Low temperature thermal properties and intrinsic defects in vitreous silica

Measurements of the low temperature specific heatC _p (0.04KT2.4K) and thermal conductivityk (0.5KT20K) of high purity vitreous silica (Suprasil W) in the as-received and electron-irradiated states are reported. In the temperature range where the localized excitations inherent in glasses dominateC _p (T0.5K) no change is observed upon electron irradiation of up to 10¹⁹e^– (total dose). An anomalyC around 1.8K is observed inC _p which is reduced by 40% upon irradiation. However, ask is not affected by electron irradiation, localized excitations as origin forC can be ruled out. The density of paramagnetic centers in the most heavily irradiated sample is 510¹⁷cm^–3 as obtained from the ESR signal. It has been suggested that these centers have diamagnetic precursors in the unirradiated glass. Our measurements indicate that those defects are not associated with the localized excitations.     

Measurement of the reaction γp → K0Σat photon energies up to 2.6 GeV⋆

The reaction p K⁰⁺ was measured in the photon energy range from threshold up to 2.6 GeV with the SAPHIR detector at the electron stretcher facility, ELSA, in Bonn. Results are presented on the reaction cross-section and the polarization of the ⁺ as a function of the kaon production angle in the centre-of-mass system, cos^c.m._K, and the photon energy. The cross-section is lower and varies less with photon energy and kaon production angle than that of p K⁺⁰. The ⁺ is polarized predominantly at cos^c.m._K 0. The data presented here are more precise than previous ones obtained with SAPHIR and extend the photon energy range to higher values. They are compared to isobar model calculations.     

Upper critical fields of single-crystalline and polycrystalline Ca-Sr-Bi-Cu-O compounds

The ac resistivity of a 110 K phase multiphase polycrystalline Ca-Sr-Bi-Cu-O compound and an 85 K phase single-crystalline Ca_0.9Sr_2.1Cu_2.0O_{8 +} has been measured in various magnetic fields up to 8 T. Values forB _c ^2/ (0) of 71.5 T and forB _c2 (0) of 542 T are found for the 85 K phase sample. A value forB _c2(0) of 57.9 T is estimated for the 110K phase compound.     

Geometric expansion of the boundary free energy of a dilute gas

We consider a dilute classical gas in a volume ^–1 which tends to ^d by dilation as 0. We prove that the pressurep(^–1) isC ^q in at =0 (thermodynamic limit), for anyq, provided the boundary isC ^q and provided the Ursell functionsu _n (x ₁, ...,x _n) admit moments of degreeq and have nice derivatives.     

Manifestation of Extracoordination in the Resonance Raman Spectra of Water‐Soluble Cation Co‐Porphyrins

Resonance Raman spectra (RRS) of Co(II) and Co(III)5,10,15,20tetrakis(4Nmethylpyridinium)porphyrin ((Co^II(TmpyP4), and Co^III(TMPyP4)) in aqueous solutions at different pH as well as in organic solvents (methanol, ethanol, DMSO, DMF) are obtained. The increased sensitivity of the oscillation frequencies ₂, ₄, ₈, and ₆ — the markers of the oxidation state of a metal — to the nature of an axial ligand has been revealed. For Co^III(TmpyP4), the shifts of the indicated frequencies in extracoordination have turned out to be twofold larger than those for Co^II(TmpyP4). The spectral effects observed are related to different electron influence of the extraligands on the system of the porphyrin ring. In the case of Co(III)porphyrin, interaction of the d orbitals of the metal and the e _g ^*orbitals of the macrocycle is more efficient since its ionic radius is smaller than for the Co(II)complex. For Co^III(TmpyP4), a linear correlation between the oscillation frequencies ₂, ₄, ₈, and ₆ and the experimental Gutmann parameters characterizing the electronacceptor properties of solvents is found.     

Differential algebras for quantum groups of type B, C, and D

We study higher order bicovariant differential calculi on the quantum groups O_q(N) and Sp _q (N). We show that the second antisymmetrizer exterior algebra _u is the quotient of the universal exterior algebra _u by the principal ideal generated by . Here denotes the unique up to scalars biinvariant 1-form. Moreover is central in _u and _u is an inner differential calculus. We show that the quadratic dual to the left-invariant algebra _{s L} is isomorphic to the reflection equation algebra. Let be an arbitrary left-covariant first order differential calculus. We show that the dimension of the space of left-invariant 2-forms in the universal exterior algebra equals the number of linearly independent quadratic-linear relations in the quantum tangent space.     

