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1.
Yu.V. Skripkin A.A. Pasynskii V.T. Kalinnikov M.A. Porai-Koshits L.Kh. Minacheva A.S. Antsyshkina V.N. Ostrikova 《Journal of organometallic chemistry》1982,231(3):205-217
The heteronuclear Cp2Nb(CO)(μ-CO)Mn(CO)4 (I), Cp2Nb(CO)(μ-H)Ni(CO)3 (II) and [Cp2Nb(CO)(μ-H)]2M(CO)4 (III, M = Mo;IV, M = W) complexes were prepared by reaction of Cp2NbBH4/Et3N with Mn2(CO)10 in refluxing toluene, direct reaction of Cp2NbBH4 with Ni(CO)4 in ether, and reaction of Cp2NbBH4/Et3N with M(CO)5. THF complexes (M = Mo or W) in THF/benzene mixture. An X-ray investigation of compounds I–III was performed. It is established that in I the bonding between Mn(CO)5 and Cp2Nb(CO) (with the angle (α) between the ring planes being 44.2(5)°) fragments takes place via a direct NbMn bond (3.176(1) Å) and a highly asymmetric carbonyl bridge (MnCco 1.837(5) Å, NbCco 2.781(5) Å). On the other hand, in complex II the sandwich Cp2Nb(CO)H molecule (angle α = 37.8°) is combined with the Ni(CO)3 group generally via a hydride bridge (NbH 1.83 Å, NiH 1.68 Å, NbHNi angle 132.7°) whereas the large Nb?Ni distance, 3.218(1) Å, shows the weakening or even absence of the direct NbNi bond. Similarly, in complex III two Cp2Nb(CO)H molecules (with α angles equal to 41.4 and 43.0°, respectively) are joined to the Mo(CO)4 group via the hydride bridges (NbH 1.83 and 1.75 Å and MoH 2.04 and 2.06 Å) producing a cis-form. The direct NbMo bonds are probably absent, since the Nb?Mo distances are rather long (3.579 and 3.565 Å). The effect of electronic and steric factors on the structure of heteronuclear niobocene carbonyl derivatives is discussed. 相似文献
2.
A.A. Pasynskii I.L. Eremenko G.Sh. Gasanov Yu.T. Struchkov V.E. Shklover 《Journal of organometallic chemistry》1984,276(3):349-362
The reaction of (CH3C5H4CrSCMe3)2S (Ia) with Cp2Mn in boiling toluene (containing some THF) has been used to prepare a pentanuclear cluster, [(CH3C5H4)2Cr2(SCMe3)(μ3-S)2]Mn (II), which is antiferromagnetic and crystallizes into the monoclinic crystal system: space group Cc, a 26.540(10), b 9.208(3), c 21.595(9) Å; β 135.30(2)°, V = 3712.1 Å3, Z = 4. According to X-ray analysis, cluster II contains a metallospirane core, Cr4Mn, which appears to be strongly distorted, compared to its earlier studied cyclopentadienyl analogue [Cp2Cr2SCMe3(μ3-S)2]2Mn, due to the short intramolecular contacts CH3…S (2.9–3.1 Å). The angle between the metal triangle planes of Cr2Mn is 109.60°. Here, the two long CrMn bonds (3.019(3) and 3.104(4) Å) are combined with the shorter Cr Cr bond (2.651(6) Å) in one triangle and, vice versa, the less extended CrMn bonds (2.839(4) and 2.967(3) Å) are combined with a longer CrCr bond (2.726(6) Å) in the other triangle of Cr2Mn. By the reaction of Ia with [CpFe(CO)2]2 (taken in the ratio of ) in boiling toluene, the antiferromagnetic cluster [(CH3C5H4)2Cr2(SCMe3)(μ3-S)2]2Fe (III) has been synthesized in which the same distortions as in cluster II are present, as revealed by X-ray analysis. In the metallospirane core of the molecule of III, the Cr2Fe triangles make an angle of 113.84° with each other. In this cluster, the CrCr distances in the peripheral binuclear fragments (CH3C5H4)2Cr2(μ-SCMe3)(μ3-S)2 are practically equal (2.688(3) and 2.661(3) Å), whereas the FeCr bond lengths are markedly different (2.749(2) and 2.827(2) Å in on triangle and 2.910(2) and 2.969(2) Å in the other). The dependence of the geometries of clusters II and III on the steric effects of the methyl substituents in the cyclopentadienyl ligands and on the electronic effect of the central metal atom (MnII or FeII) is discussed. 相似文献
3.
