Many-electron character of Rydberg series converging to the ionization thresholds of the 4<Emphasis Type="Italic">p</Emphasis><Superscript>4</Superscript>5<Emphasis Type="Italic">s</Emphasis> states of KrII

The photoionization cross sections of the 4p shell and the 4s main level and 4p ⁴(³ P) 5s ⁴ P _{5/2, 3/2} satellite subvalence levels of KrII have been calculated in the 4s-near-threshold range of excitation energies from 28.48 to 28.70 eV. The calculation takes into account the core relaxation by the methods of the theory of non-orthogonal orbitals, the interaction between resonant states through autoionization channels by solving the complex secular equation, and the interaction between the channels of the continuous spectrum in all orders of the perturbation theory by the K-matrix method. Good quantitative agreement between the energy-integrated theoretical and experimental photoionization cross sections for the satellite levels has been obtained for the first time. It is shown that only simultaneous consideration of the above-mentioned effects leads to such agreement. The resonant structure of the photoionization cross sections in this excitation energy range is related to the autoionization decay of the 4p ⁴5s(⁴ P _1/2)np and 4p ⁴5s(² P _3/2)np Rydberg series. The specificity of this process is that both series manifest themselves not independently but owing to their strong electrostatic interaction with the prominent 4p ⁴(¹ D)5s ² D _5/2 6p _3/2 resonance, which lies in this excitation energy range.     

Excitation of resonance lines of the cadmium ion by monoenergetic electrons

The excitation of resonance lines at 226.5 and 214.4 nm, corresponding to the transitions 226.5 (5p ² P ₁ ^2/0 →5s ² S _1/2) and 5p ² P ₃ ^2/0 → 5s ² S _1/2, respectively, in the Cd⁺ ion upon collisions with monoenergetic electrons with an energy in the range of 4–130 eV is studied with high precision by a spectroscopic method in crossing beams. It is found that the dependence of the effective excitation cross sections of the resonance doublet components on the energy of the electrons has a distinct resonance structure. It is shown that the dominant mechanism responsible for this structure is the capture of an incident electron by a Cd⁺ ion with the simultaneous excitation of an electron from the subvalence 4d ¹⁰ shell to the autoionizing states of the Cd atom with their subsequent decay (directly or via cascade transitions) to resonance levels of the ion. The results obtained are compared with data from other experiments and with the results of the R-matrix strong-coupling calculation of 15 states and of semiempirical calculation using the Van Regemorter formula.     

Polarisationseffekte in der Hyperfeinstruktur von65Cu I, 3d 94s 2 m 2 D

The hyperfinestructure of the transition⁶⁵CuI, 3d ¹⁰4p ² P _3/2—3d ⁹4s ² m ² D _5/2 was investigated by optical interferometric methods. For the hfs-factors the following values were found:A(⁶⁵Cu,m ² D _5/2)=26,79(3) mK andB(⁶⁵Cu,m ² D _5/2)=5,81(10) mK. The core polarization of them ² D-terms and the Sternheimer corrections in the calculation of the quadrupolmoment of copper 65 from theB-factors of the terms 3d ⁹ 4s² m ² D and 3d ¹⁰ 4p ² P _3/2. were discussed.     

Interrelationship between the polarization moments of different parity upon optical pumping of atoms under the magnetic resonance conditions: I. Experiment on the <Superscript>133</Superscript>Cs and <Superscript>4</Superscript>He atoms

In an experiment with an optical pumping of ¹³³Cs atoms in the 6² S _1/2 ground state, the line shape of the D ^2f magnetic resonance signal for the transverse alignment component oscillating at a double frequency f of a radio-frequency (RF) magnetic field is found to strongly depend on the polarization of pumping radiation. On passage from a linearly polarized pumping light to a circularly polarized (CP) light with a sufficiently strong RF field the ordinary three-peak line with the highest central peak transforms into a two-peak line with a minimum at the center, so that the D ^2f signal line resembles the M ^f signal line of a transverse orientation oscillating at the RF field frequency f. This suggests that the orientation (the first-rank polarization moment (PM)) arising upon CP pumping affects the alignment (the second-rank PM); i.e., the PMs of Cs atoms with different parities of their ranks become coupled. No influence of the polarization of a pumping radiation on the line shape of the D ^2f signal is observed in a similar experiment with the ⁴He atoms in the 2³ S ₁ metastable state.     

