Optical and magnetic properties of Er3+ in LiYF4

High-resolution, polarized fluorescence spectroscopy has been used to study magnetically split energy levels of triply ionized erbium in the scheelite host lithium yttrium fluoride. Primary attention focused upon characterizing the Stark components of JLS manifolds involved in the material's several lasing transitions. Measurements at 2K yield energies and signed g factors which differ considerably from previously published zero-field studies and corresponding theoretical predictions of magnetic splittings. Polarization data allow definitive assignment of S₄ irreducible representations similar to those reported for erbium levels in the isomorphic host CaWO₄. Summation of g∥'s for the three Γ_7,8 levels of the ${}^4\text{I}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ multiplet yields a value of 3.16 ± 0.23, whereas the recently developed partial g-sum rule predicts 3.32.     

Observation of electronic Raman transitions from the transition metal ions Ti3+ and V4+ highly diluted in α-Al2O3

α-Al₂O₃ : Ti³⁺ (300 mass ppm concentration) at 10 K shows two electronic Raman transitions at 38 cm^-1 and 109 cm^-1. The E symmetry of the scattering matrix agrees with the selection rules for transitions between the ground state B_{$\text{3}\text{2}$} and the E_{$\text{1}\text{2}$} of the ground state manifold ²t_2g.α-Al₂o₃ : V⁴⁺ shows two very weak electronic Raman transitions at about 30 cm^-1 and 56 cm^-1 respectively.     

An amplitude analysis of the K+K− system produced in the reaction π−p→K+K−n at 10 GeV/c

We present results on an amplitude analysis of the K⁺K^? system produced in the reaction π^?p→K⁺K^?n from threshold up to 2.2 GeV. The branching ratios of f⁰ and f' to K$\text{K}$ have been determined. In the low mass region of the K$\text{K}$ system the observation of an S-wave enhancement at 1.3 GeV and the interference of the f⁰-A₂-f' mesons are studied. We observe a 3^? structure in the mass region of 1.7 GeV which is consistent with g⁰ production. With this interpretation the branching ratio $\text{g→}\text{K}\text{K}$ has been determined. Evidence for a new structure in the J^p = 2⁺ wave around 1.8 GeV with a width of ～200 MeV is presented.     

Magnetic field dependent optical dephasing in LaF3:Er3+

Optical dephasing of the 5388 Å transition between the lowest Kramers doublets of the ⁴S_{$\text{3}\text{2}$} and ⁴I_{$\text{15}\text{2}$} multiplets of Er³⁺:LaF₃ has been studied by photon echo, optical phase switching and optical free induction decay. Er³⁺?¹⁹F hyperfine interactions produce dephasing which is two orders of magnitude faster than in previously studied non-Kramers systems, but at high field changes in the spin dynamics result in microsecond dephasing. For the lower Zeeman component of ⁴S_{$\text{3}\text{2}$}, T₂ (=6μs) is independent of H₀ whereas for the upper component the dephasing is rapid and strongly field dependent. This is quantitatively accounted for by spin lattice relaxation of the upper component of ⁴S_{$\text{3}\text{2}$}. Below 20 kG concentration and temperature dependent dephasing due to electron spin diffusion is observed.     

Spectral studies of Nd3+ and Er3+ ions in POCl3:SnCl4 laser liquid

The optical absorption spectra of triply ionized neodymium and erbium ions in POCl₃SnCl₄ laser liquid have been studied for the first time in the UV-VIS and NIR regions. Spectroscopic and Judd-Ofelt intensity parameters are evaluated from the observed band positions and their intensities. Radiative lifetimes and the luminescent branching ratios for the excited fluorescent levels of Nd³⁺ and Er³⁺ ions are theoretically estimated and the possible laser transitions are indicated. From the observed splittings of certain bands in the second-derivative spectrum of the Nd³⁺ ion, the crystal field (A ₂₀,A ₄₀) parameters are evaluated assumingC _3h symmetry for the ion.     