M.David Curtis John Greene William M. Butler 《Journal of organometallic chemistry》1979,164(3):371-380
The structure of the cyclo-metalladisiloxane, Me2SiOSiMe2Ir(H)(CO)(PPh3)2, has been determined by single crystal X-ray diffraction using Mo-Kα radiation. Data were collected to 20 = 45 ° giving 6060 unique reflections,of which 4582 had I ?3σ(I). The latter were used in the full-matrix refinement. Crystallographic data: space group, P; cell constants: 12.604(7),12.470(4), 15.821(6) Å, 66.93(6)°, 105.34(7)°, 112.41(8)°;V 2095(3) Å3; p(obs) 1.45 g/cm3; p(calc) 1.46g/cm3 (Z=2). The asymmetric unit consists of one iridium complex and one molecule of ethanol of salvation. The structure was solved by standard heavy atom methods and refined with all non-hydrogen atoms anisotrophic to final R factors, R1 0.034 and R2 0.042. The iridium metallocycle has approximate Cs symmetry with the mirror plane passing through the four-membered IrSiOSi ring. The average IrP, IrSi and SiO bond lengths are 2.38, 2.41, and 1.68 Å, respectively. The IrCO and CO bond lengths are 1.903(8) and 1.133(8). The H atom bonded to Ir was not located.The Ir atom is raised out of the basal, P2Si2 plane toward the carbonyl by about 0.26 Å. The most striking feature of the structure is the strain apparent in the four-membered ring. The internal angels are: 64.7 (SiIrSi), 96.8 (IrSiO), 97.8 (IrSiO), and 99.8 (SiOSi). In an unstrained molecule, the SiOSi angle is normally in the 130–150° range. It is proposed that the strain in the ring is consistent with the catalytic activity of the metallocycle. 相似文献
4.
C5H5Co(PMe3)CS2 (IV) is formed in practically quantitative yield in the reaction of C5H5Co(PMe3)2 (I) or the heterobinuclear complex C5H5(PMe3)Co(CO)2Mn(CO)C5H4Me (III) with CS2. The crystal structure shows that the carbon disulfide bonds as a dihapto ligand through the carbon and one sulfur atom (S(2)) (CoC = 1.89, CoS(2) = 2.24 Å, S(2)CS(1) = 141.2°). The two CS bond lengths in IV (CS(2) = 1.68, CS(1) =1.60 Å) are greater than in free CS2 (1.554Å) which is in agreement with the strong π-acceptor character of h2-CS2 as shown in the spectroscopic data. IV reacts with Cr(CO)5THF and C5H5Mn(CO)2THF to give the complexes C5H5(PMe3)Co(SCS)Cr(CO)5 (V) and C5H5(PMe3)Co(SCS)Mn(CO)2C5H5 (VI) respectively, in which the sulfur atom S(1) that is not bound to cobalt coordinates to the 16-electron fragments Cr(CO)5 and Mn(CO)2C5H5. The spectroscopic data of IV, V and VI are discussed. 相似文献
5.
A.A. Pasynskii I.L. Eremenko B. Orazsakhatov Yu.V. Rakitin V.M. Novotortsev O.G. Ellert V.T. Kalinnikov G.G. Aleksandrov Yu.T. Struchkov 《Journal of organometallic chemistry》1981,210(3):385-394
The photochemical reaction between the antiferromagnetic complex (C5H5-CrSCMe3)2S (I) (containing a CrCr bond 2.689 Å long) and Fe(CO)5 results in the elimination of two carbonyl groups and one tert-butyl radical to give (C5H5Cr)2(μ2-SCMe3)(μ3-S)2 · Fe(CO)3 (III). As determined by X-ray diffraction, III contains a CrCr bond of almost the same length as in I (2.707 Å), together with one thiolate and two sulphide bridges. The latter are also linked with the Fe atom of the Fe(CO)3 moiety (average FeS bond length 2.300 Å). Fe also forms a direct bond, 2.726 Å long, with one of the Cr atoms, whereas its distance from the other Cr atom (3.110 Å) is characteristic for non-bonded interactions. Complex III is antiferromagnetic, the exchange parameter, ?2J, values for CrCr, Cr(1)Fe and Cr(2)…Fe are 380, 2600 and 170 cm?1, respectively. The magnetic properties of III are discussed in terms of the “exchange channel model”. The contributions from indirect interactions through bridging ligands are shown to be insignificant compared with direct exchange involving metalmetal bonds. The effects of steric factors and of the nature of the M(CO)n fragments on the chemical transformations of (C5H5CrSCMe3)2S · M(CO)n are discussed. 相似文献
6.
