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1.
The fine structures of the (ν1 + ν2) and (ν2 + ν3) combination bands of ozone in the 5.7-μm region have been recorded and analyzed. The two vibrational states are coupled through Coriolis and second-order distortion terms. The interaction has been treated by the numerical diagonalization of the secular determinant for the two coupled states. With the centrifugal distortion parameters fixed to the ground state values, the following constants have been obtained: ν1 + ν2 = 1796.266, A110 = 3.6104, B110 = 0.44145, , ν2 + ν3 = 1726.526, A011 = 3.5537, B011 = 0.43982, , Y13 = ?0.466, and X13 = ?0.010 cm?1. In addition, the following anharmonic constants have been obtained: x12 = ?7.821 and x23 = ?16.494 cm?1. The value of the dipole moment ratio, , is 1.30 ± 0.10. 相似文献
2.
For the model at T = 0 four susceptibilities have been calculated exactly on a sequence of finite square lattices and extrapolated to the infinite square lattice. For the ferromagnet χzz = 0 while χxx ~ N2.9; for the antiferromagnet and . 相似文献
3.
Y.B Suh 《Annals of Physics》1975,94(2):243-257
Exact analysis is presented to derive the magnetic response functions and their singularities of free-electron gas in a uniform magnetic field of arbitrary strength at T = 0 °K. The newly defined functions, Λμ(s) = ∑0[s])(s ? n)μ of , are employed to obtain the Fermi energy, magnetization, and susceptibility as functions of B. It is revealed that the spin susceptibility is composed of two parts, χs1 and χs2, where χs2 is purely oscillatory diamagnetic. A graphical method of finding the Fermi energy ?F(B) as a function of B has been obtained. The system is shown to become totally one-dimensional electron gas in the field B greater than and the total energy satisfies . The obvious extension of the present theory to the Bloch electrons on the ellipsoidal constant energy surface is also discussed. 相似文献
4.
The rotational motion of the OH? ion was studied in cubic NaOH at 575 K with quasielastic incoherent neutron scattering. The data are compared to two simple models yielding values for the radius of rotation R, the translational mean square displacement 〈u2〉H, the rotational jump rate τ?1 and the rotational diffusion coefficient DR. The following parameter values are obtained: (a) rotational jump model: , , (b) rotational diffusion model: . 相似文献
5.
The magnetic hyperfine splitting νM = |gμNBHF/h| of ; in Fe has been measured with the technique of nuclear magnetic resonance on oriented nuclei as 320.4(1) MHz. With the known hyperfine field the magnetic moment of the ground state of 175Ta is deduced to be . 相似文献
6.
The magnetic hyperfine splitting νM = |gμNBHF/h| of ; as a dilute impurity in Ni has been measured with nuclear magnetic resonance on oriented nuclei as 226.4(2) MHz. With the known hyperfine field BHF = ?264.4(3.9) kG corrected for hyperfine anomalies the g-factor and magnetic moment of 193mAu are deduced to be |g| = 1.123(17) and |μ| = 6.18(9) μN. 相似文献
7.
D. Allasia C. Angelini A. Baldini S. Barlag L. Bertanza A. Bigi V. Bisi F. Bobisut T. Bolognese R. Bonarelli E. Calimani R. Casali P. Capiluppi S. Ciampolillo J. Derkaoui E. De Wolf M.L. Faccini-Turleur R. Wigmans 《Nuclear Physics B》1984,239(2):301-310
The total νμ and nucleon charged-current cross sections have been measured in BEBC filled with deuterium and exposed to the wide-band neutrino and antineutrino beams at the CERN-SPS. Assuming a linear energy dependence for the cross sections, σ = aE(?ν, we obtained the coefficients , where the quoted error is mainly systematic. The ratio of the cross sections is .We also determined the ratio of the charged-current cross section for neutrino interactions on neutrons and protons R = σνn/σνp = 2.10 ± 0.08 (statistical) ±0.22 (sysetmatic). The dependence of R on the variables x, y and Eν is discussed. 相似文献
8.
