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1.
The theoretical calculations indicated that the monoclinic low-temperature phase of silver telluride $(\upbeta \hbox {-Ag}_{2}\hbox {Te})$ is a new binary topological insulator with highly anisotropic single Dirac cone surface. We obtained $\upbeta \hbox {-Ag}_{2}\hbox {Te}$ crystal ingots containing few grains by the Bridgman method. We also deposited thin films of tellurium, $\hbox {Ag}_{5}\hbox {Te}_{3}\hbox { and }(\hbox {Te+Ag}_{5}\hbox {Te}_{3})$ by thermal evaporation method. The Raman spectra of $\upbeta \hbox {-Ag}_{2}\hbox {Te}$ , tellurium and $\hbox {Ag}_{5}\hbox {Te}_{3}$ were measured at three excitation wave lengths: 633, 515 and 488 nm. The Raman active modes of $\upbeta \hbox {-Ag}_{2}\hbox {Te}$ , tellurium and $\hbox {Ag}_{5}\hbox {Te}_{3}$ are situated at frequencies below 300  $\hbox {cm}^{-1}$ while vibrations of other phases appear at higher frequencies.  相似文献   

2.
The primary goal of KamLAND is a search for the oscillation of \({\bar{\nu }}_\mathrm{e}\) ’s emitted from distant power reactors. The long baseline, typically 180 km, enables KamLAND to address the oscillation solution of the “solar neutrino problem” with \({\bar{\nu }}_{e} \) ’s under laboratory conditions. KamLAND found fewer reactor \({\bar{\nu }}_{e} \) events than expected from standard assumptions about \(\overline{\nu }_e\) propagation at more than 9 \(\sigma \) confidence level (C.L.). The observed energy spectrum disagrees with the expected spectral shape at more than 5 \(\sigma \) C.L., and prefers the distortion from neutrino oscillation effects. A three-flavor oscillation analysis of the data from KamLAND and KamLAND + solar neutrino experiments with CPT invariance, yields \(\Delta m_{21}^2 \) = [ \(7.54_{-0.18}^{+0.19} \times \) 10 \(^{-5}\) eV \(^{2}\) , \(7.53_{-0.18}^{+0.19} \times \) 10 \(^{-5}\) eV \(^{2}\) ], tan \(^{2}\theta _{12}\) = [ \(0.481_{-0.080}^{+0.092} \) , \(0.437_{-0.026}^{+0.029} \) ], and sin \(^{2}\theta _{13}\) = [ \(0.010_{-0.034}^{+0.033} \) , \(0.023_{-0.015}^{+0.015} \) ]. All solutions to the solar neutrino problem except for the large mixing angle region are excluded. KamLAND also demonstrated almost two cycles of the periodic feature expected from neutrino oscillation effects. KamLAND performed the first experimental study of antineutrinos from the Earth’s interior so-called geoneutrinos (geo \({\bar{\nu }}_{e} \) ’s), and succeeded in detecting geo \({\bar{\nu }}_{e} \) ’s produced by the decays of \(^{238}\) U and \(^{232}\) Th within the Earth. Assuming a chondritic Th/U mass ratio, we obtain \(116_{-27}^{+28} {\bar{\nu }}_{e}\) events from \(^{238}\) U and \(^{232}\) Th, corresponding a geo \({\bar{\nu }}_{e}\) flux of \(3.4_{-0.8}^{+0.8}\times \) 10 \(^{6}\) cm \(^{-2}\)  s \(^{-1}\) at the KamLAND location. We evaluate various bulk silicate Earth composition models using the observed geo \({\bar{\nu }}_{e} \) rate.  相似文献   

3.
$\hbox {In}_{2}\hbox {S}_{3}$ thin films have been elaborated onto glass substrate by SILAR method at room temperature using different immersion time in the solution of cation and anion and fixing the rinsing time. The film composition, morphology and structure were investigated using energy dispersive X-ray analysis (EDAX), scanning electron microscopy (SEM) and X-ray diffraction techniques. Optical properties, such transmission and band gap have been also analyzed. The effects of annealing on the morphological structure thin films are also described. The x-rays diffraction spectra indicated that the formed compounds are $\upbeta $ - $\hbox {In}_{2}\hbox {S}_{3}$ polycrystalline thin films with $\hbox {In}_{6}\hbox {S}_{7 }$ as second phase in sample S1 and sample S2 and no another phase in sample 3. SEM revealed homogeneous and relatively uniform films and EDAX shows sample 3 with S/In=1.44. For sample 1 and sample 2, we noted an increase of band gap when rinsing time increases.  相似文献   