Electron paramagnetic resonance of Cr<Superscript>3+</Superscript>-Li<Superscript>+</Superscript> centers in (Cr,Li): Mg<Subscript>2</Subscript>SiO<Subscript>4</Subscript> synthetic forsterite

Synthetic single crystals of chromium-and lithium-doped forsterite, namely, (Cr,Li): Mg₂SiO₄, are studied using electron paramagnetic resonance spectroscopy. It is revealed that, apart from the known centers Cr³⁺(M1) and Cr³⁺(M2) (with local symmetries C_i and C_s, respectively), these crystals involve two new types of centers with C₁ symmetry, namely, Cr³⁺(M1)′ and Cr³⁺(M2)′ centers. The standard parameters D and E in a zero magnetic field [zero-field splitting (ZFS) parameters expressed in GHz] and principal components of the g tensor are determined as follows: D=31.35, E=8.28, and g=(1.9797, 1.9801, 1.9759) for Cr³⁺(M1)′ centers and D=15.171, E=2.283, and g=(1.9747, 1.9769, 1.9710) for Cr³⁺(M2)′ centers. It is found that the lowsymmetric effect of misalignment of the principal axes of the ZFS and g tensors most clearly manifests itself (i.e., its magnitude reaches 19°) in the case of Cr³⁺(M2)′ centers. The structural models Cr³⁺(M1)-Li⁺(M2) and Cr³⁺(M2)-Li⁺(M1) are proposed for the Cr³⁺(M1)′ and Cr³⁺(M2)′ centers, respectively. The concentrations of both centers are determined. It is demonstrated that, upon the formation of Cr³⁺-Li⁺ ion pairs, the M1 position for chromium appears to be two times more preferable than the M2 position. Reasoning from the results obtained, the R₁ line (the ²E → ⁴A₂ transition) observed in the luminescence spectra of (Cr,Li): Mg₂SiO₄ crystals in the vicinity of 699.6 nm is assigned to the Cr³⁺(M1)′ center.     

Searching for signatures around 1920 MeV of a N<Superscript>*</Superscript> state of three hadron nature

We provide a series of arguments which support the idea that the peak seen in the \( \gamma\) p \( \rightarrow\) K ⁺ \( \Lambda\) reaction around 1920MeV should correspond to the recently predicted state of J ^P = 1/2⁺ as a bound state of K \( \bar{{K}}\) N with a mixture of a ₀(980)N and f ₀(980)N components. At the same time we propose polarization experiments in that reaction as a further test of the prediction, as well as a study of the total cross-section for \( \gamma\) p \( \rightarrow\) K ⁺ K ^- p at energies close to threshold and of dσ/dM _inv for invariant masses close to the two-kaon threshold.     

Thermal quenching of luminescence of BaY<Subscript>2</Subscript>F<Subscript>8</Subscript> crystals activated with Er<Superscript>3+</Superscript> and Tm<Superscript>3+</Superscript> ions

Thermal quenching of interconfigurational 5d-4f luminescence of Er³⁺ and Tm³⁺ ions in BaY₂F₈ crystals is studied in the temperature range of 330–790 K. The quenching temperatures are ~575 and ~550 K for Er³⁺ and Tm³⁺, respectively. It is shown that quenching of 5d-4f luminescence of Tm³⁺ ions is caused by thermally stimulated ionization of 5d electrons to the conduction band.     

Formation of lithium-like boron and nitrogen ions in the <Superscript>4</Superscript><Emphasis Type="Italic">P</Emphasis><Subscript>5/2</Subscript> state in gaseous media

