The K * Kπ and ρππ couplings in QCD

The light cone QCD sum rules are derived for the K ^* Kπ coupling g _K ^* Kπ and the ρππ coupling g _ρππ. The contribution from the excited states and the continuum is subtracted cleanly through the double Borel transform with respect to the two external momenta, p ₁ ², p ₂ ²= (p−q)². Our result g _K ^* Kπ= (8.7 ± 0.5) and g _ρππ= (11.5 ± 0.8) is in good agreement with the experimental value. Received: 31 July 1998 / Revised version: 20 November 1998     

Electronic excitation and singlet-triplet coupling in uracil tautomers and uracil-water complexes

Electronic spectra of uracil in its diketo (lactam) form and five enol (lactim) tautomeric forms have been investigated by means of combined density functional and configuration interaction methods. We have simulated the effects of hydrogen bonding with a protic solvent by recomputing the spectrum of uracil in the presence of two, four, or six water molecules. Geometries of the electronic ground state and several low-lying excited states have been optimized. Spin-orbit coupling has been determined for correlated wavefunctions employing a non-empirical spin-orbit mean-field approach. In accord with experiment, we find the diketo tautomer to be the most stable one. The calculations confirm that the first absorption band arises from the ¹( π↦π^*) S ₀↦S ₂ excitation. The experimentally observed vibrational structure in this band originates from a breathing mode of the six ring. Complexation with water molecules is seen to cause a significant blue shift of n↦π^* excitations while leaving π↦π^* excitations nearly uninfluenced. Computed radiative lifetimes are presented for the experimentally known weak phosphorescence from the π↦π^* excited T₁ state. Among the uracil lactim tautomers, one is particularly interesting from a spectroscopic point of view. In this tautomer, the π↦π^* excitation gives rise to the S₁ state. Received 18 February 2002 / Received in final form 5 June 2002 Published online 13 September 2002     

Azobenzene-functionalized alkanethiols in self-assembled monolayers on gold

Self-assembled monolayers (SAMs) of 4-trifluoromethyl-azobenzene-4′-methyleneoxy-alkanethiols (CF₃– C₆H₄–N=N–C₆H₄–O–(CH₂) _n –SH on (111)-oriented poly-crystalline gold films on mica were examined by X-ray photoelectron spectroscopy (XPS) and X-ray absorption spectroscopy (XAS). The spectra are analyzed with the help of density-functional-theory calculations of the isolated molecule. Only one doublet is detected in the sulphur 2p spectra of the investigated SAMs, consistent with a thiolate bond of the molecule to the gold surface. The C 1s XP spectra and the corresponding XAS π ^* resonance exhibit a rich structure which is assigned to the carbon atoms in the different chemical surroundings. Comparing XPS binding energies of the azobenzene moiety and calculated initial-state shifts reveals comparable screening of all C 1s core holes. While the carbon 1s XPS binding energy lies below the π ^*-resonance excitation-energy, the reversed order is found comparing core ionization and neutral core excitation of the nitrogen 1s core-hole of the azo group. This surprising difference in core-hole binding energies is interpreted as site-dependent polarization screening and charge transfer among the densely packed aromatic moieties. We propose that a quenching of the optical excitation within the molecular layer is thus one major reason for the low trans to cis photo-isomerization rate of azobenzene in aromatic-aliphatic SAMs.     

X-ray photoelectron spectroscopy and near-edge X-ray-absorption fine structure of C60 polymer films

We report core-level and valence-band X-ray photoelectron spectroscopy (XPS) and carbon [ _]K near-edge X-ray-absorptionfine structure spectroscopy (NEXAFS) results of plasma-polymerized C₆₀. In comparison with evaporated C₆₀ the C 1s peak is broader and asymmetric for the C₆₀ polymer and its shake-up satellites diminished. Furthermore, the features of the valence-band as well as the features of the π^* antibonding orbitals of the C₆₀ polymer are broader and reduced in intensity. Changes in the electronic structure are attributed to the polymerization of C₆₀, the post-plasma functionalization of the surface by oxygen after exposure to atmosphere, and the occurrence of amorphous carbon. Received: 28 May 1999 / Accepted: 31 August 1999 / Published online: 8 March 2000     

Understanding the newly observed Y(4008) by Belle

Very recently a new enhancement around 4.05 GeV was observed by the Belle experiment. We discuss some possible assignments for this enhancement, i.e. the ψ(3S) and D^*D̄^* molecular states. In these two assignments, Y(4008) can decay into J/ψπ⁰π⁰ with a branching ratio comparable with that of Y(4008)→J/ψπ⁺π^-. Thus, one suggests high energy experimentalists to look for Y(4008) in J/ψπ⁰π⁰ channel. Furthermore one proposes further experiments to search for the missing channels DD̄, DD̄^*+h.c. and especially χ_cJπ⁺π^-π⁰ and η_cπ⁺π^-π⁰, which will be helpful to distinguish the ψ(3S) and D^*D̄^* molecular state assignments for this new enhancement. PACS 13.30.Eg 13.75.Lb     

