Master equations for time correlation functions of a quantum system interacting with stochastic perturbations and applications to emission and absorption line shapes

The stochastic and quantum dynamics of open quantum systems interacting with stochastic perturbations in considered. The master equations for one time and multi-time correlation functions of such a system are derived to all orders in the interaction with the stochastic perturbations. The importance of the non-markovian character of such equations in the study of various problems in optical resonance is discussed. The simplified form of the non-markovian master equations in Born approximation is also given. It is shown that such non-markovian master equations in Born approximation are exact if there is only one random perturbation, of the telegraphic signal type, acting on the system. The master equations for the linear response functions of an open system interacting with stochastic perturbations are also derived. The non-markovian master equations for multitime correlations are used to study the behaviour of two level atoms interacting with fluctuating laser fields. Both amplitude and phase fluctuations are taken into account. Explicit results are presented for the spectrum of resonance fluorescence, absorption spectrum, photon antibunching effects etc. The calculations are done for arbitrary values of the relaxation parameters and intial conditions. In general the fluorescence spectrum is found to be asymmetric for off resonant fields.     

Kinetic theory in the weak-coupling approximation: I. Formal theory and application to classical open systems

A general formalism, where irreversible processes are related to singularities of the resolvent of the Liouville operator, is applied to classical open systems. For a system weakly coupled to a thermal reservoir, a kinetic equation is derived. It is shown that the method leads to equations defining a positivity-preserving semigroup with the Maxwell-Boltzmann distribution as a stationary solution and obeying an H-theory. It is pointed out that these properties are not always shared by irreversible equations obtained as asymptotic approximations of the so-called generalized master equation.     

Nonlinear relaxation and fluctuations of damped quantum systems

The paper reexamines the treatment of irreversible quantum systems by master equations. Shortcomings of the conventional theory of quantum Markov processes pointed out by Talkner are analyzed. It is shown that a frequently used quantum regression hypothesis is not correct, in general. A new generalized master equation determining the relaxation to equilibrium is derived by means of time-dependent projection operator techniques. It is shown that this master equation also determines the time evolution of equilibrium correlations and response functions. The Markovian approximation is discussed, and a new type of Markovian limit, the Brownian motion limit, is introduced besides the weak coupling limit. The shortcomings of the conventional approach are resolved by deriving new formulae for the time evolution of the correlation and response functions of a quantum Markov process. The symmetries of the process are emphasized, and it is shown how the fluctuation-dissipation theorem and the detailed balance symmetry emerge from the master equation approach.     

Information Dimension of Stochastic Processes on Networks: Relating Entropy Production to Spectral Properties

We consider discrete stochastic processes, modeled by classical master equations, on networks. The temporal growth of the lack of information about the system is captured by its non-equilibrium entropy, defined via the transition probabilities between different nodes of the network. We derive a relation between the entropy and the spectrum of the master equation’s transfer matrix. Our findings indicate that the temporal growth of the entropy is proportional to the logarithm of time if the spectral density shows scaling. In analogy to chaos theory, the proportionality factor is called (stochastic) information dimension and gives a global characterization of the dynamics on the network. These general results are corroborated by examples of regular and of fractal networks.     

A time convolution less density matrix approach to the nonlinear optical response of a coupled system-bath complex

Time convolution less density matrix theory (TCL) is a powerful and well established tool to investigate strong system-bath coupling for linear optical spectra. We show that TCL equations can be generalised to the nonlinear optical response up to a chosen order in the optical field. This goal is achieved via an time convolution less perturbation scheme for the reduced density matrices of the electronic system. In our approach, the most important results are the inclusion of a electron-phonon coupling non-diagonal in the electronic states and memory effects of the bath: First, the considered model system is introduced. Second, the time evolution of the statistical operator is expanded with respect to the external optical field. This expansion is the starting point to explain how a TCL theory can treat the response up to in a certain order in the external field. Third, new TCL equations, including bath memory effects, are derived and the problem of information loss in the reduced density matrix is analysed. For this purpose, new dimensions are added to the reduced statistical operator to compensate lack of information in comparison with the full statistical operator. The theory is benchmarked with a two level system and applied to a three level system including non-diagonal phonon coupling. In our analysis of pump-probe experiments, the bath memory is influenced by the system state occupied between pump and probe pulse. In particular, the memory of the bath influences the dephasing process of electronic coherences developing during the time interval between pump and probe pulses.     

