Resonant absorption in LiNdP4O12 lasers

The resonant loss in LiNdP₄O₁₂ (LNP) lasers has been investigated. The effective resonant loss coefficient for the 1.047(7) μm laser emission was measured to be 0.042 cm^-1. This value can be explained by resonant absorption due to the ⁴I_{1$\text{1}\text{2}$}→⁴F_{$\text{3}\text{2}$} transition including the reabsorption effect of the fluorescence resulting from the ⁴I_{$\text{9}\text{2}$}→⁴F_{$\text{3}\text{2}$} transition.     

Time-resolved site-selection spectroscopy studies of NdAl3(BO3)4 crystals

A pulsed, tunable dye laser was used to selectively excite Nd³⁺ ions in nonequivalent crystal field sites in NdAl₃(BO₃)₄ crystals and energy transfer between ions in different types of sites was studied by monitoring the time evolution of the fluorescence spectrum. The results show that the energy transfer rate varies as t^{$\text{-1}\text{2}$} and increases with temperature. The predictions of various models of phonon-assisted energy transfer are compared to the results.     

Valence band parameters of cubic zinc selenide derived from magnetoreflectance of the Γ6 − Γ8 exciton

Magnetoreflectance measurements on the Γ₆ ? Γ₈ free exciton ground state in cubic ZnSe in magnetic fields up to 18 Tesla are reported. The diamagnetic shift rate of the ground state components: $\text{|}\text{3}\text{2}\text{>β}$, $\text{|?}\text{3}\text{2}\text{>α}$, $\text{|}\text{1}\text{2}\text{>β}$ and $\text{|?}\text{1}\text{2}\text{>α}$ yield γ₂ = 0.53 ± 0.07 and an exciton reduced mass μ₀ = 0.117 ± 0.003, corresponding to γ₁ = 2.30 ± 0.45 for m_e¹ = 0.16 m₀. γ₁, γ₂ and an effective hole g-value $\text{κ}\text{tilde}\text{= -0.21}$ yield γ₃ = 0.82 ± 0.16 in the parabolic approximation and in agreement with the observed splitting of the $\text{|?}\text{3}\text{2}\text{>α}$, $\text{|?}\text{1}\text{2}\text{>β}$ states for B ∥ [110]. Taking into account polaron effects we derive bare valence band parameters γ₁^L = 2.71 ± 0.60, γ₂^L = 0.63 ± 0.09 and γ₃^L = 0.97 ± 0.21 from the renormalized parameters γ_i. The present results are considerably smaller than earlier theoretical calculations suggest, however they are in good agreement with a recent detailed analysis of two-photon absorption data for 2P exciton states.     

Inclusive K10(890) production in π−p interactions at 16 GeV/c

Inclusive $\text{K}{}^{10}$ production is studied in π^?p interactions at 16 GeV/c with x_? > 0.2. The $\text{K}{}^{10}$ is found to be pre-dominantly centrally produced with cross section $\text{σ(}\text{K}{}^{10}\text{) = (72 ± 12) μb}$ for x_? > 0.2 and compares closely to data on $\text{K}{}^{10}$ production in π⁺p interactions at the same energy.     

Relaxation of the 4G92 state of Nd3+ in LaCl3 and Nd3+ in La(Cl99.6Br0.4)3

The decay of the ⁴G_{$\text{9}\text{2}$} state of Nd³⁺ in LaCl₃ and La(Cl_99.6 Br_0.4)₃ was measured after pulsed laser excitation as a function of temperature. The decay rate is shown to depend besides the radiative transition on single-phonon relaxation between the states ⁴G_{$\text{9}\text{2}$} ($\text{μ =}\text{1}\text{2}$) and ⁴G_{$\text{9}\text{2}$} ($\text{μ =}\text{3}\text{2}$) and on multiphonon orbit-lattice relaxation from ⁴G_{$\text{9}\text{2}$} to ²G_{$\text{9}\text{2}$}. Partial substitution of Cl by Br only alters the radiative lifetime.     

Characterization of LiFeCl4 and AgFeCl4 ionic conductors

LiFeCl₄ and AgFeCl₄ are obtained by direct reaction between LiCl or AgCl and FeCl₃ at 300°C and 400°C respectively. Both compounds are monoclinic with $\text{a = 7.02 (1)}\text{A}\text{?}$, $\text{b = 6.33 (1)}\text{A}\text{?}$, $\text{c = 12.72 (4)}\text{A}\text{?}$, β = 92° (30') for LiFeCl₄ and $\text{a = 10.60 (5)}\text{A}\text{?}$, $\text{b = 6.30 (5)}\text{A}\text{?}$, $\text{c = 12.34 (10)}\text{A}\text{?}$, β = 106° (1) for AgFeCl₄.LiFeCl₄ is clearly isotypic of LiAlCl₄. Magnetic measurements characterize in both cases Fe³⁺ ions in a high spin tetrahedral situation. LiFeCl₄ becomes antiferromagnetic at low temperature (T_N?10 K). AgFeCl₄ reveals a more complex situation. On contrary to the silver derivative, LiFeCl₄ is a good ionic conductor with activation energy of 0.78 eV in the solid state below 105°C, and a sharp increase in the lithium mobility at this temperature.     