Study of N*(1440) from J/Ψ decays

For J/Ψ↦ pπ⁰ and pπ⁺π^-, the π⁰ p and pπ⁺π^- systems are limited to be pure isospin-(1/2) due to isospin conservation. This is a big advantage in studying N^* resonances from J/Ψ decays, compared with πN and γN experiments. The process J/Ψ↦ N ^* or p provides a new way to probe the internal structure of the N^* resonances. Here we report a quark model calculation for J/Ψ↦ p, N ^*(1440) and N ^*. The implication for the internal structure of N ^*(1440) is discussed. Received: 1 June 2001 / Accepted: 20 June 2001     

The search for and study of the strange multibaryon states in systems with Λ-hyperon and Ks0 -meson in pA collision at momentum of 10 GeV/c

Exotic strange multibaryon states have been observed in the effective mass spectra of: Λπ^±, Λπ⁺π⁻, Λp, Λpp, Λπp, ΛΛ and ΛK _s ⁰, K _s ⁰ p, K _s ⁰π^± subsystems. The measured Λ/π⁺ ratio for average multiplicities from the pC reaction is equal to (5.3 ± 0.8) × 10⁻², and it is approximately two times larger than the Λ/π⁺ ratio simulated by the FRITIOF model and than that of experimental pp reactions at the same energy. The observed wellknown resonances Σ*⁺ (1385) and K*^± (892) from PDG are good tests of this method. The mean value of the mass for the Σ*⁻(1385) resonance is shifted to 1370 MeV/c ² and the width is two times larger than the same value from PDG. Such kind of behavior for the width and invariant mass of Σ*⁻ (1385) resonance is interpreted as an extensive contribution from stopped Ξ⁻ → Λπ⁻ and medium effect. There is enhancement of the production contribution for all observed hyperons. A few events were registered by hypothesis of light H ⁰ and heavy H ^{0, +} dihyperons. Dihyperons were observed by weak decay channels: (Σ⁻ p), (Λpπ⁻), (Λpπ⁰), and (K ⁻ pp). The text was submitted by the author in English.     

Determination of electron affinity of electron accepting molecules

The unoccupied π ^* states of the solid film of electron accepting organic molecules, 7,7,8,8-tetracyanoquinodimethane (TCNQ), fluorinated TCNQ derivatives, 11,11,12,12-tetracyanonaphtho-2,6-quinodimethane (TNAP), C₆₀, and 6,6-phenyl-C₆₁-butyric acid methyl ester (PCBM) have been studied by inverse photoemission spectroscopy. The assignment of the π ^* affinity levels of these typical electron accepting molecules provides the basic information for the organic electronics and the new electronic functional molecular design. The comparison with density functional theory calculations enables understanding how the electron affinity evolves in terms of molecular orbitals. The correlation between the film morphology and the irradiation damage on the TCNQ derivative samples by electron impact during the inverse photoemission measurements is also discussed.     

On the mechanism of nonradiative decay of DNA bases: ab initio and TDDFT results for the excited states of 9H-adenine

Minimum-energy reaction paths and corresponding potential-energy profiles have been computed for the lowest excited states of the amino form of 9H-adenine. Complete-active- space self-consistent-field (CASSCF) and density functional theory (DFT) methods have been employed. The potential-energy function of the lowest ¹πσ^* state, nominally a 3s Rydberg state, is found to be dissociative with respect to the stretching of the NH bond length of the azine group. The ¹πσ^* potential-energy function intersects not only those of the ¹ππ^* and ¹ nπ^* excited states, but also that of the electronic ground state. The ¹ππ^*- ¹πσ^* and ¹πσ^*-S₀ intersections are converted into conical intersections when the out-of-plane motion of the active hydrogen atom is taken into account. It is argued that the predissociation of the ¹ππ^* and ¹ nπ^* states by the ¹πσ^* state and the conical intersection of the ¹πσ^* state with the S₀ state provide the mechanism for the ultrafast radiationless deactivation of the excited singlet states of adenine.     

