Annealing effects and short-range ordering in the non-magnetostrictive amorphous alloy Co58Ni10Fe5Si11B16

Effects of isothermal and isochronal annealing on the coercive field and the effective magnetic anisotropy in the as-quenched and the stress relieved amorphous alloy Co₅₈Ni₁₀Fe₅Si₁₁B₁₆ were investigated. The mechanisms of the deterioration of soft magnetic properties in non-magnetostrictive amorphous alloys by annealing at low temperatures,T _a <T _c , are discussed. It turned out, that short-range ordering, i.e., topological short-range ordering (TSRO) and chemical short-range ordering (CSRO), caused by annealing lead to changes of the magnetostriction _s , and of the induced magnetic anisotropyK _i . Both effects give rise to an increase of the coercive field. In addition, the kinetics of short-range ordering was studied and from these data, which are closely related to the stability of soft magnetic properties, the activation energy and a preexponential factor was derived:Q _s.r=0.7eV,v ₀=9.6×10³s^–1.     

Small angle neutron scattering from oxygen precipitates in silicon

The formation of silicon oxide precipitates from Czochralski grown silicon depends on the time and temperature of the heat treatment as well as on the initial content of interstitially dissolved oxygen. Samples containing between 5×10¹⁷ O_i/cm³ and 13×10¹⁷ O_i/cm³ have been heated at 750° C for 96 h. SiO₂ precipitates of various shape and size have been obtained and investigated by means of small angle neutron scattering (SANS) in the Q-range 0.05 Å^–1<Q<0.2 Å^–1. The obtained SANS patterns reveal a typical anisotropy of their intensity distribution, which splits into a central peak at Q<0.1 Å^–1 due to the shape of the individual particles and a number of weak intensities for large Q-values, originating from a correlation between defects, possibly between the precipitates. While these correlation peaks in the SANS patterns are seen best for rather low values of about (5–7)×10¹⁷ O_i/cm³ oxygen content, the central peak anisotropy is most pronounced for higher values of ca 10×10¹⁷ O_i/cm³. The integrated intensity of the central peak increases with increasing initial oxygen content. For comparison, untreated samples of the same initial oxygen content do not reveal any anisotropic SAN scattering or a broadened central peak beam.     

Determination of the effective strong coupling constant from CLAS spin structure function data

We present a new extraction of the effective strong coupling constant α_s,g1(Q²). The result agrees with a previous determination and extends the measurement of the low and high Q² behavior of α_s,g1(Q²) that was previously deduced from sum rules. In particular, it experimentally verifies the lack of Q²-dependence of α_s,g1(Q²) in the low Q² limit. This fact is necessary for application of the AdS/CFT correspondence to QCD calculations. We provide a parameterization of α_s,g1(Q²) that can equivalently be used to parameterize the Q²-dependence of the generalized Gerasimov–Drell–Hearn and Bjorken sums.     

The rotational-vibrational spectra of HNCS and DNCS : An analysis of the high resolution spectra

Ro-vibrational spectra of HNCS and DNCS have been obtained in the spectral range 300–4000 cm⁻¹ with a practical resolution limit of 0.06 cm⁻¹ in the region 350–1200 cm⁻¹ and 0.15 cm⁻¹ in the region 1200–4000 cm⁻¹. The observed fine structure permitted definitive assignments for some of the ^PQ_K, ^QQ_K, and ^RQ_K branches in both molecules, and yielded sets of rotational constants in substantial agreement with those obtained from recent microwave and far-infrared studies. Precise estimates of the band origins have been obtained and there is evidence of second-order Coriolis coupling between the three bending modes in each molecule. The isolation of the out-of-plane bending modes has lead to a re-assignment of ν₃, ν₄, ν₅, and ν₆ for each molecule. The band origins, uncorrected for Coriolis interaction, are for HNCS and DNCS, respectively. v₁:3538.6 ±0.3, 2644.5±0.5cm⁻¹;v₂:1989.0 ±0.3, 1944.3±0.5cm⁻¹;v₃:857.0 ±0.6, 851.0±0.1cm⁻¹;v₄:615.0 ±0.5, 549.1±0.2cm⁻¹;v₅:469.2 ±0.1, 365.8 ±0.2cm⁻¹;v₆:539.2 ±0.5, 481.0±0.1cm⁻¹;     