4.
The available data on \(|\Delta B| = |\Delta S| = 1\) decays are in good agreement with the Standard Model when permitting subleading power corrections of about \(15\,\%\) at large hadronic recoil. Constraining new-physics effects in \(\mathcal {C}_{7}^{\mathrm {}}\) , \(\mathcal {C}_{9}^{\mathrm {}}\) , \(\mathcal {C}_{10}^{\mathrm {}}\) , the data still demand the same size of power corrections as in the Standard Model. In the presence of chirality-flipped operators, all but one of the power corrections reduce substantially. The Bayes factors are in favor of the Standard Model. Using new lattice inputs for \(B\rightarrow K^*\) form factors and under our minimal prior assumption for the power corrections, the favor shifts toward models with chirality-flipped operators. We use the data to further constrain the hadronic form factors in \(B\rightarrow K\) and \(B\rightarrow K^*\) transitions.  相似文献   

5.
Magnetism in Cu-doped, Cu \(\rm _{Si}\) –V \(\rm _{Si}\) codoped, or Cu \(\rm _{Si}\) –V \(\rm _{C}\) codoped 6H-SiC are investigated using the first principle. The total density of states for the ferromagnetic Cu \(\rm _{Si}\) at doping concentration of 0.926 at. \(\%\) shows half-metallic behavior, which leads to the total magnetic moment of 2.84  \(\rm \mu _{B}\) per supercell. The total magnetic moment increases with increasing Cu content. The long-range ferromagnetic interaction between Cu atoms can be attributed to the C-mediated double exchange through the strong \(3d\) ? \(2p\) interaction between Cu and neighboring C ones. It is important to note that both V \(\rm _{Si}\) and V \(\rm _{C}\) play a negative role in ferromagnetic coupling between Cu ions. So, to obtain a larger magnetic moment from Cu-doped 6H–SiC, we should try to avoid the appearance of V \(\rm _{Si}\) and V \(\rm _{C}\) during the process of sample preparation. Our theoretical calculations give a valuable insight on how to get a large magnetic moment from Cu-doped 6H–SiC.  相似文献   

6.
Room-temperature ferromagnetism has been found in Ga-deficient GaN grown using the direct reaction of Ga \(_{2}\) O \(_{3}\) powder with NH \(_{3}\) gas. The observed magnetism in GaN induced by Ga vacancies is investigated both experimentally and theoretically. First-principles calculations reveal that the spontaneous spin polarization is created by the 3.0  \(\mu _\mathrm{B}\) local moment for GaN and magnetism originates from the polarization of the unpaired 2 \(p\) electrons of N surrounding the Ga vacancy. At the same time, the band gap can be also adjusted by changing the Ga-vacancy concentration.  相似文献   

7.
In work started in [17] and continued in this paper our objective is to study selectors of multivalued functions which have interesting dynamical properties, such as possessing absolutely continuous invariant measures. We specify the graph of a multivalued function by means of lower and upper boundary maps \(\tau _{1}\) and \(\tau _{2}.\) On these boundary maps we define a position dependent random map \(R_{p}=\{\tau _{1},\tau _{2};p,1-p\},\) which, at each time step, moves the point \(x\) to \(\tau _{1}(x)\) with probability \(p(x)\) and to \(\tau _{2}(x)\) with probability \(1-p(x)\) . Under general conditions, for each choice of \(p\) , \(R_{p}\) possesses an absolutely continuous invariant measure with invariant density \(f_{p}.\) Let \(\varvec{\tau }\) be a selector which has invariant density function \(f.\) One of our objectives is to study conditions under which \(p(x)\) exists such that \(R_{p}\) has \(f\) as its invariant density function. When this is the case, the long term statistical dynamical behavior of a selector can be represented by the long term statistical behavior of a random map on the boundaries of \(G.\) We refer to such a result as a mathematical holographic principle. We present examples and study the relationship between the invariant densities attainable by classes of selectors and the random maps based on the boundaries and show that, under certain conditions, the extreme points of the invariant densities for selectors are achieved by bang-bang random maps, that is, random maps for which \(p(x)\in \{0,1\}.\)   相似文献   

