NMR hyperfine spectrum of 143Nd in ferromagnetic cubic intermetallic NdAl2

The hyperfine spectrum of ¹⁴³Nd in NdAl₂ measured at T = 1.4 K provides values of ∣a_t∣ = 786 ± 0.5 MHz and ∣P_t∣ = 3.25 ± 0.03 MHz. The latter value is in agreement with the expected calculated value obtained from the 4f ground state wave function in a crystal field plus molecular field model, which may be deduced from inelastic neutron scattering experiments combined with susceptibility measurements, or from polarized neutron diffraction experiments. It is shown that the 4f electronic moment can be directly obtained from zero field NMR with good accuracy.     

Index of authors and papers

It is shown that a hydrodynamic matrix describing the coupling between n variables that are even under time reversal and m variables that are odd has in the dissipation-free limit 2n or 2m (whichever is smaller) purely imaginary roots and ∣n ? m∣ roots that are zero.     

Microwave cyclotron resonance of hot electrons in p-type GaSb

A microwave photocreated cyclotron resonance signal is observed in p-type GaSb in the temperature range 1–30 K. Circular polarization and other measurements identify the carriers as electrons in the (000) conduction band. The problem of a surface effect on the measured peak position, reported for the first time is avoided by bulk carrier creation. An exponential loss of signal intensity at 27 K is explained by the theory of background plasma effects. The measured ωτ of 1·5–4 yields an electron collision time of τ ～ 10^?11 sec. The scattering mechanism at liquid helium temperatures is identified as being partly due to neutral defect acceptor scattering of hot electrons, with an unidentified residual scattering process. The electron polaron effective mass is measured to be (m *(polaron)/m₀) = 0·0412 ± 0·0012 for hot electrons with an average energy of ～ 14 MeV and is isotropic within 1 per cent. When corrections for conduction-band non-parabolicity and hot polaron effects are applied, the band-edge free electron mass is calculated to be (m₀*(free)/m₀) = 0·0396 ± 0·0021 (±5·2 per cent).     

Air broadening of the hydrogen halides—I. N2-broadening and shifting in the HCl fundamental

The widths and shifts of the fundamental band vibration-rotation lines of HCl under N₂ pressure have been calculated using the resolvent operator formalism of Kolb-Griem-Baranger. Time-development operator matrix elements are evaluated in a manner that is similar to the linked-cluster techniques, except that all anisotropic terms that are bilinear and second order are accounted for, as well as isotropic effects to all orders. The calculations include the use of a parabolic trajectory model and explicit velocity averaging. It is found that the major contributions to the linewidths arise from dipole-quadrupole, quadrupole-quadrupole and vibrationally dependent isotropic dispersion forces. Due to the reduction of the dipole-quadrupole and quadrupole-quadrupole contributions with increasing ¦m¦, the widths decrease with a leveling off at high ¦m¦, where dispersion forces dominate. A comparison between calculated and measured widths and shifts, for a range of temperatures from T=163 to 295 K, shows good overall agreement.     

Magnetic moment of 57Ni

An extra neutron added to a doubly magic nuclear core should give a nuclear magnetic moment, μ, in close agreement with the Schmidt value. However, the magnetic moment of ⁵⁷Ni, measured through nuclear alignment at 3–20 mK, is equal to ∣μ∣ = 0.88±0.06 μ_N which is only 45% of the Schmidt value. Comparison with several nuclear structure calculations is made.     

Determination of the longitudinal and the transverse part in π+ electroproduction

We report on an experiment where the different contributions from the transverse and longitudinal polarization of the virtual photon are measured separately for the reaction e^?p→e^?π⁺n. The data taken above the resonance region at small ∣t∣ values in the q² range of ∣q²∣ < 0.5 GeV² show a clear dominance of the longitudinal part of the cross section and are well described by a generalized Born-term model. Using this model the electromagnetic form factor of the pion is determined. At q² = ?0.35 GeV² one gets F_π = 0.598 ± 0.021.     

Accumulation layer and interface effects in doped nonabrupt GaAs/AlxGa1 − xAs single quantum wells

The electron energy levels in doped nonabrupt GaAs/Al_xGa_1 − xAs single quantum wells 100 Å wide are calculated. Interface widths varying from zero to four GaAs unit cells are taken into account, as well as band bendings of 0–90 meV. It is shown that interface effects on the energy levels are important and sensitive to the level of doping. When interfaces of only two GaAs unit cells and a band bending of 40 meV are considered, the ground-state (first excited state) energy level shifts toward energies as high as 4 meV (20 meV).     

