Stability of {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} and {\text{SrZr}}_{{0.2}} {\text{Ce}}_{{0.7}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} under H2 atmospheres

Previous H₂ permeation tests showed a degradation of H₂ permeation flux with time. To understand the cause of degradation and develop a solution, the stability of $ {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ and $ {\text{SrZr}}_{{0.2}} {\text{Ce}}_{{0.7}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ samples were studied under dry and wet H₂ atmospheres. Total conductivity of $ {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ increased with time in dry H₂. The X-ray diffraction pattern of $ {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ after dry hydrogen atmosphere heat treatments show CeO₂ peaks indicating that $ {\text{SrCe}}_{{0.9}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ decomposes under dry H₂ atmospheres; scanning electron microscopy and energy dispersive X-ray spectroscopy analyses prove that decomposition proceeded along the grain boundaries. $ {\text{SrZr}}_{{0.2}} {\text{Ce}}_{{0.7}} {\text{Eu}}_{{0.1}} {\text{O}}_{{3 - \delta }} $ was investigated and demonstrated greater stability under dry hydrogen atmospheres. However, Zr substitution results in a tradeoff with electrical properties.     

Selectivity of anion exchange membrane modified with polyethyleneimine

Previous works have been made on the improvement of selectivity of ion exchange membranes using adsorption of polyelectrolyte on the surface of the materials. The modification of the surface material in the case of an anion exchange membrane concerns the hydrophilic/hydrophobic balance properties and its relationship with the hydration state. Starting from this goal, the AMX membrane has been modified, in this work, by adsorption of polyethyleneimine on its surface. Many conditions of modification of the AMX membrane surface were studied. A factorial experimental design was used for determining the influent parameters on the AMX membrane modification. The results obtained have shown that the initial concentration of polyethyleneimine and the pH of solution were the main influent parameters on the adsorption of polyethyleneimine on the membrane surface. Competitive ion exchange reactions were studied for the modified and the unmodified membrane involving $ {\text{C}}{{\text{l}}^{ - }} $ , $ {\text{NO}}_3^{ - } $ and $ {\text{SO}}_4^{{2 - }} $ ions. All experiments were carried out at constant concentration of 0.3?mol?L^?1 and at 25?°C. Ion exchange isotherms for the binary systems $ \left( {{\text{C}}{{\text{l}}^{ - }}/{\text{NO}}_3^{ - }} \right) $ , $ \left( {{\text{C}}{{\text{l}}^{ - }}/{\text{SO}}_4^{{2 - }}} \right) $ and $ \left( {{\text{NO}}_3^{ - }/{\text{SO}}_4^{{2 - }}} \right) $ were studied. The obtained results show that chloride was the most sorbed and the selectivity order both for the modified membrane and the unmodified one is: $ {\text{Cl}} > {\text{NO}}_3^{ - } > {\text{SO}}_4^{{2 - }} $ , under the experimental conditions. Selectivity coefficients $ {\text{K}}_{{{\text{C}}{{\text{l}}^{ - }}}}^{{{\text{NO}}_3^{ - }}} $ , $ {\text{K}}_{{2{\text{C}}{{\text{l}}^{ - }}}}^{{{\text{SO}}_4^{{2 - }}}} $ and $ {\text{K}}_{{2{\text{NO}}_3^{ - }}}^{{{\text{SO}}_4^{{2 - }}}} $ for the three binary systems and for the two membranes were determined. It was also observed that for the modified membrane the selectivity towards sulfate ion decrease and the modified membrane became more selective towards monovalent anions.     