On the direct formation of HO2 radicals after 248 nm irradiation of benzene C6H6 in the presence of O2

We present in this work the direct observation of HO₂ radicals after irradiation of benzene C₆H₆ at 248 nm in the presence of O₂. HO₂ radicals have been unambiguously identified using the very selective and sensitive detection of continuous wave cavity ring-down spectroscopy (cw-CRDS) coupled to a laser photolysis reactor. HO₂ radicals were detected in the first vibrational overtone of the OH stretch at 6638.20 cm^-1, using a DFB diode laser. This reaction might be important because 248 nm photolysis of H₂O₂ has often been used in the past for studying the OH^•-initiated degradation of C₆H₆, often using a large excess of C₆H₆ over H₂O₂. The possible importance of the title reaction with respect to these former laboratory studies has been quantified through comparison with HO₂ ^• signals obtained from 248 nm photolysis of H₂O₂: one obtains under our conditions (excess O₂ and total pressure of 6.6 kPa helium) from the 248 nm irradiation of identical initial concentrations [C₆H₆]=[H₂O₂] the following relative initial radical concentrations: [HO₂ ^•]=(0.28±0.05)×[OH^•]. Experiments with various O₂ concentrations have revealed that the origin of the HO₂ radicals is not the reaction of H-atoms with O₂, but must originate from the reaction of O₂ with excited C₆H₆ ^*. The quantum yield of C₆H₆ ^* formation has been deduced to ϕ=0.2±0.1. PACS  42.62.Fi; 82.20.Pm; 82.33.Tb     

First measurement of the helicity-dependent γ p?pη differential cross-section

The helicity dependence of the γ p↦pη reaction has been measured for the first time at a center-of-mass angle θ^* _η = 70^° in the photon energy range from 780 MeV to 790 MeV. The experiment, performed at the Mainz microtron MAMI, used a 4π-detector system, a circularly polarized, tagged photon beam, and a longitudinally polarized frozen-spin target. The helicity 3/2 cross-section is found to be small and the results for helicity 1/2 agree with predictions from the MAID analysis. Received: 19 December 2002 / Accepted: 10 March 2003 / Published online: 20 May 2003     

The research on the synthesis and structure of some new ferrocene derivatives

The reaction of C₅H₄RLi with FeCl₂ gave nine new compounds of Fe(C₅H₄R)₂ [R=C(CH₃)₂C₆H₄CH₃-p(-m,-o), C₆H₁₀C₆H₅, C(Me)₂C₆C₄OCH_3-o, C₆H₁₀C₆H₄CH₃-p(,-m,-o), C₆H₁₀C₆H₄OCH₃-p]. The compositions of compounds were determined through elementary analysis. The structural determination was made by IR and H²NMR. Mossbauer spectia were taken at room temperature. The IS and QS values are 0.41–0.45mm/s and 2.3–2.5mm/s., respectively. The solid state structure of the complex has been determined by a single crystal x-ray diffraction study, crystal data for Fe[C₅H₄C(CH₃)₂C₆H₅]₂: a=17.988(2)A, b=17. 411(2)A, c=7.496(1)A, α=β=90°, r=112.23°, Z=4, monoclinic form, space group C2/c. Our conclusions are: in π-acceptor ligand, the nucleophilic substituents decrease and the electrophilic substituts increase the metal to ligand electron cloud shift, which results in a decrease or an increase in the strength of the coordinate bonds and in the stabilization of the complexes by their steric effect.     

Study of K<Superscript>*</Superscript><Subscript>0</Subscript>(1430) and a<Subscript>0</Subscript>(980) from B→K<Superscript>*</Superscript><Subscript>0</Subscript>(1430)π and B→a<Subscript>0</Subscript>(980)K decays

We use the decay modes B→K^* ₀(1430)π and B→a₀(980)K to study the scalar mesons K^* ₀(1430) and a₀(980) within the framework of perturbative QCD. For B→K^* ₀(1430)π, we perform our calculation in two scenarios for the scalar meson spectrum. The results indicate that scenario II is more favored by the experimental data than scenario I. The important contribution from annihilation diagrams can enhance the branching ratios by about 50% in scenario I and about 30% in scenario II. The direct CP-asymmetries in B→K^* ₀(1430)π are small, which is consistent with the present experiments. The predicted branching ratio of B→a₀(980)K in scenario I differs from the experiments by a factor of 2, which indicates that a₀(980) cannot be interpreted as q̄q.     

Construction of Fredholm representations and a modification of the Higson-Roe corona

The Fredholm representation theory is well adapted to the construction of homotopy invariants of non-simply-connected manifolds by means of the generalized Hirzebruch formula [σ(M)] = 〈L(M)ch _A f*ξ, [M]〉 ∈ K _A ⁰(pt) ⊗ Q, where A = C*[π] is the C*-algebra of the group π, π = π ₁(M). The bundle ξ ∈ K _A ⁰(Bπ) is the canonical A-bundle generated by the natural representation π → A. Recently, the first author constructed a natural family of Fredholm representations that lead to a symmetric vector bundle on the completion of the fundamental group with a modification of the Higson-Roe corona, provided that the completion is a closed manifold.     

Λc(2940)+: a possible molecular state?