Study on vacancy motion in Y2O3-doped CeO2 by 17O NMR technique

The ¹⁷O NMR measurement was made to elucidate the microscopic nature of vacancy motion in Y₂O₃-doped CeO₂. Spin-lattice relaxation rate, T^?1₁, spin-spin relaxation rate, T^?1₂, and resonance intensity were measured at v₀ = 8.13 MHz as a function of temperature [385 < T (K) < 1110] and composition [$\text{0.06 <}\text{Y}{}_2\text{O}{}_3\text{(}\text{m}\text{o}\text{) < 6}$]. The static electric field gradient associated with lattice defects resulted in the composition dependences of the line width and the intensity. In low dopant concentrations, doubly peaked temperature dependence of T^?1₁ was found, while a single and asymmetric peak was observed in high concentrations. T^?1₁ of 4.0 and 6.0 $\text{m}\text{o}$ doped samples were analyzed using a barrier height distribution model for the oxygen vacancy jump. The mean value of the activation energy was found to increase with the Y₂O₃ concentration.     

Collisional quenching of HgBr(B2∑+12)

Rate coefficients for the quenching of HgBr(B²∑⁺_{$\text{1}\text{2}$}) by HgBr₂, H₂, CO₂, CO, O₂, N₂, Xe, and Br₂ are reported. HgBr(B²∑⁺_{$\text{1}\text{2}$}) is formed by the photolysis of HgBr₂ with the output from an ArF laser. The rate coefficients are determined by monitoring the time resolved B²∑⁺_{$\text{1}\text{2}$} → X²∑⁺_{$\text{1}\text{2}$} emission as quenching species are added. Radiative lifetimes at particular emission frequencies are also reported, and quenching mechanisms are discussed.     

Electron dynamics in CaB6 induced by one- and two-color femtosecond laser

We simulate nonlinear electron dynamics in CaB₆ crystal within the framework of time-dependent density functional theory (TDDFT) under one-color femtosecond laser fields (400 nm, 800 nm) and two-color cases (400 nm+800 nm$400\text{nm}+800\text{nm}$) with different relative phases of ?=0$?=0$, ?=π/4$?=\pi /4$, ?=π/2$?=\pi /2$. The time-dependent Kohn–Sham equation (TDKS) is solved in real-time and real-space evolution scheme. We investigate the energy absorption and the electron excitation of CaB₆ crystal in detail. Besides, the electron density distributions and occupations are shown after each external field ends. Computational results indicate that for one-color case, the excitation behaviors are distinct due to the different frequencies; for two-color laser, we adjust the phase and obtain the asymmetric field, which causes the change of the dynamics response comparing with the symmetric field. At the end of laser, the electron occupation is broadly distributed in the energy range of 2.4–42.4 eV, which means a high excitation rate in the narrow-gap semiconductor under intense laser field. The occurrence of the breakdown is also checked for each case in the Letter.     

Magnetic properties of CuCr2Se4 single crystals

The magnetic properties of CuCr₂Se₄ single crystals, which were grown by chemical transport reactions using iodine as a carrier, have been investigated. The magnetic moment at 0 K is found to be 5.07 μ_B per mole. The susceptibility at high temperatures follows a Curie-Weiss law with an asymptotic Curie temperature 430 K and a Curie constant 2.55 emu · $\text{deg}\text{mol}$. The magnetocrystalline anisotropy constants K₁ and K₂ are ? 6.9x 10⁵ and ? 0.9x 10⁵$\text{erg}\text{cm}{}^3$, respectively, at 5.1 K.In order to examine the effects of annealing on the magnetocrystalline anisotropy, the ferromagnetic resonance at room temperature was measured after annealing in vacuum and subsequently in an atmosphere of Se. It is found that the absolute values of K₁ and K₂ decrease after annealing in vacuum and increase to the initial values after annealing in an atmosphere of Se.     

