Thermal Dehydration and Vibrational Studies of ZnK4(P3O9)2 · 6H2O

The thermal dehydration of ZnK₄(P₃O₉)₂ · 6H₂O was studied in the range 25–500°C by thermogravimetric analysis (TGA and DSC) and X‐ray diffraction. We found, based on the TGA and DSC scans, the dehydration of this salt takes place in three stages with a loss of the six water molecules. The infrared and Raman spectra of ZnK₄(P₃O₉)₂ · 6H₂O have been recorded and interpreted using a factor group analysis. The internal modes are assigned in terms of POP and PO₂ structural units using experimental and theoretical IR and Raman frequencies.     

Ab initio investigation of tensile strengths of metal(1 1 1)/α-Al2O3(0 0 0 1) interfaces

Ab initio calculations using plane wave pseudopotential method within density funtional theory are applied to investigate mechanical and electronic properties of Al-terminated Me(1 1 1)/Al₂O₃(0 0 0 1) (Me = Al, Ag, Cu, Nb) interfaces. Stress–displacement relationships of separation perpendicular to the interface are calculated. It is shown that obtained results such as work of separation and tensile strength can be understood from electronic structure.     

Infrared and Raman Spectroscopic Characterization of the Silicate Mineral Gilalite Cu5Si6O17 · 7H2O

Gilalite is a copper silicate mineral with a general formula of Cu₅Si₆O₁₇ · 7H₂O. The mineral is often found in association with another copper silicate mineral, apachite, Cu₉Si₁₀O₂₉ · 11H₂O. Raman and infrared spectroscopy have been used to characterize the molecular structure of gilalite. The structure of the mineral shows disorder, which is reflected in the difficulty of obtaining quality Raman spectra. Raman spectroscopy clearly shows the absence of OH units in the gilalite structure. Intense Raman bands are observed at 1066, 1083, and 1160 cm^?1.

The Raman band at 853 cm^?1 is assigned to the –SiO₃ symmetrical stretching vibration and the low-intensity Raman bands at 914, 953, and 964 cm^?1 may be ascribed to the antisymmetric SiO stretching vibrations. An intense Raman band at 673 cm^?1 with a shoulder at 663 cm^?1 is assigned to the ν₄ Si-O-Si bending modes. Raman spectroscopy complemented with infrared spectroscopy enabled a better understanding of the molecular structure of gilalite.     

Structural and dielectric behaviors of Bi4Ti3O12 – lyotropic liquid crystalline nanocolloids

We investigated the structural and dielectric dynamics of nanocolloids comprising lyotropic liquid crystals and bismuth titanate (Bi₄Ti₃O₁₂) spherical nanoparticles (≈16–18 nm) of varying concentration 0.05 and 0.1 wt%. The lyotropic liquid crystalline mixture was prepared by a binary mixture of cetylpyridinuium chloride and ethylene glycol mixed in 5:95 wt% ratio. Binary lyotropic mixture exhibited hexagonal lyotropic phase. Structural and textural characterizations of nanocolloids infer that the nanoparticles were homogeneously dispersed in the liquid crystalline matrix and did not perturb the hexagonal ordering of the lyotropic phase. The dielectric constant and dielectric strength were found to be increased with the rise in the Bi₄Ti₃O₁₂ nanoparticles concertation in the lyotropic matrix. A significant increase of one order was observed in the ac conductivity of colloidal systems as compared to the non-doped lyotropic liquid crystal. Relaxation parameters of the non-doped lyotropic liquid crystal and colloidal systems were computed and correlated with other parameters.     

New physics contribution to neutral trilinear gauge boson couplings

We study the one-loop new physics effects to the CP even triple neutral gauge boson vertices γ ^⋆ γ Z, γ ^⋆ Z Z, Z ^⋆ Z γ and Z ^⋆ ZZ in the context of Little Higgs models. We compute the contribution of the additional fermions in Little Higgs models in the framework of direct product groups where [SU(2)×U(1)]² gauge symmetry is embedded in SU(5) global symmetry and also in the framework of the simple group where SU(N)×U(1) gauge symmetry breaks down to SU(2) _L ×U(1). We calculate the contribution of the fermions to these couplings when T parity is invoked. In addition, we re-examine the MSSM contribution at the chosen point of SPS1a′ and compare with the SM and Little Higgs models.     