Diffusion of Au in amorphous Zr x Ni100−x alloys studied by Rutherford Backscattering Spectrometry

The diffusion coefficients (D) of Au in three binary amorphous Zr _x Ni_100–x (x=61, 65, and 67) alloys were measured in the temperature range 549–623 K using the technique of the Rutherford Backscattering Spectrometry (RBS). The D values were found to lie in the range 1.0×10^–21–9.0×10^–20 m²s^–1 for different alloys. The activation energy (Q) was calculated in each case on the basis of an observed Arrhenius temperature dependence of D. The activation energy was found to scale with the crystallization temperature (T _x) of the alloy. Other published measurements for Au diffusion in amorphous Zr-Ni alloys also appear to follow the scaling relation between Q and T _x.     

Nuclear spin relaxation of Xe in liquid Te

By the method of time differential perturbed angular distribution following a nuclear reaction, the relaxation rateT _r ^–1 of the 8 msI =10⁺ isomer of¹³²Xe has been measured in liquid Te. Between 670 °K (supercooled liquid) and 1,000 °K the rate decreases from about 720/s by about a factor of two. From existing experimental material it is concluded thatT _r ^–1 is mainly due to quadrupolar interaction (T _r ^–1 T _Q ^–1 ). Its magnitude is discussed considering the metallic and the noble gas limit as models for the Xe-Te-interactions. The temperature dependenceT _Q(T) apparently does not correlate with the diffusion constant of Te in contrast to a simplified theoretical treatment. — The nuclearg value of the isomer has been determined to be g=(–)0.195(5) thus confirming the configuration (vh_11/2)².     

Temperature dependence of nonsteady dislocation-induced internal friction

A change in the number of weak pinning points results in the time dependence of the dislocation-induced internal friction. The paper considers the temperature dependence of the nonsteady component of the damping decrement Q^–1, induced by partial scattering of the cloud of point defects. There exists a temperature peak Q^–1(T), whose height and temperature vary as the frequency changes. The relation between the frequency, height, and temperature of the peak is considered. The results can be used to determine the character and type of weak pinning points.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 59–63, September, 1981.     

Absolute intensities for the Q-branch of the 3ν2-ν1 (465.161 cm) band of nitrous oxide

The absolute intensities of four lines, Q15–Q18 in the 03¹0–10⁰0 band, of N₂O have been measured using a tunable diode laser spectrometer at temperatures between 380 and 420 K and pressures between 4 and 15 torr. Even though these transitions are weak and produced only about 2% of absorption at the line center for a pathlength of 52m, they were measured with a signal to noise ratio of about 20 due to the high sensitivity of the instrument. The band strength derived is 1.03 × 10^-24cm molec^-1 at 296 K.     

Isothermal capacitance transient spectroscopy (ICTS) study for midgap levels in Hb-GaAs by rapid thermal annealing

We studied the midgap levels by using isothermal capacitance transient spectroscopy (ICTS) in Hb-GaAs which had been processed by rapid thermal annealing (RTA). As the annealing time at 850 °C increased, the EL2 trap (E _c–0.81 eV) was transformed to the EX2 trap (E _c–0.73 eV) and eventually to the EX1 trap (E _c–0.87 eV). The diffusivity of the EL2 trap obtained from the experimental result of the heat treatment was about 1.02·10^–8cm²/s at 850 °C. This result indicate that the EL2 trap contains an interstitial arsenic atom. The result of the transformation to the EX1 and EX2 traps suggests that, when the EL2 trap is V_AsAS_iV_GaAs_Ga, the EX2 trap may be V_AsV_GaAs_Ga, which As_i is diffused out during a thermal annealing.     