We experimentally determined the fraction of α_v of lithium-like boron B²⁺ and nitrogen N⁴⁺ ions in the ⁴ P _5/2 state having a velocity of 3.6 au that are formed upon capture of two (α₂) electrons by hydrogen-like B⁴⁺ and N⁶⁺ ions and upon capture of one (α₁) electron by helium-like (1s2s)^1,3 S metastable B³⁺ and N⁵⁺ ions in gaseous media (H₂, He, N₂, Ar), as well as upon passage through a celluloid film. In light-element media (H₂, He), α₂ increases proportional to the target thickness T _g and reaches a maximum at T _g ≈ 10¹⁶ atom/cm² (for B ions, α₂ ≈ 0.2 in H₂ and α₂ ≈ 0.4 in He). For boron and nitrogen ions passing through thin layers of heavier gases (N₂, Ne), α₂ depends considerably more weakly on T _g , and, in Ar, becomes practically constant. It is assumed that, since hydrogen and helium do not contain electrons with parallel spins, autoionizing lithium-like ions are formed as a result of successive (one by one) capture of electrons, whereas, in the heavier gases, simultaneous capture of two electrons predominates. At T _g ～ 10¹⁵ atom/cm², the fraction α₁ of boron ions is the highest in He, ～0.15, and the lowest in Ar, ～0.07, being in qualitative agreement with calculations.     

Excitation of the Yb II transitions terminating on the low-lying odd levels

Excitation of the transitions from the even levels of a singly charged ytterbium ion that terminate on the low-lying odd levels 4f ¹³(² F°)6s ^{2 2} F°, 4f ¹⁴(¹ S)6p ² P°, and 4f ¹³(² F°_7/2)5d6p(³ D)³[3/2]° is experimentally studied by measuring 51 excitation cross sections at an electron energy of 50 eV, and 16 optical excitation functions are determined within the electron energy range 0–200 eV. The largest magnitudes of the measured cross sections exceed 3 × 10^?17 cm².     

Why <Emphasis Type="Italic">X</Emphasis>(3872) is not a molecule

We discuss the scenario where the X(3872) resonance is the \(c\bar c\) = χ_c1(2P) charmonium which “sits on” the D*⁰\({\bar D^0}\) threshold. We explain the shift of the mass of the X(3872) resonance with respect to the prediction of a potential model for the mass of the χ_c1(2P) charmonium by the contribution of the virtual D*\(\bar D\) + c.c. intermediate states into the self energy of the X(3872) resonance. This allows us to estimate the coupling constant of the X(3872) resonance with the D*⁰\({\bar D^0}\) channel, the branching ratio of the X(3872) → D*⁰\({\bar D^0}\) + c.c. decay, and the branching ratio of the X(3872) decay into all non-D*⁰\({\bar D^0}\) + c.c. states. We predict a significant number of unknown decays of X(3872) via two gluon: X(3872) → gluongluon → hadrons. We suggest a physically clear program of experimental researches for verification of our assumption.     

Theoretical study of photoionization of the isoelectronic sequence Rb<Superscript>+</Superscript>, Sr<Superscript>2+</Superscript>, and Y<Superscript>3+</Superscript>

The photoionization cross sections for the 4p shell of ions of the Kr isoelectronic sequence Rb⁺, Sr²⁺, and Y³⁺ are calculated. The configuration interaction theory and the perturbation theory are used to describe the many-electron effects. The relativistic effects are taken into account in the Pauli-Fock approximation. The calculated resonance structure of photoionization cross sections for the 4p shell in the region below the 4s threshold associated with the autoionization of the 4s-np singly excited states and the 4p4p-nln′l′ doubly excited states reproduces the results of recent measurements of total photoabsorption cross sections for the Rb⁺, Sr²⁺, and Y³⁺ ions. It is found that, as the nuclear charge in the isoelectronic sequence increases, the ratio between the direct and correlation parts of amplitudes of the 4s-(n/?)p transition changes and, as the consequence, the minimum of the photoionization cross section of the 4s shell shifts from the continuous spectrum to the region of states of discrete spectrum. This accounts for the strong changes in the shape of the 4s-np resonances in the photoionization cross sections for the 4p shell of Rb⁺, Sr²⁺, and Y³⁺, as well as the distinction between the shapes of the 4s-6p _1/2 mirror resonance in the partial 4p _1/2 and 4p _3/2 photoionization cross sections for the Y³⁺ ion which do not suppress each other in the total photoionization cross section, as is the case for similar resonances in Rb⁺ and Sr²⁺.     

