A note on the tan δ(T) peak as a glass transition indicator in biosolids

The plasticization of many biosolids can take place over a fairly broad temperature range. The resulting loss of stiffness is primarily expressed by a drastic drop of G(T) whose magnitude is usually higher than G(T) by one or two orders of magnitude. Both G(T) and G(T) have characteristic properties that can vary widely among biomaterials. Consequently, the tan (T) peak need not be a mark of the transition center and it can be observed at temperatures where different materials have undergone a very different degree of plasticization as judged by the magnitude of G(T). This is demonstrated by computer simulations using typical functions that describe G(T) and G(T) at the glass transition region and with published data on the dynamic mechanical behavior of a variety of biosolids.     

Flow through a helically coiled annulus

In this paper the flow is studied of an incompressible viscous fluid through a helically coiled annulus, the torsion of its centre line taken into account. It has been shown that the torsion affects the secondary flow and contributes to the azimuthal component of velocity around the centre line. The symmetry of the secondary flow streamlines in the absence of torsion, is destroyed in its presence. Some stream lines penetrate from the upper half to the lower half, and if is further increased, a complete circulation around the centre line is obtained at low values of for all Reynolds numbers for which the analysis of this paper is valid, being the ratio of the torsion of the centre line to its curvature.Nomenclature A =constant - a outer radius of the annulus - b unit binormal vector to C - C helical centre line of the pipe - D rL - g 1000 - K Dean number=Re² - L 1+r sin - M (L ²+ ² r ²)^1/2 - n unit normal vector to C - P, P pressure and nondimensional pressure - p ₀, p pressures of O(1) and O() - Re Reynolds number=aW ₀/ - (r, , s), (r, , s) coordinates and nondimensional coordinates - nonorthogonal unit vectors along the coordinate directions - r ₀ radius of the projection of C - t unit tangent vector to C - V _r, V , V _s velocity components along the nonorthogonal directions - V_r, V, V _s nondimensional velocity components along - W ₀ average velocity in a straight annulus Greek symbols , curvature and nondimensional curvature of C - U, V, W lowest order terms for small in the velocity components along the orthogonal directions t - _r, , _s first approximations to V _r , V, V _s for small - =/=/ - kinematic viscosity - density of the fluid - , torsion and nondimensional torsion of C - , stream function and nondimensional stream function - nondimensional streamfunction for U, V - a inner radius of the annulus After this paper was accepted for publication, a paper entitled On the low-Reynolds number flow in a helical pipe, by C.Y. Wang, has appeared in J. Fluid. Mech., Vol 108, 1981, pp. 185–194. The results in Wangs paper are particular cases of this paper for =0, and are also contained in [9].     

Drag reduction by polymer solutions in a riblet-lined pipe

The flow of 3 to 100 wppm aqueous solutions of a polyethyleneoxide polymer,M _w=6.2×;10⁶, was studied in a 10.2 mm i.d. pipe lined with 0.15 mm V-groove riblets, at diametral Reynolds numbers from 300 to 150000. Measurements in the riblet pipe were accompanied by simultaneous measurements in a smooth pipe of the same diameter placed in tandem. The chosen conditions provided turbulent drag reductions from zero to the asymptotic maximum possible. The onset of polymer-induced drag reduction in the riblet pipe occurred at the same wall shear stress, * _w =0.65 N/m², as that in the smooth pipe. After onset, the polymer solutions in the riblet pipe initially exhibited linear segments on Prandtl-Karman coordinates, akin to those seen in the smooth pipe, with specific slope increment . The maximum drag reduction observed in the riblet pipe was independent of polymer concentration and well below the asymptotic maximum drag reduction observed in the smooth pipe. Polymer solution flows in the riblet pipe exhibited three regimes: (i) Hydraulically smooth, in which riblets induced no drag reduction, amid varying, and considerable, polymer-induced drag reduction; this regime extended to non-dimensional riblet heightsh ⁺<5 in solvent andh ⁺<10 in polymer solutions. (ii) Riblet drag reduction, in which riblet-induced flow enhancementR>0; this regime extended from 5<h ⁺<22 in solvent and from 10<h ⁺<30 in the 3 wppm polymer solution, with respective maximaR=0.6 ath ⁺=14 andR=1.6 ath ⁺=21. Riblet drag reduction decreased with increasing polymer concentration and increasing polymer-induced flow enhancement S. (iii) Riblet drag enhancement, whereinR<0; this regime extended for 22<h ⁺<110 in solvent, withR;–2 forh ⁺>70, and was observed in all polymer solutions at highh ⁺, the more so as polymer-induced drag reduction increased, withR<0 for allS>8. The greatest drag enhancement in polymer solutions,R=–7±1 ath ⁺=55 whereS=20, considerably exceeded that in solvent. Three-dimensional representations of riblet- and polymer-induced drag reductions versus turbulent flow parameters revealed a hitherto unknown dome region, 8<h ⁺<31, 0<S<10, 0<R<1.5, containing a broad maximum at (h ⁺,S,R) = (18, 5, 1.5). The existence of a dome was physically interpreted to suggest that riblets and polymers reduce drag by separate mechanisms.     