The two independent equations of circuits in integral form of field theory:The fundamental law of circuits

1 Introduction Historically, circuit theory was initially considered as a part of the electromagnetic theory. Later on, it branched out to become an independent theory. After several stages of its development, Kirchhoff’s law was commonly regarded as the fundamental law of circuits[1]. Especially after the 1960s, the completely topological formulation of Kirchhoff’s law made even more important contribution to the development of moderncircuit theory. However, it has been also known for a l…     

General Non-Markovian Quantum Dynamics

A general approach to the construction of non-Markovian quantum theory is proposed. Non-Markovian equations for quantum observables and states are suggested by using general fractional calculus. In the proposed approach, the non-locality in time is represented by operator kernels of the Sonin type. A wide class of the exactly solvable models of non-Markovian quantum dynamics is suggested. These models describe open (non-Hamiltonian) quantum systems with general form of nonlocality in time. To describe these systems, the Lindblad equations for quantum observable and states are generalized by taking into account a general form of nonlocality. The non-Markovian quantum dynamics is described by using integro-differential equations with general fractional derivatives and integrals with respect to time. The exact solutions of these equations are derived by using the operational calculus that is proposed by Yu. Luchko for general fractional differential equations. Properties of bi-positivity, complete positivity, dissipativity, and generalized dissipativity in general non-Markovian quantum dynamics are discussed. Examples of a quantum oscillator and two-level quantum system with a general form of nonlocality in time are suggested.     

Some properties of stochastic equations for coupled chemical reactions far from equilibrium

Solutions of master equations for coupled chemical reactions far from equilibrium with one varying molecule species are studied and used for getting information about nonlinear Fokker-Planck equations and slow time-dependent processes such as extinction to an absorbing state and transition between several steady states. The Fokker-Planck equation solution is compared to that of the master equation in a relative sense and it is shown that they agree quite well in some important situations but that in general the cases can deviate considerably, when, e.g., accounting for the mutual importance of two probability maxima.     

Anomalous transport in fluid field with random waiting time depending on the preceding jump length

Anomalous (or non-Fickian) transport behaviors of particles have been widely observed in complex porous media. To capture the energy-dependent characteristics of non-Fickian transport of a particle in flow fields, in the present paper a generalized continuous time random walk model whose waiting time probability distribution depends on the preceding jump length is introduced, and the corresponding master equation in Fourier-Laplace space for the distribution of particles is derived. As examples, two generalized advection-dispersion equations for Gaussian distribution and lévy flight with the probability density function of waiting time being quadratic dependent on the preceding jump length are obtained by applying the derived master equation.     

On a simple derivation of master equations for diffusion processes driven by white noise and dichotomic Markov noise

A very simple way is presented of deriving the partial differential equations (the master equations) satisfied by the probability density for certain kinds of diffusion processes in one dimension, in which the driving term is a Gaussian white noise, or a dichotomic noise, or a combination of the two. The method involves the use of certain ‘formulas of differentiation’ to derive the equations obeyed by the characteristic functions of the processes concerned, and thence the corresponding master equations. The examples presented cover a substantial number of diffusion processes that occur in physical modelling, including some master equations derived recently in the literature for generalizations of persistent diffusion.     

Theory of nuclear relaxation in concentrated paramagnetic solutions

Relaxation equations are derived for an electron-nuclear spin system, with account of the exchange interaction between electronic spins. It is shown that the relaxation equations can be derived by standard perturbation theory, with the help of the random-local-field method, based on a certain stochastic model of the exchange coupling. The perturbation theory is carried out to second order only for the interactions which are directly responsible for the relaxation, and the exchange interaction can be arbitrarily strong. The relaxation times are expressed in terms of the spectral densities of the correlation functions, which describe not only the thermal broadening of the electron-nuclear interactions, but also the exchange interaction. An explicit expression is obtained for these correlation functions.     