Electron exchange between Fe2+ and Fe3+ ions on octahedral sites in spinels studied by means of paramagnetic Mössbauer spectra and susceptibility measurements

Mössbauer spectra were obtained of the paramagnetic spinels $\text{Zn}{}^{\mathrm{2+}}\text{|}\text{Zn}{}^{\mathrm{2+}}{}_{\mathrm{<mtext>(1?x)</mtext><mtext>2</mtext>}}\text{Ti}{}^{\mathrm{4+}}{}_{\mathrm{<mtext>(1+x)</mtext><mtext>2</mtext>}}\text{Fe}{}^{\mathrm{3+}}{}_{\mathrm{<mtext>(1?</mtext><mtext>x)</mtext>}}\text{Fe}{}^{\mathrm{2+}}{}_{\mathrm{x}}\text{|}\text{O}{}_4$ and susceptibilities were measured. The strong difference between the paramagnetic Fe²⁺ and Fe³⁺ spectrum, due to the different quadrupole splitting, is used for the distinction between the two species. At 300 K a superposition of the Fe³⁺ and the Fe²⁺ spectra is found for most of the iron and, in addition, some continuous absorption. The latter is strongest for equal Fe³⁺ and Fe²⁺ concentration $\text{(x =}\text{1}\text{2}\text{)}$ while it disappears towards the end members (Fe³⁺ only or Fe²⁺ only) as well as with decreasing temperature (between 78 and 200 K). From this it is concluded that it arises from thermally activated electron exchange, the frequency of which passes a “critical” value of ～10⁸ sec^?1 for increasing temperature. Paramagnetic susceptibilities are found to obey a Curie-Weiss law down to low temperatures. From the dependence of the asymptotic Curie temperature on the composition the magnetic interaction parameters J₁₁ = ?1.4 K, J₂₂ = ?3.3 K and J₁₂ = + 1.6 K for the Fe³⁺Fe³⁺, Fe²⁺Fe²⁺ and Fe³⁺Fe²⁺ interactions are derived. The experimental results are discussed in terms of a hopping model with an activation energy q ～- 0.12eV and a non-equivalence of the octahedral sites expressed by a varying potential energy difference U₀ between neighbouring sites. The continuous absorption at 300 K for $\text{x =}\text{1}\text{2}$ is attributed to about 17% of the iron on sites with U₀ running from 0 to ??0.06 eV. The ferromagnetic Fe³⁺, Fe²⁺ interaction (J₁₂) is attributed to electron transfer from localized Fe²⁺ ions to Fe³⁺ neighbours via a transfer integral b of the order of 0.05 eV. The magnitudes of J₁₂ and b are tentatively explained.     

Relaxation of the 4G92 state of Nd3+ in LaCl3 and Nd3+ in La(Cl99.6Br0.4)3

The decay of the ⁴G_{$\text{9}\text{2}$} state of Nd³⁺ in LaCl₃ and La(Cl_99.6 Br_0.4)₃ was measured after pulsed laser excitation as a function of temperature. The decay rate is shown to depend besides the radiative transition on single-phonon relaxation between the states ⁴G_{$\text{9}\text{2}$} ($\text{μ =}\text{1}\text{2}$) and ⁴G_{$\text{9}\text{2}$} ($\text{μ =}\text{3}\text{2}$) and on multiphonon orbit-lattice relaxation from ⁴G_{$\text{9}\text{2}$} to ²G_{$\text{9}\text{2}$}. Partial substitution of Cl by Br only alters the radiative lifetime.     

