K _uv correlation coefficient= - P percentage of time that an azimuthal fluctuating velocity derivative dv/d is found - U streamwise velocity component U=U (, t) - V azimuthal or tangential velocity component due to flow and probe rotation V=V (, t) - mean value of streamwise velocity component - U _m resultant velocity from and - mean value of azimuthal velocity component induced by rotation - u fluctuating streamwise component of velocity u=u(, t) - v fluctuating azimuthal component of velocity v = v (, t) - u phase-averaged fluctuating streamwise component of velocity u=u(0) - v phase-averaged fluctuating azimuthal component of velocity v=v() - û average of phase-averaged fluctuating streamwise component of velocity (u()) over cases I-1, II-1 and III-1 û = û() - average of phase-averaged fluctuating azimuthal component of velocity (v()) over cases I-1, II-1 and III-1 - u fluctuating streamwise component of velocity corrected for non-uniformity of probe rotation and/or phase-related vibration u = u(0, t) - v fluctuating azimuthal component of velocity corrected for non-uniformity or probe rotation and/or phase-related vibration v=v (, t) - u ² rms value of corrected fluctuating streamwise component of velocity - rms value of corrected fluctuating azimuthal component of velocity - phase or azimuthal position of X-probe     

A three-parameter model describing the experimental relation between shear stress and shear rate for laminar flow of aqueous polymer solutions

Summary A three-parameter model is introduced to describe the shear rate — shear stress relation for dilute aqueous solutions of polyacrylamide (Separan AP-30) or polyethylenoxide (Polyox WSR-301) in the concentration range 50 wppm – 10,000 wppm. Solutions of both polymers show for a similar rheological behaviour. This behaviour can be described by an equation having three parameters i.e. zero-shear viscosity ₀, infinite-shear viscosity , and yield stress ₀, each depending on the polymer concentration. A good agreement is found between the values calculated with this three-parameter model and the experimental results obtained with a cone-and-plate rheogoniometer and those determined with a capillary-tube rheometer.

---

Zusammenfassung Der Zusammenhang zwischen Schubspannung und Schergeschwindigkeit von strukturviskosen Flüssigkeiten wird durch ein Modell mit drei Parametern beschrieben. Mit verdünnten wäßrigen Polyacrylamid-(Separan AP-30) sowie Polyäthylenoxidlösungen (Polyox WSR-301) wird das Modell experimentell geprüft. Beide Polymerlösungen zeigen im untersuchten Schergeschwindigkeitsbereich von ein ähnliches rheologisches Verhalten. Dieses Verhalten kann mit drei konzentrationsabhängigen Größen, nämlich einer Null-Viskosität ₀, einer Grenz-Viskosität und einer Fließgrenze ₀ beschrieben werden. Die Ergebnisse von Experimenten mit einem Kegel-Platte-Rheogoniometer sowie einem Kapillarviskosimeter sind in guter Übereinstimmung mit den Werten, die mit dem Drei-Parameter-Modell berechnet worden sind.

---

a Pa^–1 physical quantity defined by:a = {1 – ( / ₀)}/ ₀ - c l concentration (wppm) - D m capillary diameter - L m length of capillary tube - P Pa pressure drop - R m radius of capillary tube - u m s^–1 average velocity - v _r m s^–1 local axial velocity at a distancer from the axis of the tube - shear rate (–dv _r /dr) - local shear rate in capillary flow - s^–1 wall shear rate in capillary flow - Pa s dynamic viscosity - _a Pa s apparent viscosity defined by eq. [2] - ( _a ) Pa s apparent viscosity in capillary tube at a distanceR from the axis - ₀ Pa s zero-shear viscosity defined by eq. [4] - Pa s infinite-shear viscosity defined by eq. [5] - l ratior/R - kg m^– density - Pa shear stress - ₀ Pa yield stress - _r Pa local shear stress in capillary flow - _R Pa wall shear stress in capillary flow _R = (PR/2L) - _v m³ s^–1 volume rate of flow With 8 figures and 1 table     

Testing viscometric predictions of the internal viscosity model,using dilute viscous theta solutions

