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1.
R. Kh. Ishembetov M. Kh. Balapanov Yu. Kh. Yulaeva 《Russian Journal of Electrochemistry》2011,47(4):416-419
Temperature dependences of the Peltier coefficient are studied in the temperature range of 300–700 K under variation of the
composition of the Li
x
Cu(2 − x) − δS samples. The obtained values of the Peltier coefficient of the Li0.05Cu1.95 − δS samples with a different copper content are within the range of 0.1–0.4 J/A, which is somewhat higher than the similar parameters
of bismuth telluride, the basic material of semiconductor coolers. 相似文献
2.
Ahmad Nazrul Rosli Noriza Ahmad Zabidi Hasan A. Kassim Keshav N. Shrivastava 《Journal of Cluster Science》2011,22(3):491-499
We have performed the calculation of the vibrational frequencies, Fermi energy and binding energy for several clusters of
Ni and vanadium atoms by using the first principles. The calculations are performed by using the density-functional theory
in the local-density approximation with spin polarized orbitals. The calculation of vibrational frequencies shows that some
of the clusters have positive vibrational frequencies which describe the oscillations of the stable clusters. The negative
vibrational frequencies indicate that these clusters are instable with respect to these vibrations when no energy of this
frequency is supplied. We find that for vanadium concentration less than 11.1% the clusters of Ni and V atoms are not stable.
Hence ferromagnetism in Ni is predicted below 11.1% vanadium. We find the vibrational frequencies of several clusters for
which the vanadium concentration is more than 11.1%. We are able to find a phase transition by use of quantum mechanics alone
without the use of classical mechanical variables or thermodynamic variables such as temperature. 相似文献
3.
The phosphides (Ni1 ? x Co x )2P (0 ≤ x ≤ 0.65) crystallizing in the hexagonal system, space group P \(\bar 6\)2m, were synthesized in two steps starting from the continuous solid solution (Ni1 ? x Co x )3(PO4)2 · 8H2O. The initial phosphates were first completely dehydrated at 800°C and then reduced with hydrogen at 900–1000°C for 1–2 h. 相似文献
4.
New solid electrolytes with a high conductivity by K+ ions in the K1 − 2x
Sr
x
GaO2 system are synthesized and studied. It is found that the introduction of Sr2+ ions into potassium monogallate leads to the formation of solid solutions with KGaO2 structure in a wide range of additive concentration. These solid solutions exhibit a high conductivity; the conductivity
increases monotonically with increasing concentration of strontium within the single-phase range. The electrical characteristics
are related to the electrolyte structure. The results are compared with the earlier data for the gallate solid electrolytes
with the additives of four-charged cations and the systems based on potassium monoferrite and monoaluminate. 相似文献
5.
M. I. Pantyukhina M. S. Shchelkanova S. V. Plaksin 《Russian Journal of Electrochemistry》2010,46(7):780-783
A boundary of existence of solid solutions in the Li8−2x
Mg
x
ZrO6 system is found to be 7 mol % MgO. The transport properties of Li8 − 2x
Mg
x
ZrO6 solid solutions (the electronic component of total conductivity, the temperature and concentration dependences of conductivity
and activation energy) are studied. It is supposed that, for Li8ZrO6 phase and solid solution based on it, an abrupt change of conductivity in the temperature range from 663 to 713 K is caused
by the transition of electrolyte into the superionic state. 相似文献
6.
Petra Šulcová Lucie Vitásková Miroslav Trojan 《Journal of Thermal Analysis and Calorimetry》2010,99(2):409-413
Compounds based on CeO2 were synthesized as high-temperature environment-friendly inorganic pigments with interesting hues. The pigments have been
synthesized by using the solid state reaction in the temperature range from 1,300 to 1,600 °C. The host lattice of these pigments
is CeO2 that is doped by terbium ions. The incorporation of doped ions provides interesting orange colours after application into
ceramic glaze. The goal was to develop conditions for the synthesis of these compounds and to determine the influence of calcination
temperature on their colouring effects. The simultaneous TG-DTA measurements were used for determination of the temperature
region of the pigment formation and thermal stability of pigments. The pigments were also evaluated from the standpoint of
their structure and particle sizes. 相似文献
7.
Solid electrolytes with potassium-cation conductivity in the K1 − 2x
Pb
x
GaO2 system were synthesized and studied. It was found that solid solutions based on potassium monogallate are formed in a wide
range of compositions. They contain vacancies in the potassium sublattice that provide for high conductivity of electrolytes.
The relationship is considered between electric characteristics of solid electrolytes and the composition and structure of
solid solutions. The results are compared to the earlier obtained data for similar solid electrolytes based on potassium monoaluminate
and monoferrite. 相似文献
8.