The secondary flow induced around a sphere in an oscillating stream of elastico-viscous liquid

The present paper is devoted to the theoretical study of the secondary flow induced around a sphere in an oscillating stream of an elastico-viscous liquid. The boundary layer equations are derived following Wang's method and solved by the method of successive approximations. The effect of elasticity of the liquid is to produce a reverse flow in the region close to the surface of the sphere and to shift the entire flow pattern towards the main flow. The resistance on the surface of the sphere and the steady secondary inflow increase with the elasticity of the liquid.Nomenclature a radius of the sphere - b ^ik contravariant components of a tensor - e contravariant components of the rate of strain tensor - F() see (47) - G total nondimensional resistance on the surface of the sphere - g _ik covariant components of the metric tensor - f, g, h secondary flow components introduced in (34) - k ₀ measure of relaxation time minus retardation time (elastico-viscous parameter) - K =k ₀ ²/V ₀ ² , nondimensional parameter characterizing the elasticity of the liquid - n measure of the ratio of the boundary layer thickness and the oscillation amplitude - N, T defined in (44) - p arbitrary isotropic pressure - p _ik covariant components of the stress tensor - p ^ik contravariant components of the stress tensor associated with the change of shape of the material - R =V ₀ a/v, the Reynolds number - S =a/V ₀, the Strouhall number - r, , spherical polar coordinates - u, v, w r, , component of velocity - t time - V(, t) potential velocity distribution around the sphere - V ₀ characteristic velocity - u, v, t, y, P nondimensional quantities defined in (15) - reciprocal of s - density - defined in (32) - defined in (42) - ₀ limiting viscosity for very small changes in deformation velocity - complex conjugate of - oscillation frequency - = ₀/, the kinematic coefficient of viscosity - , defined in (52) - (, y) stream function defined in (45) - =(NT/2n)^1/2 y - /t convective time derivative (1) _ik      

Generalized Rouse model for a dilute solution of clustered polymers

A theory analogue to tha of Rouse is given, to describe the rheological behavior of dilute solutions consisting of clusters of crosslinked polymers. The frequency-dependent behavior of the dynamic moduli of these fluids differs substantially from that of the well-known Rouse-like fluid (GG^1/2). In our case the storage modulus becomes proportional to ^3/2, while the loss modulus is proportional to . The loss modulus dominates the dynamic behavior for frequencies smaller than the largest normal frequency of the clusters.     

Shear softening and thixotropic properties of wheat flour doughs in dynamic testing at high shear strain

Shear softening and thixotropic properties of wheat flour doughs are demonstrated in dynamic testing with a constant stress rheometer. This behaviour appears beyond the strictly linear domain (strain amplitude ₀ 0.2%),G,G and |^*| decreasing with ₀, the strain response to a sine stress wave yet retaining a sinusoidal shape. It is also shown thatG recovers progressively in function of rest time. In this domain, as well as in the strictly linear domain, the Cox-Merz rule did not apply but() and | ^*())| may be superimposed by using a shift factor, its value decreasing in the former domain when ₀ increases. Beyond a strain amplitude of about 10–20%, the strain response is progressively distorted and the shear softening effects become irreversible following rest.     