A stress-symmetrized internal viscosity (I.V.) model for flexible polymer chains, proposed by Bazua and Williams, is scrutinized for its theoretical predictions of complex viscosity ^* () = – i and non-Newtonian viscosity (), where is frequency and is shear stress. Parameters varied are the number of submolecules,N (i.e., molecular weightM = NM _s ); the hydrodynamic interaction,h ^*; and/f, where andf are the I.V. and friction coefficients of the submolecule. Detailed examination is made of the eigenvalues _p (N, h ^*) and how they can be estimated by various approximations, and property predictions are made for these approximations.Comparisons are made with data from our preceding companion paper, representing intrinsic properties [], [], [] in very viscous theta solutions, so that theoretical foundations of the model are fulfilled. It is found that [ ()] data can be predicted well, but that [ ()] data cannot be matched at high. The latter deficiency is attributed in part to unrealistic predictions of coil deformation in shear.     

Analysis of suddenly started laminar flow in the entrance region of a circular tube

Suddenly started laminar flow in the entrance region of a circular tube, with constant inlet velocity, is investigated analytically by using integral momentum approach. A closed form solution to the integral momentum equation is obtained by the method of characteristics to determine boundary layer thickness, entrance length, velocity profile, and pressure gradient.Nomenclature M(, , ) a function - N(, , ) a function - p pressure - p* p/1/2U ², dimensionless pressure - Q(, , ) a function - R radius of the tube - r radial distance - Re 2RU/, Reynolds number - t time - U inlet velocity, constant for all time, uniform over the cross section - u velocity in the boundary layer - u* u/U, dimensionless velocity - u ₁ velocity in the inviscid core - x axial distance - y distance perpendicular to the axis of the tube - y* y/R, dimensionless distance perpendicular to the axis - boundary layer thickness - * displacement thickness - /R, dimensionless boundary layer thickness - momentum thickness - absolute viscosity of the fluid - /, kinematic viscosity of the fluid - x/(R Re), dimensionless axial distance - density of the fluid - tU/(R Re), dimensionless time - _w wall shear stress     

Two-phase flow in heterogeneous porous media II: Numerical experiments for flow perpendicular to a stratified system

