Positron annihilation in synthetic zeolites (II) magnetic quenching effect

Positron lifetime spectra were re-measured for a series of synthetic zeolites using a large time window of observation. Magnetic quenching experiments were also performed for the zeolites, and it has been confirmed that both the ₄ and the ₃ components are due to o-Ps. The annihilation rate of the third component, ₃, showed a good correlation with the size of the largest voids, which is similar to the correlation reported for other compounds. However the annihilation rate of the longest-lived component, ₄, showed a poor correlation with the void size. The ₃ component has thus been assigned to o-Ps in the regular voids of the zeolites, and the ₄ component to that escaped to inter-particle open spaces.     

Hydromagnetic laminar flow of a conducting fluid in an annulus in presence of a radial magnetic field

The object of the present paper is to study the MHD effects on the laminar flow of a viscous, incompressible and conducting fluid in an annulus with arbitrary time-varying pressure gradient and arbitrary initial velocity in presence of a radial magnetic field. Using finite Hankel transform, solutions for both the unsteady and steady flows under different prescribed pressure gradients have been found out.Notation H a constant characterising the intensity of the magnetic field - p hydrostatic pressure - _e magnetic permeability - coefficient of viscosity - kinematic coefficient of voscosity - conductivity of the medium - density - a radius of the inner cylinder - b radius of the outer cylinder - parameter - s positive root - J (sr) Bessel's function of first kind of ordergl - Y (sr) Bessel's function of second kind of order     

Mean-Field Critical Behavior for the Contact Process

The contact process is a model of spread of an infectious disease. Combining with the result of ref. 1, we prove that the critical exponents take on the mean-field values for sufficiently high dimensional nearest-neighbor models and for sufficiently spread-out models with d>4:()– _c as _c and ()( _c–)^–1 as _c, where () and () are the spread probability and the susceptibility of the infection respectively, and _c is the critical infection rate. Our results imply that the upper critical dimension for the contact process is at most 4.     

Analysis of the order parameter for uniform nearest particle system

The uniform nearest particle system (UNPS) is studied, which is a continuoustime Markov process with state space . The rigorous upper bound ^(mf) = ( – 1)/ for the order parameter ₂, is given by the correlation identity and the FKG inequality. Then an improvement of this bound ^(mf) is shown in a similar fashion; C( – 1)/|log( – 1) for >1. Recently, Mountford proved that the critical value _c=1. Combining his result and our improved bound implies that if the critical exponent exists, it is strictly greater than the mean-field value 1 in the weak sense.     

Tunable UV radiation at short wavelengths (188–240 nm) generated by sum-frequency mixing in lithium borate

Sum-frequency mixing (₃=₁+₂) of UV laser radiation (₁=266 nm and 213 nm) and tunable coherent infrared light (₂=1.2–2.6 m) in lithium borate (LBO) generates radiation at short wavelengths (₃=188–242 nm). The UV radiation at ₁ is produced by the fourth and fifth harmonic of a pulsed Nd-YAG laser. The infrared light is generated with an optical parametric oscillator of beta barium borate. The phase-matching angle is measured as function of ₃ and compared with calculated values. For UV laser radiation at shorter wavelengths (173 nm₁213 nm) the calculations predict an extension of the tuning range of the sum-frequency generated at ₃ to wavelengths as short as the LBO transmission cutoff at 160 nm.     

Geometry and combinatorics of Julia sets of real quadratic maps

For real a correspondence is made between the Julia setB forz(z–)², in the hyperbolic case, and the set of-chains±(±(±..., with the aid of Cremer's theorem. It is shown how a number of features ofB can be understood in terms of-chains. The structure ofB is determined by certain equivalence classes of-chains, fixed by orders of visitation of certain real cycles; and the bifurcation history of a given cycle can be conveniently computed via the combinatorics of-chains. The functional equations obeyed by attractive cycles are investigated, and their relation to-chains is given. The first cascade of period-doubling bifurcations is described from the point of view of the associated Julia sets and-chains. Certain Julia sets associated with the Feigenbaum function and some theorems of Lanford are discussed.Supported by NSF grant No. MCS-8104862.Supported by NSF grant No. MCS-8203325.     