Transition moment variation in the A2Σ+ → X2Πi transition of HCl+, DCl+ and HBr+

Relative emission intensities of sixteen bands of HCl⁺ (A²Σ⁺ - X²Π_i), four bands of DCl⁺ (A²Σ⁺ - X²Π_i), and 5 bands of HBr⁺ (A²Σ - X²Π_i) have been made using both ion-beam excitation and microwave discharge sources. Intensities were determined by comparison with computer-generated spectra. Treatment of the data within the r-centroid approximation shows that in HCl⁺ the electronic transition moment decreases strongly at large $\text{r}{}_{\mathrm{v\prime v″}}$ [$\text{Re}\text{α}\text{exp}\text{(?3.6}\text{r}{}_{\mathrm{v\prime v″}}\text{)}\text{for 1.44}\text{A}\text{?}\text{< r}{}_{\mathrm{v\prime v″}}\text{< 1.82}\text{A}\text{?}$] but levels off at shorter $\text{r}{}_{\mathrm{v\prime v″}}$. DCl⁺ data agree quantitatively with HCl⁺. The variation in the HBr⁺ moment is similar, with $\text{R}\text{e}\text{α}\text{exp}\text{[?4.5}\text{r}{}_{\mathrm{v\prime v″}}\text{]}\text{for 1.58}\text{A}\text{?}\text{<}\text{r}{}_{\mathrm{v\prime v″}}\text{< 1.78}\text{A}\text{?}$.     

The effect of the next nearest neighbor ion on the X-ray photoelectron spectra of 2p levels for Co2+, Ni2+ and Cu2+ in MgO

The X-ray photoelectron spectra of Co, Ni and Cu 2p levels for samples of M_xMg_1-xO (M = Co, Ni, Cu), CoO, NiO and CuO were compared. The binding energies of metal 2p_{$\text{3}\text{2}$} levels did not change with their concentration. The shake-up satellite main peak intensity ratios and FWHM of metal 2p levels for Co²⁺ and Cu²⁺ in MgO were smaller than those for CoO and CuO. The Ni 2p_{$\text{3}\text{2}$} spectrum for Ni²⁺ in MgO had no shoulder, unlike NiO. Results indicate that next nearest neighbor ions (metal ions) may influence the final states after photoelectron ejection.     

Radiative decays of the Jψ and evidence for a new heavy resonance

The three photon final state produced in e⁺e^? collisions has been measured at the mass of the $\text{J}\text{ψ}$ resonance using the nonmagnetic part of the double arm spectrometer DASP. The decays $\text{J}\text{ψ}\text{→ ηγ, η'γ}$ and π^oγ were observed and their branching ratios are given. A four standard deviation signal was observed in the γγ mass spectrum at a mass of (2.83 ± 0.03) GeV. An upper limit is given for the direct decay $\text{J}\text{ψ}\text{→ 3γ}$.     

Electrical conductivity and defect structure of Ni-doped and “CO-reduced” Ni-doped SrTiO3 single crystals

The electrical conductivities of Ni-doped and “CO-reduced” Ni-doped SrTiO₃ single crystals were measured at temperatures 700–1200°C and P_o2's of 10^?7–10^?1 atm. Plots of log σ vs $\text{1}\text{T}$ at constant P_o2's were found to be linear, and the activation energies appeared to be 0.92 eV for Ni-doped SrTiO₃ and 0.50 eV for “CO-reduced” Ni-doped SrTiO₃ single crystals, respectively. Plots of log σ vs log P_o2 at constant temperature were found to be linear with an average slope of ?$\text{1}\text{4}$ for SrTiO₃:Ni and of ?$\text{1}\text{6}$ for “CO-reduced” SrTiO₃:Ni single crystals, respectively. The electrical conductivity dependencies on P_o2 indicate that a triply ionized titanium interstitial and an oxygen vacancy model are applicable to Nidoped and “CO-reduced” Ni-doped SrTiO₃ single crystals, respectively. The small polaron conduction was suggested on “CO-reduced” Ni-doped SrTiO₃ single crystal from the temperature dependence of conductivity.     