Spectroscopy of laser-produced cerium plasma for remote isotope analysis of nuclear fuel

A cerium oxide sample was ablated by 2nd harmonic radiation of Nd:YAG laser at a power density of 0.1 GW/cm². Time evolution of the ablation plume was investigated by laser absorption time-of-flight (TOF) measurement. It was found that the ablated ionic plume in vacuum consisted of two components having different velocities whereas the ablated neutral atoms had mainly a single component. The flow velocity perpendicular to the sample surface in vacuum was determined to be 3.5 km/s for neutral atoms, and 4.7 km/s and 9.3 km/s for singly charged ions. From the detailed plume evolution in ambient atmosphere with several pressures we obtained some experimental conditions suitable for isotope analysis of atomic cerium.     

Interpreting near-side correlations and the RHIC beam energy scan

Recent data from heavy ion collisions at RHIC show strong near-side correlations extending over several units of rapidity. This ridge-like correlation exhibits an abrupt onset with collision centrality. In this talk, I argue that the centrality and beam-energy dependence of these near-angle correlations could provide access to information about the Quark Gluon Plasma phase boundary and the Equation of State of nuclear matter. A beam-energy-scan at RHIC will better reveal the true source of these correlations and should be a high priority at RHIC.     

Cross-sections of large-angle hadron production in proton– and pion–nucleus interactions II: beryllium nuclei and beam momenta from ±3 GeV/c to ±15 GeV/c

We report on double-differential inclusive cross-sections of the production of secondary protons and charged pions, in the interactions with a 5% λ _abs thick stationary beryllium target, of proton and pion beams with momentum from ±3 GeV/c to ±15 GeV/c. Results are given for secondary particles with production angles 20° <θ<125°.     

High-gain Al2O3:Nd3+ channel waveguide amplifiers at 880 nm, 1060 nm, and 1330 nm

Neodymium-doped aluminum oxide films with a range of Nd³⁺ concentrations are deposited on silicon wafers by reactive co-sputtering, and single-mode channel waveguides with various lengths are fabricated by reactive ion etching. Photoluminescence at 880, 1060, and 1330 nm from the Nd³⁺ ions with a lifetime of 325 μs is observed. Internal net gain at 845–945 nm, 1064, and 1330 nm is experimentally and theoretically investigated under continuous-wave excitation at 802 nm. Net optical gain of 6.3 dB/cm at 1064 nm and 1.93 dB/cm at 1330 nm is obtained in a 1.4-cm-long waveguide with a Nd³⁺ concentration of 1.68×10²⁰ cm^?3 when launching 45 mW of pump power. In longer waveguides a maximum gain of 14.4 dB and 5.1 dB is obtained at these wavelengths, respectively. Net optical gain is also observed in the range 865–930 nm and a peak gain of 1.57 dB/cm in a short and 3.0 dB in a 4.1-cm-long waveguide is obtained at 880 nm with a Nd³⁺ concentration of 0.65×10²⁰ cm^?3. By use of a rate-equation model, the gain on these three transitions is calculated, and the macroscopic parameter of energy-transfer upconversion as a function of Nd³⁺ concentration is derived. The high internal net gain indicates that Al₂O₃:Nd³⁺ channel waveguide amplifiers are suitable for providing gain in many integrated optical devices.     

Wavelength-independent all-optical synchronization of a Q-switched 100-ps microchip laser to a femtosecond laser reference source

We present a Q-switched microchip laser emitting 1064-nm pulses as short as 100 ps synchronized to a cavity dumped femtosecond laser emitting 800-nm pulses as short as 80 fs. The synchronization is achieved by presaturating the saturable absorber of the microchip laser with femtosecond pulses even though both lasers emit at widely separated wavelengths. The mean timing jitter is 40 ps and thus considerably shorter than the pulse duration of the microchip laser.     