The ground state energy of Sdhrödinger operators

We studye()=inf spec(-+V) and examine whene()<0 for all 0. We prove thatc ²e()–d ² for suitableV and all small ||.Research partially funded under NSF grant number DMS-9101716.     

On the maximization of the central gravitational red-shift of a schwarzschild sphere with a given surface gravitational red-shift

Following Bondi static, spherically symmetric equilibrium configurations with a core and an envelope have been considered. It has been shown that for any configurations with nonnegative pressure and density and with a surface red-shiftz _s 4.77 arbitrarily large central red-shiftsz _c are possible in the limiting case of arbitrarily large radius. The effects of imposition of further constraints in the form of a real speed of sound not exceeding the speed of light are also examined. It is seen that for a given limiting sound-to-light-speed ratio . (i) There exists a limiting surface red-shiftz _s() 1.71. (ii) A configuration withz _s >z _s() is not possible, (iii) A configuration withz _s=z _s() has a unique and finitez _c=z _c(). (iv) Forz _s<z _s() arbitrarily large central red-shifts can be obtained for configurations with arbitrarily large radii.     

Stimulated IR- and vacuum-UV emission following two-photon-excitation of molecular hydrogen using an ArF laser

Hydrogen molecules are excited by two 193 nm-photons [X¹ _g ⁺ E,F¹ _g ⁺ ;Q₀₂(1)] generated with a commerical oscillator-amplifier ArF laser. Stimulated emission is subsequently observed in the IR (=752.4 nm to 836.6 nm;E, FB) and in the VUV (=134.0 nm to 160.9 nm;BX) with a VUV conversion efficiency of 0.2%. The rotational fine-structure, the saturation behaviour, pump depletion as well as SRS-onset on and off two-photon resonance are investigated.     

Realization of holonomic constraints and freezing of high frequency degrees of freedom in the light of classical perturbation theory. Part II

As in Part I of this paper, we consider the problem of the energy exchanges between two subsystems, of which one is a system of harmonic oscillators, while the other one is any dynamical system ofn degrees of freedom. Such a problem is of interest both for the realization of holonomic constraints of classical mechanics, and for the freezing of the internal degrees of freedom in molecular collisions. The results of Part I, which referred to the particular case =1, are here extended to the more difficult case >1. For the rate of energy transfer we find exponential estimates of Nekhoroshev's type, namely of the form exp (_*/)^1/a , where is a positive real number giving the size of the involved frequencies, and _* anda are constants. For the particularly relevant constanta we find in generala=1/ however, in the particular case when the frequencies are equal (collision of identical molecules), we finda=1 independently of , as conjectured by Jeans in the year 1903.     

Study of the influence of iron and lanthanum oxides on the band structure of Pb(Zr,Ti) O3

The measurements of diffuse reflectance spectra in the range of 400; 2500 nm and of photoacoustic spectra in the range of 350; 800 nm were used for the study of the influence of iron (III) oxide and lathanum oxide additions on the band structure of polycrystalline lead zirconate — lead titanate solid solutions. The molar ratio of zirconium and titanium in the studied solid solutions was 60 40, and the concentrations of the dopants werex FeO_1.5, andy LaO_1.5, werex 0; 0·05 mol, andy 0; 0·10 mol, respectively. The diffuse reflectance spectra were expressed in terms of the Kubelka-Munk function values versus incident electromagnetic radiation energy. These dependences were decomposed into partial absorption bands using a computer. Transitions of charged carriers between energy levels or bands which differ mutually by the energy of 0·9, 1·2–1·3, 1·6, 1·65–1·7, 2·4–2·5, 2·75–2·8, 2·9–3·2, 3·4–3·8 eV, were identified. Their intensities depend on the concentration of Fe and/or on La in the Pb(Zr_0.60 Ti_0.40) solid solutions.The authors are very grateful to Mrs. Iva Havlasová, Vra Andrsová, Ing. Jan Netuka, and Mrs. Liana Karlíková from the first authors' institute, for their technical assistance.     

