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A hydrothermal technique was used to synthesize nickel ferrite nanoparticles (NF-NPs) deposited on multi-walled carbon nanotubes (MWCNTs). The material was characterized by scanning electron microscopy, energy dispersive spectrometry, and X-ray powder diffraction which showed that the NF-NPs are located on the surface of the carboxylated MWCNTs. The material was used to modify a glassy carbon electrode which then was characterized via cyclic voltammetry, electrochemical impedance spectroscopy, and amperometry. The electrode displays strong electrochemical response to hydrazine. A potential hydrazine sensing scheme is suggested.
Figure
A fast and sensitive hydrazine electrochemical sensor has been fabricated by dipping nickel ferrite/multi-walled carbon nanotubes onto the pretreated glassy carbon electrode. The sensor had excellent stability, rapid response, ease of construction and utilization for hydrazine determination.  相似文献   

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An electrode sensitive to uric acid was prepared by electrodeposition of nickel(II) hexacyanoferrate(III) on the surface of a glassy carbon electrode modified with multi-walled carbon nanotubes. The morphology of the material was characterized by scanning electron microscopy and Fourier transform infrared spectrometry. The modified electrode were characterized via cyclic voltammetry and amperometry (i - t). It exhibited efficient electron transfer ability and a strong and fast (< 3?s) response towards uric acid which is linear in the range from 0.1???M to 18???M, with a lower detection limit of 50 nM (at an S/N ratio of 3). In addition, the electrode exhibited good reproducibility and long-term stability.
Figure
A fast and sensitive uric acid electrochemical sensor has been fabricated by electrodepositing nickel hexacyanoferrate nanoparticles onto multi-walled carbon nanotubes/glassy carbon electrode. The sensor had excellent stability, rapid response, ease of construction and utilization for uric acid determination  相似文献   

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We report on an amperometric sensor for ascorbic acid (AA) that is based on highly dense gold-silver nanotubes in a chitosan film on a glassy carbon electrode. The nanotubes were synthesized by a poly(vinyl pyrrolidone)-mediated polyol method employing a replacement reaction with silver nanowires as templates, and were characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and X-ray diffraction. Under the optimal conditions, the sensor exhibits good electrocatalytic activity towards the oxidation of AA, and this enables the determination of AA in the 5 μM to 2 mM concentration range, with a detection limit at 2 μM (at an S/N of 3). The response time is 2 s. The sensor displays good reproducibility, selectivity, sensitivity, and long-term stability.
Figure
In this paper, an amperometric electrochemical sensor for detection of ascorbic acid was fabricated based on highly dense gold-silver nanotubes and chitosan film. The biosensor showed good reproducibility, anti-interferant ability, high sensitivity, low detection limit, fast response, and long-term stability.  相似文献   

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We have developed a highly sensitive and selective sensor for lead(II) ions. A glassy carbon electrode was modified with Fe3O4 nanospheres and multi-walled carbon nanotubes, and this material was characterized by scanning electron microscopy and X-ray diffraction. The electrode displays good electrochemical activity toward Pb(II) and gives anodic and cathodic peaks with potentials at ?496 mV and ?638 mV (vs. Ag/AgCl) in pH?6.0 solution. The sensor exhibits a sensitive and fairly selective response to Pb(II) ion, with a linear range between 20 pM and 1.6 nM, and a detection limit as low as 6.0 pM (at a signal-to noise ratio of 3). The sensor was successfully applied to monitor Pb(II) in spiked water samples.
Figure
A fast and sensitive Pb(II) electrochemical sensor has been fabricated by modifying Fe3O4 nanospheres and multi-walled carbon nanotubes onto the pretreated glassy carbon electrode. The electrode displays good electrochemical activity toward Pb(II). And a low detection limit of 6.0 pM, high sensitivity, good reproducibility and stability provide the Fe3O4/MWCNTs/GCE a definite candidate for monitoring lead ion in real samples.  相似文献   