The hypernucleus 12ΛB and the decay process 12ΛB → π− + 3α

The characteristics of the decay sequences ${}^{12}{}_{\mathrm{\Lambda }}\text{B}\text{→ π}{}^{\mathrm{?}}\text{+}{}^{12}\text{C}{}^1\text{,}{}^{12}\text{C}{}^1\text{→ 3α}$ are discussed for the two sharp levels of ¹²C¹ at excitation energies of 12.7 MeV (J_f = 1⁺, T = 0) and 16.11 MeV (J_f = 2⁺, T = 1), which are observed prominently in this decay process. The transition rates for these processes and the angular correlations in the final four-particle state αααπ^? are discussed quantitatively, using the intermediate coupling model for both the ¹²_ΛB and ¹²C¹ systems, as a function of the ¹²_ΛB spin J. Three distinct tests are proposed, which are sensitive to the spin J for ground-state ¹²_ΛB, and which have been used by the European K^? Collaboration to deduce that J = 1 for ¹²_ΛB. The implications of this conclusion for the ΛN and ΛNN interactions are briefly discussed.     

Simultaneous cw laser oscillation on transitions of Cd+ and I+ in a hollow-cathode He-CdI2 discharge

Continuous-wave laser oscillation has been obtained on four transitions of Cd⁺ and eleven transitions of I⁺ using a hollow-cathode He-CdI₂ discharge as active medium. Laser output characteristics are similar for both Cd⁺ and I⁺ transitions, and simultaneous cw oscillation has been achieved at wavelengths ranging from blue (4416 Å Cd⁺) through green $\text{(}\text{5337}\text{5378}$ Å Cd⁺, 5407 Å I⁺), yellow $\text{(}\text{5678}\text{5761}$ Å I⁺) and orange (6127 Å I⁺) to red (6585 Å I⁺).     

The ionic distribution in Mn2+ and Zn2+ β″-alumina

The ionic distributions in Mn²⁺ and Zn²⁺ β″-alumina (idealized formula: $\text{X}{}_{\mathrm{<mtext>5</mtext><mtext>6</mtext>}}\text{Mg}{}_{\mathrm{<mtext>2</mtext><mtext>3</mtext>}}\text{Al}{}_{\mathrm{<mtext>31</mtext><mtext>3</mtext>}}\text{O}{}_{17}\text{;}\text{X}\text{=}\text{Mn}\text{and}\text{Zn}\text{)}$ at 296 K are reported from single-crystal X-ray diffraction studies. Mn²⁺ β″-alumina exhibits the shortest c-axis found so far in any divalent β″-alumina: 33.141(3) Å;Zn²⁺ β″-alumina, which involves the smallest divalent ion studied in the frame-work, has a considerably longer c-axis: 33.517(3) Å. Both compounds show clear evidence of short-range correlation effects in the X²⁺ ion arrangement by way of departures from the centrosymmetric space-group $\text{R}\text{3}\text{m}$ of the β″-skeleton. Both 6c end-sites and 9d mO-sites ($\text{R}\text{3}\text{m}$ notation) are occupied for both ion-types, a significantly larger occupation (60% compared to 28% of the total) lying at or near the 9d mid-oxygen sites in Mn²⁺ β″-alumina compared to Zn²⁺ β″-alumina. Disorder is also found in the column-oxygen O(5) in both cases; the O(5) displacement from the 3b site in Mn²⁺ β″-alumina (0.59 Å) is the largest found in any divalent β″-alumina. The formula-unit/cell-layer, deduced on the basis of the amounts of X²⁺ ions refined, and assuming charge compensation through Mg substitution alone, are: Mn_0.79Mg_0.57Al_10.43O₁₇ and Zn_0.87Mg_0.74Al_10.26O₁₇.     