非平衡系统的概率模型及Master方程的建立

针对非平衡态统计中出现的非线性及多元线性Master方程,明确提出了一般的概率假定;应用概率论的方法建立了一般的非线性及多元线性Master方程;讨论了它们与宏观动力学方程的一致性问题;最后应用多元线性Master方程讨论了Brusselator的涨落,并对其耗散结构的产生作了初步解释。 关键词：     

Theory of nonlinear dispersive waves and selection of the ground state

A theory of time-dependent nonlinear dispersive equations of the Schr?dinger or Gross-Pitaevskii and Hartree type is developed. The short, intermediate and large time behavior is found, by deriving nonlinear master equations (NLME), governing the evolution of the mode powers, and by a novel multitime scale analysis of these equations. The scattering theory is developed and coherent resonance phenomena and associated lifetimes are derived. Applications include Bose-Einstein condensate large time dynamics and nonlinear optical systems. The theory reveals a nonlinear transition phenomenon, "selection of the ground state," and NLME predicts the decay of excited state, with half its energy transferred to the ground state and half to radiation modes. Our results predict the recent experimental observations of Mandelik et al. in nonlinear optical waveguides.     

Diffusion equation for the quasi-incoherent motion of Frenkel excitons in molecular crystals

In a recent paper a master equation describing the quasi-incoherent motion of Frenkel excitons in molecular crystals has been derived within the Haken-Strobl model for the coupled coherent and incoherent motion of Frenkel excitons. Starting from this master equation and using only the translational symmetry of the crystal lattice, for crystals with one molecule in the unit cell a diffusion equation is derived. For crystals with several molecules in the unit cell instead of a diffusion equation one obtains a set of diffusion-like equations. These equations are solved explicitly for the case of two molecules in the unit cell and asymptotic expressions are discussed. It is shown that this asymptotic behaviour is again described by a diffusion equation.     

Superradiance and energy transfer within a system of atoms

We investigate cooperative effects in energy relaxation and energy transfer for N atoms in a thermal radiation field with superradiance master equations as well as a closed set of coupled moment equations. Both spatially large and spatially small systems are considered. For small systems nonlinear rate equations for the energy are related to the moment equations. Symmetry of the small system to interchanging atoms is used to incorporate off-diagonal solutions of the superradiance master equation in expressions for the probability of the transfer of energy from one group of atoms to another. The long time excitation probability for initially unexcited atoms is large and strongly correlated. Cooperative processes in a large system which fall off with the distance between a cooperating pair of atoms include energy loss and transfer terms in the master equation. The energy transfer is oscillatory in time. Energy relaxation is shown by numerical solution to become cooperative in a very sudden manner as the scale of the atomic system is decreased through the resonant wavelength.     

On the theory of electronic processes in ionic crystal semiconductors II

In preceding papers a completely atomistic theory of electronic processes in ionic crystal semiconductors was developed, where these processes were restricted to single impurities. In this paper the theory is extended to include electronic processes for several impurity centers, in order to obtain the connection with the phenomenological rate equations of semiconductor physics. The treatment is completely atomistic again and all constants and the special form of the rate equations are deduced from first principles. To derive sufficiently detailed information the treatment is performed for a suitable example, namely for the F-F′-reaction kinetics.     

THE DIELECTRIC FUNCTION OF AN ELECTRON SYSTEM IN A PERIODIC STRUCTURE: VAA THEORY+

A general expression for the dielectric function of an electron system in a period structure has been derived by using linear response theory with the assumption that the equilibrium electronic density differs slight1y from its average value. Starting from the BBGKY equations,the theory is formulated in the Velocity Average Approximation.Numerical results for the dispersion and damping of plasmons and for the longitudinal dielectric function are given in the case of sinusoidally modulated structures.     

General theory for the interference of two-photon and one-photon processes in semiconductor heterostructures

We develop a general theory for the dynamics of multi-photon processes in semiconductor heterostructures. The resulting effective multi-band Bloch equations describe the dynamics of electrons in the reduced set of bands between which the optical pulses induce quasi-resonant transitions. The model is specialized to the case of interfering one- and two-photon transitions across the band gap. The withdrawn bands are included as intermediate states for an effective interaction that is quadratic in the electromagnetic fields. The benefit of this perturbative approach is to lead to equations of motion for slowly varying quantities only, in the spirit of the rotating wave approximation. Coulomb interaction and relaxation can also easily be included. Finally, a general expression for the time dependent polarization current that is consistent with the approximations involved by the effective multi-band Bloch equations is derived.