Observation of high efficiency of Raman scattering in the process of the three-photon ionization of samarium atom

Very high efficiency of Raman scattering on samarium atoms in the process of three-photon ionization has been detected. An intense maximum attributed to the one-photon transition 4f ⁶5d6s ⁹ H ₂ → 4f ⁵5d6s ^{2 7} D ₃° between two excited states is observed in the dependence of the yield of Sm⁺ ions on the laser-radiation frequency. The 4f ⁶5d6s ⁹ H ₂ state is populated owing to the spontaneous Raman scattering 4f ⁶6s ^{2 7} F ₃ + ω ? ν → 4f ⁶5d6s ⁹ H ₂.     

Search for superheavy hydrogen isotopes <Superscript>4,5</Superscript>H in reactions of pion absorption by <Superscript>10,11</Superscript>B nuclei

The results of searching for production of superheavy hydrogen isotopes ^4,5H in reactions of absorption of stopped π^? mesons by ^10,11B nuclei are reported. A peak near 3 MeV was observed in the missing mass spectra measured in the reactions ^10,11B(π^?, t⁴He)X, ¹⁰B(π^?, d⁴He)X, and ¹⁰B(π^?, t³He)X. A structure caused by two ⁵H states with the resonance energies E _R = 5.2 and 10.4 MeV was observed in the missing mass spectra measured in the reactions ¹¹B(π^?, d⁴He)X, ¹¹B(π^?, t³He)X, and ¹⁰B(π^?, d³He)X.     

Cohesive energy of zincblende (A<Superscript>III</Superscript>B<Superscript>V</Superscript> and A<Superscript>II</Superscript>B<Superscript>VI</Superscript>) structured solids

In this paper we present an expression relating the cohesive energy (E _coh in kcal/mol) of A^IIIB^V and A^IIB^VI semiconductors with the product of ionic charges (Z ₁ Z ₂) and nearest-neighbour distance d (Å). The cohesive energy values of these solids exhibit a linear relationship when plotted on a log-log scale against the nearest-neighbour distance d (Å), but fall on different straight lines according to the ionic charge product of the solids. A good agreement has been found between the experimental and calculated values of the cohesive energy of A^IIIB^V and A^IIB^VI semiconductors.     

Electron paramagnetic resonance of Gd<Superscript>3+</Superscript> aqua complexes in vitrified aqueous solutions and Gd<Superscript>3+</Superscript> aqua ions adsorbed on the capillary surface

Electron paramagnetic resonance (EPR) spectra of Gd³⁺ aqua complexes are measured in dilute aqueous solutions of Gd(NO₃)₃ (C<0.2 M) at room temperature. A partial resolution of the fine structure observed in the spectra is characteristic of solid disordered systems and results in an increase in the effective width of the EPR line with a decrease in the Gd³⁺ concentration. This phenomenon is explained in terms of adsorption of Gd³⁺ aqua ions on the surface of the measuring capillaries. The fine structure is revealed in the EPR spectra of Gd(NO₃)₃ aqueous solutions, namely, the Gd(NO₃)₃ solutions vitrified at a temperature of 77 K (with an addition of 10–15 vol % glycerol) and Gd(NO₃)₃ solutions quasi-vitrified at 298 K (with an addition of 70–90 vol % glycerol). Analysis of the EPR spectra demonstrates that these solutions contain two types of aqua complexes with fine structure parameters D₁=180 G and D₂=580 G. Reasoning from a comparison with x-ray diffraction data, the fine structure parameters D₁ and D₂ are assigned to higher symmetric eight-coordinate and lower symmetric nine-coordinate Gd³⁺ aqua complexes, respectively.     

Effect of the Lattice and Spin-Phonon Contributions on the Temperature Behavior of the Ground State Splitting of Gd<Superscript>3+</Superscript> in SrMoO<Subscript>4</Subscript>

The temperature behavior of the EPR spectra of the Gd³⁺ impurity center in single crystals of SrMoO₄ in the temperature range T = 99–375 K is studied. The analysis of the temperature dependences of the spin Hamiltonian b ₂ ⁰ (T) = b₂(F) + b₂(L) and P ₂ ⁰ (T) = P₂(F) + P₂(L) (for Gd¹⁵⁷) describing the EPR spectrum and contributing to the Gd³⁺ ground state splitting ΔE is carried out. In terms of the Newman model, the values of b₂(L) and P₂(L) depending on the thermal expansion of the static lattice are estimated; the b₂(F) and P₂(F) spin-phonon contributions determined by the lattice ion oscillations are separated. The analysis of b ₂ ⁰ (T) and P ₂ ⁰ (T) is evidence of the positive contribution of the spin-phonon interaction; the model of the local oscillations of the impurity cluster with close frequencies ω describes well the temperature behavior of b₂(F) and P₂(F).     