8.
In this article, we study the $\frac{1} {2}^ -$ and $\frac{3} {2}^ -$ heavy and doubly heavy baryon states $\Sigma _Q \left( {\frac{1} {2}^ - } \right)$ , $\Xi '_Q \left( {\frac{1} {2}^ - } \right)$ , $\Omega _Q \left( {\frac{1} {2}^ - } \right)$ , $\Xi _{QQ} \left( {\frac{1} {2}^ - } \right)$ , $\Omega _{QQ} \left( {\frac{1} {2}^ - } \right)$ , $\Sigma _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Xi _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Omega _Q^* \left( {\frac{3} {2}^ - } \right)$ , $\Xi _{QQ}^* \left( {\frac{3} {2}^ - } \right)$ and $\Omega _{QQ}^* \left( {\frac{3} {2}^ - } \right)$ by subtracting the contributions from the corresponding $\frac{1} {2}^ +$ and $\frac{3} {2}^ +$ heavy and doubly heavy baryon states with the QCD sum rules in a systematic way, and make reasonable predictions for their masses.  相似文献   

9.
We report connection conductivity ( \(C_{\rm c}\) ) of adhesive which including \(\hbox {In}_2\hbox {O}_3\) \(\hbox {SnO}_2\) (ITO) particles developed for fabrication of stacked-type-multi-junction solar cells. The commercial 20- \(\upmu \) m sized ITO particles were heated in vacuum at temperature ranging from 800 to 1,300  \(^{\circ }{\rm C}\) for 10 min to increase \(C_{\rm c}\) . 6.2 wt% ITO particles were dispersed in commercial Cemedine adhesive gel to form 100 samples structured with n-type Si/adhesive/n-type Si (n-Si sample) and p-type Si/adhesive/p-type Si (p-Si sample). Current density as a function of voltage (J–V) characteristics gave \(C_{\rm c}\) . It ranged from 4.3 to 1.0 S/cm \(^2\) for the n-Si sample with 800 \(^{\circ }{\rm C}\) heat-treated ITO particles. Its standard deviation was 0.59 S/cm \(^2\) . On the other hand, it ranged from 2.0 to 0.6 S/cm \(^2\) for the p-Si sample with 800  \(^{\circ }{\rm C}\) heat-treated ITO particles. Its standard deviation was 0.22 S/cm \(^2\) . The distribution of \(C_{\rm c}\) mainly resulted from contact efficiency of ITO particles to substrate. We theoretically estimated that present \(C_{\rm c}\) achieved a low loss of the power conversion efficiency ( \(E_{\rm ff}\) ) lower than 0.3 % in the application of fabrication of multi-junction solar cell with an intrinsic \(E_{\rm ff}\) of 30 % and an open circuit voltage above 1.9 V.  相似文献   

10.
We rely on a recent method for determining edge spectra and we use it to compute the Chern numbers for Hofstadter models on the honeycomb lattice having rational magnetic flux per unit cell. Based on the bulk-edge correspondence, the Chern number \(\sigma _\mathrm{H}\) is given as the winding number of an eigenvector of a \(2 \times 2\) transfer matrix, as a function of the quasi-momentum \(k\in (0,2\pi )\) . This method is computationally efficient (of order \(\mathcal {O}(n^4)\) in the resolution of the desired image). It also shows that for the honeycomb lattice the solution for \(\sigma _\mathrm{H}\) for flux \(p/q\) in the \(r\) -th gap conforms with the Diophantine equation \(r=\sigma _\mathrm{H}\cdot p+ s\cdot q\) , which determines \(\sigma _\mathrm{H}\mod q\) . A window such as \(\sigma _\mathrm{H}\in (-q/2,q/2)\) , or possibly shifted, provides a natural further condition for \(\sigma _\mathrm{H}\) , which however turns out not to be met. Based on extensive numerical calculations, we conjecture that the solution conforms with the relaxed condition \(\sigma _\mathrm{H}\in (-q,q)\) .  相似文献   

11.
We study the phenomenon of “crowding” near the largest eigenvalue \(\lambda _\mathrm{max}\) of random \(N \times N\) matrices belonging to the Gaussian Unitary Ensemble of random matrix theory. We focus on two distinct quantities: (i) the density of states (DOS) near \(\lambda _\mathrm{max}\) , \(\rho _\mathrm{DOS}(r,N)\) , which is the average density of eigenvalues located at a distance \(r\) from \(\lambda _\mathrm{max}\) and (ii) the probability density function of the gap between the first two largest eigenvalues, \(p_\mathrm{GAP}(r,N)\) . In the edge scaling limit where \(r = \mathcal{O}(N^{-1/6})\) , which is described by a double scaling limit of a system of unconventional orthogonal polynomials, we show that \(\rho _\mathrm{DOS}(r,N)\) and \(p_\mathrm{GAP}(r,N)\) are characterized by scaling functions which can be expressed in terms of the solution of a Lax pair associated to the Painlevé XXXIV equation. This provides an alternative and simpler expression for the gap distribution, which was recently studied by Witte et al. in Nonlinearity 26:1799, 2013. Our expressions allow to obtain precise asymptotic behaviors of these scaling functions both for small and large arguments.  相似文献   

