Correlations of Spin States for Icosahedral Double Group

The irreducible bases of the icosahedral double groups I and I_h are explicitly presented in their respective group spaces. Applying these bases to the spin states |j, , we obtain a simple formula for combining the spin states into the symmetry-adapted bases which belong to a given row of given irreducible representations of I and I_h.     

Mixed-valence states in TCNQ salts of monoalkylbiferrocenes and their mixed crystals with dialkyl derivative

TCNQ salts of 1-monoalkylbiferrocenes showed a temperature-independent trapped-valence state as expected for the unsymmetrical structure of cations. On the other hand, mixed crystals of 1-monobutyl- and 1.1-dibutylbiferrocenium⁺(TCNQ) ₃ ^– showed a temperature dependence of the mixed-valence states, showing that the lattice affects the mixed-valence states.     

The electrodynamics and statistical mechanics of linear plasma response functions

The purpose of this paper is to review and to extend, wherever possible, the Kramers-Kronig relations, sum rules, and symmetry properties for the electrodynamic transport tensors of a linear plasma medium. For complete generality, we consider both nonrelativistic and relativistic plasmas with and without external magnetic fields. Our study is carried out first within the framework of classical electrodynamics. We then exploit the statistical-mechanical fluctuation-dissipation theorem to further obtain the Onsager symmetry relations and Kubo sum-rule frequency moments. Of special significance is the emergence of a variety of new Kramers-Kronig formulae andf-sum rules for the inverse dispersion tensor.Nomenclature E(k,) electric field intensity - Ê(k,) electric field in absence of plasma particles, - (k,) electric field due to the plasma particles (=E-Ê) - B(k,) magnetic induction - D(k,) electric induction - H(k,) magnetic field strength - B ₀ constant external magnetic field - A ₀ vector potential corresponding toB ₀ - (k,),j(k, co) charge and current densities due to the plasma particles - (k,),J(k,) charge and current densities of the external agency - (k,,B ₀) dielectric tensor of the plasma medium in the presence of B₀ - (k,,B ₀) diamagnetic tensor - (k, co,B ₀) (k,,B ₀) – 1, electric polarizability tensor - (k,,B ₀) magnetic polarizability tensor - (k,,B ₀) ordinary conductivity tensor - (k,,B ₀) external conductivity tensor - D(k,,B ₀) n²T–(k,,B ₀), dispersion tensor, where T=1-kk is the transverse projection tensor (k being the unit vector in the direction ofk) andn = kc/ the index of refraction - n²T – 1, = vacuum wave operator (value of D in vacuum) - 1/2( + ), Hermitian part of - ^{^} 1/2( – ), Anti-Hermitian part of a - , real and imaginary parts of a - R(r,t) dissipated power per unit volume of plasma - U total energy absorbed by the plasma - R(k,) E^*(k,) · (k,,b ₀) ·E(k,) corresponding spectral energy density - W(r,t) 1/2₀E²(r, 0 + (l/2₀) B²(r,t), field energy density - W(k,) 1/2₀E^*k,) ·E(k,) + (l/2₀)B ^*(k,) · B(k,), energy content in a certain domain of (k,)-space for a single mode - x _i,p _i,v _i coordinate, momentum, and velocity of ith electron - _i [1–(_i ²/c²)]^–1/2 - X _j,P _j,V _j coordinate, momentum, and velocity of jth ion - {A _q}, {E_q} field coordinates and momenta - j_k(t),J _k(t) perturbations in the microscopic electron and ion current densities due to the presence of the small external vector potential agencyâ(r,t) = (1/L³) â_k(t) expi k ·r - Liouville distribution function = ⁰ + - ⁰ macrocanonical distribution function characterizing the equilibrium state of the system in the infinite past - small perturbation due toA - H⁰ Hamiltonian of equilibrium system which includes interaction - H Hamiltonian for the interaction between the system and the small external perturbing agencyA - ⁰ = d^R()⁰ expectation value of any quantity over the equilibrium ensemble (d^R is an element of hypervolume in -phase space) - G(12) two-particle distribution function - F(1) one-particle distribution function - g(¦x₂ – x₁ ¦) [G(12)/F(1)F(2)] – 1, pair correlation function - N total number of electron in volume L³ - n ₀ equilibrium density (of electrons) - ^–1 temperature (in energy units) - ₀ (n₀e²/m₀)^1/2, equilibrium electron plasma frequency - _c ¦e ¦–B ₀/m, electron frequency - ^–1 ( ₀/n₀e²)^1/2, Debye length - ₀ (n₀Ze²/M₀)^1/2, equilibrium ion plasma frequency - _c ZeB₀/M, ion cyclotron frequency     