Multiplicity distributions in canonical and microcanonical statistical ensembles

The aim of this paper is to introduce a new technique for the calculation of observables, in particular multiplicity distributions, in various statistical ensembles at finite volume. The method is based on Fourier analysis of the grand canonical partition function. A Taylor expansion of the generating function is used to separate contributions to the partition function in their power in volume. We employ Laplace’s asymptotic expansion to show that any equilibrium distribution of multiplicity, charge, energy, etc. tends to a multivariate normal distribution in the thermodynamic limit. A Gram–Charlier expansion additionally allows for the calculation of finite volume corrections. Analytical formulas are presented for the inclusion of resonance decay and finite acceptance effects directly into the partition function of the system. This paper consolidates and extends previously published results of the current investigation into the properties of statistical ensembles.     

Studying the relative bottom contribution via heavy-quark decay electron measurements in STAR

We report measurements of the azimuthal angular correlation distribution of heavy-quark decay electrons and open charmed mesons in pp collisions at  GeV in the STAR experiment at RHIC. This measurement in combination with current theoretical model calculations allows to extract the relative bottom contribution to the heavy-quark decay electrons, which is important for the interpretation of the observed strong suppression of the high-p _T electron yield in central Au+Au collisions.     

Information-Geometric Indicators of Chaos in Gaussian Models on Statistical Manifolds of Negative Ricci Curvature

A new information-geometric approach to chaotic dynamics on curved statistical manifolds based on Entropic Dynamics (ED) is proposed. It is shown that the hyperbolicity of a non-maximally symmetric 6N-dimensional statistical manifold ℳ _s underlying an ED Gaussian model describing an arbitrary system of 3N degrees of freedom leads to linear information-geometric entropy growth and to exponential divergence of the Jacobi vector field intensity, quantum and classical features of chaos respectively.     

Distributional and Classical Solutions to the Cauchy Boltzmann Problem for Soft Potentials with Integrable Angular Cross Section

This paper focuses on the study of existence and uniqueness of distributional and classical solutions to the Cauchy Boltzmann problem for the soft potential case assuming S ^n?1 integrability of the angular part of the collision kernel (Grad cut-off assumption). For this purpose we revisit the Kaniel–Shinbrot iteration technique to present an elementary proof of existence and uniqueness results that includes the large data near local Maxwellian regime with possibly infinite initial mass. We study the propagation of regularity using a recent estimate for the positive collision operator given in (Alonso et al. in Convolution inequalities for the Boltzmann collision operator. arXiv:0902.0507 [math.AP]) , by E. Carneiro and the authors, that allows us to show such propagation without additional conditions on the collision kernel. Finally, an L ^p -stability result (with 1≤p≤∞) is presented assuming the aforementioned condition.     

Review of searches for Higgs bosons and beyond the Standard Model Physics at the Tevatron

The energy frontier is currently at the Fermilab Tevatron accelerator, which collides protons and antiprotons at a center-of-mass energy of 1.96 TeV. The luminosity delivered to the CDF and DØ experiments has now surpassed the 4 fb^?1. This paper reviews the most recent direct searches for Higgs bosons and beyond-the-standard-model (BSM) physics at the Tevatron. The results reported correspond to an integrated luminosity of up to 2.5 fb^?1 of Run II data collected by the two Collaborations. Searches covered include the standard model (SM) Higgs boson (including sensitivity projections), the neutral Higgs bosons in the minimal supersymmetric extension of the standard model (MSSM), charged Higgs bosons and extended Higgs models, supersymmetric decays that conserve or violate R-parity, gauge-mediated supersymmetric breaking models, long-lived particles, leptoquarks, compositeness, extra gauge bosons, extra dimensions, and finally signature-based searches. Given the excellent performance of the collider and the continued productivity of the experiments, the Tevatron physics potential looks promising for discovery with the coming larger data sets. In particular, evidence for the SM Higgs boson could be obtained if its mass is light or near 160 GeV. The observed (expected) upper limits are currently a factor of 3.7 (3.3) higher than the expected SM Higgs boson cross section at m _H =115 GeV and 1.1 (1.6) at m _H =160 GeV at 95% C.L.     