12.
In this work, we present a study of the magneto transport properties in magnetic multilayered structure $\text{ Ni }_{81}\text{ Fe }_{19}\text{/Zr }$ Ni 81 Fe 19 /Zr . The magnetic $(\text{ Ni }_{81}\text{ Fe }_{19})$ ( Ni 81 Fe 19 ) and non magnetic (Zr) layer thickness $(\mathbf{t}_\mathbf{NiFe}, \mathbf{t}_\mathbf{zr})$ ( t NiFe , t zr ) effects on the magneto resistance (MR) are discussed theoretically in the framework of the Johnson–Camley semi classical approach based on the Boltzmann transport equation. A comparison between calculated and measured MR is obtained. The observed MR ratio oscillates for Zr layer thickness with an average period of 7Å. A generally weak $\text{ MR }(\text{ t }_{\mathrm{NiFe}})$ MR ( t NiFe ) ratio for fixed $\mathbf{t}_\mathbf{zr}$ t zr is obtained and it shows a maxima peak of the MR with a value of 1.8 % located at $\mathbf{t}_\mathbf{NiFe}= 80$ t NiFe = 80 Å.  相似文献   

13.
For two particles' relative position and total momentum we have introduced the entangled state representation |μ〉, and its conjugate state|ξ〉 In this work, for the first time; we study theln via the integration over ket bra operators in -ordering or -ordering, where Q-ordering means all Qs are to the left, of all Ps and -ordering means all Ps are to the left of all Qs. In this way we newly derive -ordered (or Q-ordered) expansion formulas of the two-mode squeezing operator which can show the squeezing effect on both the two-mode coordinate and momentum eigenstates. This tells that not only the integration over ket bra operators within normally ordered, but also within - ordered (or -ordered) are feasible and useful in developing quantum mechanical representation and transtbrlnation theory.  相似文献   

14.
“Post-sphaleron baryogenesis”, a fresh and profound mechanism of baryogenesis accounts for the matter–antimatter asymmetry of our present universe in a framework of Pati–Salam symmetry. We attempt here to embed this mechanism in a non-SUSY SO(10) grand unified theory by reviving a novel symmetry breaking chain with Pati–Salam symmetry as an intermediate symmetry breaking step and as well to address post-sphaleron baryogenesis and neutron–antineutron oscillation in a rational manner. The Pati–Salam symmetry based on the gauge group \(\mathrm{SU}(2)_L \times \mathrm{SU}(2)_{R} \times \mathrm{SU}(4)_C\) is realized in our model at \(10^{5}\) \(10^{6}\)  GeV and the mixing time for the neutron–antineutron oscillation process having \(\Delta B=2\) is found to be \(\tau _{n-\bar{n}} \simeq 10^{8}\) \(10^{10}\)  s with the model parameters, which is within the reach of forthcoming experiments. Other novel features of the model include low scale right-handed \(W^{\pm }_R\) , \(Z_R\) gauge bosons, explanation for neutrino oscillation data via the gauged inverse (or extended) seesaw mechanism and most importantly TeV scale color sextet scalar particles responsible for an observable \(n\) \(\bar{n}\) oscillation which may be accessible to LHC. We also look after gauge coupling unification and an estimation of the proton lifetime with and without the addition of color sextet scalars.  相似文献   

15.
The variation of two-photon absorption (TPA) coefficient \(\beta _{\mathrm{TPA}} (\omega )\) of Si excited at difference photon energy was investigated. The TPA coefficient was measured by using a picosecond pulsed laser with the wavelength could be tuned in a wide photon-energy range. An equivalent RC circuit model was adapted to derive the TPA coefficient \(\beta _{\mathrm{TPA}} (\omega )\) . The results showed that \(\beta _{\mathrm{TPA}} (\omega )\) varied from \(4.2 \times 10^{-4}\) to \(1.17 \times 10^{-3 }\)  cm/GW in the transparent wavelength region \(1.80<\lambda <1.36\,\upmu \) m of Si. The increasing tendency of \(\beta _{\mathrm{TPA}} (\omega )\) with the incident photon energy can be qualitatively interpreted as the photon energy increases from \(E_{\mathrm{ig}}/2\) to nearly \(E_{\mathrm{ig}}\) , the electrons excited from the valance band find an increasing availability of conduction band states. Comparing with the high-energy side transitions, the TPA coefficient in low-energy side is about 10 times too small. This can be attributed that the TPA transition in low-energy side is the process of photon-assisted electron transitions from valence to conduction band occurring between different points in k-space, while is direct transition in high-energy side.  相似文献   