Low-temperature time-resolved VUV luminescence spectroscopy of SrF<Subscript>2</Subscript>: Er<Superscript>3+</Superscript> crystals

Time-resolved excitation and emission spectra of SrF₂: Er³⁺ upon selective excitation with synchrotron radiation in the VUV and ultrasoft x-ray ranges at T = 8 K were studied. The VUV luminescence of SrF₂: Er³⁺ derives from high-energy interconfiguration 4f¹⁰5d-4f¹¹ transitions in the Er³⁺ ion. The VUV emission spectrum revealed, in addition to the 164.5-nm band (millisecond-range kinetics), a band at 146.4 nm (with a decay time of less than 600 ps). The formation of excitation spectra for the f-f and f-d transitions in the Er³⁺ ion is discussed.     

Experimental Study and Analysis of Absorption Spectra of Ni<Superscript>2+</Superscript> Ions in Nickel Orthoborate Ni<Subscript>3</Subscript>(BO<Subscript>3</Subscript>)<Subscript>2</Subscript>

The results of studies of the absorption spectra of nickel orthoborate Ni₃(BO₃)₂ in the range of electronic d–d-transitions are reported. The obtained data are analyzed in the framework of the crystal field theory. The Ni²⁺ ions are located in two crystallographically nonequivalent positions 2a and 4f with point symmetry groups C_2h and C₂, respectively, surrounded by six oxygen ions forming deformed octahedra. The absorption spectra exhibit three intense bands corresponding to spin-resolved transitions from the ground state of nickel ion ³A_2g (³F) to the sublevels of the ³T_2g (³F), ³T_1g (³F) and ³T_1g (³P) triplets split by the spinorbit interaction and the rhombic component of the crystal field. At temperatures below 100 K, the spectra exhibit a thin structure, in which phonon-free lines can be distinguished. Comparison of the calculated frequencies of the zero-phonon transitions with the experimental data allows estimating parameters of the crystal field acting on the nickel ions in the 2a- and 4f-positions, as well as the parameters of electrostatic interaction between the 3d electrons and spin-orbit interaction constants.     

4<Emphasis Type="Italic">p</Emphasis><Superscript>5</Superscript>4<Emphasis Type="Italic">d</Emphasis><Superscript>2</Superscript> configuration in the spectra of rubidium-like Ru VIII and Rh IX ions

The spectra of ruthenium and rhodium excited in a low-inductive vacuum spark have been obtained using a vacuum grazing-incidence spectrograph with a grating of 3600 lines/mm 3 m in radius in the range of 180–350 Å. The bidium-like spectra of Ru VIII and Rh IX were analyzed. Ten spectral lines of the 4p ⁶4d-4p ⁵4d ² transitions are identified and six energy levels in the 4p ⁵4d ² configuration with an excited internal electron were found for each ion for the first time.     

Energy levels of ions of silver and rhodium isoelectronic sequences with <Emphasis Type="Italic">Z</Emphasis> < 86

The method of extrapolation of the parameter of a model potential for states of one electron (4f, 5s, 5p, 5d, 5f) above the core 1s ²2s ²2p ⁶3s ²3p ⁶3d ¹⁰4s ²4p ⁶4d ¹⁰ and one vacancy (4d ⁹) in the same core is applied to calculate the energy levels in the silver and rhodium isoelectronic sequences with the maximum nuclear charge Z = 86. The energy levels of Ag-and Rh-like ions were used for the calculation of the energies of resonance transitions to the ground state ¹ S ₀ in Pd-like ions. Good agreement between the theoretical and calculated energies of the resonance transitions in Pd-like ions indicates the reliability of the results obtained.