Direct observation of the second-order Stark effect of theX-B transition in molecular iodine

The second-order Stark shift of the components of the hyperfine structure of the transition¹ _g ⁺ ( = 0,j = 13, 15) ³ _ou ⁺ ( = 43,j = 12, 16) (of molecular iodine have been studied by means of saturated absorption spectroscopy in an external cell with the I₂ vapour located in an electric field. The anisotropic polarizabilities of the upper and lower levels together with the difference between the isotropic polarizabilities of the levels of the transition have been obtained.     

The λϕ 3 4 field theory in a finite volume

The unnormalized doubly cutoff Schwinger functions converge as the ultraviolet cutoff is removed. The limits, the finite volume unnormalized Schwinger functions, are tempered distributions and areC in the coupling constant. They have asymptotic expansions given by perturbation theory. For sufficiently small they can be normalized and then they are the moments of a measure onI (IR³).Supported in part by the National Science Foundation under Grant GP 40354X.     

Correlations between clusterization and electrical properties within fluorite-type anions excess solid solutions: Setting of a model

We proposed a model to correlate, in a continuous manner, the composition dependence of electrical properties and the progressive extension of clusterization when the substitution rate increases in a fluoride anion excess CaF₂-type solid solution of M_1–xM _x ²⁺ F_2+x(=1,2,3). A new classification of clusters is given based on the presence or absence of coexistence between two types of interstitial fluoride ions.The second part of the paper is devoted to the representation of the sum of interstitial fluoride ionsn _{F int} and the sum of vacancies in normal sitesn according to the general equationy=(mx ³+qx)/(x ²+q). This model allows us to correlate the structural and electrical properties of a large number of solid solutions with fluorite-type structure.     

Temperature Dependence of the Gibbs State in the Random Energy Model

We consider the problem of temperature dependence of the Gibbs states in two spin-glass models: Derrida's Random Energy Model and its analogue, where the random variables in the Hamiltonian are replaced by independent standard Brownian motions. For both of them we compute in the thermodynamic limit the overlap distribution ^N _{i=1 i i} /N[–1,1] of two spin configurations , under the product of two Gibbs measures, which are taken at temperatures T,T respectively. If TT are fixed, then at low temperature phase the results are different for these models: for the first one this distribution is D _{0 0}+D _{1 1}, with random weights D ₀, D ₁, while for the second one it is ₀. We compute consequently the overlap distribution for the second model whenever T–T0 at different speeds as N.     

Microwave dielectric properties of Ti4+/MgO and Ni2+/MgO

The dielectric properties of titanium-doped magnesium oxide (Ti/MgO) and nickel-doped magnesium oxide (Ni/MgO) single crystals have been measured in the range of temperature from 300 to 450 K at the microwave frequency of 9.31 GHz. For both crystals the dielectric properties are found similar. From the conductivity data, the activation energy in the measured temperature region has been estimated to be 0.15 eV. The values of the temperature dependence (–1)^–1(+2)^–1 (/T) _p have been calculated. The data confirms the Bosmann and Havinga postulate that, for materials in which the dielectric constant; is less than 20 the temperature dependence should be positive.     

Analytical electron microscopy study of diffusion-bonded multiphase system

This study presents diffusion experiments of NiAl coupled with pure Ni (Ni/NiAl). The couple produces the Ni₃Al-based intermetallic phase ( phase) as an intermediate layer at the interface during diffusion annealing. Analytical electron microscopy is used to examine microstructural features, crystallographic orientation and compositional variations across the interface. Interdiffusivities are measured from the compositional variations. It is shown that the growing behavior of the phase changes between higher and lower annealing temperatures. The growth kinetics of the phase is also discussed.     

