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1.
A simple sol–gel route was demonstrated for the synthesis of LiNb0.6Ti0.5O3 (M-phase) powder, using cheap and manageable starting materials at a relatively low temperature. The phase transitions in both chemical and solid-state processes were studied by X-ray diffraction (XRD) in detail. The results showed that in the sol–gel process the anatase TiO2 phase first appeared at 400 °C and then LiNbO3 solid solution (LiNbO3 ss) emerged at 500 °C. When calcined to 600 °C, the M-phase started to appear along with the decrease of TiO2 and LiNbO3 ss. Single M-phase could be formed at 700 °C, which is 300 °C lower than that by the traditional solid-state method. A plausible evolution mechanism of the as-synthesized powder in calcination was proposed. The produced powder has potential applications in microelectronics systems.  相似文献   

2.
Nano-sized amorphous Al2O3–2SiO2 powder was prepared by a sol–gel method coupled with azeotropic distillation. The structure of the powder was investigated by DTS, BET, TEM, FT-IR, TG-DTA and XRD, showing that n-butanol azeotropic distillation could effectively remove water from the aluminosilicate gels and prevent the formation of hard agglomerates in the drying process. The average particle diameter of the powder was about 70 nm. The largest BET specific surface area of the powder was 669 m2/g. To examine the alkali-activation reactivity of the powder, alkali-activation tests were performed with the powder reacting with sodium silicate solution. The synthetic powder was found to be highly reactive.  相似文献   

3.
Spherical Sb-doped SnO2 (ATO) nanoparticles were synthesized by the sol–gel route, employing SnCl4·5H2O and SbCl3 as precursors in an ethanol solution. The influences of the calcining temperature and calcining time on the crystallite size, crystallinity, lattice parameters, lattice distortion ratio and the resistivity of the ATO nanoparticles were synthetically investigated. The results suggested that the ATO nanoparticles were crystallized in a tetragonal cassiterite structure of SnO2 with a highly (1 1 0)-plane-preferred orientation. The calcining temperature had a dominating effect on the crystallite size, crystallinity, lattice distortion ratios and resistivity of the ATO. As the calcining temperature increased, the average crystallite size increased, the crystallinity was promoted accompanied by a decrease in the lattice distortion ratio and a corresponding decrease in the resistivity of the ATO. X-ray diffraction (XRD) and Fourier transform infrared spectrophotometer (FTIR) analysis revealed that Sb ions could not entirely supplant the Sn ions in the SnO2 lattice for a calcining time of less than 0.5 h, even at a calcining temperature of 1000 °C. The ATO nanoparticles calcined at 1000 °C for 3.0 h possessed the lowest resistivity of 10.18 Ω cm.  相似文献   

4.
We propose to analyse power law shear stress relaxation modulus observed at the sol–gel transition (SGT) in many gelling systems in terms of fractional calculus. We show that the critical gel (gel at SGT) can be associated to a single fractional element and the gel in the post-SGT state to a fractional Kelvin–Voigt model. In this case, it is possible to give a physical interpretation to the fractional derivative order. It is associated to the power law exponent of the shear modulus related to the fractal dimension of the critical gel. A preliminary experimental application to silica alkoxide-based systems is given.
Alain PontonEmail:
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5.
Tin dioxide is a useful n-type oxide semiconductor used in a variety of applications owing to its superior optical, electrical, and multifunctional properties. Here, we used a network of resorcinol–formaldehyde (RF) gel to synthesize mesoporous tin dioxide via a sol–gel process. The effects of various synthesis parameters on the morphology and mesoporosity of the obtained product were investigated, including aging time of the RF gel, tin-to-formaldehyde molar ratio, resorcinol-to-carbonate molar ratio, and the aging time of the tin/RF mixed gel. Our experimental results showed that the interaction between the network of the RF gel and tin-containing sol is a key factor that affected the structural strength of the porous network and the porosity of the final product. Through control of the interactions in the tin/RF mixed gel we obtained porous tin dioxide materials that could be effectively used to form large-surface area films with desirable mesoporous properties.  相似文献   

