Immiscible Displacement in the Interacting Capillary Bundle Model Part I. Development of Interacting Capillary Bundle Model

An interacting capillary bundle model is developed for analysing immiscible displacement processes in porous media. In this model, pressure equilibration among the capillaries is stipulated and capillary forces are included. This feature makes the model entirely different from the traditional tube bundle models in which fluids in different capillaries are independent of each other. In this work, displacements of a non-wetting phase by a wetting phase at different injection rates were analysed using the interacting capillary bundle model. The predicted evolutions of saturation profiles were consistent with both numerical simulation and experimental results for porous media reported in literature which cannot be re-produced with the non-interacting tube bundle models.     

Fluid transfer between tubes in interacting capillary bundle models

The interacting capillary bundle model proposed by Dong et al. [Dong, M., Dullien, F.A.L., Zhou, J.: Trans. Porous Media 31, 213–237 (1998); Dong, M., Dullien, F.A.L., Dai, L., Li, D.: Trans. Porous Media 59, 1–18 (2005); Dong, M., Dullien, F.A.L., Dai, L., Li, D.: Trans. Porous Media 63, 289–304 (2006)] has simulated correctly various aspects of immiscible displacement in porous media, such as oil production histories at different viscosity ratios, the effects of water injection rate and of the oil–water viscosity ratio on the shape of the displacement front and the independence of relative permeabilities of the viscosity ratio. In the interacting capillary bundle model pressure equilibrium was assumed at any distance x measured along the bundle. Interaction between the capillaries also results in transfer of fluids across the capillaries. In the first part of this paper the process of fluid transfer between two capillaries is analysed and an algebraic expression for this flow is derived. Consistency with the assumption of pressure equilibration requires that all transfer must take place at the positions of the oil/water menisci in the tubes without any pressure drop. It is shown that fluid transfer between the tubes has no effect on the predictions obtained with the model. In the second part of the paper the interacting tube bundle model is made more realistic by assuming fluid transfer between the tubes all along the single phase flow regions across a uniform resistance, resulting in pressure differences throughout the single phase regions between the fluids present in the different tubes. The results of numerical simulations obtained with this improved interacting capillary bundle model show only small differences in the positions of the displacement front as compared with the predictions of the idealized model.     

Relative Permeability Analysis of Tube Bundle Models,Including Capillary Pressure

The analytical equations for calculating two-phase flow, including local capillary pressures, are developed for the bundle of parallel capillary tubes model. The flow equations that are derived were used to calculate dynamic immiscible displacements of oil by water under the constraint of a constant overall pressure drop across the tube bundle. Expressions for averaged fluid pressure gradients and total flow rates are developed, and relative permeabilities are calculated directly from the two-phase form of Darcy's law. The effects of pressure drop and viscosity ratio on the relative permeabilities are discussed. Capillary pressure as a function of water saturation was delineated for several cases and compared to a steady-state mercury-injection drainage type of capillary pressure profile. The bundle of serial tubes model (a model containing tubes whose diameters change randomly at periodic intervals along the direction of flow), including local Young-Laplace capillary pressures, was analyzed with respect to obtaining relative permeabilities and macroscopic capillary pressures. Relative permeabilities for the bundle of parallel tubes model were seen to be significantly affected by altering the overall pressure drop and the viscosity ratio; relative permeabilities for the bundle of serial tubes were seen to be relatively insensitive to viscosity ratio and pressure, and were consistently X-like in profile. This work also considers the standard Leverett (1941) type of capillary pressure versus saturation profile, where drainage of a wetting phase is completed in a step-wise steady fashion; it was delineated for both tube bundle models. Although the expected increase in capillary pressure at low wetting-phase saturation was produced, comparison of the primary-drainage capillary pressure curves with the pseudo-capillary pressure profiles, that are computed directly using the averaged pressures during the displacements, revealed inconsistencies between the two definitions of capillary pressure.     

A Semi-Analytical Model for Two Phase Immiscible Flow in Porous Media Honouring Capillary Pressure

This article describes a semi-analytical model for two-phase immiscible flow in porous media. The model incorporates the effect of capillary pressure gradient on fluid displacement. It also includes a correction to the capillarity-free Buckley–Leverett saturation profile for the stabilized-zone around the displacement front and the end-effects near the core outlet. The model is valid for both drainage and imbibition oil–water displacements in porous media with different wettability conditions. A stepwise procedure is presented to derive relative permeabilities from coreflood displacements using the proposed semi-analytical model. The procedure can be utilized for both before and after breakthrough data and hence is capable to generate a continuous relative permeability curve unlike other analytical/semi-analytical approaches. The model predictions are compared with numerical simulations and laboratory experiments. The comparison shows that the model predictions for drainage process agree well with the numerical simulations for different capillary numbers, whereas there is mismatch between the relative permeability derived using the Johnson–Bossler–Naumann (JBN) method and the simulations. The coreflood experiments carried out on a Berea sandstone core suggest that the proposed model works better than the JBN method for a drainage process in strongly wet rocks. Both methods give similar results for imbibition processes.     

