正交LiMnO2中的重入自旋玻璃行为

用水热技术合成了单相正交LiMnO2(o-LiMnO2)粉末,X射线衍射表明其空间群为Pmnm.X射线衍射精修结果指出该材料存在少量的阳离子无序,但这种无序对材料的磁性没有表现出明显的影响.静态和动态的磁性研究结果表明o-LiMnO2中存在重入自旋玻璃行为,即在T≤TC≈118 K,反铁磁态转向铁磁态,在T≤Tf≈50 K,铁磁态又转向自旋倾斜玻璃态.     

自旋玻璃的重入行为及CoxZn1-x(FeyCr1-y)2O4尖晶石系统的磁相图

本文研究了Co_xZn_1-x(Fe_yCr_1-x2O₄尖晶石系统的磁性,测量了不同成份样品的低频弱场交流磁化率与低场直流磁化强度的温度关系。根据实验结果,给出了该系统可能的磁相图。发现在该系统中相当宽的成份范围内,都存在自旋玻璃的重入现象。同时发现,自旋玻璃的重入温度随磁性离子浓度增加而增加。这些行为是磁性离子浓度含量较高和多种磁性离子共存系统的共同特性。还讨论了自旋玻璃重入行为 关键词：     

压力对纳米CoFe2O4/SiO2复合材料结构的影响

 采用溶胶-凝胶工艺和高温高压实验技术,制备了纳米CoFe₂O₄/SiO₂复合材料。利用X射线衍射仪、扫描电子显微镜和振动样品磁强计,对样品的结构、微观形貌和磁性进行了研究,并对CoFe₂O₄中阳离子的占位情况进行了讨论。结果表明,随着处理压力的升高,样品的晶粒尺寸增大,晶格常数减小,比饱和磁化强度增大。通过计算结果可以推断,压力的升高导致CoFe₂O₄中的部分Fe³⁺从A位移向了B位,而部分Co²⁺则从B位移向了A位。     

块状Ta2O5-TiO2复合气凝胶的制备与表征

 以乙醇钽、钛酸丁酯为原料,以乙醇为溶剂,通过溶胶-凝胶法及超临界干燥成功制备了Ta₂O₅-TiO₂复合气凝胶。用场发射扫描电镜（SEM）、透射电镜（TEM）、扫描电镜模式下的电子能谱仪（EDS）以及比表面积吸附仪（BET）对其进行表征。结果表明:该气凝胶是由粒径在nm量级的Ti和Ta的羟基氧化物胶体颗粒堆积而成的低密度、高比表积的多孔网络结构材料,孔径分布主要集中在5~15 nm,比表面积为492.9 m²/g,密度为90 mg/cm³左右。     

基于TaCl5的Ta2O2气凝胶制备工艺

 主要介绍了以TaCl₅为前驱体,低分子醇类为溶剂,分别采用环氧丙烷和环氧氯丙烷作为凝胶促进剂制备Ta₂O₂湿凝胶,湿凝胶经过CO₂超临界干燥而获得白色Ta₂O₂气凝胶。透射电镜图谱表明气凝胶是由粒度为10～20 nm的颗粒堆积而成。N₂等温吸附-脱附分析表明,气凝胶的比表面积为800～900 m²/g。     

双层反铁磁体K3Cu2F7 中轨道序驱动的自旋二聚化

基于自旋-轨道-晶格Hamilton量,应用团簇自洽场方法,研究了双层钙钛矿结构材料K₃Cu₂F₇基态的晶格、磁及轨道结构,发现近孤立的双层的对称破缺和Jahn-Teller晶格畸变使得Cu²⁺离子在每层内交替占据 z²-x²〉/ z²-y²〉轨道,进而导致双层的层间表现为强的反铁磁耦合,层内为弱的铁磁耦合.强反铁磁耦合导致层间     

氧氩比对SnO2/Ag/SnO2透明导电膜光电性能的影响

在室温及不同的氧氩比条件下,采用射频磁控溅射Ag层和直流磁控溅射SnO₂层,在载玻片衬底上制备出了SnO₂/Ag/SnO₂多层薄膜.用霍尔效应测试仪、四探针电阻测试仪和紫外-可见-近红外光谱仪等表征了薄膜的电学性质和光学性质.实验结果表明:当氧氩比为1:14时,所制得的薄膜的光电性质优良指数最大,为1.69×10^-2 Ω^-1;此时,薄膜的电阻率为9.8×10^-5 Ω·cm,方电阻为9.68 Ω/sq,在400~800 nm可见光区的平均光学透射率达85%;并且,在氧氩比为1:14时,利用射频磁控溅射Ag层和直流磁控溅射SnO₂层在PET柔性衬底上制备出了光电性质优良的柔性透明导电膜,其在可见光区的平均光学透过率达85%以上,电阻率为1.22×10^-4 Ωcm,方电阻为12.05 Ω/sq.     