Determination of molar mass polydispersity index from dynamic rheological measurements

The polydispersity of the molar mass of a material influences the behaviour of its dynamic rheological propertiesG () andG (). This is exemplified by the deviation from unity of the indexI = [2 – (d logG/d log)]/[1 – (d logG/d log)] in the terminal zone, i.e. at low frequencies. For a normal logarithmic distribution of species, a quantitative correlation may be established between the rheological properties and the parameter that is characteristic of the polydispersity for these species. This correlation can, in certain cases, be drawn from measurements in just the terminal zone or it may require measurements both in the terminal zone and at the beginning of the plateau zone. In each case, the parameter of dispersion can be determined by simple graphical or numerical methods. Finally, an example of the application of these methods to entangled liquid polymers is presented.     

Dissipation effects on MHD free convection flow past a semi-infinite vertical plate

Viscous and Joule dissipation effects are considered on MHD free convection flow past a semi-infinite isothermal vertical plate under a uniform transverse magnetic field. Series solutions in powers of a dissipation number (=gx/c _p) have been employed and the resulting ordinary differential equations have been solved numerically. The velocity and temperature profiles are shown on graphs and the numerical values of ₁(0)/₀(0) (, temperature function) have been tabulated. It is observed that the dissipation effects in the MHD case become more dominant with increasing values of the magnetic field parameter (=M ²/(Gr _x /4)^1/2) and the Prandtl number.     

On the relationship between swelling of myofibrils and their suspension rheology

The swelling of myofibrils extracted from white bovine muscle was followed by measuring their suspension rheology. Swelling of the myofibril with increasing pH and ionic strength was accompanied by an increase in both the steady shear viscosity of the suspension and the dynamic viscoelastic properties. Swelling was continuously monitored by measuringG while the ionic strength of the suspension was being changed by dialysis. The relationship between the degree of swelling and the rheological parameters is complicated because myofibrils are rodshaped and swell radially and therefore swelling results in a change in shape. To allow for this an attempt was made to generalize the data by plotting viscosity andG againstcS/ø _m , wherec is the protein concentration in the suspension,S is the swollen volume of the myofibrils per weight of protein, and ø _m is the maximum packing fraction.The best fit to the data was represented by the equations _sp = 1.05 (cS/ _m – 0.84)^1.23 Pa · sG = 8.78 (cS/ _m – 0.67)^2.22 N m^–2. The scatter was greatest forG, possibly because at low degrees of shear the myofibrils were associated and this was confirmed by optical microscopy. Pronounced non-Newtonian behavior was observed and it was suggested that this was due to the disruption of aggregate structures, although at low concentration, orientation of the rods in the shear field may also be important.     

Rheological properties of skim milk gels at various temperatures; interrelation between the dynamic moduli and the relaxation modulus

The rheological properties of rennet-induced skim milk gels were determined by two methods, i.e., via stress relaxation and dynamic tests. The stress relaxation modulusG _c (t) was calculated from the dynamic moduliG andG by using a simple approximation formula and by means of a more complex procedure, via calculation of the relaxation spectrum. Either calculation method gave the same results forG _c (t). The magnitude of the relaxation modulus obtained from the stress relaxation experiments was 10% to 20% lower than that calculated from the dynamic tests.Rennet-induced skim milk gels did not show an equilibrium modulus. An increase in temperature in the range from 20° to 35 °C resulted in lower moduli at a given time scale and faster relaxation. Dynamic measurements were also performed on acid-induced skim milk gels at various temperatures andG _c (t) was calculated. The moduli of the acid-induced gels were higher than those of the rennet-induced gels and a kind of permanent network seemed to exist, also at higher temperatures. G storage shear modulus,N·m^–2; - G loss shear modulus,N·m^–2; - G _c calculated storage shear modulus,N·m^–2; - G _c calculated loss shear modulus,N·m^–2; - G _e equilibrium shear modulus,N·m^–2; - G _ec calculated equilibrium shear modulus,N·m^–2; - G(t) relaxation shear modulus,N·m^–2; - G _c (t) calculated relaxation shear modulus,N·m^–2; - G ^*(t) pseudo relaxation shear modulus,N·m^–2; - H relaxation spectrum,N·m^–2; - t time,s; - relaxation time,s; - angular frequency, rad·s^–1. Partly presented at the Conference on Rheology of Food, Pharmaceutical and Biological Materials, Warwick, UK, September 13–15, 1989 [33].     