E. Hammarén E. Liukkonen M. Piiparinen J. Kownacki Z. Sujkowski Th. Lindblad H. Ryde 《Nuclear Physics A》1979,321(1):71-108
The 146, 148Nd(α, χn) and 148, 150Nd(3He, χn) reactions at Eα = 20–43 MeV and E3He = 19–27 MeV, are used to study excited states in the 149Sm86 and 149Sm87 nucleides and consequently the low-spin odd-parity excitation. The mixing ratios and multipolarities of the most prominent transitions are deduced from the combined evidence of angular distribution and electron conversion data. The spin-parity assignments for most of the levels observed are established. In 148Sm the ground state band extending to Iπ = 10+ is predominantly populated. A negative-parity odd-spin band extending from Iπ = 3?through 11? is also observed. The bands in 148Sm are interpreted within the framework of the interacting boson approximation model. In 149Sm positive-parity levels with spin up to and negative-parity levels with spins up to are observed. The predominant γ-decay proceeds via transitions associated with , , and intrinsic configurations. The branching ratios B(E1)/B(E2) are calculated and compared in both 148Sm and 149Sm nucleides. The B(E1)/B(E2) dependence on the value of Z for some N = 86 (as well as 88 and 84) isotones showing a minimum of Z = 64 was noted. A 4 ns high-spin isomer mainly decaying into the positive-parity band based on the state in 149Sm is found. Experimental evidence is presented to interprete the , , … and , , …, ΔI = 2, sequences in 149Sm as arising from the coupling of an neutron to the octupole and quadrupole modes of the 148Sm core nucleus. The absolute reaction cross sections for the 146, 148, 150Nd(3He, χn) reactions have been determined for different bombarding energies. The mixing of the and shells is discussed in the framework of an axial-particle-rotor model calculation. 相似文献
9.
A.R.W McKellar 《Journal of Molecular Spectroscopy》1981,86(1):43-54
Magnetic dipole transitions between the and components of the ground electronic state of BrO have been detected using the technique of laser magnetic resonance on three CO2 laser lines between 964 and 970 cm?1. This is the first direct observation of the state in BrO. The spin-orbit splitting parameter, A, is determined to be ?967.9831(2) cm?1 for 79Br16O and ?967.9981(2) cm?1 for 81Br16O. Accurate values for the rotational constant , the hyperfine parameters () and d, the Λ-doubling parameter p, and the Zeeman parameter g| are also determined from an analysis of the measured spectra. 相似文献
10.
The (1-0), (2-0), and (3-0) transitions of 15N16O and 15N18O are investigated. The wavenumbers of the rotation-vibration lines are reported for the overtone bands and the (1-0) subband. It is shown that in the data reduction it is advantageous to calculate first merged spectroscopic constants ignoring the Λ-type doubling. The vibrational constants ωe, ωexe, ωeye and the vibrational dependence of the rotational constants are determined. The study of 15N18O allows the determination of the equilibrium values of the centrifugal distortion correction ADe to the spin-orbit constant and of the spin-rotation constant γe from the isotopic invariance of the ratios and . It is found that and . 相似文献
11.
Anil K. Bhatnagar B. Bhanu Prasad N. Ravi R. Jagannathan T.R. Anantharaman 《Solid State Communications》1982,44(6):905-909
Amorphous Fe40Ni40B20 (VITROVAC 0040) alloy has been investigated using 57Fe Mössbauer Spectroscopy. The Curie temperature Tc is found to be well defined and is 695 ± 1 K. The quadrupole splitting just above Tc is 0.64 mm sec?1. The crystallization temperature is 698 ± 2 K, close to but definitely above Tc. The average hyperfine field Heff(T) of the glassy state shows a temperature dependence of indicative of the existence of spin wave excitations. The values of and are found to be 0.40 and 0.06, respectively, for T/Tc ? 0.72. At temperatures close to Tc, Heff(T) varies as (1 ? T/Tc)β where β is one of the critical exponents and its value is found to be 0.29 ± 0.02. 相似文献
12.
The Raman active fundamentals ν1(A1g), ν2(Eg), ν5(F2g), and the overtone 2ν6 of SF6 have been investigated with a higher resolution and the band origins were estimated to be: ν1 = 774.53 cm?1, ν2 = 643.35 cm?1, ν5 = 523.5 cm?1, and 2ν6 = 693.8 cm?1. Raman and infrared data have been combined for estimation of several anharmonicity constants. The ν6 fundamental frequency is calculated as 347.0 cm?1. From the analysis of the ν2 Raman band, the following rotational constants of both the ground and upper states have been calculated: ; . 相似文献
13.
The threshold behaviour of pion production presented in our earlier work is successfully compared with the new SPEAR data. By using duality and sum rules we derive FT(π+)(x) ≈ FL(π+)(x) ≈ FT(π0)(x) ? FL(π0)(x) for x near 1. An accompanying results is for large s. 相似文献
14.