Fast proton conduction path in {\text{Ni}} - {\text{BaCe}}_{{0.8}} {\text{Y}}_{{0.2}} {\text{O}}_{{2.9 - \delta }} membrane

The effect of metal-to-oxide grain boundary layer in $ {\text{Ni}} - {\text{BaCe}}_{{0.8}} {\text{Y}}_{{0.2}} {\text{O}}_{{3 - \delta }} $ (BCY) cermet membrane on hydrogen permeation was studied by applying the different size of oxide grain on Ni-BCY membranes. Two types of cermet membranes having different grain size of oxide were prepared by using different starting particle size of oxide powder. The hydrogen flux of coarse-oxide-grain membrane showed higher flux than that of small-oxide-grain membrane. It was understood that the negative potential at metal-to-oxide grain boundary, reference to the bulk oxide ( $ \phi _{0} < \phi _{\infty } = 0 $ ), was developed, and the accumulation of the effectively positively charged protons may occur at the grain boundary layer (space charge layer), which may result in providing highly conductive proton path by shifting the charge neutrality condition from $ {\left[ {OH^{ \bullet }_{O} } \right]} = {\left[ {Y^{/}_{{Ce}} } \right]} $ to $ {\left[ {OH^{ \bullet }_{O} } \right]} = n $ .     

Theoretical study of collision and collision-free radiative lifetimes of {{\text{S}}_2}\left( {{{\text{B}}^3}\Sigma_{\text{u}}^{-} \left( {{\upsilon^{\prime}} = 0 - 9} \right)} \right)

We calculate multireference configuration-interaction wavefunctions and the potential-energy curves for the $ {B^3}\Sigma_u^{-} $ and $ {X^3}\Sigma_g^{-} $ states of the collision-free S₂ molecule and the T-shape collision complex S₂?CHe using cc-pVQZ basis sets. We obtain the transition dipole moments of the $ {{\text{S}}_2}\left( {{B^3}\Sigma_u^{-} \to {X^3}\Sigma_g^{-} } \right) $ and the Franck?CCondon factors between the vibrational levels of this two states. We evaluate the radiative lifetimes of $ {{\text{S}}_2}\left( {{B^3}\Sigma_u^{-} \left( {{\upsilon^{\prime}} = 0 - 9} \right)} \right) $ levels of the collision complex and the collision-free molecule and compare them with the experiments. The collision provides little change in the radiative lifetimes of $ {{\text{S}}_2}\left( {{B^3}\Sigma_u^{-} \left( {{\upsilon^{\prime}} = 0 - 9} \right)} \right) $ according to the previous calculations. We obtain excellent agreement between the theoretical results and the experiments. The data calculated are very useful in the study of the microwave-driven high-pressure sulfur lamp and an S₂ laser pumped by a transverse fast discharge.     

A new analysis improving the evidence of a narrow peak in the invariant-mass distribution of the \Lambdap system observed in the \bar{{p}} annihilation at rest on 4He

The presence of a narrow peak in the $ \Lambda$ p invariant-mass distribution observed in the $ \bar{{p}}$ annihilation reaction at rest $\ensuremath \bar{p} {}^4\mathrm{He}\rightarrow p\pi^-p\pi^+\pi^-n X$ is discussed again through an analysis procedure which improves the ratio signal/background in comparison with the previous analysis. The peak is centred at 2223.2±3.2_stat±1.2_syst MeV and has a statistical significance of 4.7 $ \sigma$ , values compatible with those published previously. If interpreted as the result of the decay into $ \Lambda$ p of a $\ensuremath { }_{\bar{K}}{}^2\mathrm{H}$ bound system, the corresponding binding energy should be B = - 151.0±3.2_stat±1.2_syst MeV and the width $ \Gamma_{{FWHM}}^{}$ < 33.9±6.2 MeV. The production rate has a lower limit of 1.2 10^-4. Data on the $ \bar{{p}}$ annihilation reaction at rest $ \bar{{p}}$ ⁴He $ \rightarrow$ p $ \pi^{-}_{}$ p $ \pi^{-}_{}$ p _s X , analyzed for the first time, lead to a result in qualitative agreement with the previous one.     