Far infrared laser magnetic resonance spectrum of CH

Laser magnetic resonance spectra between 0 and 17 kG have been recorded and analyzed for $\text{(J′ ← J″) = (}\text{7}\text{2}\text{←}\text{5}\text{2}\text{)}$, $\text{(}\text{5}\text{2}\text{←}\text{3}\text{2}\text{)}$, and $\text{(}\text{3}\text{2}\text{←}\text{1}\text{2}\text{)}$ transitions in the CH molecule, using the optically pumped far infrared lasers: 118.8 μm (CH₃OH), 180.7 μm (CD₃OH), 554.4 μm (CH₂CF₂), 561.3 μm (DCOOD), and 567.9 μm (CH₂CHCl). Other transitions in CH were detected with the ¹³CH₃OH laser at 115.8, 149.3, and 203.6 μm. The CH radical was generated in a low-pressure methane and atomic fluorine flame within the laser cavity. Analysis of the M′_J ← M″_J structure yields wavenumbers for the rotational transitions mentioned above of 84.3494, 55.3397, and 17.8376 cm^?1, respectively. Combining results from the M_J analysis with the $\text{J =}\text{1}\text{2}\text{Λ-}\text{doubling}$ interval derived from radioastronomy measurements yields Λ-doubling values for the $\text{J =}\text{3}\text{2}\text{,}\text{5}\text{2}$, and $\text{7}\text{2}$ states of 0.0237, 0.1620, and 0.3759 cm^?1, respectively. Both the rotational intervals and the Λ-doublings are in good agreement with earlier less precise optical results. Analysis of the hyperfine structure yields values for the Frosch and Foley hyperfine parameters of a = +52, b = ?74, c = +52, and d = +43.6 MHz, in good agreement with recent ab initio estimates and radioastronomy measurements.     

Absorption of CO2 laser pulses at different wavelengths by ground-state and vibrationally heated SF6

The absorption of CO₂ laser pulses by low pressure SF₆ gas has been investigated over a wide range of energy fluxes. For laser energy fluxes of 0.01–1 J cm^-2 the effective absorption cross section varies between 0.2 and 2 × 10^-18 cm². For each laser line an individual dependence on the energy is found and in some cases minor changes in the absorption behaviour seem to occur around 0.1 J cm^-2. SF₆ excited with an average vibrational energy content of up to 20 photons/molecule does not absorb measurable amounts of 9.4 μm laser light. The influence of various SF₆ and Ar pressures on the temporal shape of the transmitted pulses has been investigated.     

20Ne + n → 21Ne(T = 32) resonances

$\text{T =}\text{3}\text{2}$ resonances in ²¹Ne have been studied in measurements of the total neutron cross section of ²⁰Ne using the 190 m neutron time-of-flight facility of the Karlsruhe Isochronous Cyclotron. The high time-of-flight resolution of 6.6 ps/m enabled the study of sharp $\text{T =}\text{3}\text{2}$ resonances in ²¹Ne with an effective energy resolution of up to 4000. Five $\text{T =}\text{case3}\text{2}$ levels have been observed as sharp resonances allowing the precise determination of total width Λ, partial decay with Λ_no and resonance energy E_R. The c.m. resonance parameters of the first $\text{T =}\text{3}\text{2}$ state in ²¹Ne are E_R = 2098.6 ± 0.3 keV, Λ = 2.2 ± 0.5 keV and Λ_no = 0.21 ± 0.05 keV. Upper limits for the partial decay widths are deduced for those $\text{T =}\text{3}\text{2}$ levels which do not appear as resonance anomalies. A search for additional $\text{T =}\text{3}\text{2}$ states was undertaken. The resonance energies are discussed in the framework of the isbobaric mass multiplet equation. The decay widths are compared with shell-model predictions of isospin mixing and the systematics of isospin-non-conserving particle decays.     

Doppler-limited dye laser excitation spectrum of the C2 Swan band (v′ − v″ = 1 − 0)

The dye laser excitation spectrum of the Swan band (v′ ? v″ = 1 ? 0) has been observed with Doppler-limited resolution. The C₂ molecule was generated by the reaction of microwave discharge products of CF₄ with CH₄. The high sensitivity of laser excitation spectroscopy has enabled us to observe not only $\text{ΔΩ}\text{= 0}$ transitions, but also $\text{ΔΩ}\text{= ± 1}$ transitions and to determine molecular constants including the spin-orbit coupling constant for both the d³Π_g and a³Π_u states. The parameters thus obtained for a³Π_u were favorably compared with those previously obtained from the Ballik-Ramsay band. The present results on the d³Π_gv = 1 state were combined with those of an earlier Fourier spectroscopic study on the Swan band (v′ ? v″ = 0 ? 0) to derive equilibrium molecular constants for the d³Π_g state. The contributions of the spin-rotation interaction and the centrifugal correction for the spin-orbit coupling to the energy levels in a ³Π state have been discussed in detail.     

