Quantum phase transitions in electronic systems

Quantum phase transitions occur at zero temperature when some non‐thermal control‐parameter like pressure or chemical composition is changed. They are driven by quantum rather than thermal fluctuations. In this review we first give a pedagogical introduction to quantum phase transitions and quantum critical behavior emphasizing similarities with and differences to classical thermal phase transitions. We then illustrate the general concepts by discussing a few examples of quantum phase transitions occurring in electronic systems. The ferromagnetic transition of itinerant electrons shows a very rich behavior since the magnetization couples to additional electronic soft modes which generates an effective long‐range interaction between the spin fluctuations. We then consider the influence of rare regions on quantum phase transitions in systems with quenched disorder, taking the antiferromagnetic transitions of itinerant electrons as a primary example. Finally we discuss some aspects of the metal‐insulator transition in the presence of quenched disorder and interactions.     

Quantum critical behavior of the cluster glass phase

In disordered itinerant magnets with arbitrary symmetry of the order parameter, the conventional quantum critical point between the ordered phase and the paramagnetic Fermi liquid (PMFL) is destroyed due to the formation of an intervening cluster glass (CG) phase. In this Letter, we discuss the quantum critical behavior at the CG-PMFL transition for systems with continuous symmetry. We show that fluctuations due to quantum Griffiths anomalies induce a first-order transition from the PMFL at T = 0, while at higher temperatures a conventional continuous transition is restored. This behavior is a generic consequence of enhanced non-Ohmic dissipation caused by a broad distribution of energy scales within any quantum Griffiths phase in itinerant systems.     

Disorder promotes ferromagnetism: rounding of the quantum phase transition in Sr(1-x)Ca(x)RuO3

The subtle interplay of randomness and quantum fluctuations at low temperatures gives rise to a plethora of unconventional phenomena in systems ranging from quantum magnets and correlated electron materials to ultracold atomic gases. Particularly strong disorder effects have been predicted to occur at zero-temperature quantum phase transitions. Here, we demonstrate that the composition-driven ferromagnetic-to-paramagnetic quantum phase transition in Sr(1-x)Ca(x)RuO3 is completely destroyed by the disorder introduced via the different ionic radii of the randomly distributed Sr and Ca ions. Using a magneto-optical technique, we map the magnetic phase diagram in the composition-temperature space. We find that the ferromagnetic phase is significantly extended by the disorder and develops a pronounced tail over a broad range of the composition x. These findings are explained by a microscopic model of smeared quantum phase transitions in itinerant magnets. Moreover, our theoretical study implies that correlated disorder is even more powerful in promoting ferromagnetism than random disorder.     

Coexistence of ferromagnetism and superconductivity close to a quantum phase transition: the Heisenberg- to Ising-type crossover

A microscopic mean-field theory of the phase coexistence between ferromagnetism and superconductivity in the weakly ferromagnetic itinerant electron system is constructed, while incorporating a realistic mechanism for superconducting pairing due to the exchange of critical spin fluctuations. The self-consistent solution of the resulting equations determines the superconducting transition temperature which is shown to depend strongly on the exchange splitting. The effect of phase crossover from isotropic (Heisenberg-like) to uniaxial (Ising-like) spin fluctuations near the quantum phase transition is analyzed and the generic phase diagram is obtained. This scenario is then applied to the case of itinerant ferromagnet ZrZn2, which sheds light on the proposed phase diagram of this compound. A possible explanation of superconductivity in UGe2 is also discussed.     

New universality class of quantum criticality in Ce- and Yb-based heavy fermions

A new universality class of quantum criticality emerging in itinerant electron systems with strong local electron correlations is discussed. The quantum criticality of a Ce- or Yb-valence transition gives us a unified explanation for unconventional criticality commonly observed in heavy fermion metals such as YbRh(2)Si(2), β-YbAlB(4), YbCu(5-x)Al(x), and CeIrIn(5). The key origin is due to the locality of the critical valence fluctuation mode emerging near the quantum critical end point of the first-order valence transition, which is caused by strong electron correlations for f electrons. The wider relevance of this new criticality and important future measurements to uncover its origin are also discussed.     

Tricritical point and wing structure in the itinerant ferromagnet UGe₂

Precise resistivity measurements on the ferromagnetic superconductor UGe2 under pressure p and magnetic field H reveal a previously unobserved change of the anomaly at the Curie temperature. Therefore, the tricritical point (TCP) where the paramagnetic-to-ferromagnetic transition changes from a second order to a first order transition is located in the p-T phase diagram. Moreover, the evolution of the TCP can be followed under the magnetic field in the same way. It is the first report of the boundary of the first order plane which appears in the p-T-H phase diagram of weak itinerant ferromagnets. This line of critical points starts from the TCP and will terminate at a quantum critical point. These measurements provide the first estimation of the location of the quantum critical point in the p-H plane and will inspire similar studies of the other weak itinerant ferromagnets.     

Phase diagram of the random Heisenberg antiferromagnetic spin-1 chain

We present a new perturbative real space renormalization group (RG) to study random quantum spin chains and other one-dimensional disordered quantum systems. The method overcomes problems of the original approach which fails for quantum random chains with spins larger than S=1/2. Since it works even for weak disorder, we are able to obtain the zero temperature phase diagram of the random antiferromagnetic Heisenberg spin-1 chain as a function of disorder. We find a random singlet phase for strong disorder. As the disorder decreases, the system shows a crossover from a Griffiths to a disordered Haldane phase.     