16.
By using GaAs wafer as the saturable absorber, the laser-diode pumped passively Q-switched composite Nd:YVO \(_{4}\) laser has been successfully demonstrated. For this passively Q-switched operation, the average output power obtained is as high as 846 mW at the incident pump power of 5.31 W, while the pulse duration is as short as 14.5 ns. The largest single-pulse energy of 2.49 \(\upmu \) J and the highest peak power of 166 W are obtained. The GaAs saturable absorber with thickness of 400 \(\upmu \) m has shown more excellent laser performance comparing with 700 \(\upmu \) m thick GaAs.  相似文献   

17.
This paper inquires into the concavity of the map \(N\mapsto v_s(N)\) from the integers \(N\ge 2\) into the minimal average standardized Riesz pair-energies \(v_s(N)\) of \(N\) -point configurations on the sphere \(\mathbb {S}^2\) for various \(s\in \mathbb {R}\) . The standardized Riesz pair-energy of a pair of points on \(\mathbb {S}^2\) a chordal distance \(r\) apart is \(V_s(r)= s^{-1}\left( r^{-s}-1 \right) \) , \(s \ne 0\) , which becomes \(V_0(r) = \ln \frac{1}{r}\) in the limit \(s\rightarrow 0\) . Averaging it over the \(\left( \begin{array}{c} N\\ 2\end{array}\right) \) distinct pairs in a configuration and minimizing over all possible \(N\) -point configurations defines \(v_s(N)\) . It is known that \(N\mapsto v_s(N)\) is strictly increasing for each \(s\in \mathbb {R}\) , and for \(s<2\) also bounded above, thus “overall concave.” It is (easily) proved that \(N\mapsto v_{-2}^{}(N)\) is even locally strictly concave, and that so is the map \(2n\mapsto v_s(2n)\) for \(s<-2\) . By analyzing computer-experimental data of putatively minimal average Riesz pair-energies \(v_s^x(N)\) for \(s\in \{-1,0,1,2,3\}\) and \(N\in \{2,\ldots ,200\}\) , it is found that the map \(N\mapsto {v}_{-1}^x(N)\) is locally strictly concave, while \(N\mapsto {v}_s^x(N)\) is not always locally strictly concave for \(s\in \{0,1,2,3\}\) : concavity defects occur whenever \(N\in {\mathcal {C}}^{x}_+(s)\) (an \(s\) -specific empirical set of integers). It is found that the empirical map \(s\mapsto {\mathcal {C}}^{x}_+(s),\ s\in \{-2,-1,0,1,2,3\}\) , is set-theoretically increasing; moreover, the percentage of odd numbers in \({\mathcal {C}}^{x}_+(s),\ s\in \{0,1,2,3\}\) is found to increase with \(s\) . The integers in \({\mathcal {C}}^{x}_+(0)\) are few and far between, forming a curious sequence of numbers, reminiscent of the “magic numbers” in nuclear physics. It is conjectured that these new “magic numbers” are associated with optimally symmetric optimal-log-energy \(N\) -point configurations on \(\mathbb {S}^2\) . A list of interesting open problems is extracted from the empirical findings, and some rigorous first steps toward their solutions are presented. It is emphasized how concavity can assist in the solution to Smale’s \(7\) th Problem, which asks for an efficient algorithm to find near-optimal \(N\) -point configurations on \(\mathbb {S}^2\) and higher-dimensional spheres.  相似文献   