J.C.D. Brand U.D. Deshpande A.R. Hoy S.M. Jaywant 《Journal of Molecular Spectroscopy》1983,100(1):143-150
The E-B (0g+-0u+) band system of Br2 has been investigated at Doppler-limited resolution using polarization labeling spectroscopy. Merged E state data for the three naturally occurring isotopes in the range vE = 0–16, expressed in terms of the constants for 79Br2, are (in cm?1) Y0,0 = 49 777.962(54), Y1,0 = 150.834(22), Y2,0 = ?0.4182(28), Y3,0 = 6.6(11) × 10?4, Y0,1 = 4.1876(28) × 10?2, Y1,1 = ?1.607(16) × 10?4, and Y0,2 = 1.39(39) × 10?8. The bond distance is , and the diabatic dissociation energy to . 相似文献
15.
Jon T. Hougen 《Journal of Molecular Spectroscopy》1984,106(1):134-154
Rotational energy levels in vibronic ground states of 2A, 2E, and 2F electronic states of open-shell XY4 molecules, as well as rotational line intensities for allowed transitions between such states, are discussed, including the effects of spin-orbit interaction and tetrahedral splittings. Jahn-Teller effects are assumed to be small, and are only taken into account implicitly, through their contributions to various parameters in the effective Hamiltonian. Qualitative information is obtained by considering several limiting-case coupling schemes among the electron spin angular momentum S, the electron orbital angular momentum L, and the pure rotational angular momentum R. These limiting cases are similar in spirit to Hund's coupling cases in diatomic molecules, but differ sufficiently from the latter to make detailed correspondences unhelpful. Quantitative information on rotational energy levels and line intensities is obtained numerically by diagonalizing a Hamiltonian matrix set up in a basis set characterized by uncoupled moleculefixed projections of S, L, and the total angular momentum J, and symmetrized so that all basis set functions belong to a definite species in the subgroup D2d of the true point group Td. Hamiltonian matrix elements are determined by ladder operator techniques. Three sample calculated spectra, corresponding to , , and are presented. As one might expect, when the spin-orbit constant A is set equal to zero, then both qualitative and quantitative aspects of the rotational-electronic problem in open-shell XY4 molecules can be mapped easily onto discussions of the rotation-vibration problem from the CH4 literature. 相似文献
16.
Two-magnon Raman scattering in the planar quadratic antiferromagnet K2FeF4 is investigated. The temperature dependence of the energy shift is in good agreement with second-order Green-function theory, as is the linewidth at low temperature. Numerical results, including renormalization, are the Heisenberg exchange and the anisotropy , but with . 相似文献
17.
D. Ziemińska 《Nuclear Physics A》1975,242(3):461-466
The branching ratios are calculated for 11ΛB decay to the 11C ground and excited states below 8 MeV for two possible spin values of 11ΛB. It is found that the decay rate to the 11C★ state at E★ = 6.48 MeV is comparable in magnitude to that leading to the 11C ground state if is assumed. This result, unlike the branching ratios calculated for the case, is in accord with experiment and lends support to the assumption that holds for 11ΛB. The necessity of the reinterpretation of some of the so-called 13ΛC events in terms of is indicated. 相似文献
18.
The magnetic hyperfine splitting vM=|gμNBHF/h| of 196mAu (jπ=12?; configuration ¦(π(; as dilute impurity in Ni has been determined with nuclear magnetic resonance on oriented nuclei as 96.0(2) MHz. With the known hyperfine field BHF = ?264.4(3.9) kG corrected for hyperfine anomalies the g-factor and magnetic moment of 196mAu are deduced to be |g| = 0.476(7) and |μ| = 5.72(8) μN. Taking into account the known magnetic properties of and isomeric states in the neighbouring odd Pt, Au and Hg nuclei the structure of the 12? state is discussed. 相似文献
19.
The lifetime and hyperfine structure constants A and B of the state in41K have been measured by the quantum beat method. The obtained values are: τ = 895(26) ns, |A| = 0.14(2) MHz, |B| = 0.05(2) MHz and B/A > 0. 相似文献
20.
Nuclear spectroscopic quadrupole moments of the radioactive isotopes 131Cs, 132Cs, and 136Cs have been determined from the hyperfine structure of the state by the level crossing method. The results including a Sternheimer correction are: , , . The quadrupole moments of all the Cs isotopes from A = 131 to A = 137 are recalculated. It is shown, that nuclear quadrupole moments of a specific isotope obtained from different atomic P-states only agree within the limits of error after application of the Sternheimer correction. The increase of Qs with decreasing neutron number conforms with other observations and theoretical calculations stating that for elements around Z = 55 nuclear deformation develops below N = 82. The staggering of the sign of Qs may be interpreted as consequence of an oblate-prolate degeneracy of the nuclear energy surface. Some magnetic moments have been slightly improved: , (corrected for diamagnetism). 相似文献