Relative Permeability Analysis of Tube Bundle Models

The analytical solution for calculating two-phase immiscible flow through a bundle of parallel capillary tubes of uniform diametral probability distribution is developed and employed to calculate the relative permeabilities of both phases. Also, expressions for calculating two-phase flow through bundles of serial tubes (tubes in which the diameter varies along the direction of flow) are obtained and utilized to study relative permeability characteristics using a lognormal tube diameter distribution. The effect of viscosity ratio on conventional relative permeability was investigated and it was found to have a significant effect for both the parallel and serial tube models. General agreement was observed between trends of relative permeability ratios found in this work and those from experimental results of Singhal et al. (1976) using porous media consisting of mixtures of Teflon powder and glass beads. It was concluded that neglecting the difference between the average pressure of the non-wetting phase and the average pressure of the wetting phase (the macro-scale capillary pressure) – a necessary assumption underlying the popular analysis methods of Johnson et al. (1959) and Jones and Roszelle (1978) – was responsible for the disparity in the relative permeability curves for various viscosity ratios. The methods therefore do not account for non-local viscous effects when applied to tube bundle models. It was contended that average pressure differences between two immiscible phases can arise from either capillary interfaces (micro-scale capillary pressures) or due to disparate pressure gradients that are maintained for a flow of two fluids of viscosity ratio that is different from unity.     

A Parametric Model for Predicting Relative Permeability-Saturation-Capillary Pressure Relationships of Oil–Water Systems in Porous Media with Mixed Wettability

A parametric two-phase, oil–water relative permeability/capillary pressure model for petroleum engineering and environmental applications is developed for porous media in which the smaller pores are strongly water-wet and the larger pores tend to be intermediate- or oil-wet. A saturation index, which can vary from 0 to 1, is used to distinguish those pores that are strongly water-wet from those that have intermediate- or oil-wet characteristics. The capillary pressure submodel is capable of describing main-drainage and hysteretic saturation-path saturations for positive and negative oil–water capillary pressures. At high oil–water capillary pressures, an asymptote is approached as the water saturation approaches the residual water saturation. At low oil–water capillary pressures (i.e. negative), another asymptote is approached as the oil saturation approaches the residual oil saturation. Hysteresis in capillary pressure relations, including water entrapment, is modeled. Relative permeabilities are predicted using parameters that describe main-drainage capillary pressure relations and accounting for how water and oil are distributed throughout the pore spaces of a porous medium with mixed wettability. The capillary pressure submodel is tested against published experimental data, and an example of how to use the relative permeability/capillary pressure model for a hypothetical saturation-path scenario involving several imbibition and drainage paths is given. Features of the model are also explained. Results suggest that the proposed model is capable of predicting relative permeability/capillary pressure characteristics of porous media mixed wettability.     

A Non-isothermal Pore Network Drying Model with Gravity Effect

The concept of immiscible displacement as an invasion percolation (IP) process driven by heat and mass transfer is used in a pore network model for convective drying of capillary porous media. The coupling between heat and mass transfer occurs at the liquid–gas interface through temperature-dependent equilibrium vapor pressure and surface tension as well as the phase change enthalpy (in evaporation and condensation). The interfacial effects due to capillary forces and gravity are combined in an invasion potential; viscous forces are neglected. Simulation results show stabilized invasion patterns and finite drying front width by the influence of gravity.     

Enhancing Immiscible Fluid Displacement in Porous Media by Capillary Pressure Discontinuities