Melvyn Rowen Churchill Clifford Bueno David A. Young 《Journal of organometallic chemistry》1981,213(1):139-150
The species FeRu3(CO)13(μ-PPH2)2, synthesized from Ru3(CO)12 and Fe(CO)4(Ph2PPPh2),has been characterized both spectroscopically and via a single-crystal X-ray structural analysis. This complex crystallizes in the centrosymmetric triclinic space group P [No. 2, Ci1] with a 10.066(3), b 12.899(3), c 17.003(4) Å, α 111.89(2), β 91.02(2), γ 102.00(2)°, V 1992.7(9) Å3, Z 2, ?(obsd) 1.79(2) g cm-3 and ?(calcd) 1.82 cm-3. Diffraction data were collected with a Syntex P21 automated four-circle diffractometer and the structure was refined to RF 6.0% and RWF 3.6% for all 5213 reflections (RF 3.8%, RWF 3.6% for those 4140 reflections with |Fo|> 3σ(|Fo|).The metal atoms define a planar triangulated rhombus, with atoms Ru(1) and Ru(2) at the bridgehead, and Fe(1) and Ru(3) at the acute apices. Fe(1) is linked to four terminal carbonyl ligands and is associated with the heteronuclear bonds Fe(1)Ru(1) 2.861(1) Å and Fe(1)Ru(2) 2.868(1) Å. The ruthenium atoms are each bonded to three terminal carbonyl groups. The retheniumruthenium distances are Ru(1)Ru(2) 3.098(1), Ru(1)Ru(3) 3.147(1), and Ru(2)Ru(3) 3.171(1) Å. The structure is completed by Ph2P bridges across the Ru(1)Ru(3) and Ru(2)(ru(3) vectors (<Ru(1)P(1)Ru(3) 84.89(5)° and <Ru(2)P(2)Ru(3) 85.56(6)°). 相似文献
7.
The crystal and molecular structures of [tris(trimethylsilyl)silyl]pentacarbonylmanganese, (Me3Si)3SiMn(CO)5, have been determined from three-dimensional X-ray data obtained by counter methods. The compound crystallizes in space group P of the triclinic system, with two molecules in a unit cell of dimensions: a = 9.002(2), b = 9.655(2), c = 15.639(3) Å, α = 83.66(1), β = 105.65(1), γ = 114.61(1)°.The observed and calculated densities are 1.20 (±0.03) and 1.23 g-cm?3 respectively. Full-matrix least-squares refinement of the structure has led to a final value of the conventional R factor of 0.059 for the 818 independent reflections having F2 > 3σ(F2).The coordination geometry about the manganese atom is approximately octahedral and, about the silicon atom bonded to the manganese atom, tetrahedral.The relative orientations of carbonyl and trimethylsilyl groups, when viewed down the MnSi bond, appear consistent with minimization of energy due to nonbonded interactions.Two of the equatorial carbonyl groups are displaced out of the equatorial plane towards the silicon ligand by 6°. The SiMn bond is 2.564(6) Å long and has no multiple character. 相似文献
8.
Gerhard Thiele Günther Liehr Ekkehard Lindner 《Journal of organometallic chemistry》1974,70(3):427-435
The molecular structure of [(C6H5)3P]2Pd(C3H4) has been determined from three-dimensional X-ray diffraction data. The crystal belongs to the triclinic system, space group P, with two formula units in a cell of dimensions: a = 19.475(2), b = 10.204(2), c = 18.341(2) Å, α = 108.46(2), β = 85.46(1), and γ = 118.80(1)°.One of the olefinic bonds of allene is coordinated to the palladium atom: PdC(1) = 2.118(9) and PdC(2) = 2.067(8) Å. The coordinated allene is no longer linear, the C(1)C(2)C(3) angle being 148.3(8)°. The C(1)C(2) distance is 1.401(11) Å, whereas the uncoordinated bond remains unchanged [C(2)C(3) = 1.304(12) Å]. The Pd, P(1), P(2), C(1) and C(2) atoms lie almost in the same plane. 相似文献
9.
Michael Laing Magriet J. Nolte Eric Singleton Erwin van der Stok 《Journal of organometallic chemistry》1978,146(1):77-86
The crystal structure of [(C8H12)6H3Me)(OC6H4Me)2} {P(OCH2)3CMe}] has been determined. a 18.32, b 18.98, c 9.35 Å, U 3251 Å3, Pn21a, Z = 4, R = 0.048, 2541 observed data.The coordination about the iridium atom is distorted trigonal bipyramidal; the two phosphorus atoms are equatorial, the σ-bonded carbon is axial, and the bidentate cyclooctadiene is bonded axialequatorial. The IrC(axial) bonds are longer than the IrC(equatorial) bonds: 2.22, 2.26; 2.17, 2.19 Å. The IrC(σ) bond length is 2.19 Å, not significantly different from the formally π-bonded C to Ir distances. The IrP lengths of 2.201 and 2.240 Å and the PIrP angle of 108.7° are normal. The longer IrP bond is in the five-membered chelate ring. The inertness to substitution is discussed. 相似文献
10.