6.
A clean method for preparing layered double hydroxides (LDHs) has been developed, featured by using the hydroxides of two different metals as starting materials by atom-economic reaction. The reactions were carried out under hydrothermal conditions in either a high pressure autoclave or a microwave digester. The compositions, structural parameters and thermal behavior of the resulting LDHs are very similar to those of materials produced by using the separate nucleation and aging steps (SNAS) method. The major advantage of the new method is that no by-product is produced, so that filtration and washing processes are unnecessary. The consequent reduction in water consumption is beneficial to the environment.  相似文献   

7.
In this paper, the dynamics of piezo-actuated stick–slip micro-drives are studied experimentally and theoretically. First, the stick–slip-based force-generating test stand is introduced, and experimental results are presented. Then, a numerical model is formulated which explicitly includes the dynamics of normal and tangential properties of the contact areas in the frictional driving elements of the drive. The contact forces are simulated using the method of dimensionality reduction. We show that the experimentally observed behavior can be described without using any fitting parameters or assuming any generalized laws of friction if the explicit contact mechanics of the frictional contacts is taken into account. Furthermore, an even simpler model of the drive is developed to get a qualitative understanding of the system. It is employed to gain a new actuation method, which reduces the vibrations of the drive’s runner and therefore enhances its performance.  相似文献   

8.
This paper presents aeroelastic analyses of wind turbines, using the compressible flow Helicopter Multi-Block (HMB2) solver of Liverpool University, coupled with a Computational Structural Dynamics method. For this study, the MEXICO and NREL Phase VI wind turbines were employed. A static aeroelastic method was first employed for the analysis of the MEXICO blade and the effect of the torsional stiffness was studied at 10, 15 and 24 m/s axial wind speeds. The torsional deformations showed strong dependency on this parameter and the blade region from mid-span to the tip was the most susceptible to aeroelastic effects. The work progressed by studying both the static and dynamic response on the NREL wind turbine, where the nacelle and the tower were considered. Mean deflections between the static and dynamic methods showed consistency and, due to the structural properties of this blade, flapping modes were dominant. The dynamic aeroelastic method enabled an assessment of the effect of flapping on the blade loads, in conjunction with the effect of tower. Aeroelastic effects were found to be secondary for the MEXICO blade, but had a stronger effect on the larger NREL Phase VI blade.  相似文献   

9.
Sol–gel auto-ignition was used to prepare nano-scale magnesium aluminate spinel, using nitrate salts as an oxidizer and glycine–starch mixtures as the fuel. The glycine–starch mixture was varied to understand the effect of fuel mixing ratio on the structural characteristics of the resulting magnesium aluminate. The products were characterized by thermogravimetric-differential thermal analyses, Fourier-transform infrared spectroscopy, X-ray diffraction, Brunauer–Emmett–Teller surface area measurements, and transmission electron microscopy. The phase purity and crystallite size of the powder products depended on the fuel mixing ratio. The presence of starch in the fuel facilitated the preparation of pure nano-particles. To prepare nano-particles of uniform spherical morphology and diameter of <13 nm, the starch content should be optimized to avoid agglomeration.  相似文献   

10.
This article presents analytic solutions of energy release rates of a cracked laminate by using a global–local method. Deformations of a cracked laminate subjected to pure bending moments are analyzed and then a new mode partition equation is proposed. By using this partition equation, closed-form solutions of energy release rates GI and GII are derived by using a global method. For a cracked laminate subjected to axial forces and bending moments, a local method based on the crack-tip force model is used and the unknown coefficient is solved by combining the present analytic solutions for the bending moment loading case. Numerical results of the mode mixity predicted by the present closed-form formulations correlate well with those numerically calibrated on the basis of the singular field and crack-tip force models.  相似文献   