Light absorption by free semiconductor carriers in the presence of a laser wave

Within the framework of the conditions ; » ^–1 ( ^–1 is the mean time of momentum relaxation), the coefficient of absorption () of a weak electromagnetic wave by the free carriers of a polar semiconductor is calculated in the presence of a strong wave (of frequency ), for arbitrary values of and . Photon absorption by band electrons is due to these latter interacting with optical phonons (of frequency _o). The problem is solved by using an analogous approach to the theory of the linear Kubo reaction. The results are valid in the absence of electron heating, when a strong wave only influences the scattering probability. The appearance of a photostimulated tail of absorption is predicted for < _o, including the jump () for ( – _o + ) ₀T as well as peaks in the function () at the points _s=s (s=1, 2, 3,...). The value (₁) is determined by the formula for the absorption coefficient for one strong wave.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 105–109, July, 1981.The authors are grateful to É. M. Épshtein and Sh. M. Kogan for useful discussions.     

A contribution to the theory of the triple crystal diffractometer

The first part of the paper gives a general equation for triple-crystal arrangement with perfect crystals on the assumption that the third crystal is rotated. It is shown that in the case of perfect crystals the shape of the reflection curve is practically independent of the vertical divergence. The case of mosaic crystals is also solved and the possibility of rotation by other than the third crystal is considered. A method is proposed for investigating the imperfection of a crystal which is different from methods used up to now. The paper is supplemented by some experimental results.

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The modular group and super-KMS functionals

Every normal, faithful, self-adjoint functional on a von Neumann algebraA canonically determines a one-parameter-weakly continuous *-automorphism group (the analog of the modular group) and a canonical ₂ grading onA, commuting with . We show that the functional satisfies the weak super-KMS property with respect to and Furthermore, we prove that and are the unique pair of a-weakly continuous one-parameter *-automorphism group and a grading of the algebra, commuting with each other, with respect to which is weakly super-KMS. The above results thus provide a complete extension of the theory of Tomita and Takesaki to the nonpositive case.Supported in part by the National Science Foundation under Grant DMS-8922002.     

A solution spectrum of the nonlinear Schrödinger equation. II

It was shown in a previous communication that the nonlinear Schrödinger equation exhibits a spectrum of eigenfunctions of the form = _k,A _k (coshkx) ^–k and = _k B _k (coshkx) ^–k–1sinhkx, and the corresponding eigenvalues of the energy are related to a band structure with a characteristic energy gap as a significant feature. In the present paper, it is shown that a further spectrum exists exhibiting the general structure = _k=0 A _k(cosh kx)^–k–1/2and = _k=0 B_k(cosh kx)^–k–3/2sinhkx and yielding also a band structure. An extension of the solution spectrum to a nonlinear Klein-Gordon equation and a nonlinear Dirac equation does not imply essential difficulties, and the corresponding characteristic band structure has to be related to a mass spectrum.     

Characteristics analysis of metal-clad and absorptive dielectric waveguides by a simple and accurate perturbation method

We present a simple and accurate method for characteristic analysis of metal-clad dielectric waveguides and absorptive waveguides. The real partN of the complex modal indexN=N + iN is obtained by solving the corresponding real eigenvalue equation, and the imaginary partN is given by (n/), where= + i is the complex dielectric constant of the absorptive layer, and N/ is obtained by numerical differentiation. The method is straightforward, and the cumbersome solution of complex transcendental equations is completely eliminated. Results for simple structures are in good agreement with those obtained by exact analysis.     

A generalized representation for dielectric dispersion

The generalized formulation for dielectric dispersion is extended for dielectrics exhibiting strongly overlapping arcs in the- complex plane. Subsequently, a novel network representation is developed whereby Negative Impedance Converters (NICs) are employed along with passive R-C elements. Satisfactory agreement is obtained in comparing the experimental results with those calculated using the new formulation.     

Sensitivity of approximate formulas for determining optical constants of thin films

The sensitivity of approximate formulas for determining the optical constants of thin films using measurement of reflectancesR and transmittancesT at normal incidence have been investigated theoretically. The ranges of refractive indexn, absorption indexk,2nk (=₂) andn ²–k ²(=₁) within relative errors of 5%, 10%, and 20% may be obtained. Selected signs of (₁)⁺ or (₁)^– have been determined. Validity of the condition n₀ A=n _s A has been also evaluated (A=1–R –T andA=1–R–T).     