18.
Compelling experimental evidences of neutrino oscillations and their implication that neutrinos are massive particles have given neutrinoless double beta decay ( \(\beta \beta 0\nu \) ) a central role in astroparticle physics. In fact, the discovery of this elusive decay would be a major breakthrough, unveiling that neutrino and antineutrino are the same particle and that the lepton number is not conserved. It would also impact our efforts to establish the absolute neutrino mass scale and, ultimately, understand elementary particle interaction unification. All current experimental programs to search for \(\beta \beta 0\nu \) are facing with the technical and financial challenge of increasing the experimental mass while maintaining incredibly low levels of spurious background. The new concept described in this paper could be the answer which combines all the features of an ideal experiment: energy resolution, low cost mass scalability, isotope choice flexibility and many powerful handles to make the background negligible. The proposed technology is based on the use of arrays of silicon detectors cooled to 120 K to optimize the collection of the scintillation light emitted by ultra-pure crystals. It is shown that with a 54 kg array of natural CaMoO \(_4\) scintillation detectors of this type it is possible to yield a competitive sensitivity on the half-life of the \(\beta \beta 0\nu \) of \(^{100}\) Mo as high as \(\sim \) \(10^{24}\)  years in only 1 year of data taking. The same array made of \(^{40}\) Ca \(^{\mathrm {nat}}\) MoO \(_4\) scintillation detectors (to get rid of the continuous background coming from the two neutrino double beta decay of \(^{48}\) Ca) will instead be capable of achieving the remarkable sensitivity of \(\sim \) \(10^{25}\)  years on the half-life of \(^{100}\) Mo \(\beta \beta 0\nu \) in only 1 year of measurement.  相似文献   

19.
There are four types of two-Higgs doublet models under a discrete \(Z_2\) symmetry imposed to avoid tree-level flavor-changing neutral current, i.e. type-I, type-II, type-X, and type-Y models. We investigate the possibility to discriminate the four models in the light of the flavor physics data, including \(B_s\) \(\bar{B}_s\) mixing, \(B_{s,d} \rightarrow \mu ^+ \mu ^-\) , \(B\rightarrow \tau \nu \) and \(\bar{B} \rightarrow X_s \gamma \) decays, the recent LHC Higgs data, the direct search for charged Higgs at LEP, and the constraints from perturbative unitarity and vacuum stability. After deriving the combined constraints on the Yukawa interaction parameters, we have shown that the correlation between the mass eigenstate rate asymmetry \(A_{\Delta \Gamma }\) of \(B_{s} \rightarrow \mu ^+ \mu ^-\) and the ratio \(R=\mathcal{B}(B_{s} \rightarrow \mu ^+ \mu ^-)_\mathrm{exp}/ \mathcal{B}(B_{s} \rightarrow \mu ^+ \mu ^-)_\mathrm{SM}\) could be a sensitive probe to discriminate the four models with future precise measurements of the observables in the \(B_{s} \rightarrow \mu ^+ \mu ^-\) decay at LHCb.  相似文献   

20.
Chemiluminescence experiments have been performed to assess the state of current $\mathrm{CO}_{2}^{*}$ kinetics modeling. The difficulty with modeling $\mathrm{CO}_{2}^{*}$ lies in its broad emission spectrum, making it a challenge to isolate it from background emission of species such as CH? and CH2O?. Experiments were performed in a mixture of 0.0005H2+0.01N2O+0.03CO+0.9595Ar in an attempt to isolate $\mathrm{CO}_{2}^{*}$ emission. Temperatures ranged from 1654 K to 2221 K at two average pressures, 1.4 and 10.4 atm. The unique time histories of the various chemiluminescence species in the unconventional mixture employed at these conditions allow for easy identification of the $\mathrm{CO}_{2}^{*}$ concentration. Two different wavelengths to capture $\mathrm{CO}_{2}^{*}$ were used; one optical filter was centered at 415 nm and the other at 458 nm. The use of these two different wavelengths was done to verify that broadband $\mathrm{CO}_{2}^{*}$ was in fact being captured, and not emission from other species such as CH? and CH2O?. As a baseline for time history and peak magnitude comparison, OH? emission was captured at 307 nm simultaneously with the two $\mathrm{CO}_{2}^{*}$ filters. The results from the two $\mathrm{CO}_{2}^{*}$ filters were consistent with each other, implying that indeed the same species (i.e., $\mathrm{CO}_{2}^{*}$ ) was being measured at both wavelengths. A first-generation kinetics model for $\mathrm{CO}_{2}^{*}$ and CH2O? was developed, since no comprehensively validated one exists to date. CH2O? and CH? were ruled out as being present in the experiments at any measurable level, based on calculations and comparisons with the data. Agreement with the $\mathrm{CO}_{2}^{*}$ model was only fair, which necessitates future improvements for a better understanding of $\mathrm{CO}_{2}^{*}$ chemiluminescence as well as the kinetics of the ground state species.  相似文献   

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