Fluid displacement in porous media plays an important role in many industrial applications, including biological filtration, carbon capture and storage, enhanced oil recovery, and fluid transport in fuel cells. The displacement front is unstable, which evolves from smooth into ramified patterns, when the mobility (ratio of permeability to viscosity) of the displacing fluid is larger than that of the displaced one; this phenomenon is called viscous fingering. Viscous fingering increases the residual saturation of the displaced fluid, considerably impairing the efficacy of fluid displacement. It is of practical importance to develop suitable methods to improve fluid displacement. This paper presents an experimental study on applying the discontinuity of capillary pressure to improve immiscible fluid displacement in drainage for which the displacing fluid (air) wets the porous media less preferentially than does the displaced fluid (silicone oil). The concept involves using a heterogeneous packing system, where the upstream region features large pores and small capillary pressure, and the downstream region features small pores and large capillary pressure. The increase in capillary pressure prevents fingering from directly crossing the media interface, thus enhancing the displacement. The experimental apparatus was a linear cell comprising porous media between two parallel plates, and glass beads of 0.6 and 0.125 mm diameter were packed to compose the heterogeneous porous media. The time history of the finger flow was recorded using a video camera. Pressure drops over the model from the inlet to the outlet were measured to compare viscous pressure drops with capillary pressures. The results show that the fluid displacement was increased by the capillary discontinuities. The optimal displacement was determined through linear regression by adjusting the relative length of the large- and small-pore region. The results may assist in the understanding of fingering flow across the boundaries of different grain-sized bands for the gas and oil reservoir management, such as setting the relative location of the injection and production wells. The findings may also serve as a reference for industrial applications such as placing the grain bands in an adequate series to improve the displacement efficacy in biological filtration.     

Oil Displacement for One-Dimensional Three-Phase Flow with Phase Change in Fractured Media

In this article, the numerical simulations for one-dimensional three-phase flows in fractured porous media are implemented. The simulation results show that oil displacement in matrix is dominated by oil–water capillary pressure only under certain conditions. When conditions are changed to decrease the amount of water entering into the fractured media from the boundary of the flow field, water in fracture may be vaporized to superheated steam. In these cases, the appearance of superheated steam in fracture rather than in matrix will decrease the fracture pressure and generate the pressure difference between matrix and fracture, which results in oil flowing from matrix to fracture. Assuming that oil is wetting to steam, the matrix steam–oil capillary pressure will decrease the matrix oil-phase pressure as the matrix steam saturation increases. After the steam–oil capillary pressure finally exceeds the pressure difference due to the appearance of superheated steam in fracture, the oil displacement in matrix will stop. It is also shown that variations of the water relative permeability curve in matrix do not result in different mechanisms for oil displacement in matrix. The simulation results suggest that the amount of liquid water supply from the boundary of flow field fundamentally influence the mechanisms for oil displacement in matrix.     

Analysis of capillary interaction and oil recovery under ultrasonic waves

Although, the effects of ultrasonic irradiation on multiphase flow through porous media have been studied in the past few decades, the physics of the acoustic interaction between fluid and rock is not yet well understood. Various mechanisms may be responsible for enhancing the flow of oil through porous media in the presence of an acoustic field. Capillary related mechanisms are peristaltic transport due to mechanical deformation of the pore walls, reduction of capillary forces due to the destruction of surface films generated across pore boundaries, coalescence of oil drops due to Bjerknes forces, oscillation and excitation of capillary trapped oil drops, forces generated by cavitating bubbles, and sonocapillary effects. Insight into the physical principles governing the mobilization of oil by ultrasonic waves is vital for developing and implementing novel techniques of oil extraction. This paper aims at identifying and analyzing the influence of high-frequency, high-intensity ultrasonic radiation on capillary imbibition. Laboratory experiments were performed using cylindrical Berea sandstone and Indiana limestone samples with all sides (quasi-co-current imbibition), and only one side (counter-current imbibition) contacting with the aqueous phase. The oil saturated cores were placed in an ultrasonic bath, and brought into contact with the aqueous phase. The recovery rate due to capillary imbibition was monitored against time. Air–water, mineral oil–brine, mineral oil–surfactant solution and mineral oil-polymer solution experiments were run each exploring a separate physical process governing acoustic stimulation. Water–air imbibition tests isolate the effect of ultrasound on wettability, capillarity and density, while oil–brine imbibition experiments help outline the ultrasonic effect on viscosity and interfacial interaction between oil, rock and aqueous phase. We find that ultrasonic irradiation enhances capillary imbibition recovery of oil for various fluid pairs, and that such process is dependent on the interfacial tension and density of the fluids. Although more evidence is needed, some runs hint that wettability was not altered substantially under ultrasound. Preliminary analysis of the imbibition recoveries also suggests that ultrasound enhances surfactant solubility and reduce surfactant adsorption onto the rock matrix. Additionally, counter-current experiments involving kerosene and brine in epoxy coated Berea sandstone showed a dramatic decline in recovery. Therefore, the effectiveness of any ultrasonic application may strongly depend on the nature of interaction type, i.e., co- or counter-current flow. A modified form of an exponential model was employed to fit the recovery curves in an attempt to quantify the factors causing the incremental recovery by ultrasonic waves for different fluid pairs and rock types.     