Conditions for the formation of single-phase compounds in the synthesis of solid solutions Bi4V2 − x
FexO11 − x
are studied. The sequence of phase transitions is determined. Parameters of unit cells of solid solutions are determined. The net conductance as a function of temperature and composition is studied.__________Translated from Elektrokhimiya, Vol. 41, No. 5, 2005, pp. 607–609.Original Russian Text Copyright © 2005 by Emel’yanova, Buyanova, Zhukovskii. 相似文献
9.
V. G. Ponomareva V. V. Martsinkevich Yu. A. Chesalov 《Russian Journal of Electrochemistry》2011,47(5):605-612
The transport and thermal properties of Cs1 − x
Rb
x
H2PO4 in a wide range of compositions were studied. The binary salts Cs1 − x
Rb
x
H2PO4 (x = 0–0.9) contain solid solutions with a structure of CsH2PO4. The binary salts were synthesized by mechanically mixing the starting components and growing crystals by isothermal evaporation
from aqueous solutions. The properties of Cs1 − x
Rb
x
H2PO4 salts obtained by different procedures were found to differ considerably. At higher rubidium contents in compounds obtained
by mechanical mixing, the superionic transition temperature rose insignificantly, the high-temperature phase conductivity
decreased twofold, the low-temperature conductivity increased within the limits of the order of magnitude, and the system
of hydrogen bonds was slightly weakened. In Cs1 − x
Rb
x
H2PO4 crystals grown from solutions, the temperature of the superionic transition decreased along with its slowing down, and the
low-temperature conductivity increased by more than three orders of magnitude because of the higher contents of residual acid
aqueous centers in the structure of the salt. These systems are characterized by increased thermal stability. 相似文献
10.
Zhang Lan Xin Chen Sheng Zhang Jihuai Wu 《Journal of Solid State Electrochemistry》2018,22(2):347-353
Three-dimensional TiO2 hierarchical nanostructures (3D-TiO2-HNs) containing TiO2 nanotrees and nest-like hollow spheres were synthesized and used as backbones for CdSe x S1?x quantum dot (QD) loading. These CdSe x S1?x QD-sensitized 3D-TiO2-HNs were then used as photoelectrodes in the preparation of quantum-dot-sensitized solar cells. As revealed by TEM images, the highly porous 3D-TiO2-HNs represent an excellent framework on which to deposit a large number of CdSe x S1?x QDs in order to form homogeneous and compact CdSe x S1?x -sensitized layers in photoelectrodes using a spin-assisted successive ionic layer adsorption and reaction method (spin-SILAR). Following careful adjustment of the molar ratio of Se2? to S2?, the number of spin-SILAR cycles, and the thickness of the CdS passivation layer used, the best-performing QDSC was shown to yield a short-circuit current density of 18.22 mA cm?2, an open-circuit voltage of 0.520 V, a fill factor of 0.510, and a power conversion efficiency of 4.83%. This high performance is possible because the device is able to absorb a relatively broad range of wavelengths and because charge recombination is suppressed in the device. 相似文献
11.
Nitrogen-doped titania was coupled with the commercial titania nanoparticles by mechanical milling in liquid medium. The as-prepared
nanocomposites (TiO2/TiO2−x
N
y
) were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) specific surface area, UV–Vis spectroscopy,
chemiluminescence, and acetaldehyde decomposition activity techniques. When a small amount of nitrogen-doped titania was added
into the commercial titania, higher intensity and longer lifetime of 1O2 was observed, and the photocatalytic activity was efficiently improved. The TiO2−x
N
y
acts as the acceptor of photoinduced holes. The recombination of the electron-hole was effectively depressed by the heterogeneous
electron transfer. This could be an effective way to obtain highly active photocatalysts. 相似文献
12.
Guanghua Li Ke Zhang Mohammed Adnan Mezaal Lixu Lei 《Journal of Solid State Electrochemistry》2016,20(2):421-427
La1-x Sr x MnO3 (x?=?0.1~0.4) catalysts for primary and rechargeable zinc-air batteries have been successfully synthesized by the citrate method and their electrochemical properties measured. The materials can catalyze both ORR and OER, and the one with ideal composition of La0.8Sr0.2MnO3 catalyst exhibits the highest catalytic activity and durability in alkaline medium. The resulting primary zinc-air cell shows a peak power density of 146 mW cm?2 at 235 mA cm?2. The secondary cell exhibits a charge-discharge voltage gap of 1.0 V at 10 mA cm?2, which is highly stable over many charge-discharge cycles. 相似文献
13.
The sol-gel method was used to prepare Y1–xBaxFeO3 (x = 0, 0.05, 0.1, 0.15, 0.2) nanocrystals. The influence of the dopant content on the particle size and magnetic properties of yttrium ferrite was examined. 相似文献
14.