A new baryonic state Λ_c(2940)⁺ has recently been discovered by the Babar collaboration in the D⁰p channel. Later Belle collaboration also observed this state in the Σ_c(2455)^0,++π^±→Λ_c ⁺π⁺π^- channel. The mass of Λ_c(2940)⁺ is just a few MeV below the sum of D^*0 and p masses suggesting a possibility that this state may be a D^*0p molecular state. In this paper we study whether such a molecular state can be consistent with data. We find that the molecular structure can explain data and that if Λ_c(2940)⁺ is a D^*0p molecular state it is likely a 1/2^- state. Several other decays modes are also suggested to further test the molecular structure of Λ_c ⁺(2940). PACS 13.30.Eg; 14.20.Lg; 12.39.Pn     

Memorino on the ‘1/2 versus 3/2 puzzle’ in B̄→lν̄X<Subscript>c</Subscript> – a year later and a bit wiser

The OPE treatment that has been so successful in describing inclusive B̄→lν̄X_c decays yields sum rules (in particular the Uraltsev sum rule and its higher moments) implying the dominance of the P wave j_q=3/2 charm states in X_c over their j_q=1/2 counterparts. This prediction is supported by other general arguments as well as quark model calculations, which illustrate the OPE results, and by preliminary lattice findings. Its failure would indicate a significant limitation in our theoretical understanding of B̄→lν̄X_c. Some experimental issues have been clarified since a preliminary version of this note had appeared; yet, the verdict on the composition of the final states beyond D, D^* and the two narrow j_q=3/2 resonances remains unsettled. Establishing which hadronic configurations – D/D^*+π,D/D^*+2π,... – contribute, what their quantum numbers are, and their mass distributions will require considerable experimental effort. We explain the theoretical issues involved and why a better understanding of them will be of considerable value. Having significant contributions from a mass continuum distribution below 2.5 GeV raises serious theoretical questions for which we have no good answer. Two lists are given, one with measurements that need to be done and one with items of theoretical homework. Some of the latter can be done by employing existing theoretical tools, whereas others need new ideas.     

Strange multibaryon states with Λ hyperon systems in pA collision at 10 GeV/<Emphasis Type="Italic">c</Emphasis>

Experimental data from the 2m propane bubble chamber have been analyzed for exotic baryon states search. A number of peculiarities were found in the effective mass spectra of Λπ⁺ (Σ*⁺ (1382), PDG), Λp, and Λpp subsystems. A few events detected on the photographs of the propane bubble chamber exposed to a 10 GeV/c proton beam were interpreted as S = −2H ⁰ light(<M _(ΛΛ)) and heavy H ^{0, +}. A new event detected on the photographs of the propane bubble chamber was interpreted as heavy H ⁺ (2488) dibaryon by weak decay channels of K ⁻ pp or Σ⁺ pπ⁻. The text was submitted by the author in English.     

Wavelength-agile fiber laser using group-velocity dispersion of pulsed super-continua and application to broadband absorption spectroscopy

A swept-wavelength source is created by connecting four elements in series: a femtosecond fiber laser at 1.56 μm, a non-linear fiber, a dispersive fiber and a tunable spectral bandpass filter. The 1.56-μm pulses are converted to super-continuum (1.1–2.2 μm) pulses by the non-linear fiber, and these broadband pulses are stretched and arranged into wavelength scans by the dispersive fiber. The tunable bandpass filter is used to select a portion of the super-continuum as a scan-wavelength output. A variety of scan characteristics are possible using this approach. As an example, an output with an effective linewidth of approximately 1 cm^-1 is scanned from 1350–1550 nm every 20 ns. Compared to previous scanning benchmarks of approximately 1 nm/μs, such broad, rapid scans offer new capabilities: a gas sensing application is demonstrated by monitoring absorption bands of H₂O, CO₂, C₂H₂ and C₂H₆O at a pressure of 10 bar. Received: 5 August 2002 / Revised version: 23 September 2002 / Published online: 22 November 2002 RID="*" ID="*"Corresponding author. Fax: +1-608/265-2316, E-mail: ssanders@engr.wisc.edu     

Photon-pion transition form factor at high photon virtualities within the nonlocal chiral quark model

Recently, the BABAR collaboration reported the measurements of the photon-pion transition form factor F _πγγ*(Q ²), which are in strong contradiction to the predictions of the standard factorization approach to perturbative QCD. In the present work, based on a nonperturbative approach to the QCD vacuum and on rather universal assumptions, we show that there exist two asymptotic regimes for the pion transition form factor. One regime with the asymptotic behavior F _πγ*γ(Q ²) ∼ 1/Q ² corresponds to the result of the standard QCD factorization approach, while other violates the standard factorization and leads to asymptotic behavior as F _πγ*γ(Q ²) ∼ ln(Q ²)/Q ². Furthermore, considering specific nonlocal chiral quark models, we find the region of parameters, where the existing CELLO, CLEO and BABAR data for the pion transition form factor are successfully described.