Localization in a quantum spin Hall system

The localization problem of electronic states in a two-dimensional quantum spin Hall system (that is, a symplectic ensemble with topological term) is studied by the transfer matrix method. The phase diagram in the plane of energy and disorder strength is exposed, and demonstrates "levitation" and "pair annihilation" of the domains of extended states analogous to that of the integer quantum Hall system. The critical exponent nu for the divergence of the localization length is estimated as nu congruent with 1.6, which is distinct from both exponents pertaining to the conventional symplectic and the unitary quantum Hall systems. Our analysis strongly suggests a different universality class related to the topology of the pertinent system.     

Spin dynamics in (III,Mn)V ferromagnetic semiconductors: the role of correlations

We address the role of correlations between spin and charge degrees of freedom on the dynamical properties of ferromagnetic systems governed by the magnetic exchange interaction between itinerant and localized spins. For this we introduce a general theory that treats quantum fluctuations beyond the random phase approximation based on a correlation expansion of the Green's function equations of motion. We calculate the spin susceptibility, spin-wave excitation spectrum, and magnetization precession damping. We find that correlations strongly affect the magnitude and carrier concentration dependence of the spin stiffness and magnetization Gilbert damping.     

Reentrant hidden order at a metamagnetic quantum critical end point

Magnetization measurements of URu2Si2 in pulsed magnetic fields of 44 T reveal that the hidden order phase is destroyed before appearing in the form of a reentrant phase between approximately 36 and 39 T. Evidence for conventional itinerant electron metamagnetism at higher temperatures suggests that the reentrant phase is created in the vicinity of a quantum critical end point.     

Quantum phase transition in the two-band hubbard model

The interaction between itinerant and Mott localized electronic states in strongly correlated materials is studied within dynamical mean field theory in combination with the numerical renormalization group method. A novel nonmagnetic zero temperature quantum phase transition is found in the bad-metallic orbital-selective Mott phase of the two-band Hubbard model, for values of the Hund's exchange which are relevant to typical transition metal oxides.     

Random field effects in field-driven quantum critical points

We investigate the role of disorder for field-driven quantum phase transitions of metallic antiferromagnets. For systems with sufficiently low symmetry, the combination of a uniform external field and non-magnetic impurities leads effectively to a random magnetic field which strongly modifies the behavior close to the critical point. Using perturbative renormalization group, we investigate in which regime of the phase diagram the disorder affects critical properties. In heavy fermion systems where even weak disorder can lead to strong fluctuations of the local Kondo temperature, the random field effects are especially pronounced. We study possible manifestation of random field effects in experiments and discuss in this light neutron scattering results for the field driven quantum phase transition in CeCu_5.8Au_0.2.     

Criticality in inhomogeneous magnetic systems: application to quantum ferromagnets

We consider a phi4 theory with a position-dependent distance from the critical point. One realization of this model is a classical ferromagnet subject to nonuniform mechanical stress. We find a sharp phase transition where the envelope of the local magnetization vanishes uniformly. The first-order transition in a quantum ferromagnet also remains sharp. The universal mechanism leading to a tricritical point in an itinerant quantum ferromagnet is suppressed, and in principle, one can recover a quantum critical point with mean-field exponents. Observable consequences of these results are discussed.     

Phase bifurcation and quantum fluctuations in Sr3Ru2O7

The bilayer ruthenate Sr3Ru2O7 has been cited as a textbook example of itinerant metamagnetic quantum criticality. However, recent studies of the ultrapure system have revealed striking anomalies in magnetism and transport in the vicinity of the quantum critical point. Drawing on fresh experimental data, we show that the complex phase behavior reported here can be fully accommodated within the framework of a simple Landau theory. We discuss the potential physical mechanisms that underpin the phenomenology, and assess the capacity of the ruthenate system to realize quantum tricritial behavior.     

Quantum critical behavior of clean itinerant ferromagnets

We consider the quantum ferromagnetic transition at zero temperature in clean itinerant electron systems. We find that the Landau-Ginzburg-Wilson order parameter field theory breaks down since the electron-electron interaction leads to singular coupling constants in the Landau- Ginzburg-Wilson functional. These couplings generate an effective long-range interaction between the spin or order parameter fluctuations of the form 1 <r ² d?1, with d the spatial dimension. This leads to unusual scaling behavior at the quantum critical point in 1 < d ≤ 3, which we determine exactly. We also discuss the quantum-to-classical crossover at small but finite temperatures, which is characterized by the appearance of multiple temperature scales. A comparison with recent results on disordered itinerant ferromagnets is given.     

Noncoplanar magnetic ordering driven by itinerant electrons on the pyrochlore lattice

Exchange interaction tends to favor collinear or coplanar magnetic orders in rotationally invariant spin systems. Indeed, such magnetic structures are usually selected by thermal or quantum fluctuations in highly frustrated magnets. Here we show that a complex noncoplanar magnetic order with a quadrupled unit cell is stabilized by itinerant electrons on the pyrochlore lattice. Specifically, we consider a Kondo-lattice model with classical localized moments at quarter filling. The electron Fermi "surface" at this filling factor is topologically equivalent to three intersecting Fermi circles. Perfect nesting of the Fermi lines leads to magnetic ordering with multiple wave vectors and a definite handedness. The chiral order might persist without magnetic order in a chiral spin liquid at finite temperatures.     

Room-temperature ferromagnetism in hydrothermally treated glassy carbon

Extraordinary room-temperature ferromagnetism was observed in our hydrothermally treated glassy carbon systems, taken to comprise nearly graphitized regions. Strong correlation between the ferromagnetic response and the diamagnetic susceptibility, superposed together, suggests the ferromagnetic long-range order in the graphitic phase to be of itinerant nature. Besides, the graphitization process associated with the itinerant spins and the ferromagnetic order revealed a systematic correlation with the average graphitic cluster size.