A rotating hot-wire technique for spatial sampling of disturbed and manipulated duct flows

The documentation and control of flow disturbances downstream of various open inlet contractions was the primary focus with which to evaluate a spatial sampling technique. An X-wire probe was rotated about the center of a cylindrical test section at a radius equal to one-half that of the test section. This provided quasi-instantaneous multi-point measurements of the streamwise and azimuthal components of the velocity to investigate the temporal and spatial characteristics of the flowfield downstream of various contractions. The extent to which a particular contraction is effective in controlling ingested flow disturbances was investigated by artificially introducing disturbances upstream of the contractions. Spatial as well as temporal mappings of various quantities are presented for the streamwise and azimuthal components of the velocity. It was found that the control of upstream disturbances is highly dependent on the inlet contraction; for example, reduction of blade passing frequency noise in the ground testing of jet engines should be achieved with the proper choice of inlet configurations.List of symbols K _uv correlation coefficient= - P percentage of time that an azimuthal fluctuating velocity derivative dv/d is found - U streamwise velocity component U=U (, t) - V azimuthal or tangential velocity component due to flow and probe rotation V=V (, t) - mean value of streamwise velocity component - U _m resultant velocity from and - mean value of azimuthal velocity component induced by rotation - u fluctuating streamwise component of velocity u=u(, t) - v fluctuating azimuthal component of velocity v = v (, t) - u phase-averaged fluctuating streamwise component of velocity u=u(0) - v phase-averaged fluctuating azimuthal component of velocity v=v() - û average of phase-averaged fluctuating streamwise component of velocity (u()) over cases I-1, II-1 and III-1 û = û() - average of phase-averaged fluctuating azimuthal component of velocity (v()) over cases I-1, II-1 and III-1 - u fluctuating streamwise component of velocity corrected for non-uniformity of probe rotation and/or phase-related vibration u = u(0, t) - v fluctuating azimuthal component of velocity corrected for non-uniformity or probe rotation and/or phase-related vibration v=v (, t) - u ² rms value of corrected fluctuating streamwise component of velocity - rms value of corrected fluctuating azimuthal component of velocity - phase or azimuthal position of X-probe     

Analysis of melt spinning transients in Lagrangian coordinates

Transients in melt spinning of isothermal power law and Newtonian fluids were found to be governed by an extremely simple partial differential equation ² ( ^1/n )/() = 0 in Lagrangian coordinates where is the cross-sectional area,n the power law exponent, the time and the the time at which a fluid molecule constituting the spinline left the spinneret. The general integral ^1/n =f() +g () of the above governing equation containing two arbitrary functions represents physically attainable spinline transients. Hitherto unknown analytical transient solutions of the above governing equation were obtained for the response of isothermal constant tension spinlines to a stepwise change in tension, spinneret hole area, extrusion speed or extrusion viscosity and for the starting transient in gravitational spinning. Linearized perturbation solutions and the stability limit of the spinline derived from the above new found nonlinear solutions were in agreement with previous findings and the above nonlinear response of the spinline to a step increase in the spinneret hole area was found to be equivalent to Orowan's tandem cylinder model of dent growth in filament stretching.     

Dynamic-mechanical properties of a bitumen-silica composite

Summary Dynamic-mechanical properties of bitumen-silica composite materials, measured at room temperature, do not vary with the volume ratio () in a simple manner as do usual bituminous concretes. However,E is a linear function of the interfacial area () between the filler and the binder per unit volume. ThusE = E ₀ +a(), wherea is a constant related to the storage modulus, in the absence of voids and with a void ratio factor. The loss moduli, plotted against () go through a maximum in a similar way as when plotted versus decreasing temperatures.