11.
12.
We investigate the impact of the inexact interpolation on the Eulerian–Lagrangian solution of the advection equation by combining numerical experiments and formal analysis. The simulations, respectively, using the Eulerian–Lagrangian method (ELM) and the upwind scheme are compared. The artificial resistance of the ELM is observed which is characterised by the higher free-surface elevation and the distorted turbulent properties at a smaller time step. Through analysis, we find that the abnormalities are caused by the fact the conventional linear interpolation does not adapt well to the nonlinear velocity distribution, which produces an advection computation error that increases with a decreasing time step. The phenomena are explained and an improved method ELM is proposed based on the illustrations and analysis. The new method combines the face-controlled interpolation and the adjustable sub time steps to skip the large computation error domain in the backtracking, and it is validated by the original test case.  相似文献   

13.
Dynamic fluid–solid interactions are widely found in chemical engineering, such as in particle-laden flows, which usually contain complex moving boundaries. The immersed boundary method (IBM) is a convenient approach to handle fluid–solid interactions with complex geometries. In this work, Uhlmann's direct-forcing IBM is improved and implemented on a supercomputer with CPU–GPU hybrid architecture. The direct-forcing IBM is modified as follows: the Poisson's equation for pressure is solved before evaluation of the body force, and the force is only distributed to the Cartesian grids inside the immersed boundary. A multidirect forcing scheme is used to evaluate the body force. These modifications result in a divergence-free flow field in the fluid domain and the no-slip boundary condition at the immersed boundary simultaneously. This method is implemented in an explicit finite-difference fractional-step scheme, and validated by 2D simulations of lid-driven cavity flow, Couette flow between two concentric cylinders and flow over a circular cylinder. Finally, the method is used to simulate the sedimentation of two circular particles in a channel. The results agree very well with previous experimental and numerical data, and are more accurate than the conventional direct-forcing method, especially in the vicinity of a moving boundary.  相似文献   

14.
In this work a velocity-dependent friction is introduced into a depth-averaged Savage–Hutter dynamical model for shallow granular flows. The process of granular material flowing along an inclined plane and then depositing on a horizontal plane is simulated. The surface profiles and evolution of various types of energy are investigated and compared when using the standard Coulomb-type friction versus velocity-dependent friction. Interestingly, there is a small difference between the two different types of friction.  相似文献   

15.
Electrical capacitance tomography (ECT) is a promising technique for multi-phase flow measurement due to its high speed, low cost and non-intrusive sensing. Image reconstruction for ECT is an inverse problem of finding the permittivity distribution of an object by measuring the electrical capacitances between sets of electrodes placed around its periphery. The conjugate gradient (CG) method is a popular image reconstruction method for ECT, in spite of its low convergence rate. In this paper, an advanced version of the CG method, the projected CG method, is used for image reconstruction of an ECT system. The solution space is projected into the Krylov subspace and the inverse problem is solved by the CG method in a low-dimensional specific subspace. Both static and dynamic experiments were carried out for gas–solid two-phase flows. The flow regimes are identified using the reconstructed images obtained with the projected CG method. The results obtained indicate that the projected CG method improves the quality of reconstructed images and dramatically reduces computation time, as compared to the traditional sensitivity, Landweber, and CG methods. Furthermore, the projected CG method was also used to estimate the important parameters of the pneumatic conveying process, such as the volume concentration, flow velocity and mass flow rate of the solid phase. Therefore, the projected CG method is considered suitable for online gas–solid two-phase flow measurement.  相似文献   

16.
An approach to calculate the natural frequencies of an elastic parallelepiped with different boundary conditions is proposed. The approach rationally combines the inverse-iteration method of successive approximations and the advanced Kantorovich–Vlasov method. The efficiency of the approach (the accuracy of the results and the number of approximating functions) is demonstrated against the Ritz method with different basis systems, including B-splines. The dependence of the lower frequencies of a three-dimensional cantilever beam on its cross-sectional dimensions is examined  相似文献   