A study of some resonances in the 54Fe(p, γ)55Co reaction

Excitation functions for the ⁵⁴Fe(p, γ)⁵⁵Co reaction have been recorded in the energy region E_p = 1100–1760 keV. The decay schemes and branching ratios of ten resonances have been investigated. Angular distributions of primary γ-rays have been measured for three resonances to establish resonance spins. Resonance strengths for six resonances and gamma widths for three resonances have been determined. The isobaric analogues of the ground ($\text{J}{}^{\mathrm{\pi }}\text{=}\text{7}\text{2}{}^{\mathrm{?}}\text{)}\text{and}\text{1919}\text{keV}$$\text{J}{}^{\mathrm{\pi }}\text{=}\text{3}\text{2}$^?) states of the parent nucleus ⁵⁵Fe have been identified at 4722 and 6712 keV respectively in ⁵⁵Co. The Coulomb displacement energies of the observed analogue pairs (0–4722 keV) and (1919–6712 keV) have been obtained. The strengths of the possible analogue-antianalogue transitions for the proton capture state at E_p = 1679 keV have also been determined.     

V4+ in SrTiO3: A Jahn-Teller impurity

EPR results of V⁴⁺, with $\text{S =}\text{1}\text{2}$, in SrTiO₃ are reported. The tetragonal local symmetry of the impurity ion is related to strong T_2g × ?_g coupling as evidenced by intensity variations in the presence of stress. At 4.2 K the V⁴⁺ EPR behaviour is related to the intrinsic local strain in SrTiO₃.     

Infrared electronic transitions of Eu+3 in GdAlO3

Infrared ⁷F_O → ⁷F_J electronic transitions are reported for Eu⁺³ in GdAlO₃. The low symmetry of the crystalline field allows the observation, for the first time, of transitions with J = 3, 4, 5 and 6. The spectra are explained by means of a crystal-field model where a C_s term is added as a perturbation to the cubic field in order to take into account the lattice distortion. This model predicts energy levels which are in good agreement with the experimental data.     

Effects of Eu3+  Fe3+ exchange interaction on the spin Hamiltonian parameters of Fe3+ in EuGaG

The anisotropic exchange $\text{1}\text{3}\text{a}{}_{\mathrm{\mu \nu }}\text{Y}{}_{\mathrm{\mu \nu }}\text{(L}{}_{\mathrm{<mtext>Eu</mtext>}}\text{)S}{}_{\mathrm{<mtext>Eu</mtext>}}\text{· S}{}_{\mathrm{<mtext>Fe</mtext>}}\text{(0 < μ ? 6)}$ is incorporated with the isotropic exchange ?2 a₀₀S_Eu · S_Fe to interpret the observed spin-Hamiltonian parameters g and D of Fe³⁺ doped into EuGaG. Calculations from the observed g shifts yield a value of a₀₀ equal to 0.01 K. In order to explain the observed D shift, it is concluded that the spherical harmonics Y_μν(L_Eu) with μ > 2 are of dominant importance.     

The emission spectra of H35Cl+, H37Cl+, D35Cl+, and D37Cl+ in the region 2700–4100 Å

The $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}\text{-X}{}^2\text{Π}$ emission spectrum of HCl⁺ has been measured and analyzed for four isotopic combinations. These analyses extend previous work and provide rotational constants for the v = 0–2 levels of the ground state and for the v = 0–9 levels of the excited state. RKR potentials have been determined for both states, although the upper state could not be fitted precisely to such a model. Calculated relative intensities based on these potentials demonstrated that the electronic transition moment must change rapidly with lower state vibrational quantum number. Although considerable caution should be exercised in applying the concept of equilibrium constants to the $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}$ state, the following are the best estimates of these constants (in cm^?1) for the $\text{X}{}^2\text{Π}$ state of H³⁵Cl⁺: B_e = 9.9406, ω_e = 2673.7, A_e = ? 643.7, and $\text{r}{}_{\mathrm{e}}\text{= 1.315}\text{A}\text{?}$. For the $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}$ state of H³⁵Cl: T_e = 28 628.08, B_e ～ 7.505, ω_e ～ 1606.5, and $\text{r}{}_{\mathrm{e}}\text{= 1.514}\text{A}\text{?}$.