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Yang P  Wei W  Tao C 《Analytica chimica acta》2007,585(2):331-336
Novel nano-silver coated multi-walled carbon nanotube composites were prepared and used to fabricate a modified electrode. The application of the nano-silver coated multi-walled carbon nanotube composites modified electrode for determination of trace thiocyanate is demonstrated for the first time. The influence of substrate, pH and interference of coexisting substances was investigated for response properties of the electrode. There was a linear relationship at the range 2.5 × 10−9 to 5 × 10−8 mol L−1 and 5 × 10−8 to 1 × 10−6 mol L−1 of thiocyanate with the decrement of anodic DPV peak currents. The limit of detection was 1 × 10−9 mol L−1(S/N = 3). The constructed electrode showed excellent reproducibility and stability. Actual urine and saliva samples of smoker and non-smoker were analyzed and satisfactory results were obtained. This method provides a new way to construct any electrode for biological and environmental analysis.  相似文献   

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We report on an electrochemical sensor for the sensitive amperometric determination of ascorbic acid (AA). Aniline containing suspended silicotungstic acid and carbon nanotubes was electropolymerized on the surface of a glassy carbon electrode in a single step which provides a simple and controllable method and greatly improves the electrocatalytic oxidation of AA. The effects of scan rate, solution pH and working potential were studied. A linear relationship exists between the current measured and the concentration of AA in the range from 1 μM to 10 μM and 0.01 mM to 9 mM, with a limit of detection as low as 0.51 μM (S/N?=?3). The sensor is selective, stable and satisfyingly reliable in real sample experiments. In our eyes, it has a large potential for practical applications.
Figure
Aniline containing suspended silicotungstic acid and carbon nanotubes was electropolymerized on the surface of a glassy carbon electrode in a single step. Due to the novel properties of silicotungstic acid and carbon nanotubes doped in the polyaniline film, this sensor showed excellent analytical performance for the amperometric determination of ascorbic acid at a low potential.  相似文献   

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We discovered a novel method to prepare a protein-based hydrogel, that is, a “Three-Dimensional Nanostructured Protein Hydrogel (3D NPH)”, which is composed of protein–polymer hybrid nanoparticles. In this study, we propose a novel protein microarray whose 3D NPH spots were prepared by dispensing a small volume of the solution of protein–polymer mixture on a substrate. The dispensed solution had a short time for cross-linking before its drying-up and the resulting 3D NPH had loosely cross-linked, thin spongy structure. Therefore, the reaction ratio between ligands and analytes was drastically improved in this system compared with the large volume system for Surface Plasmon Resonance (SPR) protein microarray.  相似文献   

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A cobalt(II) tetrakisphenylporphyrin (Co(II)TPP) film modified glassy carbon electrode (Co(II)TPP-GCE) was prepared by just coating Co(II)TPP solution on the surface of the electrode. It can be used for the simultaneous determination of ascorbic acid and uric acid. The anodic peaks of AA and UA can be separated well. Owing to the strongly hydrophobic property of porphyrin, the modified electrode has good stability and long life. The linear range for UA and AA were 2.0 x 10(-6)-1.0 x 10(-4) M and 9.0 x 10(-6)-2.0 x 10(-3) M with detection limits of 5.0 x 10(-7) and 5.0 x 10(-6) M, respectively. Furthermore, metalloporphyrins of other kinds were also used to construct modified electrodes. Their performances were inferior compared with that of the Co(II)TPP modified electrode.  相似文献   

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Xu  Wailan  He  Junlin  Gao  Liuliu  Zhang  Jing  Yu  Chao 《Mikrochimica acta》2015,182(13):2115-2122

We describe a nanostructured immunosensor for the cardiovascular biomarker netrin 1. A glassy carbon electrode was consecutively modified with multi-walled carbon nanotubes (MWCNTs), nafion (to retain the MWCNTs), thionine-coated gold nanoparticles (Thi@AuNPs), and monoclonal antibodies against netrin 1. The modified electrode was characterized by transmission electron microscopy, cyclic voltammetry, differential pulse voltammetry, UV-visible spectrophotometry and X-ray diffraction. The presence of Thi@AuNPs warrants direct and convenient immobilization of the antibody. This immunoelectrode enables netrin 1 to be determined, best at a voltage of −300 mV (vs. SCE), with a limit of detection of 30 fg mL−1 (at an S/N ratio of 3) after a 50 min incubation time. The detection range extends from 0.09 to 1800 pg∙mL−1. The method is simple, sensitive, specific and reproducible. We presume this stable and reproducible biosensor to be useful for the early detection of cardiovascular diseases.