Radiative open charm decay of the Y(3940) , Z(3930) , X(4160) resonances

We determine the radiative decay amplitudes for the decay into D^* and $ \bar{{D}}$ $ \gamma$ , or D ^* _s and $ \bar{{D}}_{s}^{}$ $ \gamma$ of some of the charmonium-like states classified as X , Y , Z resonances, plus some other hidden charm states which are dynamically generated from the interaction of vector mesons with charm. The mass distributions as a function of the $ \bar{{D}}$ $ \gamma$ or $ \bar{{D}}_{s}^{}$ $ \gamma$ invariant mass show a peculiar behavior as a consequence of the D ^* $ \bar{{D}}^{*}_{}$ nature of these states. The experimental search of these magnitudes can shed light on the nature of these states.     

Haag Duality and the Distal Split Property for Cones in the Toric Code

We prove that Haag duality holds for cones in the toric code model. That is, for a cone ??, the algebra ${\mathcal{R}_{\Lambda}}$ of observables localized in ?? and the algebra ${\mathcal{R}_{\Lambda^c}}$ of observables localized in the complement ?? ^c generate each other??s commutant as von Neumann algebras. Moreover, we show that the distal split property holds: if ${\Lambda_1 \subset \Lambda_2}$ are two cones whose boundaries are well separated, there is a Type I factor ${\mathcal{N}}$ such that ${\mathcal{R}_{\Lambda_1} \subset \mathcal{N} \subset \mathcal{R}_{\Lambda_2}}$ . We demonstrate this by explicitly constructing ${\mathcal{N}}$ .     

Level-Rank Duality via Tensor Categories

We give a new way to derive branching rules for the conformal embedding $$(\hat{\mathfrak{sl}}_n)_m\oplus(\hat{\mathfrak{sl}}_m)_n\subset(\hat{\mathfrak{sl}}_{nm})_1. $$ In addition, we show that the category ${\mathcal{C}(\hat{\mathfrak{sl}}_n)_m^0}$ of degree zero integrable highest weight ${(\hat{\mathfrak{sl}}_n)_m}$ -representations is braided equivalent to ${\mathcal{C}(\hat{\mathfrak{sl}}_m)_n^0}$ with the reversed braiding.     

Theoretical Investigation into Production of Double-Λ Hypernuclei from Stopped Ξ − on 6Li

We have investigated theoretically a feasible nuclear reaction to produce light double-Λ hypernuclei by choosing a suitable target. In the reaction from stopped Ξ ^? on ⁶Li target light doubly-strange nuclei, ${^5_{\Lambda\Lambda}{\rm H}}$ and ${^6_{\Lambda\Lambda}{\rm He}}$ , are produced: we have calculated the formation ratio of ${^5_{\Lambda\Lambda}{\rm H}}$ to ${^6_{\Lambda\Lambda}{\rm He}}$ for Ξ ^? absorptions from 2S, 2P and 3D orbitals of Ξ ^?–⁶Li atom by assuming a d?α cluster model for ⁶Li. From this cluster model the d?α relative wave functions has a node due to Pauli exclusion among nucleons belonging to d and α clusters. Two kinds of d?α wave functions, namely 1s relative wave function with a phenomenological one-range Gaussian (ORG) potential and that of an orthogonality-condition model (OCM) are used. It is found that the probability of ${^5_{\Lambda\Lambda}{\rm H}}$ formation is larger than that of ${^6_{\Lambda\Lambda}{\rm He}}$ for all absorption orbitals: in the case of the major 3D absorption their ratio is 1.08 for ORG and 1.96 for OCM. The dominant low momentum component of the d?α relative wave function favors the ${^5_{\Lambda\Lambda}{\rm H}}$ formation with a low Q value compared to the ${^6_{\Lambda\Lambda}{\rm He}}$ formation with a high Q value. We have also calculated momentum distributions of emitted particles, d and n, displaying continuum spectra for single-Λ hypernuclei, ${^4_{\Lambda}{\rm H}}$ and ${^5_{\Lambda}{\rm He}}$ , and line spectra for the ${^5_{\Lambda\Lambda}{\rm H}}$ and ${^6_{\Lambda\Lambda}{\rm He}}$ nuclei. Thus, our present theoretical analysis would be a significant contribution to experiments in the strangeness ?2 sector of hypernuclear physics.     