Diode laser pumped Gd2O3:Er3+/Yb3+ phosphor as optical nano-heater

An intense green upconversion (UC) emission (λ _exc=976 nm) followed by the heating effect in Yb³⁺/Er³⁺ co-doped Gd₂O₃ nanoparticles has been detected. A temperature rise up to 504 K has been observed (on a noteworthy low laser excitation of 290 mW) using fluorescence intensity ratio (FIR) method of the thermalized UC luminescence bands ²H_11/2→⁴I_15/2 and ⁴S_3/2→⁴I_15/2 of Er³⁺ ion. The reported controlled optical heating of nanoparticles and its nano-volume has potential applications in biomedicines and in the creation of holes in soft materials.     

On the evaluation of gluon condensate effects in the holographic approach to QCD

In holographic QCD the effects of gluonic condensate can be encoded in a suitable deformation of the 5D metric. We develop two different methods for the evaluation of first order perturbative corrections to masses and decay constants of vector resonances in 5D Hard-Wall models of QCD due to small deformations of the metric. They are extracted either from a novel compact form for the first order correction to the vector two-point function, or from perturbation theory for vector bound-state eigenfunctions: the equivalence of the two methods is shown. Our procedures are then applied to flat and to AdS 5D Hard-Wall models; we complement results of existing literature evaluating the corrections to vector decay constant and to two-pion–one-vector couplings: this is particularly relevant to satisfy the sum rules. We concentrate our attention on the effects for the Gasser–Leutwyler coefficients; we show that as in the Chiral Quark model, the addition of the gluonic condensate improves the consistency, the understanding and the agreement with phenomenology of the holographic model.     

Monopolium production from photon fusion at the Large Hadron Collider

Magnetic monopoles have attracted the attention of physicists since the founding of the electromagnetic theory. Their search has been a constant endeavor which was intensified when Dirac established the relation between the existence of monopoles and charge quantization. However, these searches have been unsuccessful. We have recently proposed that monopolium, a monopole–antimonopole bound state, so strongly bound that it has a relatively small mass, could be easier to find and become an indirect but clear signature for the existence of magnetic monopoles. Here we extend our previous analysis for its production to two photon fusion at LHC energies.     

The modification effect in magnetization behaviors for CoFe2O4–p-NiFe2O4 binary ferrofluids

The magnetization curves of CoFe₂O₄ ferrofluids, p-NiFe₂O₄ paramagnetic fluids and CoFe₂O₄–p-NiFe₂O₄ binary ferrofluids, in which the volume fraction of CoFe₂O₄ particles φ _Co is 0.6% and one of p-NiFe₂O₄ particles φ _Ni is 0.2%, 0.4%, 0.6% and 0.8% respectively, prepared by the Massart method, have been measured at room temperature. Comparison of the experimental data from the CoFe₂O₄ ferrofluids with the Langevin theory curves demonstrates a considerable difference between them, but a curve fitted using a model of a gas-like compression (MGC) agrees with the experimental data very well. The experimental results show that the magnetization of the CoFe₂O₄–p-NiFe₂O₄ binary ferrofluid is not a simple summation of the ferrimagnetic CoFe₂O₄ part and the paramagnetic p-NiFe₂O₄ part. From the fitted results, it was found that the saturation magnetization of the CoFe₂O₄ part of the binary ferrofluid depends non-monotonically on the p-NiFe₂O₄ particle volume fraction, and the CoFe₂O₄ part is a stronger “hard” magnet than CoFe₂O₄ in simple ferrofluids. The magnetization behavior of the binary ferrofluids is explained by the modification of the microstructure of CoFe₂O₄ nanoparticle system by the p-NiFe₂O₄ nanoparticle system.     

Quantum corrections to the entropy of charged rotating black holes

Hawking radiation from a black hole can be viewed as quantum tunneling of particles through the event horizon. Using this approach we provide a general framework for studying corrections to the entropy of black holes beyond semiclassical approximations. Applying the properties of exact differentials for three variables to the first law thermodynamics, we study charged rotating black holes and explicitly work out the corrections to entropy and horizon area for the Kerr–Newman and charged rotating BTZ black holes. It is shown that the results for other geometries like the Schwarzschild, Reissner-Nordström and anti-de Sitter–Schwarzschild spacetimes follow easily.