Kinetic theory of adsorption and desorption

In this paper we use stochastic methods to discuss adsorption and desorption. The paper derives generalized coefficients of sticking and accomodation depending on surface temperatureT _s and gas temperatureT _g and shows, that for additive Markov processes, these kinetic coefficients are identical. Furthermore, exact solutions of the kinetic equations for certain simple transition probabilitiesP(, ) are found and an approximation method for more complicatedP(, ) is given. The comparison of the theory with experimental results for noble gas-metal systems indicate a quadratic relationship between the first moment of the transition probabilityP(, ) and the well depth of the physisorption system.     

Ising Models on Hyperbolic Graphs II

We consider Ising models with ferromagnetic interactions and zero external magnetic field on the hyperbolic graph (v, f), where v is the number of neighbors of each vertex and f is the number of sides of each face. Let T _c be the critical temperature and T _c =supTT _c: ^f=( ⁺+ ^–)/2, where ^f is the free boundary condition (b.c.) Gibbs state, ⁺ is the plus b.c. Gibbs state and ^– is the minus b.c. Gibbs state. We prove that if the hyperbolic graph is self-dual (i.e., v=f) or if v is sufficiently large (how large depends on f, e.g., v35 suffices for any f3 and v17 suffices for any f17) then 0<T _c <T _c, in contrast with that T _c =T _c for Ising models on the hypercubic lattice Z ^d with d2, a result due to Lebowitz.⁽²²⁾ While whenever T<T _c , ^f=( ⁺+ ^–)/2. The last result is an improvement in comparison with the analogous statement in refs. 28 and 33, in which it was only proved that ^f=( ⁺+ ^–)/2 when TT _c and it remains to show in both papers that ^f =( ⁺+ ^–)/2 whenever T<T _c . Therefore T _c and T _c divide [0, ] into three intervals: [0, T _c ), (T _c , T _c), and (T _c, ] in which ^{+ –} but ^f =( ⁺+ ^–)/2, ^{+ –} and ^f ( ⁺+ ^–)/2, and ⁺= ^–, respectively.     

Magnetic relaxation spectrum of ferrites Mn x Fe3−x O4+γ

The initial permeability disaccommodation in ferritesMn _x Fe₃–xO₄₊ , 0·5x1, was studied in a temperature range around –200°C to +180°C. Four separate bands were found in the relaxation spectrum of these ferrites.

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Mn _x Fe_3–x O₄₊

Mn _x Fe_3–x O₄₊ , 0,5x1, –200°C +180°C. .

     

UV cavity enhanced absorption spectroscopy of the hydroxyl radical

We present the application of a continuous-wave ultra-violet tuneable light source for detection of the hydroxyl radical (OH) using cavity-enhanced absorption spectroscopy of the Q₁₁(2) and Q₂₁(2) absorption lines in the A²⁺(v=0)²_3/2(v=0) band at ca. 308 nm. A tuneable infra-red diode laser operating at 835 nm and either an Ar⁺ laser or a single frequency continuous-wave intracavity frequency-doubled diode laser, both operating at ca. 488 nm, were used to produce 0.1–0.5 W of tuneable radiation at ca. 308 nm by sum frequency generation in a BaB₂O₄ crystal. Cavity enhanced absorption spectroscopy was used to detect OH generated by UV photolysis of water vapour in argon, nitrogen, neon and helium at atmospheric pressure. A noise-equivalent (1) absorption sensitivity of 2.1×10^-7 cm^-1Hz^-1/2 measured over 128 scans in a time of 1.16 s was demonstrated with mirrors of reflectivity 0.9963 in a cavity of length 58.5 cm for a 2 cm^-1 scanning range at a UV power of 0.5 W. An OH detection limit (1) of 3.84×10⁹ moleculecm^-3 was estimated in argon at atmospheric pressure. OH collisional broadening in humidified N₂, Ar, Ne and He was determined at atmospheric pressure . PACS 39.30.+w; 42.55.Px; 42.62.Fi; 42.68.Ca