纤维状TiO2/Bi2O3光催化剂的制备及其光催化性能

以C₁₆H₃₆O₄Ti和Bi(NO₃)·5H₂O为原料,以棉花纤维为生物模板,合成了系列纤维状TiO₂/Bi₂O₃光催化剂．采用XRD、SEM、UV-Vis等测试技术对样品的相结构、形貌和吸光性能等进行了表征分析．结果表明,样品中的Bi₂O₃为单斜相和四方相共存的混晶,纤维长度达到毫米级,     

AdS5\otimes S1, AdS5\otimes S5和AdS2\otimes S2超弦模型的一种KRR参数化新方法

给出了3种典型超弦模型AdS₅\otimes S¹, AdS₅\otimes S⁵和AdS₂\otimes S²的一种简单的KRR参数化新方法, 并结合这些超弦模型所具有的κ对称性给出了它们的卡当1-form, Maurer-Cartan方程, 作用量和运动方程.     

用于白光LED的单一基质白光荧光粉Ca2SiO3Cl2:Eu2+，Mn2+的发光性质

用高温固相法合成了Eu²⁺，Mn²⁺共激活的Ca₂SiO₃Cl₂高亮度白色发光材料，并对其发光性质进行了研究. 该荧光粉在近紫外光激发下发出强的白色荧光，Eu^{2+中心形成峰值为419 nm和498 nm的特征宽带，通过Eu2+中心向Mn2+中心的能量传递导致了峰值为578 nm的发射，三个谱带叠加从而在单一基质中得到了白光. 激发光谱均分布在250—415 nm的波长范围，红绿蓝三个发射带的激发谱峰值分别位于385 nm，412 nm，370 nm和396 nm处，可以被InGaN管芯产生的紫外辐射有效激发. Ca₂SiO₃Cl₂:Eu2+，Mn2+是一种很有前途的单一基质白光LED荧光粉.}     

Reentrant spin glass behavior in antiferromagnetic single crystalline Ba6Mn24O48 nanoribbons

Single crystalline Ba₆Mn₂₄O₄₈ nanoribbons with diameters ranging from one hundred nanometers to a few hundred nanometers and length up to tens of microns are synthesized via a facile molten salt method. These nanoribbons are characterized by a range of methods including X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), selected area electron diffraction (SAED) and high-resolution transmission electron microscopy (HRTEM). The magnetic properties of Ba₆Mn₂₄O₄₈ nanoribbons are investigated by the zero-field-cooled (ZFC), field-cooled (FC) magnetization, and ac susceptibility. Upon cooling, we find the reentrant spin glass (RSG) behavior in these nanoribbons, i.e., paramagnetic (PM), antiferromagnetic (AFM), and spin glass (SG). The RSG behavior might be due to the surface spin disorder, geometrical frustration and Mn³⁺/Mn⁴⁺ mixture in Ba₆Mn₂₄O₄₈ nanoribbons.     

相分离Nd0.5Ca0.5MnO3体系的再入型自旋玻璃行为和电荷有序

研究了Nd_0.5Ca_0.5MnO₃体系的结构和输运特性. 结构 分析表明，在300K下，体系表现为O′型正交结构并存在典型的Jahn-Teller畸变.在8 T磁场 下，体系出现顺磁绝缘-铁磁金属的转变，庞磁电阻效应发生. 磁测量发现，样品的奈尔温 度T_N和电荷有序转变温度T_CO分别在150和240K左右，在41K左右出 现典型再入型自旋玻璃行为，同时观察到了负的磁化率异常. 结果表明，Nd关键词： 庞磁电阻 自旋玻璃态 负磁化强度 电荷有序     

Size-controlled hydrothermal synthesis and electrochemical behavior of orthorhombic LiMnO2 nanorods

Large amount of uniform orthorhombic LiMnO₂ (o-LiMnO₂) nanorods was fabricated by a hydrothermal route in 180 °C using γ-MnOOH nanorods as precursors through an isomorphous ion exchange process. The size of as-obtained o-LiMnO₂ nanorods was determined by that of γ-MnOOH precursors, which could be deliberately controlled. The electrochemical performance of o-LiMnO₂ nanorods was characterized via galvanostatic tests, which suggested that the size of as-obtained products played an important role in their electrochemical performances.     

Antiferromagnetic order and spin glass behavior in Dy2CuIn3

The magnetic properties of the intermetallic compound Dy₂CuIn₃ have been investigated. Ac and dc-susceptibility measurements indicate an onset of antiferromagnetic ordering at T_N=19.5 K and an additional frequency dependent transition at T_ds∼9 K. Neutron diffraction studies confirm the ordered transition at 19.5±1 K. The magnetic unit cell can be described by the propagation vector k=(0.25,0.25,0) with the magnetic moment μ=2.63(4)μ_B/Dy³⁺ parallel to the c-axis. Nevertheless, neutron diffraction reveals no additional magnetic phase transition around or below 9 K, which suggests that, at lower temperatures, a spin glass state may be formed in coexistence with the antiferromagnetic mode as a result of frustration and the antagonism between ferromagnetic and antiferromagnetic exchange interactions.     