In this work, we make use of numerical experiments to explore our original theoretical analysis of two-phase flow in heterogeneous porous media (Quintard and Whitaker, 1988). The calculations were carried out with a two-region model of a stratified system, and the parameters were chosen be consistent with practical problems associated with groundwater flows and petroleum reservoir recovery processes. The comparison between theory (the large-scaled averaged equations) and experiment (numerical solution of the local volume averaged equations) has allowed us to identify conditions for which the quasi-static theory is acceptable and conditions for which a dynamic theory must be used. Byquasi-static we mean the following: (1) The local capillary pressure,everywhere in the averaging volume, can be set equal to the large-scale capillary pressure evaluated at the centroid of the averaging volume and (2) the large-scale capillary pressure is given by the difference between the large-scale pressures in the two immiscible phases, and is therefore independent of gravitational effects, flow effects and transient effects. Bydynamic, we simply mean a significant departure from the quasi-static condition, thus dynamic effects can be associated with gravitational effects, flow effects and transient effects. To be more precise about the quasi-static condition we need to refer to the relation between the local capillary pressure and the large-scale capillary pressure derived in Part I (Quintard and Whitaker, 1990). Herep _c ¦_y represents the local capillary pressure evaluated at a positiony relative to the centroid of the large-scale averaging volume, and {p _c }¦_x represents the large-scale capillary pressure evaluated at the centroid.In addition to{p _c } ^c being evaluated at the centroid, all averaged terms on the right-hand side of Equation (1) are evaluated at the centroid. We can now write the equations describing the quasi-static condition as , , This means that the fluids within an averaging volume are distributed according to the capillary pressure-saturation relationwith the capillary pressure held constant. It also means that the large-scale capillary pressure is devoid of any dynamic effects. Both of these conditions represent approximations (see Section 6 in Part I) and one of our main objectives in this paper is to learn something about the efficacy of these approximations. As a secondary objective we want to explore the influence of dynamic effects in terms of our original theory. In that development only the first four terms on the right hand side of Equation (1) appeared in the representation for the local capillary pressure. However, those terms will provide an indication of the influence of dynamic effects on the large-scale capillary pressure and the large-scale permeability tensor, and that information provides valuable guidance for future studies based on the theory presented in Part I.Roman Letters A scalar that maps {}*/t onto - A scalar that maps {}*/t onto - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - A interfacial area between the -region and the -region contained within, m² - a vector that maps ({}*/t) onto , m - a vector that maps ({}*/t) onto , m - b vector that maps ({p}– g) onto , m - b vector that maps ({p}– g) onto , m - B second order tensor that maps ({p}– g) onto , m² - B second order tensor that maps ({p}– g) onto , m² - c vector that maps ({}*/t) onto , m - c vector that maps ({}*/t) onto , m - C second order tensor that maps ({}*/t) onto , m² - C second order tensor that maps ({}*/t) onto . m² - D third order tensor that maps ( ) onto , m - D third order tensor that maps ( ) onto , m - D second order tensor that maps ( ) onto , m² - D second order tensor that maps ( ) onto , m² - E third order tensor that maps () onto , m - E third order tensor that maps () onto , m - E second order tensor that maps () onto - E second order tensor that maps () onto - p _c =(), capillary pressure relationship in the-region - p _c =(), capillary pressure relationship in the-region - g gravitational vector, m/s² - largest of either or - - - i unit base vector in thex-direction - I unit tensor - K local volume-averaged-phase permeability, m² - K local volume-averaged-phase permeability in the-region, m² - K local volume-averaged-phase permeability in the-region, m² - {K } large-scale intrinsic phase average permeability for the-phase, m² - K –{K }, large-scale spatial deviation for the-phase permeability, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K –{K }, large-scale spatial deviation for the-phase permeability in the-region, m² - K ^* large-scale permeability for the-phase, m² - L characteristic length associated with local volume-averaged quantities, m - characteristic length associated with large-scale averaged quantities, m - I _i i = 1, 2, 3, lattice vectors for a unit cell, m - l characteristic length associated with the-region, m - ; characteristic length associated with the-region, m - l _H characteristic length associated with a local heterogeneity, m - - n unit normal vector pointing from the-region toward the-region (n =–n ) - n unit normal vector pointing from the-region toward the-region (n =–n ) - p pressure in the-phase, N/m² - p local volume-averaged intrinsic phase average pressure in the-phase, N/m² - {p } large-scale intrinsic phase average pressure in the capillary region of the-phase, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p local volume-averaged intrinsic phase average pressure for the-phase in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - p –{p }, large scale spatial deviation for the-phase pressure in the-region, N/m² - P _c p –{p }, capillary pressure, N/m² - {p_c}^c large-scale capillary pressure, N/m² - r ₀ radius of the local averaging volume, m - R ₀ radius of the large-scale averaging volume, m - r position vector, m - , m - S /, local volume-averaged saturation for the-phase - S ^* {}*{}*, large-scale average saturation for the-phaset time, s - t time, s - u , m - U , m² - v -phase velocity vector, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - v local volume-averaged phase average velocity for the-phase in the-region, m/s - {v } large-scale intrinsic phase average velocity for the-phase in the capillary region of the-phase, m/s - {v } large-scale phase average velocity for the-phase in the capillary region of the-phase, m/s - v –{v }, large-scale spatial deviation for the-phase velocity, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - v –{v }, large-scale spatial deviation for the-phase velocity in the-region, m/s - V local averaging volume, m³ - V volume of the-phase in, m³ - V large-scale averaging volume, m³ - V capillary region for the-phase within, m³ - V capillary region for the-phase within, m³ - V _c intersection of m³ - V volume of the-region within, m³ - V volume of the-region within, m³ - V () capillary region for the-phase within the-region, m³ - V () capillary region for the-phase within the-region, m³ - V () , region in which the-phase is trapped at the irreducible saturation, m³ - y position vector relative to the centroid of the large-scale averaging volume, m Greek Letters local volume-averaged porosity - local volume-averaged volume fraction for the-phase - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region - local volume-averaged volume fraction for the-phase in the-region (This is directly related to the irreducible saturation.) - {} large-scale intrinsic phase average volume fraction for the-phase - {} large-scale phase average volume fraction for the-phase - {}* large-scale spatial average volume fraction for the-phase - –{}, large-scale spatial deviation for the-phase volume fraction - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - –{}, large-scale spatial deviation for the-phase volume fraction in the-region - a generic local volume-averaged quantity associated with the-phase - mass density of the-phase, kg/m³ - mass density of the-phase, kg/m³ - viscosity of the-phase, N s/m² - viscosity of the-phase, N s/m² - interfacial tension of the - phase system, N/m - , N/m - , volume fraction of the-phase capillary (active) region - , volume fraction of the-phase capillary (active) region - , volume fraction of the-region ( + =1) - , volume fraction of the-region ( + =1) - {p }– g, N/m³ - {p }– g, N/m³     