Extremal invariant states with a spectrum condition and Borchers' theorem

If the energy spectrum of an extremal invariant state is not the whole real line, it is shown that is either pure or uniquely decomposed into mutually disjoint pure states in the way that =^-1 F _{0 t} dt where is a pure state satisfying = with >0. Next we give a slightly generalized version of Borchers' theorem [1] on the innerness of some automorphism group of a von Neumann algebra with a spectrum condition.     

Exact distribution of cluster size and perimeter for two-dimensional percolation

Exact series expansion data of Sykes et al. are used to calculate the average numberc _n and perimeters _n of clusters of sizen20 in the site percolation problem for the triangular, square, and honeycomb lattice. At the percolation thresholdp _n we find a sharply peaked distribution of perimeterss _n with mean s _n =((1–p _n )/p _c )n+O(n ) and width s _n ² –S _n ²n ^1.6 where1/=0.39. This perimeter s _n should not be interpreted as a cluster surface in the usual sense. Two tests confirm the universality hypothesis with reasonable accuracy. The asymptotic decay of the cluster numbersc _n withn is consistent with the postulated asymmetry aboutp _c : logc _n –n forn with1 forp<p _c and1/2 forp>p _c .     

Fock representations of the affine Lie algebraA 1 (1)

The aim of this note is to show that the affine Lie algebraA ₁ ⁽¹⁾ has a natural family _, ,v of Fock representations on the spaceC[x _i,y _j;i andj ], parametrized by (,v) C ². By corresponding the highest weight _, of _, to each (,), the parameter spaceC ₂ forms a double cover of the weight spaceC₀C –₁ with singularities at linear forms of level –2; this number is (–1)-times the dual Coxeter number. Our results contain explicit realizations of irreducible non-integrable highest wieghtA ₁ ⁽¹⁾ -modules for generic (,v).     

Orientation of an oxygen-induced non-axially symmetric electric field gradient at Ta in Nb

The interaction of dilute Hf in Nb with interstitially dissolved oxygen has been investigated via the --TDPAC-technique applied to the 482 keV state of¹⁸¹Ta. After melting the parent radioactivity¹⁸¹Hf with Nb the trapping of oxygen at the probe atoms leads to a quadrupole interaction frequency _Q =268(1) MHz with an asymmetry parameter of =0.68(1). The temperature dependence of this frequency between 17 K and 293 K was found to be very weak whereas varies considerably. In a single crystal experiment the orientation of the three principal axes of the electric field gradient tensor leading to _Q has been determined. TheV _zz -axis points into a 110, theV _yy -axis into a 100 and theV _x -axis into a 110 direction. The results can be explained in the point charge model by assuming that one oxygen atom is trapped on the second nearest neighbour octahedral position next to the substitutional atom and the covalent bonds between the daughter Ta and the oxygen lead to a localization of charge near the probe atom.     

On the stability of spin waves at finite temperatures

The temperature dependent exchange stiffnessD, defined for long wavelength spin waves by=Dq ², is calculated for very weak itinerant ferromagnets. It is found that for a general single band of d-electrons,D reduces to a very simple form givingD(T)=D(0)/ ₀ in the limit ₀0. The stability condition for spin waves at finite temperatures is thenD(0) > 0 and/ ₀ > 0, where is the relative occupation ± spin sub-bands and ₀ its value at 0°K.The authors are grateful to E. P. Wohlfarth for helpful discussions.     

More inequalities for critical exponents

A variety of rigorous inequalities for critical exponents is proved. Most notable is the low-temperature Josephson inequalitydv +2 2–. Others are 1 1 +v, 1 1 , 1,d 1 + 1/ (for d),dv, ₃ + (for d), ₄ , and _{2m 2m+2} (form 2). The hypotheses vary; all inequalities are true for the spin-1/2 Ising model with nearest-neighbor ferromagnetic pair interactions.NSF Predoctoral Fellow (1976–1979). Research supported in part by NSF Grant PHY 78-23952.     

Energy level crossings in quantum mechanics

From the eigenvalue equationH \ _n () =E _n ()\ _n () withH H ₀ +V one can derive an autonomous system of first order differential equations for the eigenvaluesE _n () and the matrix elementsV _mn () where is the independent variable. To solve the dynamical system we need the initial valuesE _n ( = 0) and \ _n ( = 0). Thus one finds the motion of the energy levelsE _n (). We discuss the question of energy level crossing. Furthermore we describe the connection with the stationary state perturbation theory. The dependence of the survival probability as well as some thermodynamic quantities on is derived. This means we calculate the differential equations which these quantities obey. Finally we derive the equations of motion for the extended caseH =H ₀ +V ₁ + ² V ₂ and give an application to a supersymmetric Hamiltonian.     