A. S. Shkvarin Yu. M. Yarmoshenko N. A. Skorikov A. I. Merentsov A. N. Titov 《Journal of Structural Chemistry》2011,52(1):70-75
Solid solutions of 1T-Cr x Ti1?x Se2 (x = 0?0.83) were synthesized for the first time. To study the electronic structure of Cr x Ti1?x Se2 monocrystals, photoemission spectra of core levels, resonance spectra of valence bands, and absorption spectra of Ti and Cr were obtained. Titanium and chromium atoms were found to have the oxidation state 4+ and 3+, which is supported by atomic multiplet calculations for Ti and Cr in the octahedral environment. According to calculation of the local density of chromium electronic states, the Cr3d electrons are spin-polarized, and the density of chromium states is of half-metal nature. The calculation agrees well with the experimental data. 相似文献
15.
16.
The homogeneous substitution of cations (K+) and anions (H2PO4−) for CsHSO4 is performed. The dependences of protonic conductivity and structure of (1 − x)CsHSO4-xKH2PO4 (x = 0.05–0.9) compounds on the composition are studied. It is found that the introduction of KH2PO4 leads to the formation of a new highly conductive phase. At small amounts of introduced KH2PO4 (x = 0.05), a mixed salt forms; its low-temperature conductivity is by more than two orders of magnitude higher than that of
the source salts. The thermal behavior of mixed salt (1 − x)CsHSO4-xKH2PO4 of various compositions and the peculiarities of crystal structure are studied. The structural parameters of the salt at
x = 0.05–0.5 are close to those of Cs3(HSO4)2(H2PO4). At higher x, another phase forms, whose structure has yet to be determined. The thermal stability of the salt decreases with increasing
fraction of KH2PO4 introduced. The conductivity of the composites based on the mixed salt and silicon dioxide (1 − y){xKH2PO4-(1 − x)CsHSO4}-ySiO2 (x = 0.05, 0.1; y = 0.1–0.7) is studied. It is shown that, in the low-temperature range, the conductivity of composite systems increases within
an order of magnitude, passes through a maximum, and, then, decreases at y > 0.5 due to the percolation effect. 相似文献
17.
A novel electrode material, Zn2Sn1 − x
Ti
x
O4 (x = 0 and 0.1), which is superior in its electrochemical characteristics to the reverse spinel Zn2SnO4, is synthesized by hydrothermal method. The admixture of TiO2 levels out the volume expanding caused by the Li-Sn and Li-Zn alloy formation thus improving the material’s cyclability. 相似文献
18.
Z. F. Tomashik R. A. Denisyuk V. N. Tomashik A. S. Chernyuk I. M. Rarenko 《Russian Journal of Inorganic Chemistry》2009,54(6):881-884
Chemical etching of Cd1 ? x Mn x Te (0.04 < x < 0.5) solid solution (ss) single crystals in I2 + CH3OH etching mixtures was studied. Concentration and kinetic curves of etching rates were plotted. As the manganese concentration of the solid solution increases, the rates of their etching by iodine-methanol etchants increase, too. The etchant compositions and chemical-dynamic polishing protocols for Cd1 ? x Mn x Te single crystals were optimized. 相似文献
19.
Mixed SiGe:H nanocrystals have been studied within the framework of Density Functional Theory. (DFT) using the hybrid non-local
exchange-correlation functional of Becke, Lee, Parr and Yang (B3LYP). In addition to ground-state DFT/B3LYP calculations,
excited-state calculations for the determination of the optical absorption spectrum have been performed employing the time-dependent
density functional theory (TDDFT). In order to fully investigate the substitution of Si by Ge, on structural, cohesive, electronic
and optical properties, we have used the Si
x
Ge47−x
:H nanocrystal, as a representative medium size nanosystem. Our results show that the optical gap depends not only on the
relative concentrations of silicon, germanium and hydrogen, but also on the relative position of the silicon and germanium
shells relative to the surface of the nanocrystal. This is also true for the structural, cohesive and electronic properties.
This dependence allows for the possibility of electronic and optical gap engineering. 相似文献
20.
Chengbin Jing Haiyang Shan Chuanjian Zhang Xiaodan Zang Wei Bai Junhao Chu 《Journal of Sol-Gel Science and Technology》2009,51(2):139-145
The solids content and gelation time of aqueous germanate solution were examined in this work. Samples of 5, 10 and 20 mol%
Mn doped Ge were prepared by using the aqueous germanate solution as a liquid Ge precursor. No second phase such as Mn5Ge3 was detected in the 5 and 10 mol% Mn doped samples, implying that Mn ions were uniformly diluted into the Ge host matrix.
The 5 and 10 mol% Mn-doped Ge samples exhibit room-temperature ferromagnetic behaviors that are likely originated from the
RKKY (Ruderman–Kittel–Kasuya–Yosida)-like interaction between the localized Mn ions in the Ge matrix. Therefore, the aqueous
germanate solution can be an alternative sol–gel precursor for preparation of the Mn
x
Ge1−x
diluted magnetic semiconductors (DMSs). 相似文献