Oscillator strengths from line absorption in a high-temperature furnace—II. The (0,0) band of the B2σ+—X2σ+ transition in CN*

Quantitative high-resolution absorption spectroscopy was applied to the (0,0) violet band of CN. The CN radical was prepared in a furnace at 1421°K containing pure cyanogen gas. Since the calculated CN concentration is dependent on the controversial CN heat of formation, only the relationship, f_υ = 6·84 X 10^-3exp (0·354δ), where f_υ is the excess over the initially assumed ΔH⁰_f(CN) = 100·8 kcal/mole, could be directly determined in this study with an estimated error in f_υ of ±20%. For δ = 0, our f_υ is a factor of 4·8 smaller than an average value of 0·033±0· derived from other measurements. If this latter value of f_υ is assumed, our relationship yields ΔH⁰_f(CN) = 105·3±1· kcal/mole or D₀(CN) = 7·66±0·05 eV. The rotational temperature and line widths for this band were also measured.     

Comparative analysis of multi-wave mixing and measurements of the higher-order nonlinearities in resonant media

The features of degenerate multi-wave mixing in resonant media (dye solutions) have been studied theoretically and experimentally. It has been demonstrated that thermal nonlinearity due to the induced absorption from the excited level contributes significantly to the efficiency of four-wave mixing, but results in lower efficiency of higher-order interactions. The measurement results obtained for the energy efficiency of four-, six- and eight-wave mixing enable calculations of the third-, fifth- and seventh-order nonlinear optical susceptibilities, respectively. Experimentally, the method proposed for measurements of the higher-order nonlinearities has been realized with the use of the multi-wave mixing at second harmonic λ = 532 nm of monopulse YAG:Nd³⁺ laser radiation in a Rhodamine 6G dye solution. The ratios ∣χ⁽⁵⁾∣/∣χ⁽³⁾∣ and ∣χ⁽⁷⁾∣/∣χ⁽⁵⁾∣ are determined to be of the order of 10⁻⁵ cm³/erg.     

Pressure broadening and shifting parameters for the spectral lines in the fundamental vibration-rotation bands of HBr and HI in mixtures with rare gases

We report measurements of the line broadening and shifting coefficients in the (1 ← 0) fundamental absorption bands of the HBr and HI molecules in mixtures with rare gases He, Ne, Ar, Kr, and Xe. Comparison is given with the published data on other HHal-Rg systems. The measured line shifts are separated into terms symmetric and asymmetric in the line number m. The magnitudes of the symmetric shifts change in a regular manner in the series of rare gases and reach perturber-specific asymptotic values at higher ∣m∣. It is found that the asymptotic values of the symmetric line shifts linearly correlate with the respective C₆ potential energy constants and that the slopes of these correlations are proportional to the vibrational ground state dipole moments squared of the hydrogen halide molecules.     

Experimental investigation of reflection coefficients for lossy liquid-solid-liquid systems

The reflection coefficient for a bounded ultrasonic beam incident on a liquid-solid-liquid system (LSL) is studied. Systematic measurements were carried out to investigate the variations of the amplitude of the reflection modulus ∣R_LSL∣ with incident angle and parameter Fd (frequency-thickness of the plate). The experimental plots confirm the theoretical works of Claeys et al¹ and Bogy and Gracewski². It is shown that the attenuation of the media has a great influence on the variations of this coefficient as has been already mentioned in the literature, for liquid-solid configurations.     

Neutron-proton elastic scattering from 10 to 70 GeV/c

The neutron-proton elastic differential cross section has been measured for incident momenta between 10 and 70 GeV/c and for values of the momentum transfer squared between 0.1 and 2.8 (GeV/c)². The forward peak and the break at about ∣t∣ = 1 (GeV/c)² are very similar to corresponding pp data.     

Optical absorption edge in SnS

Optical absorption in single crystals of tin sulfide has been studied at many temperatures between 100 and 300 °K, in the wavelength range 2·2–0·8 μ. From the interference fringe patterns the absorption coefficient, reflection coefficient and index of refraction as a function of wavelength were determined for two light polarizations (ε∥a and ε∥b). From an analysis of the data, indirect band gaps of 1·142 and 1·095 eV were found for the two directions of polarization. Also it was found that the phonon assisted transitions required the participation of two phonons at different energy thresholds with energies 0·033 or 0·038 eV and 0·082 or 0·113 eV, with reference to the two axis. The temperature dependence of the indirect band gap for each direction of light polarization is linear with a slope ?4·05 × 10^?3eV and ?4·37 × 10^?3 eV respectively.     

Stark broadening parameters of Si I,Si II and Si III lines

Spectral lines emited by first three ionisation species of silicon were studyed in a wide range of plasma parameters. The silicon was present as an impurity in the argon plasma created in an electromagneticT tube. Four various condenser bank energies give the plasma in a range of temperatures 8700 to 16400°K and electron concentrations 2.95·10¹⁷ cm^?3to 5.6·10¹⁷ cm^?3. Measured line widths and shifts were compared with theories of Griem [1, 2] and Sahal Brechet [3, 10]. The agreement is reasonably good, the measured values are in general smaller than calculated ones.     