The paramagnetic state (μ+e−) in silicon and tellurium at high temperature

The paramagnetic state (⁺e^–) in Si and Te was observed in a longitudinal magnetic field. The mean lifetimes of these states were obtained: _Si = 1.45(3) s, _Te = 12.5(8) s at 290 K, _Te = 12(2) s at 250 K.     

Direct observation of the second-order Stark effect of theX-B transition in molecular iodine

The second-order Stark shift of the components of the hyperfine structure of the transition¹ _g ⁺ ( = 0,j = 13, 15) ³ _ou ⁺ ( = 43,j = 12, 16) (of molecular iodine have been studied by means of saturated absorption spectroscopy in an external cell with the I₂ vapour located in an electric field. The anisotropic polarizabilities of the upper and lower levels together with the difference between the isotropic polarizabilities of the levels of the transition have been obtained.     

Exact gravitational field of the infinitely long rotating hollow cylinder

The vacuum line element inside an infinitely long rotating hollow cylinder is the usual flat space line element. It is fitted in a most general way to the general cylindrical vacuum field outside at the singular hypersurfaceR ₀=const, representing the infinitely thin hollow cylinder. With the use of the jump conditions atR ₀=const the surface densities , of which the energy-momentum-stress tensor of the shell consists, are calculated. The physical properties of the cylinder, as derived from the eigenvalues and -vectors of , and the generated gravitational field are discussed in full detail.     

Equivalence of vacuum Yang-Mills gravitation and vacuum Einstein gravitation

In the Yang-Mills formulation of gravitational dynamics based uponSL(2,C) spin transformations acting on Dirac spinors, the vacuum field equations are R +C R = 0 and and . HereR is the Ricci curvature andC is the Weyl conformal curvature; is a coupling constant. We show the equivalence between solutions of these equations and the vacuum Einstein equationsR = 0. The proof uses the Newman-Penrose formalism.Supported by a NATO fellowship.Supported by a SRC fellowship.     

Dynamic structure factor in a random diffusion model

Let {X _t:0} denote random walk in the random waiting time model, i.e., simple random walk with jump ratew ^–1(X _t), where {w(x):x^d} is an i.i.d. random field. We show that (under some mild conditions) theintermediate scattering function F(q,t)=E ₀ (q^d) is completely monotonic int (E ₀ denotes double expectation w.r.t. walk and field). We also show that thedynamic structure factor S(q, w)=2 ₀ cos(t)F(q, t) exists for 0 and is strictly positive. Ind=1, 2 it diverges as 1/||^1/2, resp. –ln(||), in the limit 0; ind3 its limit value is strictly larger than expected from hydrodynamics. This and further results support the conclusion that the hydrodynamic region is limited to smallq and small such that ||D |q|², whereD is the diffusion constant.     

The Becker-Döring cluster equations: Basic properties and asymptotic behaviour of solutions

Existence and uniqueness results are established for solutions to the Becker-Döring cluster equations. The density is shown to be a conserved quantity. Under hypotheses applying to a model of a quenched binary alloy the asymptotic behaviour of solutions with rapidly decaying initial data is determined. Denoting the set of equilibrium solutions byc ⁽⁾, 0 _s , the principal result is that if the initial density _{0 s} then the solution converges strongly toc ^(o), while if ₀ > _s the solution converges weak* toc ^(s). In the latter case the excess density ₀– _s corresponds to the formation of larger and larger clusters, i.e. condensation. The main tools for studying the asymptotic behaviour are the use of a Lyapunov function with desirable continuity properties, obtained from a known Lyapunov function by the addition of a special multiple of the density, and a maximum principle for solutions.     

Representations of state space transformations by Markov kernels

Every convex subset of a locally convex Hausdorff space (X, ) is equipped with the (-algebra generated by its-relatively open subsets. Within the set () of probability measures on two particular convex subsets are considered: (a) the set ^s () of probability measures with a separable support, and (b) the set ^c () of probability measures with a compact convex support. If is the base of a cone inX, then there exists an affine barycenter map from ^c () onto whose composition with the natural embedding of in ^c () yields the identity map on , and every-continuous affine transformation of can be represented by an affine transformation of ^c () that is induced by a Markov kernel. If (X, ) is a Banach space and is a closed, bounded, generating cone base inX that is contained in a hyperplane, then analogous results are obtained with respect to ^s (). Since the state spaces considered in noncommutative measure theory are cone bases and every change in time of an empirical system can be thought of as an affine transformation of the associated state space (Schrödinger picture), the existence of these representation theorems implies that the time evolution of general empirical systems can be described by dynamical concepts borrowed from classical probability theory.