Deformation to breaking of deep water gravity waves

The results of laboratory observations of the deformation of deep water gravity waves leading to wave breaking are reported. The specially developed visualization technique which was used is described. A preliminary analysis of the results has led to similar conclusions than recently developed theories. As a main fact, the observed wave breaking appears as the result of, first, a modulational instability which causes the local wave steepness to approach a maximum and, second, a rapidly growing instability leading directly to the breaking.List of symbols L total wave length - H total wave height - crest elevation above still water level - trough depression below still water level - wave steepness =H/L - crest steepness =/L - trough steepness =/L - F ₁ forward horizontal length from zero-upcross point (A) to wave crest - F ₂ backward horizontal length from wave crest to zero-downcross point (B) - crest front steepness =/F ₁ - crest rear steepness =/F ₂ - vertical asymmetry factor=F ₂/F ₁ (describing the wave asymmetry with respect to a vertical axis through the wave crest) - µ horizontal asymmetry factor=/H (describing the wave asymmetry with respect to a horizontal axis: SWL) - T ₀ wavemaker period - L ₀ theoretical wave length of a small amplitude sinusoïdal wave generated at T _inf0 ^sup–1 frequency - ₀ average wave height     

An optical method for the measurement of unsteady film thickness

This paper describes a measurement technique to quantify temporal variations in the thickness of an unsteady liquid film with a resolution which is independent of the thickness. The optical transformation function has been derived for fringes of equal inclination and, for a temporally varying film, allows the unsteady component of film thickness to be measured in terms of frequency modulated signal analysis of light intensity variations. As it does not require calibration, the method is suited to in-situ measurements of complex and rapidly varying films as encountered in engineering two-phase flows. It requires the inversion of the frequency time-series of the light intensity observed by a photodetector which represents the absolute values of the time-derivative of the thickness variation.The technique has been used to measure the thickness of the film formed as a result of impingement of a pulsating two-phase jet onto a heated flat plate with surface temperatures of 150 °C and 240 °C and located 143 nozzle exit diameters downstream of the nozzle. The angle between the jet axis and the surface normal was 20 degrees and the injection frequency was 16.7 Hz corresponding to a flow rate of 7.2 mm³ per injection. The results along the line of incidence showed that the ensemble-averaged space-time structure of the film was qualitatively independent of the plate temperature with three peaks, two of which occurred at large radial distances and disappeared in less than 10 ms. The third peak was close to the impingement region and persisted for more than 50 ms due to the small velocities of the incoming two-phase jet as the nozzle needle closed and the low momentum wall jet which was unable to transport the droplets radially outwards. At the higher surface temperature, the rate of evaporation and the amplitude variation of the unsteady component of the overall film thickness increased, and the film covered a smaller area.List of symbols A amplitude of electric field - E electric field produced at a point - f _i (t) instantaneous frequency - f _PMT (t) frequency observed by photomultiplier tube - h thickness resolution - h _m minimum thickness that can be measured - h (t, x) unsteady film thickness - h _s (x) steady film thickness - h _t (t,x) overall film thickness - H nozzle-to-plate distance - i - I light intensity at a point - interference term - k wavenumber of the monochromatic point source - n refractive index of the air - refractive index of thin film material - r radial distance from the geometrical impingement point - rms root-mean-square - t time - t ₀ zero-crossing time defined in Fig. 2 - t _r rise-time defined in Fig. 2 - T _w wall temperature - x position vector in 3-D space Greek symbols angle of impingement - angle of reflection - integration constant defined in Eq. (15) - _c integration constant at r = 0 - phase angle - P optical path difference - P minimum optical path difference - azimuthal coordinate defined in Fig. 3 a - initial phase angle defined as = h _s (x) - wavelength of the illuminating source - initial phase of an electric field produced by a source - _f (t) ensemble-averaged rms series for f _PMT (t) - angle of incidence - angle of refraction - angular frequency of the electric field produced by a source - optical transformation function     