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Zusammenfassung Die bei Zimmertemperatur gemessenen dynamischmechanischen Eigenschaften von Bitumen, welches mit Siliziumdioxid gefüllt worden ist, ändern sich nicht in einer so einfachen Weise mit dem Volumenanteil des Füllstoffs, wie es bei gewöhnlichen Asphaltbetonen der Fall ist. Dagegen ergibt sich der SpeichermodulE als eine lineare Funktion der Grenzfläche zwischen Bindemittel und Füllstoff pro Volumeneinheit:E = E ₀ +a(), wobeia eine Konstante bedeutet, die zum einen von dem Speichermodul bei Abwesenheit von Hohlräumen und zum andern von einem durch solche Hohlräume bedingten Faktor abhängt. Der Verlustmodul als Funktion von zeigt ein Maximum ähnlich wie bei der Auftragung gegen die Temperatur.

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Résumé Les propriétés mécaniques dynamiques, mesurées à la température ambiante, d'un système composite bitume-silice, n'évoluent pas simplement avec la fraction volumique de charges comme dans le cas des enrobés usuels. En effet, le module de conservationE varie linéairement avec l'aire de l'interface liant-charge par unité de volume (). Ainsi la relation suivante a pu être mise en évidence:E = E ₀ +a(), la constantea étant fonction d'un module indépendant du taux de vide et d'un terme relié à ce dernier. Si augmente, les modules de perte passent par une valeur maximale. Ces variations sont semblables à celles que l'on aurait si l'on portait ces modules en fonction de la température.

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With 9 figures and 2 tables     

Green's functions,bi-linear forms,and completeness of the eigenfunctions for the elastostatic strip and wedge

The bi-harmonic Green's functionG(r,r) for the infinite strip region -1y1, -<x<, with the boundary conditionsG=G/y ony=±1, is obtained in integral form. It is shown thatG has an elegant bi-linear series representation in terms of the (Papkovich-Fadle) eigenfunctions for the strip. This representation is then used to show that any function bi-harmonic in arectangle, and satisfying the same boundary conditions asG, has a unique representation in the rectangle as an infinite sum of these eigenfunctions. For the case of the semi-infinite strip, we investigate conditions on sufficient to ensure that is exponentially small asx. In particular it is proved that this is so, solely under the condition that be bounded asx.A corresponding pattern of results is established for the wedge of general angle. The Green's function is obtained in integral form and expressed as a bilinear series of the (Williams) eigenfunctions. These eigenfunctions are proved to be complete for all functions bi-harmonic in anannular sector (and satisfying the same boundary conditions as the Green's function). As an application it is proved that if an elastostatic field exists in a corner region with free-free boundaries, and with either (i) the total strain energy bounded, or (ii) the displacement field bounded, then this field has a unique representation as a sum of those Williams eigenfunctions whichindividually posess the properties (i), (ii).The methods used here extend to all other linear homogeneous boundary conditions for these geometries.On leave of absence at the University of British Columbia, Vancouver, B.C. Canada, during 1977–79. This work was supported in part by N.R.C. grants Nos. A9259 and A9117.     

Theory of single well tests in a leaky aquifer. Analytical solution for non steady flow

The evaluation of a pump test or a slug test in a single well that completely penetrates a leaky aquifer does not yield a unique relation between the hydraulic properties of the aquifer, independent of the testing conditions. If the flow is transient, the drawdown is characterized by a single similarity parameter that does not distinguish between the storativity and the leakage factor. If the flow is quasi stationary, the drawdown is characterized by a single similarity parameter that does not distinguish between the transmissivity and the leakage factor. The general non steady solution, which is derived in closed form, is characterized bythree similarity parameters.Nomenclature a e 0.8905 = auxiliary parameter - b thickness of the aquifer - b _c thickness of the semipervious stratum - B() auxiliary function - f(s),g(s) auxiliary functions in the complex plane - F(t),G(t) auxiliary functions of time - h undisturbed level of the phreatic surface - K conductivity of the aquifer - K _c conductivity of the semipervious stratum - m ₀ leakage factor - m dimensionless leakage factor - N(s) auxiliary function in the complex plane - Q _w (t) discharge flux - Q steady discharge flux - Q ₀ constant discharge flux during limited time - Q(t) dimensionless discharge flux - r ₀ radius of the well - r radial coordinate - r dimensionless radial coordinate - s complex variable - s ₀ pole - S storativity of the aquifer - S _n n'th part of an integration contour - t time - t dimensionless time - T transmissivity of the aquifer - ,,,,, dimensionless parameters - Euler's number - dummy variable - ₁(), ₂() auxiliary functions - (r, t) drawdown - ₀(t) drawdown in the well - (r, t) dimensionless drawdown - ₀(t) dimensionless drawdown in the well     