Near-ordering structural transitions in amorphous metal alloys

The temperature variations in the modulus of elasticity (Young’s modulus) E and internal friction Q ⁻¹ of the amorphous metal alloys Ti₅₀Cu_50−x Ni_x (5⩽x⩽20) are studied at temperatures of 300–800 K. There is an anomalous increase in E(T) at temperatures above T _x (which varies from 440 to 525 K, depending on the composition). When the amount of nickel in the alloy is high (x>12 at. %), a small peak shows up in Q ⁻¹(T). These effects are related to structural transitions in near-ordering regions (clusters). A model for structural relaxation of near ordering in amorphous alloys is proposed on the basis of these experiments. Fiz. Tverd. Tela (St. Petersburg) 40, 389–392 (March 1998)     

Measurement of the proton structure functionF2 from the 1993 HERA data

The ZEUS detector has been used to measure the proton structure functionF ₂. During 1993 HERA collided 26.7 GeV electrons on 820 GeV protons. The data sample corresponds to an integrated luminosity of 0.54 pb^–1, representing a twenty fold increase in statistics compared to that of 1992. Results are presented for 7Q ²<>⁴ GeV² andx values as low as 3×10^–4. The rapid rise inF ₂ asx decreases observed previously is now studied in greater detail and persists forQ ² values up to 500 GeV².supported by Worldlab, Lausanne, Switzerland     

Crystalline-electric-field level scheme of NdB6

We have determined the crystalline-electric-field (CEF) level scheme of NdB₆ by means of Raman spectroscopy. We could resolve two CEF-transitions at 92 cm^–1 and 98 cm^–1 due to the spectral resolution of 2 cm^–1 (=0.25 meV). The temperature dependent Raman scattering reveals the two transitions to be on top of one another, in agreement with fits of the temperature dependence of the magnetic susceptibility. The spectroscopically determined CEF level scheme yields a good fit of the elastic constants and hence the mean field prediction of a ferroquadrupolar ordering near 6 K. This result sheds new light on the phase transition in NdB₆ nearT _N =8.6 K which has so far been interpreted only in terms of antiferromagnetic ordering.Work supported by Deutsche Forschungsgemeinschaft, SFB 125Work supported by Deutsche Forschungsgemeinschaft, SFB 126     

On the rise of the proton structure function F2 towards low x

A measurement of the derivative (∂ lnF₂/∂ lnx)_Q²≡−λ(x,Q²) of the proton structure function F₂ is presented in the low x domain of deeply inelastic positron–proton scattering. For 5×10⁻⁵x0.01 and Q²1.5 GeV², λ(x,Q²) is found to be independent of x and to increase linearly with lnQ².     

Excitation of the 7s2P1/2, 3/2 levels of Xe+ due to charge exchange in the negative glow of a glow discharge in a neon-xenon mixture

It is shown that in the negative glow of a glow discharge in mixtures of neon with xenon (xenon contents of 5.5·10^–3 to 2% of the total pressure P of the mixture) with P=15 torr and discharge currents i=40 mA (cathode diameter 30 mm), the 7s²P_{1/2, 3/2} levels of the Xe⁺ ion are excited by the charge exchange reaction Xe ^m + Ne⁺ Xe^+* + Ne.The effective cross section Q_3/2 for excitation of the 7s²P_3/2 level is estimated to lie between 10^–14 and 10^–15 cm² and Q_3/26.5 × Q_1/2, where Q_1/2 is the effective cross section for excitation of the 7s²P_1/2 level.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii Fizika, No. 3, pp. 96–99, March, 1979.     

The temperature dependences of electromechanical properties of PLZT ceramics

The mechanical and electrical properties in lanthanum modified lead zirconate-titanate ceramics of 5/50/50 and 10/50/50 were studied by mechanical loss Q ^{- 1}, Young's modulus E, electric permittivity ε and tangent of dielectric loss of angle tgδ measurements. The internal friction Q ^{- 1} and Young modulus E measured from 290 K to 600 K shows that Curie temperature T_C is located at 574 K and 435 K (1^st cycle of heating) respectively for ceramic samples 5/50/50 and 10/50/50. The movement of T_C in second cycle of heating to lower temperature (561 K for 5/50/50 and 420 K for 10/50/50) has been observed. Together with Q ^{- 1} and E measurements, temperature dependences of ε=f(T) and tgδ=f(T) were determinated in temperature range from 300 K to 730 K. The values of T_C obtained during ε and tgδ measurements were respectively: 560 K for 5/50/50 and 419 K for 10/50/50. These temperatures are almost as high as the temperatures obtained by internal friction Q ^{- 1} measurements in second cycle of heating. In ceramic sample 10/50/50 the additional maximum on internal friction Q ^{- 1} curve at the temperature 316 K was observed.     