Fractal Prediction Model of Spontaneous Imbibition Rate

By utilizing fractal dimension as one of the parameters to characterize rocks, a mathematical model was derived to predict the production rate by spontaneous imbibition. This fractal production model predicts a power law relationship between spontaneous imbibition rate and time. Fractal dimension can be estimated from the fractal production model using the experimental data of spontaneous imbibition in porous media. The experimental data of recovery in gas-water-rock and oil–water–rock systems were used to test the fractal production model. The rocks (Berea sandstone, chalk, and The Geysers graywacke) in which the spontaneous water imbibition experiments were conducted had different permeabilities ranging from 0.5 to over 1000 md. The results demonstrate that the fractal production model can match the experimental data satisfactorily in the cases studied. The fractal dimension data inferred from the model match were approximately equal to the values of fractal dimension measured using a different technique (mercury-intrusion capillary pressure) in Berea sandstone.     

Experiment and Capillary Bundle Network Model of Micro Polymer Particles Propagation in Porous Media

In this paper, a microscopic visualization experiment is conducted to explore the heterogeneous flow pattern of micro polymer particles in micron pore. A capillary bundle network model for micro polymer particles in porous media is established. The migration and retention mechanism of polymer particles can be clearly observed in the experiment and simulated with this numerical model. The result demonstrates that the block of large particles is one of the main factors by which micro polymer particles increase the flow resistance. The simulation results are consistent with the experimental results.     

A Multi-Scale Approach to Model Two-Phase Flow in Heterogeneous Porous Media

The immiscible displacement of a wetting fluid by a non-wetting one in heterogeneous porous media is modeled using a multi-scale network-type analysis: (1) The pressure-controlled immiscible displacement of water by oil in pore-and-throat networks (1st length scale ~ 1?mm) is simulated as a capillary-driven process. (2) The pressure-controlled immiscible displacement in uncorrelated cubic lattices (2nd length scale ~ 1?cm) is simulated as a site percolation process governed by capillary and gravity forces. At this scale, each node represents a network of the previous scale. (3) The rate-controlled immiscible displacement of water by oil in cubic networks (3rd length scale ~ 10?cm), where each node represents a lattice of the previous scale, is simulated by accounting for capillary, gravity, and viscous forces. The multi-scale approach along with the information concerning the pore structure properties of the porous medium can be employed to determine the transient responses of the pressure drop and axial distribution of water saturation, and estimate the effective (up-scaled) relative permeability functions. The method is demonstrated with application to data of highly heterogeneous soils.     

Numerical study of non-uniqueness of the factors influencing relative permeability in heterogeneous porous media by lattice Boltzmann method

The effects of capillary number Ca and viscosity ratio M on non-uniqueness of the relative permeability (RP) – wetting saturation (S_w) relationships of steady-state immiscible two-phase flow in the heterogeneous porous media are studied by a developed lattice Boltzmann method (LBM). In this work, it is suggested that the non-uniqueness of capillary number Ca and viscosity ratio M influencing RP–S_w curves is due to the presence of the heterogeneity of porous media. For the different Ca and M, the RP–S_w curves in the homogenous and heterogeneous porous media with the same porosity are discussed in detail. It is found that (1) the pore-size distributions in porous media have significant effect on the RPs of both wetting phase (WP) and non-wetting phase (NWP); (2) the heterogeneity of porous media has negative effect on the increment of the RP of NWP caused by the large capillary number. The lubricating effect is strongly dependent on pore-size distributions in porous media; and (3) the large viscosity ratio increases the RP of NWP, while it has little effect on the RP of WP. The effect on the RP of NWP may be magnified by the heterogeneity of porous media.     

Efficiency of Capillary Imbibition Dominated Displacement of Nonwetting Phase by Wetting Phase in Fractured Porous Media

The critical and optimum injection rates as well as the critical fracture capillary number for an efficient displacement process are determined based on the experimental and numerical modeling of the displacement of nonwetting phase (oil) by wetting phase (water) in fractured porous media. The efficiency of the process is defined in terms of the nonwetting phase displaced from the system per amount of wetting phase injected and per time. Also, the effects of injection rate on capillary imbibition transfer dominated two-phase flow in fractured porous media are clarified by visualizing the experiments. The results reveal that as the injection rate is increased, fracture pattern begins to become an effective parameter on the matrix saturation distribution. As the rate is lowered, however, the system begins to behave like a homogeneous system showing a frontal displacement regardless the fracture configuration.     