Supersonic flow past axisymmetric flared cones

Systematic data on the determination of the aerodynamic characteristics of axisymmetric bodies with a break in the generating line (Fig. 1a, b) in supersonic flow at zero angle of attack are presented in [1, 2, and others]. A characteristic feature of the flow past such bodies is the appearance of an extensive separation zone dec in the region of the break in the generator when the break angle exceeds some minimum value _min, which for a turbulent boundary layer depends basically on the Mach number M at the body surface ahead of the separation zone. In this case, compression waves which change into the oblique compression shocks dc and cc, emanate both from the beginning of the separation zone (point c) and from the end of it (point d). These shocks, intersecting at the point c, form the triple shock configuration acd and acc for which we introduce the notationac[c, d]. The maximum value (_max) of the generator break angle is limited by the possibility of the existence of an attached compression shock, dc. According to these data a change in the generator break angle for the range _minmax of the angle does not disrupt the nature of the flow in the separation zone, but only alters the size of this zone.We shall examine the flow past cones with values of the generator break angles (_max) for which the attached shock dc cannot exist.     

Beschreibung des visko-elastischen Verhaltens des polymeren Mischsystems Phenolnovolakharz-Nitrilkautschuk (PF/NBR) mit Hilfe der Van-der-Poel-Gleichung

Zusammenfassung Morphologische Untersuchungen an dem polymeren Mischsystem Phenolnovolakharz-Nitrilkautschuk haben gezeigt, daß diese Mischungen eine Struktur aufweisen, in der harte kugelige PF-Teilchen in einer Kautschukmatrix bzw. weiche Kautschukteilchen in einer Harzmatrix eingebettet sind. Mit Hilfe der morphologischen und mechanisch-dynamischen Untersuchungen wird versucht, das viskoelastische Verhalten von Polyblends mit der Van-der-Poel-Gleichung zu beschreiben. Es konnte gezeigt werden, daß bis zu ModulwertenGhart/Gweich ~ 100 eine gute Übereinstimmung mit der Van-der-Poel-Gleichung gefunden wird. Hohe Modulverhältnisse der harten Einlagerungskomponente zur weichen KomponentenGhart/Gweich ~ 1000, wie sie im kautschukelastischen Bereich auftreten, zeigen eine Übereinstimmung mit der Van-der-Poel-Gleichung nur bei einer Volumenkonzentration der harten EinlagerungskomponenteV _f < 0,3. Diese Ergebnisse werden mit anderen bekannten theoretischen Überlegungen über den Zusammenhang zwischen Elastizitätsmodul und Zusammensetzung von Verbundwerkstoffen verglichen.Schlüsselwörter Phenolnovolakharz-Nitrilkautschuk-System, viskoelastisches Verhalten, Torsionspendel, Van-der-Poel-Gleichung

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Summary Morphological investigations of the polymer compound-system novolak resin-nitril rubber (PF/NBR) have shown, that these mixtures exhibit structures, in which hard spherical particles are embedded in a rubber matrix, respectively soft rubber particles in a resin matrix.An attempt was made to describe the viscoelastic behaviour of these polyblends by means of morphological and dynamic-mechanical investigations with the relation given by Van der Poel.Up to ratios of the moduliGhard/Gsoft ~ 100 a good agreement with the Van-der-Poel equation was found. In the rubber elastic region at ratiosG hard/G soft ~ 1000 this agreement was found for volume concentrations of the phenolic componentV _f ~ 0.3 only.The results are compared with other existing theories on the correlation between elastic modulus and composition of compound materials.