A relation between a.c. spectrum of ergodic Jacobi matrices and the spectra of periodic approximants

We study ergodic Jacobi matrices onl ²(Z), and prove a general theorem relating their a.c. spectrum to the spectra of periodic Jacobi matrices, that are obtained by cutting finite pieces from the ergodic potential and then repeating them. We apply this theorem to the almost Mathieu operator: (H _{, ,} u)(n)=u(n+1)+u(n–1)+ cos(2n+)u(n), and prove the existence of a.c. spectrum for sufficiently small , all irrational 's, and a.e. . Moreover, for 0<2 and (Lebesgue) a.e. pair , , we prove the explicit equality of measures: |_ac|=||=4 –2.Work partially supported by the US-Israel BSF     

Modified London model for the determination of λ and ζ in a high κ superconductor

We present a modified London model suggested by Brandt [1–3] which introduces a finite vortex core size appropriate for isotropic superconductors in which the average internal field is less than approximately (1/4)H _c2. TheSR lineshape resulting from this model possesses a distinctive shape due to the magnetic penetration depth and the vortex core diameter (approximately equal to twice the coherence length ). However, for a given lineshape, there is a large range of values of and which produce nearly the same lineshape. Lineshape smearing caused by disorder in the vortex lattice increases uncertainty in values for and . If well-determined values of either (T) or (T) are not available from another technique, both of them can be determined bySR measurements alone if runs in more than one applied field at the same temperature are fit with and as shared parameters. We also present our method of estimating the degree of disorder in the vortex lattice.     

The asymmetric contact process on a finite set

The contact process onZ has one phase transition; let _c be the critical value at which the transition occurs. Let _N be the extinction time of the contact process on {0,...,N}. Durrett and Liu (1988), Durrett and Schonmann (1988), and Durrett, Schonmann, and Tanaka (1989) have respectively proved that the subcritical, supercritical, and critical phases can be characterized using a large finite system (instead ofZ) in the following way. There are constants ₁() and ₂() such that if < _c , lim _{N N} /logN = 1/₁(); if > _c , lim _N log _N /N = ₂(); if = _c , lim _{N N} /N= and lim _{N N} /N ⁴=0 in probability. In this paper we consider the asymmetric contact process onZ when it has two distinct critical values _c1< _c2. The arguments of Durrett and Liu and of Durrett and Schonmann hold for < _c1 and > _c2. We show that for [ _c1< _c2), lim _{N N} /N=-1/, (where _i is an edge speed) and for = _c2, lim _N log _N /logN=2 in probability.     

Kac-Moody symmetry of generalized non-linear Schrödinger equations

The classical non-linear Schrödinger equation associated with a symmetric Lie algebra =km is known to possess a class of conserved quantities which from a realization of the algebrak []. The construction is now extended to provide a realization of the Kac-Moody algebrak[, ^–1] (with central extension). One can then define auxiliary quantities to obtain the full algebra [, ^–1]. This leads to the formal linearization of the system.     

The slow passage through a steady bifurcation: Delay and memory effects

We consider the following problem as a model for the slow passage through a steady bifurcation: dy/dt = (t) y – y³ +, where is a slowly increasing function oft given by= _i + t ( ⁱ,<0). Both and are small parameters. This problem is motivated by laser experiments as well as theoretical studies of laser problems. In addition, this equation is a typical amplitude equation for imperfect steady bifurcations with cubic nonlinearities. When=0, we have found that=0 is not the point where the bifurcation transition is observed. This transition appears at a value = ^j > 0. We call ^j the delay of the bifurcation transition. We study this delay as a function of ⁱ, the initial position of, and, the imperfection parameter. To this end, we propose an asymptotic study of this equation as 0, small but fixed. Our main objective is to describe this delay in terms of the relative magnitude of and. Since time-dependent imperfections are always present in experiments, we analyze in the second part of the paper the effect of a small-amplitude but time-periodic imperfection given by (t) = cos(t).     