Study of the ion exchange equilibrium of Cl−, NO_3^{ - } , and SO_4^{{2 - }} ions on the AMX membrane

Equilibrium between the ion exchange membrane and solutions of anions at various valences has been the subject of this investigation. Competitive ion exchange reactions were studied on a strong base anion exchange membrane AMX manufactured by Tokuyama, commercialized by Eurodia, involving Cl^?, $ {\text NO}_3^{ - } $ and $ {\text SO}_4^{{2 - }} $ ions. Solution concentrations studied were 0.05 and 0.1 M for all the systems reported. Experiments were performed with sodium as the counter ion, and the temperature was kept constant (T?=?298 K). Ionic exchange isotherms for the binary systems— $ {{\text Cl}^{ - }}/{\text NO}_3^{ - } $ , $ {{\text Cl}^{ - }}/{\text SO}_4^{{2 - }} $ , and $ {\text NO}_3^{ - }/{\text SO}_4^{{2 - }} $ —were established. The obtained results show that the sulfate was the most strongly sorbed, and the selectivity order is $ {\text SO}_4^{{2 - }} > {\text NO}_3^{ - } > {{\text Cl}^{ - }} $ at 0.05 M and $ {\text NO}_3^{ - } > {\text SO}_4^{{2 - }} > {{\text Cl}^{ - }} $ at 0.1 M under the experimental conditions. Selectivity coefficients $ K_{{{{{\text Cl} }^{ - }}}}^{{{\text NO}_3^{ - }}} $ , $ K_{{2{{{\text Cl} }^{ - }}}}^{{{\text SO}_4^{{2 - }}}} $ , and $ K_{{2{\text NO}_3^{ - }}}^{{{\text SO}_4^{{2 - }}}} $ for the three binary systems were determined. All the results given by this membrane were compared with those obtained, in the same conditions, with the RPA membrane (produced by RHONE POULENC). Ternary equilibrium data were taken for $ {{\text Cl}^{ - }}/{\text NO}_3^{ - }/{\text SO}_4^{{2 - }} $ . The prediction of the ternary system based only on the binary data was consistent with the experimental data obtained for this system. The good agreement between the experimental and the predicted data showed that the proposed framework can be considered as an effective method to predict many ternary systems from binary systems.     

One-range Addition Theorems for Noninteger n Slater Functions using Complete Orthonormal Sets of Exponential Type Orbitals in Standard Convention

By the use of complete orthonormal sets of ${\psi ^{(\alpha^{\ast})}}$ -exponential type orbitals ( ${\psi ^{(\alpha^{\ast})}}$ -ETOs) with integer (for α ^* = α) and noninteger self-frictional quantum number α ^*(for α ^* ≠ α) in standard convention introduced by the author, the one-range addition theorems for ${\chi }$ -noninteger n Slater type orbitals ${(\chi}$ -NISTOs) are established. These orbitals are defined as follows $$\begin{array}{ll}\psi _{nlm}^{(\alpha^*)} (\zeta ,\vec {r}) = \frac{(2\zeta )^{3/2}}{\Gamma (p_l ^* + 1)} \left[{\frac{\Gamma (q_l ^* + )}{(2n)^{\alpha ^*}(n - l - 1)!}} \right]^{1/2}e^{-\frac{x}{2}}x^{l}_1 F_1 ({-[ {n - l - 1}]; p_l ^* + 1; x})S_{lm} (\theta ,\varphi )\\ \chi _{n^*lm} (\zeta ,\vec {r}) = (2\zeta )^{3/2}\left[ {\Gamma(2n^* + 1)}\right]^{{-1}/2}x^{n^*-1}e^{-\frac{x}{2}}S_{lm}(\theta ,\varphi ),\end{array}$$ where ${x=2\zeta r, 0<\zeta <\infty , p_l ^{\ast}=2l+2-\alpha ^{\ast}, q_l ^{\ast}=n+l+1-\alpha ^{\ast}, -\infty <\alpha ^{\ast} <3 , -\infty <\alpha \leq 2,_1 F_1 }$ is the confluent hypergeometric function and ${S_{lm} (\theta ,\varphi )}$ are the complex or real spherical harmonics. The origin of the ${\psi ^{(\alpha ^{\ast})} }$ -ETOs, therefore, of the one-range addition theorems obtained in this work for ${\chi}$ -NISTOs is the self-frictional potential of the field produced by the particle itself. The obtained formulas can be useful especially in the electronic structure calculations of atoms, molecules and solids when Hartree–Fock–Roothan approximation is employed.     