On the cross-effects of coupled macroscopic transport equations in porous media

In this paper, the derivation of macroscopic transport equations for this cases of simultaneous heat and water, chemical and water or electrical and water fluxes in porous media is presented. Based on themicro-macro passage using the method of homogenization of periodic structures, it is shown that the resulting macroscopic equations reveal zero-valued cross-coupling effects for the case of heat and water transport as well as chemical and water transport. In the case of electrical and water transport, a nonsymmetrical coupling was found.Notations b mobility - c concentration of a chemical - D rate of deformation tensor - D molecular diffusion coefficient - D _ij ^eff macroscopic (or effective) diffusion tensor - electric field - E ₀ initial electric field - k _ij molecular tensor - j, j ^*, current densities - K _ij macroscopic permeability tensor - l characteristic length of the ERV or the periodic cell - L characteristic macroscopic length - L _ijkl coupled flows coefficients - n _i unit outward vector normal to - p pressure - q _t ,q _t ⁺ , heat fluxes - q _c ,q _c ⁺ , chemical fluxes - s specific entropy or the entropy density - S entropy per unit volume - t time variable - t _ij local tensor - T absolute temperature - v _i velocity - V ₀ initial electric potential - V electric potential - x macroscopic (or slow) space variable - y microscopic (or fast) space variable - _i local vectorial field - _i local vectorial field - electric charge density on the solid surface - , bulk and shear viscosities of the fluid - _ij local tensor - _ij local tensor - _i local vector - _ij molecular conductivity tensor - _ij ^eff effective conductivity tensor - homogenization parameter - fluid density - ₀ ion-conductivity of fluid - _ij dielectric tensor - _i ¹ , _i ² , _i ³ local vectors - ⁴ local scalar - _S solid volume in the periodic cell - _L volume of pores in the periodic cell - boundary between _S and _L - ^s rate of entropy production per unit volume - total volume of the periodic cell - _l volume of pores in the cell On leave from the Politechnika Gdanska; ul. Majakowskiego 11/12, 80-952, Gdask, Poland.     

Mean and turbulent velocity measurements of supersonic mixing layers

The behavior of supersonic mixing layers under three conditions has been examined by schlieren photography and laser Doppler velocimetry. In the schlieren photographs, some large-scale, repetitive patterns were observed within the mixing layer; however, these structures do not appear to dominate the mixing layer character under the present flow conditions. It was found that higher levels of secondary freestream turbulence did not increase the peak turbulence intensity observed within the mixing layer, but slightly increased the growth rate. Higher levels of freestream turbulence also reduced the axial distance required for development of the mean velocity. At higher convective Mach numbers, the mixing layer growth rate was found to be smaller than that of an incompressible mixing layer at the same velocity and freestream density ratio. The increase in convective Mach number also caused a decrease in the turbulence intensity ( _u/U).List of symbols a speed of sound - b total mixing layer thickness between U ₁ – 0.1 U and U ₂ + 0.1 U - f normalized third moment of u-velocity, f u³/(U)³ - g normalized triple product of u² , g u²/(U)³ - h normalized triple product of u ², h u ²/(U)³ - l _u axial distance for similarity in the mean velocity - l _u axial distance for similarity in the turbulence intensity - M Mach number - M _c convective Mach number (for ₁ = ₂), M _c (U ₁ – U ₂)/(a ₁ + a ₂) - P static pressure - r freestream velocity ratio, r U ₂/U ₁ - Re unit Reynolds number, Re U/ - s freestream density ratio, s ₂/₁ - T _t total temperature - u instantaneous streamwise velocity - u deviation of u-velocity, uu – U - U local mean streamwise velocity - U ₁ primary freestream velocity - U ₂ secondary freestream velocity - average of freestream velocities, (U ₁ + U ₂)/2 - U freestream velocity difference, U U ₁ – U ₂ - instantaneous transverse velocity - v deviation of -velocity, – V - V local mean transverse velocity - x streamwise coordinate - y transverse coordinate - y ₀ transverse location of the mixing layer centerline - ensemble average - ratio of specific heats - boundary layer thickness (y-location at 99.5% of free-stream velocity) - similarity coordinate, (y – y ₀)/b - compressible boundary layer momentum thickness - viscosity - density - standard deviation - dimensionless velocity, (U – U ₂)/U - 1 primary stream - 2 secondary stream A version of this paper was presented at the 11th Symposium on Turbulence, October 17–19, 1988, University of Missouri-Rolla