A Discussion of the Effect of Tortuosity on the Capillary Imbibition in Porous Media

In the past decades, there was considerable controversy over the Lucas–Washburn (LW) equation widely applied in capillary imbibition kinetics. Many experimental results showed that the time exponent of the LW equation is less than 0.5. Based on the tortuous capillary model and fractal geometry, the effect of tortuosity on the capillary imbibition in wetting porous media is discussed in this article. The average height growth of wetting liquid in porous media driven by capillary force following the [`(L)] _s(t) ~ t^1/2D_T{\overline L _{\rm {s}}(t)\sim t^{1/{2D_{\rm {T}}}}} law is obtained (here D _T is the fractal dimension for tortuosity, which represents the heterogeneity of flow in porous media). The LW law turns out to be the special case when the straight capillary tube (D _T = 1) is assumed. The predictions by the present model for the time exponent for capillary imbibition in porous media are compared with available experimental data, and the present model can reproduce approximately the global trend of variation of the time exponent with porosity changing.     

Analytical Model for The Capillary Pressure Gradient in Oil–Water–Rock System

A simplified analytical expression for the capillary pressure gradient in homogeneous porous media is proposed. Basic assumptions are: (1) the three phase contact angle between two fluids and porous rock is finite, (2) the surface area of contact between two fluids is small in comparison with contact surface areas between each fluid and porous rock in the unit volume of the system under consideration, (3) the model corresponds to conditions when both phases are continuous.     

LBM Simulation of Viscous Fingering Phenomenon in Immiscible Displacement of Two Fluids in Porous Media

This article presents the lattice Boltzmann simulation of viscous fingering phenomenon in immiscible displacement of two fluids in porous media. Such phenomenon generally takes place when a less viscous fluid is used to displace a more viscous fluid, and it can be found in many industrial fields. Dimensionless quantities, such as capillary number, Bond number and viscosity ratio between displaced fluid and displacing fluid are introduced to illustrate the effects of capillary force, viscous force, and gravity on the fluid behaviour. The surface wettability, which has an impact on the finger pattern, is also considered in the simulation. The numerical procedure is validated against the experiment about viscous fingering in a Hele-Shaw cell. The displacement efficiency is investigated using the parameter, areal sweep efficiency. The present simulation shows an additional evidence to demonstrate that the lattice Boltzmann method is a useful method for simulating some multiphase flow problems in porous media.     

Two-Phase Flow in Porous Media: Predicting Its Dependence on Capillary Number and Viscosity Ratio

Motivated by the need to determine the dependencies of two-phase flow in a wide range of applications from carbon dioxide sequestration to enhanced oil recovery, we have developed a standard two-dimensional, pore-level model of immiscible drainage, incorporating viscous and capillary effects. This model has been validated through comparison with several experiments. For a range of stable viscosity ratios (M = μ _injected,nwf/μ _{defending, wf} ≥ 1), we had increased the capillary number, N _c and studied the way in which the flows deviate from fractal capillary fingering at a characteristic time and become compact for realistic capillary numbers. This crossover has enabled predictions for the dependence of the flow behavior upon capillary number and viscosity ratio. Our results for the crossover agreed with earlier theoretical predictions, including the universality of the leading power-law indicating its independence of details of the porous medium structure. In this article, we have observed a similar crossover from initial fractal viscous fingering (FVF) to compact flow, for large capillary numbers and unstable viscosity ratios M < 1. In this case, we increased the viscosity ratio from infinitesimal values, and studied the way in which the flows deviate from FVF at a characteristic time and become compact for non-zero viscosity ratios. This crossover has been studied using both our pore-level model and micro-fluidic flow-cell experiments. The same characteristic time, τ = 1/M ^0.7, satisfactorily describes both the pore-level results for a range of large capillary numbers and the micro-fluidic flow cell results. This crossover should lead to predictions similar to those mentioned above.     

Phenomenological Meniscus Model for Two-Phase Flows in Porous Media

A new macroscale model of a two-phase flow in porous media is suggested. It takes into consideration a typical configuration of phase distribution within pores in the form of a repetitive field of mobile menisci. These phase interfaces give rise to the appearance of a new term in the momentum balance equation, which describes a vectorial field of capillary forces. To derive the model, a phenomenological approach is developed, based on introducing a special continuum called the Meniscus-continuum. Its properties, such as a unique flow velocity, an averaged viscosity, a compensation mechanism and a duplication mechanism, are derived from a microscale analysis. The closure relations to the phenomenological model are obtained from a theoretical model of stochastic meniscus stream and from numerical simulations based on network models of porous media. The obtained transport equation remains hyperbolic even if the capillary forces are dominated, in contrast to the classic model which is parabolic. For the case of one space dimension, the analytical solutions are obtained, which manifest non-classical effects as double displacement fronts or counter-current fronts.