Hydrogenic donors in doping superlattices: A model calculation

The binding energy and wavefunction of a hydrogenic donor in an effective potential ν(z) = ∣e∣?∣z∣ in a semicondusctor is calculated variationally as a function of the effective electric field ?. Such a potential represents the limit of a doping superlattice in which the donor doping layer is very thin, and it allows the properties of shallow donor states for which the effective potential varies substantially across the wavefunction to be discussed. It is found that substantial variations of the binding energy and wavefunction result for fields which are readily realizable experimentally.     

The effects of nonlinear couplings and external magnetic field on the thermal entanglement in a two-spin-qutrit system

We investigate the effects of nonlinear couplings and external magnetic field on the thermal entanglement in a two-spin-qutrit system by applying the concept of negativity. It is found that the nonlinear couplings favor the thermal entanglement creating. Only when the nonlinear couplings ∣K∣ are larger than a certain critical value does the entanglement exist. The dependence of the thermal entanglement in this system on the magnetic field and temperature is also presented. The critical magnetic field increases with the increasing nonlinear couplings constant ∣K∣. And for a fixed nonlinear couplings constant, the critical temperature is independent of the magnetic field B.     

The phonon spectra of trigonal selenium at 77 and 298°K

Phonon dispersion curves in the principal symmetry directions of trigonal selenium single crystals have been measured by neutron inelastic scattering, using a three-axis spectrometer. The acoustic modes and the three lowest-lying optical modes (q = 0 energy transfers of 13·5 and 18·5 meV) have been measured at 77°K. The acoustic modes have also been measured at 298°K. There are small frequency shifts between the two temperatures, but the general agreement between the acoustic mode frequencies measured at the two temperatures is excellent. The data have been fit by a force constant model which assumes completely general harmonic forces between the first two neighbors in the same covalently bonded chain and axially symmetric forces derived from a potential of the form V = ? Ar^?m + Br^?n between all other atoms out to an interatomic distance of 6·5 . Fits were carried out with (m; n) = (3; 5) and (6; 12). For the former, the best values of A and B correspond to a Van der Waals equilibrium distance of 3·9and a minimum energy at this distance of 1·5 × 10^?13 ergs (about 2 kcal/mol). There are, however, significant discrepancies between the calculated and observed dispersion curves which indicate that a more sophisticated force model is needed.     

Der Zerfall des Co60m und Zr90m

Co^60m was produced by the reaction Co⁵⁹ (n,γ) Co^60m ; its decay has been investigated by scintillation spectrometers. The half-period has been remeasured yielding a value ofT _1/2=(10·35 ±0·20) min. The isomeric decay mainly leads to the Co⁶⁰ ground state by a (58·6±0·6) keV transition. TheK-conversion coefficientα _K= 41±3 and the total conversion coefficientα=47±3 indicate the transition to beM3 and the spin of Co^60m to be 2⁺. Further Co^60m decays by beta transitions to Ni⁶⁰. The beta component (8·6±1·2)·10^?3%, log ft=7·32 leading to a (2·16±0·02) MeV level has been measured for the first time. A second component (0·24±0·03)%, log ft=7·23 leads to the 1·33 MeV level. The 2·16 MeV level decays to the Ni⁶⁰ ground state mainly by a 0·83–1·33 MeV cascade, in a few cases by a direct transition. The spin of the 2·16 MeV level is 2⁺. Zr^90m was produced by the reaction Zr⁹⁰ (n,n′) Zr^90m . The half-period was measured yielding a value ofT _1/2=(0·83±0·03) sec. Zr^90m decays in the following way: (77±5) % by a direct (2·31±0·02) MeV —E 5 transition to the Zr ground state and (23±5)% by a (132·5±1·5) keV-(2·18±0·03) MeV cascade detected for the first time in the isomeric decay. TheK-conversion coefficient of the 132·5 keV transition isα _k=(2·2±0·3) indicating this transition to beE3 and the spin of the 2·18 MeV level to be 2⁺. The Zr^90m -decay sheme is in accordance with the level sequence of Zr⁹⁰ as measured in the Nb⁹⁰ decay.     

Effect of interband scattering on kinetic coefficients and estimates of the parameters of the band spectrum of Sb2Te3

It has been shown that uncertainties in the interpretation of experimental data on transport phenomena in Sb₂Te₃ are resolved in the two-band model with the consistent inclusion of the interband hole scattering. The performed calculation is in quantitative agreement with the experimental data in the temperature range from 77 to 400 K for the following parameters of the band spectrum: the effective mass of the density of states of light holes m _d1 ≈ 0.6m ₀ (where m ₀ is the free electron mass), the effective mass of the density of states of heavy holes m _d2 ≈ 1.8m ₀, and the energy gap between nonequivalent extrema of the valence band ΔE _v(T) ≈ 0.15–2.5 × 10^?4 T eV.     

On the transition moment of the CO2 40°1II-00°0 band near 7740 cm-1

Using intensity measurements on the CO₂ 40°1_II-00°0 band obtained by Valero and Boese, we have expanded the F(m)-factor for the parallel band by using the Herman-Wallis formula. We have calculated the transition moment and determined the coefficients in the expansion of F(m).