The structure of [Pt2Cl(CO) (μ-Ph2PCH2PPh2)2] [PF6] was determined by -ray methods and refined to = 0.082, using diffractometric intensities of 5646 independent reflections. The crystals are monoclinic, space group 21/, = 12.919(3), = 15.576(6), = 25.151(5)Å, β = 94.82(3)°, = 4. They are built of octahedral hexafluorophosphate anions and dinuclear platinum(I) cations. The latter contain PtCl and PtCO fragments linked to one another by a PtPt σ-bond and by two bridging bis(diphenylphosphino)methane ligands. The platinum atoms are in square planar environments and the dihedral angle between the two coordination planes is 40.1°. Selected bond lengths are: PtPt 2.620(1), PtCl 2.384(5), PtC 1.89(3) and PtP 2.291(5) – 2.308(5)Å. 相似文献
11.
Michael I. Bruce Brian K. Nicholson Jennifer M. Patrick Allan H. White 《Journal of organometallic chemistry》1983,254(3):361-369
The X-ray structure of H4Ru4(CO)9(PMe2Ph)[P(OC6H4Me-p)3][P(OCH2)3CEt], a chiral cluster complex, has been determined. The complex is triclinic, space group P, a 19.812(7), b 14.299(4), c 10.323(4) Å, α 100.09(3), β 98.18(3), γ 102.23(3)°. The unit cell contains an enantiomeric pair of molecules. The Ru4 core contains two short (av. 2.785 Å) and four long (2.967 Å) RuRu separations with approximate D2d symmetry. RuP separations are 2.254(6) Å [to P(OCH2)3CEt], 2.270(6) Å [to P(OC6H4Me-p)3] and 2.326(7) Å [to PMe2Ph]; all P-donor ligands are trans to short RuRu vectors. 相似文献
12.
C. Anklin P.S. Pregosin F. Bachechi P. Mura L. Zambonelli 《Journal of organometallic chemistry》1981,222(1):175-185
Platinum(II) and palladium(II) complexes containing chelating acyl ligands have been synthesized from salicylaldehyde, 2-hydroxynaphthaldehyde and 2-hydroxy-3-methoxybenzaldehyde. The platinum(II) complexes [Pt(acyl)L2], acyl OC6H4CO, OC10H6CO, O(m-CH3OC6H3CO), L tertiary phosphine, 1/2 diphenylphosphinoethane, can be isolated with both monodentate and chelating diphosphines, whereas for palladium only the compounds with chelating phosphines are readily obtainable. The reactions of [Pt(OC6H4CO)L2] with HCl afford trans-[PtCl(OHC6H4CO)L2], L monodentate tertiary phosphine and cis-[PtCl(OHC6H4CO)L2], L2 1,2-bis-diphenylphosphinoethane, in which the metal—carbon bond remains intact. The structure of [Pt(OC6H4CO)-(P(p-CH3C6H4)3)2] has been determined by X-ray diffraction methods and found to have the expected square planar structure. Some relevant bond lengths and angles are: PtP; 2.271(4) and 2.348(5) Å; PtC; 1.96(2) Å and PtO; 2.07(1) Å; PPtP 101°, CPtO 82°. 相似文献
13.
Rudolf Allmann Wolfgang Henke Peter Krommes Jörg Lorberth 《Journal of organometallic chemistry》1978,162(3):283-287
The molecular and crystal structure of tris(bistrimethylsilylamin)thallium was determined by means of single-crystal X-ray spectroscopy: in the space group P1c with a = 16.447(7), c = 8.456(7) Å; and Dc = 1.149 g cm?3 two molecules are located in the unit cell. The compound is isomorphous to the analogues Fe[N(SiMe3)2]3 or Al[N(SiMe3)2]3, respectively, which show a propellar-twist of the Si2N-groups versus the plane of the metal atom and the three nitrogen-atoms: Tl(N)3/Si2N 49.1°; SiNSi 122.6°; NSiC 111.8°; CSiC 107.1°; TlN 2.089 Å;; SiN 1.738 Å;; 1.889 Å;. 相似文献
14.