Femtosecond relaxation kinetics of highly excited \mathrm{M}_{\mathrm{Na}}^{**} states in CaF2 at 3.2 eV and 4.7 eV

Femtosecond (fs) laser pulses at variable delay times allowed us to track the fast non-radiative transitions between the manifold of highly excited $\mathrm{M}_{\mathrm{Na}}^{**}$ states to the lower lying fluorescent $\mathrm{M}_{\mathrm{Na}}^{*}$ state in CaF₂. Two distinct $\mathrm{M}_{\mathrm{Na}}^{**}$ states of the manifold at 3.16?eV ( $\mathrm{M}_{\mathrm{Na}2}^{**}$ ) and 4.73?eV ( $\mathrm{M}_{\mathrm{Na}3}^{**}$ ) were populated using the second (SH) and third harmonics (TH) of fs laser light at 785?nm. The population kinetics of the fluorescent $\mathrm{M}_{\mathrm{Na}}^{*}$ state in the 2?eV excitation energy range was revealed by depleting its fluorescence centered at 740?nm using fundamental near infrared (NIR) fs laser pulses. The related time constants for $\mathrm{M}_{\mathrm{Na}2,3}^{**}{\sim}{>} \mathrm{M}_{\mathrm{Na}}^{*}$ relaxation amounted to 1.0±0.14?ps and 3.0±0.3?ps upon SH and TH excitation, respectively.     

Spectroscopy of the hyperfine structure of antiprotonic 4He and 3He

The spin magnetic moment $\mu^{\overline{p}}_{s}$ of the antiproton can be determined by comparing the measured transition frequencies in $\overline{p}^4$ He^?+? with three-body QED calculations. A comparison between the proton and antiproton can then be used as a test of CPT invariance. The highest measurement precision of the difference between the proton and the antiproton spin magnetic moments to date is 0.3%. A new experimental value of the spin magnetic moment of the antiproton was obtained as $\mu^{\overline{p}}_{s} = -2.7862(83)\mu_{N}$ , slightly better than the previously best measurement. This agrees with $\mu^{p}_{s}$ within 0.24%. In 2009, a new measurement with antiprotonic ³He has been started. A comparison between the theoretical calculations and experimental results would lead to a stronger test of the theory and address systematic errors therein. A measurement of this state will be the first HF measurement on $\overline{p}^3$ He^?+?. We report here on the new experimental setup and the first tests.     

Finite W-Superalgebras and Truncated Super Yangians

Let ${Y_{m|n}^{\ell}}$ be the super Yangian of general linear Lie superalgebra for ${\mathfrak{gl}_{m|n}}$ . Let ${e \in \mathfrak{gl}_{m\ell|n\ell}}$ be a “rectangular” nilpotent element and ${\mathcal{W}_e}$ be the finite W-superalgebra associated to e. We show that ${Y_{m|n}^{\ell}}$ is isomorphic to ${\mathcal{W}_e}$ .     