Reentrant spin glass behavior and large initial permeability of Co0.5−xMnxZn0.5Fe2O4

A series of polycrystalline ferrites having nominal chemical composition Co_0.50−xMn_xZn_0.5Fe₂O₄ (0<x<0.4) have been synthesized by the solid-state reaction technique. The XRD analysis confirms single phase cubic spinel structure for all compositions. Lattice constant increases from 0.84195 to 0.84429 nm with the increasing Mn content and obeys Vegard's law. The average grain size increases by increasing both Mn content and sintering temperatures. Room temperature saturation magnetization increases for x=0.1 and decreases for increasing Mn content. The coercivity decreases with increasing Mn content due to the decrease of anisotropy constant. A reentrant spin glass behavior of these samples is observed from the zero field cooled magnetization measurements. The real part of the initial permeability increases by increasing both Mn content and sintering temperatures. This is due to the homogeneous grain growth and densification of the ferrites. The highest initial permeability 137 is observed for x=0.4 sintered at 1573 K on the other hand, the highest relative quality factor (2522) is obtained for the sample Co_0.2Mn_0.3Zn_0.5Fe₂O₄ sintered at 1523 K. The Mn substituted Co_0.50−xMn_xZn_0.5Fe₂O₄ ferrites showed improved magnetic properties.     

Reentrant spin glass behaviour in Nd0.84K0.12MnO3

Polycrystalline Nd_0.84K_0.12MnO₃ was prepared in single phase form with Pbnm space group. The magnetic properties are studied from magnetization, linear and non-linear susceptibility, and thermoremanent magnetization measurements. The sample exhibits paramagnetic to ferromagnetic transition followed by low temperature spin glass like transition. From frequency variation of ac susceptibility measurements, the spin glass transition temperature is found to be 97.6±0.1 K with critical exponents zυ=1.13±0.06. The critical exponent γ corresponding to spin glass transition has been determined from the third harmonic susceptibility analysis and it is found to be 3.09±0.05. The effective number of spins blocked under frustration and their correlation length are determined from the analysis of thermoremanent magnetization.     

基于熔融玻璃的预沉积法生长毫米级单晶MoS2及WS2-MoS2异质结

MoS₂是一种具有优异光电性能和奇特物理性质的二维材料,在电子器件领域具有巨大的应用潜力.高效可控生长出大尺寸单晶MoS₂是该材料进入产业应用所必须克服的重大难关,而化学气相沉积技术被认为是工业化生产二维材料的最有效手段.本文介绍了一种利用磁控溅射预沉积钼源至熔融玻璃上,通过快速升温的化学气相沉积技术生长出尺寸达1 mm的单晶MoS₂的方法,并通过引入WO₃粉末生长出了二硫化钼与二硫化钨的横向异质结(WS₂-MoS₂).拉曼和荧光光谱仪测试表明所生长的样品具有较好的晶体质量.利用转移电极技术制备出了背栅器件样品并对其进行了电学测试,在室温常压下开关比可达10~5,迁移率可达4.53 cm~2/(V·s).这种低成本高质量的大尺寸材料生长方法为二维材料电子器件的大规模应用找到了出路.     

Cluster spin glass in concentrated alloys

Spin glass and structural states of Ni-Mn, Ni₃Mn-Ni₃V and Ni₃Mn-Ni₂Cr systems of alloys are investigated. The “freezing” temperature T _g of spin glass and Curie temperatures are obtained from the temperature dependence of the differential magnetic susceptibility χ_ac. Structural states of alloys are studied by the neutron diffraction technique. A cluster mechanism of spin glass formation is established.     

Replica symmetry breaking in a fermionic cluster spin glass model in a transverse field

We analyze a fermionic Ising spin glass model in the presence of a transverse magnetic field Γ within a cluster mean field theory. The model considers a Sherrington-Kirkpatrick type interaction between magnetic moments of clusters with a ferromagnetic intra-cluster coupling J₀. The spin site operators are written as a bilinear combination of fermionic operators. In these quantum spin glass model, the inter-cluster disorder is treated by using a framework of one-step replica symmetry breaking within the static approximation. The effective intra-cluster interaction is then computed by means of an exact diagonalization method. Results for several cluster size n_s, values of Γ and J₀ are presented. For instance, the specific heat shows a broad maximum (for n_s>1) at a temperature above the freezing temperature T_f, which is characterized by the inter-cluster replica symmetry breaking. Phase diagrams T versus Γ show that the critical temperature T_f(Γ) decreases for any value of n_s when Γ increases until it reaches a quantum critical point at some value of Γ_c.