Mit 7 Abbildungen und 6 Tabellen     

The value of the critical exponent for reaction-diffusion equations in cones

Let D R ^N be a cone with vertex at the origin i.e., D = (0, )x where S ^N–1 and x D if and only if x = (r, ) with r=¦x¦, . We consider the initial boundary value problem: u _t = u+u ^p in D×(0, T), u=0 on Dx(0, T) with u(x, 0)=u ₀(x) 0. Let ₁ denote the smallest Dirichlet eigenvalue for the Laplace-Beltrami operator on and let ₊ denote the positive root of (+N–2) = ₁. Let p ^* = 1 + 2/(N + ₊). If 1 < p < p ^*, no positive global solution exists. If p>p ^*, positive global solutions do exist. Extensions are given to the same problem for u _t=+¦x¦ u ^p .This research was supported in part by the Air Force Office of Scientific Research under Grant # AFOSR 88-0031 and in part by NSF Grant DMS-8 822 788. The United States Government is authorized to reproduce and distribute reprints for governmental purposes not withstanding any copyright notation therein.     

Unsteady convective diffusion in a rotating parallel plate channel

The paper presents an exact analysis of the dispersion of a passive contaminant in a viscous fluid flowing in a parallel plate channel driven by a uniform pressure gradient. The channel rotates about an axis perpendicular to its walls with a uniform angular velocity resulting in a secondary flow. Using a generalized dispersion model which is valid for all time, we evaluate the longitudinal dispersion coefficientsK _i (i=1, 2, ...) as functions of time. It is shown thatK ₁=0 andK ₃,K ₄, ... decay rapidly in comparison withK ₂. ButK ₂ decreases with increasing (the dimensionless rotation parameter) for values of upto approximately =2.2. ThereafterK ₂ increases with further increase in and its value gets saturated for large values of (say, 500) and does not change any further with increase in . A physical explanation of this anomalous behaviour ofK ₂ is given.

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Instationäre konvektive Diffusion in einem rotierenden Parallelplattenkanal

Zusammenfassung In dieser Untersuchung wird eine exakte Analyse der Ausbreitung eines passiven Kontaminierungsstoffes in einer zähen Flüssigkeit gegeben, die, befördert durch einen gleichförmigen Druckgradienten, in einem Parallelplattenkanal strömt. Der Kanal rotiert mit gleichförmiger Winkelgeschwindigkeit um eine zu seinen Wänden senkrechte Achse, wodurch sich eine Sekundärströmung ausbildet. Unter Verwendung eines generalisierten, für alle Zeiten gültigen Dispersionsmodells werden die longitudinalen DispersionskoeffizientenK _i (i=1, 2, ...) als Funktionen der Zeit ermittelt. Es wird gezeigt, daßK ₁=0 gilt und dieK ₃,K ₄, ... gegenüberK ₂ schnell abnehmen.K ₂ nimmt ab, wenn , der dimensionslose Rotationsparameter, bis etwa zum Wert 2,2 ansteigt. Danach wächstK ₂ mit bis auf einem Endwert an, der etwa ab =500 erreicht wird. Dieses anomale Verhalten vonK ₂ findet eine physikalische Erklärung.

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List of symbols C solute concentration - D molecular diffusivity - K _i longitudinal dispersion coefficients - 2L depth of the channel - P ₀ dimensionless pressure gradient along main flow - Pe Péclet number - q velocity vector - Q _x,Q _y mass flux along the main flow and the secondary flow directions - dimensionless average velocity along the main flow direction - (x, y, z) Cartesian co-ordinates Greek symbols dimensionless rotation parameter - the inclination of side walls withx-axis - kinematic viscosity - fluid density - dimensionless time - angular velocity of the channel - dimensionless distance along the main flow direction - dimensionless distance along the vertical direction - dimensionless solute concentration - integral of the dispersion coefficientK ₂() over a time interval     

Convexity conditions for strain-dependent energy functions for membranes

The forms that the convexity, polyconvexity, and rank-one convexity inequalities take when the strain energy is required to be a function of the strain G are studied. It is shown in particular that W(G) must be an increasing function of G, in the sense that W(G)W(G) if G – G is non-negative definite. Relatively simple sufficient conditions in terms of G alone are given. Necessary and sufficient conditions in terms of G alone are found to be rather complex.