Ionic Synthesis of Ga1–x In x As Solid Solution Films

The Ga_1–x In _x As compound obtained by In-ion implantation (100 keV and (0.45–6)·10¹⁷ cm^–2) followed by thermal (800 °C and 15') or high-energy electron-beam (1 MeV, 0.6 mA·cm^–2, 660 °C, and 16 s) annealing is investigated by Rutherford backscattering, optical absorption, and capacitor photoelectromotive force. It is shown that x increases from 0.07 up to 0.21, and the band gap decreases from 1.34 down to 1.21 eV as the implantation dose increases. The surface potential decreases from 0.79 down to 0.58 V. A high efficiency of electron-beam annealing is pointed out.     

The low temperature electric quadrupole orientation of184Ir and185Ir in rhenium

The half-lives of¹⁸⁴Ir,¹⁸⁵Ir and¹⁸⁶Ir have been determined to be 3.14(2) h, 14.4(1) h and 16.64(3) h, respectively. The quadrupole frequenciesv _Q = e²qQ_s/h of¹⁸⁴Ir and¹⁸⁵Ir in rhenium single crystal have been determined to be Q_s(¹⁸⁴Ir) = + 2.0(3) b MHz and Q_s(¹⁸⁵Ir) = +2.0(3) b MHz. Adopting the value of –3.6(2)×10¹⁷ V·cm^–2 for the electric field gradient eq at T=0 K, the values of the ground-state spectroscopic quadrupole moments of these isotopes are determined to be Q_s(¹⁸⁴Ir)=+2.0(3) b and Q_s(¹⁸⁵Ir)=–2.5(3) b. The¹⁸⁵Ir moment is only consistent with the ground state Nilsson configuration , the¹⁸⁴Ir moment is consistent with K4 with a predominant K=4 component, in disagreement with K=0,1 found for¹⁸⁶Ir. Our analysis differs in detail from the recent nuclear orientation study by Hagn et al.[1].     

Analysis of the ν3 band of NO2

The rotational structure of the ν₃ fundamental of ¹⁴N¹⁶O₂ has been recorded by employing a vacuum grating infrared spectrograph. The analysis has led to the assignment of over 500 R- and P-branch transitions in the spectral region 1562–1650 cm⁻¹. Molecular constants for the upper state, 001, have been presented. No Q-branch transitions were used in the evaluation of these constants. The presently obtained and the band center ν₀ = 1616.846 cm⁻¹ differ significantly from previous determinations. Spin splitting was observed but no information was extracted about upper state spin splitting parameters.     

Amplitude dependence of the internal friction in a Pb-62% Sn alloy

The method of forced flexural vibrations is used to obtain the amplitude dependence of the internal friction (Q ⁻¹(ɛ₀)) in the Pb-62% Sn alloy, which exhibits superplasticity at room temperature. A phenomenological model of the internal friction, in which the plasticity of alloys is considered as a hybrid relaxation-hysteresis process, is proposed. The numerical values of the cyclic-strain-hardening exponent n of the Pb-62% Sn alloy are determined in the microplastic and superplastic states, and the nature of the experimentally detected asymmetric maximum in Q ⁻¹(ɛ₀) is discussed.     

Annealing effect on the superconductivity of In2O3–ZnO thin films

We have investigated the relation among ρ–T characteristics, superconductivity, annealing conditions and the crystallinity of polycrystalline (In₂O₃)_1−x–(ZnO)_x films. We annealed as-grown amorphous films in air by changing annealing temperature and time. It is found that the films annealed at 200 °C or 300 °C for a time over 0.5 h shows the superconductivity. Transition temperature T_c and the carrier density n are T_c < 3.3 K and n ≈ 10²⁵–10²⁶ m⁻³, respectively. Investigations for films with x = 0.01 annealed at 200 °C have revealed that the T_c, n and crystallinity depend systematically on annealing time. Further, we consider that there is a suitable annealing time for sharp resistive transition because the transition width becomes wider with longer annealing times. We studied the upper critical magnetic field H_c2(T) for the film with different annealing time. From the slope of dH_c2/dT for all films, we have obtained the resistivity ρ dependence of the coherence length ξ(0) at T = 0 K.