Spectral properties of a HgBr2 photodissociation laser

A small-size HgBr₂ photodissociation laser is operated without buffer gas. It is shown, that in the laser emission as well as in the flourescence spectrum, excited with the wavelength of an ArF laser at 193 nm, approximately the 10 lowest-lying vibrational levels of the $\text{B}{}^2\text{Σ}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{+}}$ state contribute to the emission.     

Non-cubic Mn2+-centers in BaF2

The EPR spectra of thermally treated BaF₂: Mn samples is reported. After thermal annealing at 900 K a trigonal Mn²⁺ center with g=2.000±0.005, |D|=2725±40MHz, |A|=265±10MHz, $\text{D}\text{A}\text{>0}$, is observed. Annealing at 1200 K produces an orthorhombic Mn²⁺ center with g=2.00±0.01, |D|=2430±40MHz, |E|=570±20MHz, |A|=265±10MHz, $\text{D}\text{A}\text{<0}$. The superhyperfine (SHF) structures due to interactions with the neighbouring fluorines indicates that the trigonal manganese interacts with four fluorines, three of them equivalent. The orthorhombic Mn²⁺ shows interaction with four equivalent fluorine nuclei.     

Isomers in the N = 83 nucleus 149Dy

Energy levels in the N = 83 nucleus ¹⁴⁹Dy were studied by the reaction ¹⁵²Gd(α, 7n) at 106 MeV bombarding energy using in-beam γ-ray spectroscopy methods. The measurements identified three isomers in this nucleus, at 1073 keV (13 ± 3 ns), at 2700±150keV (5 μs < T_{$\text{1}\text{2}$} < 0.5 s), and above 3.5 MeV (50 ± 15 ns). The low-lying isomer is interpreted as i_{$\text{13}\text{2}$}. The configuration $\text{27}\text{2}$^?(πh_{$\text{11}\text{2}$}²)₁₀₊ ×vf_{$\text{7}\text{2}$} is suggested for the state at 2.7 MeV.     

Magnetoreflectance of the Γ6 — Γ8 exciton in ZnTe

Magnetoreflectance measurements on the Γ₆ – Γ₈ free exciton state in magnetic fields up to 11.5 Tesla are reported. Five of the theoretically expected eight subcomponents of the 1s state are clearly observed. The transverse eigenenergies corresponding to the measured reflectance structures are derived by a lineshape analysis. From the splitting of the |;1,+1> and |;1,-1> states and that of the |;2,0> and |;1,0> states we derive the conduction electron g-value g_c = - 0.57 and the effective hole g-value $\text{g}\text{?}\text{k = - 0.06}$, corresponding to κ_Lutt = + 0.13. A nonzero short-range electron hole spin exchange Δ could not be observed and an upper limit Δ ? 0.1 meV is derived. The observed diamagnetic shifts are slightly smaller (15–20% at 10T) than predicted by existing low field theories, even if corrections as calculated for the case of a hydrogenic atom in a magnetic field are applied taking into account that the low field limit (γ ? 0.4) is already reached at ～7T     

Diode laser measurements of intensities,N2-broadening,and self-broadening coefficients of lines of the ν2 band of 14N16O2

A diode laser spectrometer (resolution 0.0013 cm^?1) was used to record, in the 12-μm region, high-quality spectra of the ν₂ band of NO₂. Using these spectra, it was possible to obtain the N₂-broadening coefficients and an average self-broadening coefficient from measurements made for seven lines of this band. In addition, 30 single spin-component line intensities were measured. From them, through a least-squares fit, the purely vibrational transition moment of the ν₂ band, as well as two correcting rotational terms involved in the expansion of the transition moment operator, were obtained. These results led to the determination of the dipole moment derivative $\text{?μ}{}_{\mathrm{x}}\text{?q}{}_2\text{= ?0.0604}{}_1\text{± 0.0037}\text{D}$. It was also demonstrated that there is good consistency between the correcting terms deduced from the observed intensities and their theoretical estimates. Finally, a complete spectrum of the ν₂ band of NO₂ was computed, providing a total band intensity S_v(ν₂) = 0.542 × 10^?18cm^?1/molecule cm^?2 at 296 K.     

Lithium aluminum nitride,Li3AlN2 as a lithium solid electrolyte

Single phase of Li₃AlN₂ was prepared from the mixture of Li₃N/AlN = 1.2 to 1.5 in molar ratio at 700°C and at 900°C. It crystalizes in the cubic system derived from antifluorite-type structure having the lattice parameter $\text{a = 9.470}\text{A}\text{?}$. It is a pure ionic conductor having conductivity of 5 × 10^?8ω^?1cm^?1 at room temperature and an activation energy of 52 kJ/ mol. Its decomposition voltage was 0.85 V at 104°C. The TiS₂/Li₃AlN₂/Li cell could be discharged at a constant current of 45 μA/cm² at 104°C.