17.
In this paper fluid–structure interaction simulations regarding a gust generator experiment are presented, which has been conducted in 2010 in the Transonic Wind Tunnel in Göttingen (DNW-TWG), Germany. The main objective of the experiment was the investigation of the dynamic response problem of an elastic wing model concerning an encountering generic gust induced by a gust generator. Fluid–structure simulations, using a finite element structural model and a computational fluid dynamics model based on time-accurate, Reynolds-averaged Navier–Stokes equations, are compared to the experiment to validate the numerical methodology. Comparisons include steady and unsteady deflections of the elastic wing and pressure distributions. Finally, the results of simulated transfer functions of the gust generator to the elastic wing are presented in comparison to the test data.  相似文献   

18.
The stability of partly liquid filled spacecraft with flexible attachment was investigated in this paper.Liquid sloshing dynamics was simplified as the spring–mass model, and flexible attachment was modeled as the linear shearing beam. The dynamic equations and Hamiltonian of the coupled spacecraft system were given by analyzing the rigid body, liquid fuel, and flexible appendage. Nonlinear stability conditions of the coupled spacecraft system were derived by computing the variation of Casimir function which was added to the Hamiltonian. The stable region of the parameter space was given and validated by numerical computation. Related results suggest that the change of inertia matrix, the length of flexible attachment,spacecraft spinning rate, and filled ratio of liquid fuel tank have strong influence on the stability of the spacecraft system.  相似文献   

19.
Ren  Hai-Peng  Zhou  Zi-Xuan  Grebogi  Celso 《Nonlinear dynamics》2020,102(2):771-784

Silicon crystal puller (SCP) is key equipment in silicon wafer manufacture, which is, in turn, the base material for the most currently used integrated circuit chips. With the development of the techniques, the demand for longer mono-silicon crystal rod with larger diameter is continuously increasing in order to reduce the manufacture time and the price of the wafer. This demand calls for larger SCP with an increasing height, though it causes serious swing phenomenon of the crystal seed. The strong swing of the seed increases the possibility of defects in the mono-silicon rod and the risk of mono-silicon growth failure. The main aim of this paper is to analyze the nonlinear dynamics in flexible shaft rotating–lifting (FSRL) system of the SCP. A mathematical model for the swing motion of the FSRL system is derived. The influence of relevant parameters, such as system damping, excitation amplitude, and rotation speed, on the stability and the responses of the system is analyzed. The stability of the equilibrium, bifurcation, and chaotic motion is demonstrated, which have been observed in practical situations. Melnikov method is used to derive the possible parameter region which leads to chaotic motion. Three routes to chaos are identified in the FSRL system, including period doubling, symmetry-breaking bifurcation, and crisis. The work in this paper analyzes and explains the complex dynamics in FSRL system of the SCP, which will be helpful for the designers in the designing process in order to avoid the swing phenomenon in the SCP.

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20.
The Herschel–Bulkley rheological parameters of an environmentally friendly drilling fluid formulated based on an Algerian bentonite and two polymers—hydroxyethyl cellulose and polyethylene glycol—have been optimized using a genetic algorithm. The effect of hydroxyethyl cellulose, temperature, pH and sodium chloride (NaCl) on the three-parameter Herschel-Bulkley model was also studied. The genetic algorithm technique provided improved rheological parameter characterization compared to the nonlinear regression, especially in the case of drilling fluids formulated with sodium chloride making it a better choice. Furthermore, the oscillatory test offered more reliable yield stress values. The rheological parameters were found to be very sensitive to different conditions. Yield stress and consistency index increased with increasing the hydroxyethyl cellulose concentration, reaching maximum at a temperature of 65 °C and decreased with decreasing pH and also when adding sodium chloride to the drilling fluid. The flow index changed inversely to yield stress and consistency index. The physical origins of these changes in rheological parameters were discussed and correlation between variation in rheological parameters and bentonite suspension properties were concluded. Based on these results, it is recommended to use the proposed formulation of drilling fluid at high temperature and when the formation of alkaline pH is encountered due to the gelation mechanism and to select the optimum concentration of NaCl to avoid degradation of the rheological parameters.
Graphical abstract ?
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