Singular $$ \mathcal{R}$$ -Matrices and Drinfeld's Comultiplication

We compute the $\mathcal{R}$ -matrix which intertwines two dimensional evaluation representations with Drinfeld comultiplication for ${\text{U}}_q \left( {\widehat{{\text{sl}}}_{\text{2}} } \right)$ . This $\mathcal{R}$ -matrix contains terms proportional to the δ-function. We construct the algebra $A\left( \mathcal{R} \right)$ generated by the elements of the matrices L^±(z) with relations determined by $\mathcal{R}$ . In the category of highest-weight representations, there is a Hopf algebra isomorphism between $A\left( \mathcal{R} \right)$ and an extension $\overline {\text{U}} _q \left( {\widehat{{\text{sl}}}_{\text{2}} } \right)$ of Drinfeld's algebra.     

Oxidation of Pyrite Grains: A Mössbauer Spectroscopy and Mineral Magnetism Study

Fe²⁺ in pyrite is found in a low-spin d⁶ configuration, a necessary condition for diamagnetic and semi-conducting properties of material. The semi-conducting property of pyrite has been studied since the time when pyrite was used as a rectifier in early radios. Pyrite posses the highest possible crystal field stabilisation energy and offers a better altemative as solar material compared to Si-based materials. Unfortunately, pyrite is difficult to study due to its inherent deviation from stoichiometry and its ease of oxidation. Since pyrite and its oxidation products are all Fe-bearing phases, combining Mössbauer spectroscopy with mineral magnetic methods provides enough information to monitor the oxidation of pyrite in air and identify the different phases produced and their relation to different experimental parameters. For mm-sized grain samples, heating FeS₂ at temperatures between 450 °C and 650 °C five different mineral assemblages are identified. FeS₂ is oxidized to α-Fe₂O₃ along two separate routes: $${\text{FeS}}_{2} \to {\text{FeSO}}_{4} \to \varepsilon {\text{ - Fe}}_{2} {\text{O}}_{3} \to \alpha {\text{ - Fe}}_{2} {\text{O}}_{3} ;\;{\text{and}}$$ $${\text{FeS}}_{2} \to {\text{FeSO}}_{4} \to {\text{Fe}}_{2} {\left( {{\text{SO}}4} \right)}_{3} \to \beta {\text{ - Fe}}_{2} {\text{O}}_{3} \to \alpha {\text{ - Fe}}_{2} {\text{O}}_{3} $$      

A stable and easily sintering {\text{BaCe}}_{0.7} {\text{Sn}}_{0.1} {\text{Gd}}_{0.2} {\text{O}}_{3 - \delta } electrolyte for solid oxide fuel cells

${\text{BaCe}}_{0.7} {\text{Sn}}_{0.1} {\text{Gd}}_{0.2} {\text{O}}_{3 - \sigma } $ (BCSG) and ${\text{BaCe}}_{0.8} {\text{Gd}}_{0.2} {\text{O}}_{3 - \sigma } $ (BCG) powders were prepared by solid-state reaction method. After exposure in 5% CO₂?+?5% H₂O?+?90% N₂ at 500 °C for 5 h, the BCSG powders were hardly affected while the BCG powders decomposed into CeO₂ and BaCO₃ phases. Moreover, the relative density of BCSG reaches 97%, while the BCG just displays 91% after sintering at 1,400 °C. The BCSG displays a conductivity of 0.01 S/cm at 700 °C in humid hydrogen, which is quite close to 0.012 S/cm for BCG. A fuel cell with BCSG exhibits 1.02 V for open circuit voltage, 420 mW/cm² for peak performance and 0.23 Ω cm² for interfacial resistance at 700 °C, respectively.     