Analyticity of scattering for the ϕ4 theory

We consider scattering for the equation (+m ²)+³=0 on four-dimensional Minkowski space. Form>0, one-to-one and onto wave operatorsW _± :HH are known to exist for all 0, whereH denotes the Hilbert space of finite-energy Cauchy data. We prove that the maps (,u)W _± (u) and (,u)(W _± )^–1 (u) are continuous from [0, )×H toH, and extend to real-analytic functions from an open neighborhood of {0}×H×{0}×H to the Hilbert spaceH _–1 of Cauchy data with Poincaré-invariant norm. Form=0, wave operatorsW _± are known to exist as diffeomorphisms ofH for all 0, where hereH denotes the Hilbert space of finite Einstein energy Cauchy data. In this case we prove that the maps (,u)(W _± ) (u) and (,u)(W _± )^–1 (u) extend to real-analytic functions from a neighborhood of [0, )×H×H toH.     

Parametric relaxation of spectra

We study the change of an quasienergy spectrum upon variation of the weight of a perturbation in the Floquet operatorF=F ₀e^–iV . Employing ideas from level dynamics and random matrix-theory we show that the distribution of nearest-neighbor spacings can display effectively irreversible behavior. Small deviations from equilibrium relax in a certain collision time which scales with the numberN of levels as _collN ^–3/2.     

Photometric and fluorimetric study of the acid-base behavior of 2,2′-diquinolyl and 2,2′,2″-terpyridyl

A photometric and fluorimetric study of the acid-base behavior of 2,2-diquinolyl and 2,2,2-terpyridyl was performed. In sulfuric acid medium, the doubly charged 2,2-diquinolynium ion undergoes the first dissociation atH ₀=0.20±0.09, as determined by fluorimetry (_ex=336 nm, _em=424 nm). Photometric titration is less accurate because of the overlapping of the absorption spectra. The second dissociation constant of 2,2-diquinolyl was determined by fluorimetric titration (_ex=336 nm, _em=420 nm), obtaining a value of 3.67±0.03. The triply charged 2,2,2-terpyridyl molecule was found to undergo the first dissociation atH ₀=–7.17±0.04, as determined by fluorimetric titration (_ex=316 nm, _em=350 nm), in aqueous sulfuric acid medium. Photometric titration (=335 nm) was performed in the presence of 6.5% ethanol because of the low solubility of the compound in water. In this ethanolicwater medium, a value of the dissociation constant atH ₀=–7.39±0.03 was calculated. The second dissociation constant was determined to be 2.81±0.12 by photometric titration at 285 nm, and values of 4.03±0.26 and 4.16±0.20 were found for the third dissociation constant by photometric titrations at 320 and 295 nm, in 10% ethanol, in close agreement with previously reported values. The fluorimetric titration profile obtained by exciting at 274 nm and measuring the fluorescence emission at 350 nm, in the zone betweenH ₀=–3 and pH=10, is complicated by the several equilibria involved.     

Low-temperature transport properties of UCu5

The electrical resistivity (T) and the thermal conductivity (T) have been measured for UCu₅ in the temperature range between 0.02 and 20 K. Two distinct anomalies in (T) are due to previously established phase transitions at approximately 15 and 1 K, respectively. They indicate considerable changes in the electronic structure of this compound, implying sizeable truncations of the Fermi surface with decreasing temperature at both transitions. In almost the entire covered temperature range the thermal conductivity is dominated by phonon contributions. Its temperature dependence is fairly well reproduced by a calculation considering phonon scattering by electrons and by point defects. At very low temperatures, asT approaches 0 K, the Wiedemann-Franz law _e L ₀ T, where _e is the electronic part of (T) andL ₀ is the Lorenz number, is almost perfectly fulfilled.