A high sensitivity immunoassay was developed for the detection of netrin 1 based on multi-walled carbon nanotubes, thionine and gold nanoparticles. Its excellent performance is ascribed to the good conductivity of MWCNTs and the combination of materials.

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Deng  Pei-Hong  Fei  Jun-Jie  Zhang  Jun  Li  Ju-Nan 《Mikrochimica acta》2009,165(1-2):211-216

A glassy carbon electrode modified with multi-walled carbon nanotubes (MWCNT) was prepared and the determination of trace amount of vanadium(V) based on the anodic adsorptive voltammetry of the vanadium-alizarin red S (ARS) complex is described for the first time. The results show that the sensitivity and the selectivity of the method are excellent. The second derivative linear scan voltammograms of the complex were recorded using a polarographic analyzer in the range from 0 to 1,000 mV (vs. SCE). It was found that the complex can be adsorbed on the surface of the electrode, yielding a peak at about 706 mV, corresponding to the oxidation of ARS in the complex. The peak current increases linearly with the V(V) concentration in the range of 6.0 nM to ∼1.0 μM (4.0 μM ARS), 2.0 μM∼10 μM (40 μM ARS) and the detection limit (at S/N = 3) was 2.0 nM (accumulation time 120 s). The method was successfully applied to the determination of trace amounts of vanadium in water samples.

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Electrochemical properties of nicotine at the glassy carbon electrode modified with multi-walled carbon nanotubes were explored. Nicotine underwent irreversible reduction at the modified electrode, which was an adsorption-controlled process with two protons and two electrons. The reductive peak current of nicotine significantly increased at the modified electrode compared with the bare glassy carbon electrode, suggesting that the multi-walled carbon nanotubes can enhance the electron transfer rate. The current was proportional to the concentration of nicotine over two line ranges, and the detection limit was 9.3 µM (at S/N?=?3). For ten parallel detections of 0.62 mM nicotine, the relative standard deviation was 2.67%, suggesting that the film modified electrode had excellent reproducibility. The modified electrode was applied to the direct determination of nicotine in tobacco samples with good sensitivity, selectivity and stability.  相似文献   

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Microchimica Acta - Gold nanoparticles (AuNP) were deposited on the surface of multiwalled carbon nanotubes (MWCNT) by in-situ thermal decomposition of gold acetate under solvent and reducing agent...  相似文献   

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Electrocatalytic oxidation of sulfide ion on a glassy carbon electrode (GCE) modified with multiwall carbon nanotubes (MWCNTs) and a copper (II) complex was investigated. The Cu(II) complex was used due to the reversibility of the Cu(II)/Cu(III) redox couple. The MWCNTs are evaluated as a transducer, stabilizer and immobilization matrix for the construction of amperometric sensor based on Cu(II) complex adsorbed on MWCNTs immobilized on the surface of GCE. The modified GCE was applied to the selective amperometric detection of sulfide at a potential of 0.47 V (vs. Ag/AgCl) at pH 8.0. The calibration graph was linear in the concentration range of 5 µM–400 µM; while the limit of detection was 1.2 µM, the sensitivity was 34 nA µM?1. The interference effects of SO3 2?, SO4 2?, S2O3 2?, S4O6 2?, Cysteine, and Cystein were negligible at the concentration ratios more than 40 times. The modified electrode is more stable with time and more easily restorable than unmodified electrode surface. Also, modified electrode permits detection of sulfide ion by its oxidation at lower anodic potentials.   相似文献   

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A highly sensitive and mercury-free method for determination of bisphenol A (BPA) was established using a glassy carbon electrode that was modified with carboxylated multi-walled carbon nanotubes. A sensitive oxidation peak is found at 550?mV in linear sweep voltammograms at pH?7. Based on this finding, trace levels of bisphenol A can be determined over a concentration range that is linear from 10?nM to 104?nM, the correlation coefficient being 0.9983, and the detection limit (S/N?=?3) being 5.0?nM. The method was successfully applied to the determination of BPA in food package.
Figure
A new electrochemical method was developed for the determination of bisphenol A based on carboxylated multi-walled carbon nanotubes modified electrode.  相似文献   

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