A DFG-based cavity ring-down spectrometer for trace gas sensing in the mid-infrared

Continuing studies into an all-diode laser-based 3.3 μm difference frequency generation cavity ring-down spectroscopy system are presented. Light from a 1,560 nm diode laser, amplified by an erbium-doped fibre amplifier, was mixed with 1,064 nm diode laser radiation in a bulk periodically poled lithium niobate crystal to generate 16 μW of mid-IR light at 3,346 nm with a conversion efficiency of $0.05\,\%\,{\text{W}}^{-1}\,{\text{cm}}^{-1}$ . This radiation was coupled into a 77 cm long linear cavity with average mirror reflectivities of 0.9996, and a measured baseline ring-down time of $6.07\pm 0.03\,\upmu{\rm s}$ . The potential of such a spectrometer was illustrated by investigating the $P(3)$ transition in the fundamental $\nu_{3}(F_{2})$ band of ${\text{CH}}_4$ both in a 7.5 ppmv calibrated mixture of ${\text{CH}}_4$ in air and in breath samples from methane and non-methane producers under conditions where the minimum detectable absorption coefficient ( $\alpha_{\rm min}$ ) was $2.8 \times 10^{-8}\,{\rm cm}^{-1}$ over 6 s using a ring-down time acquisition rate of 20 Hz. Allan variance measurements indicated an optimum $\alpha_{\rm min}$ of $2.9\times 10^{-9}\,{\rm cm}^{-1}$ over 44 s.     

Fougerite FeII − III oxyhydroxycarbonate in environmental chemistry and nitrate reduction

The identification of the fougerite mineral responsible for the bluish-green shade of gleysols in aquifers as being the Fe^II???III oxyhydroxycarbonate $\text{GR}(\text{CO}_{3}^{2-})^*$ of formula, $[\text{Fe}^{\rm II}_{6x}\text{Fe}^{\rm III}_{6(1 - x)}\text{O}_{12}\text{H}_{2(7-3x)}]^{2+}\bullet[\text{CO}_{3}^{2-}\bullet3\text{H}_{2}\text{O}]^{2-}$ where the ferric molar ratio x = [Fe^III/Fe_total] is restricted to the domain [1/3–2/3] induces to study the reactivity of the synthetic green rust for reducing some major pollutants. The oxidation within the solid compound $\text{GR}(\text{CO}_{3}^{2-})^*$ in the presence of nitrates is followed by miniaturized Mössbauer spectrometer (MIMOS). Ratio x = [Fe^III/Fe_total] increases up to 0.67 where $\text{GR}(\text{CO}_{3}^{2-})^*$ transforms gradually into magnetite. This could well explain the composition variability of fougerite occurrences.     

Complex Vector Formalism of Harmonic Oscillator in Geometric Algebra: Particle Mass,Spin and Dynamics in Complex Vector Space

Elementary particles are considered as local oscillators under the influence of zeropoint fields. Such oscillatory behavior of the particles leads to the deviations in their path of motion. The oscillations of the particle in general may be considered as complex rotations in complex vector space. The local particle harmonic oscillator is analyzed in the complex vector formalism considering the algebra of complex vectors. The particle spin is viewed as zeropoint angular momentum represented by a bivector. It has been shown that the particle spin plays an important role in the kinematical intrinsic or local motion of the particle. From the complex vector formalism of harmonic oscillator, for the first time, a relation between mass $m$ and bivector spin $S$ has been derived in the form $\varvec{\sigma }_3 mc^2{\mathcal {J}}_{\pm } =\lambda \Omega _{\mathbf{s}} \cdot \mathrm{{S}} {\mathcal {J}}_{\pm }$ . Where, $\Omega _{s}$ is the angular velocity bivector of complex rotations, $c$ is the velocity of light. The unit vector $\varvec{\sigma }_3$ acts as an operator on the idempotents ${\mathcal {J}}_{+}$ and ${\mathcal {J}}_{-}$ to give the eigen values $\lambda =\pm 1.$ The constant $\lambda $ represents two fold nature of the equation corresponding to particle and antiparticle states. Further the above relation shows that the mass of the particle may be interpreted as a local spatial complex rotation in the rest frame. This gives an insight into the nature of fundamental particles. When a particle is observed from an arbitrary frame of reference, it has been shown that the spatial complex rotation dictates the relativistic particle motion. The mathematical structure of complex vectors in space and spacetime is developed.