D. Lalage S. Brown Joseph A. Connor Henry A. Skinner 《Journal of organometallic chemistry》1974,81(3):403-409
From measurements of the heats of iodination of CH3Mn(CO)5 and CH3Re(CO)5 at elevated temperatures using the ‘drop’ microcalorimeter method, values were determined for the standard enthalpies of formation at 25° of the crystalline compounds: ΔHof[CH3Mn(CO)5, c] = ?189.0 ± 2 kcal mol?1 (?790.8 ± 8 kJ mol?1), ΔHof[Ch3Re(CO)5,c] = ?198.0 ± kcal mol?1 (?828.4 ± 8 kJ mo?1). In conjunction with available enthalpies of sublimation, and with literature values for the dissociation energies of MnMn and ReRe bonds in Mn2(CO)10 and Re2(CO)10, values are derived for the dissociation energies: D(CH3Mn(CO)5) = 27.9 ± 2.3 or 30.9 ± 2.3 kcal mol?1 and D(CH3Re(CO)5) = 53.2 ± 2.5 kcal mol?1. In general, irrespective of the value accepted for D(MM) in M2(CO)10, the present results require that, D(CH3Mn) = D(MnMn) + 18.5 kcal mol?1 and D(CH3Re) = D(ReRe) + 30.8 kcal mol?1. 相似文献
15.
The reaction of Rh(CO)2acac with triphenylantimony in the presence of cesium benzoate in tetraethylene glycol/dimethyl ether solution resulted in the selective formation of [Rh12Sb(CO)27]3- (66% yield) after 3 h of contact time under ≈400 atm of carbon monixide and hydrogen (CO/H2 1) at 140–160°C. The cluster has been isolated as the [Cs(18-Crown-6)2]+, [(CH3)4]+, [(C2H5)4N]+, (Ph3P)2N]+ and [PhCH2N(C2H5)3]+ salts. The [(C2H5)4N]3 [Rh12Sb(CO)27] complex has been characterized via a complete three-dimensional X-ray diffraction study. The complex crystallizes in the space group Rc with a 23.258(13) Å, c 22.811(4) Å, V 10 686 Å3 and p(calcd.) 2.334 g cm-3 for mol.wt. 2503.66 and Z 6. Diffraction data were collected with an Enraf-Nonius CAD 4 automated diffractometer using graphite-monochromatized Mo-Kα radiation. The structure was solved by direct methods and refined by difference-Fourier and least-squares techniques. All non-hydrogen atoms have been located and refined: final discrepancy indices are Rf 3.5% and Rwf 4.6% for 3011 reflections. The anion's structure consists of twelve rhodium atoms situated at the corners of a distorted icosahedron with contacts of 2.807(1), 2.861(1), 2.874(1), 2.999(1), 3.017(1) and 3.334(1) Å and rhodium—antimony contacts of 2.712(0) Å. Rhodium—rhodium bond distances of 2.807 and 3.017 Å are in the range usually found for these complexes although a distance of 3.334 Å may be longer than expected from bonding interactions. The sum of the covalent radii of antimony and rhodium, 2.80 Å, is intermediate between the two observed RhSb contacts. The anion cluster structure is that of distorted icosahedron. This polyhedron has previously been found in [B12H12]2- but not with transition metal clusters. A comparison between the structures of rhodium carbonyl clusters and boranes shows the occurrence of similar structural features. Applications of bonding theories based on the boranes, such as Wade's rules, to rhodium carbonyl clusters shows the extent in which these rules are obeyed. 相似文献
16.
The structure of Mn(NO)3PPh3 has been analyzed by single-crystal X-ray diffraction. It shows a tetrahedral geometry with essentially linear nitrosyl groups, and an eclipsed configuration around the MnP bond. Average distances and angles are: MnN 1.686(7) Å, MnP 2.315(2) Å, NO 1.165(10) Å, PC 1.815(4) Å, MnNO 177.2(7)°, PMnN 103.6(2)°, NMnN 114.7(4)°. Final R factor 7.3% for 2064 non-zero reflections. The structure of the five-coordinate nitrito complex Mn(NO)2(ONO)(PEt3)2 is also mentioned briefly. 相似文献
17.
Alan H. Cowley Andreas Decken Claudia A. Olazbal Nicholas C. Norman 《无机化学与普通化学杂志》1995,621(11):1844-1848
Further investigation of the reaction of Ar*GaCl2 (Ar* = 2,4,6-t-Bu3C6H2) with Na[Mn(CO)5] resulted in the new compound, [Ga(Ar*){Mn(CO)5}2] 2 . The new indium compounds, [In(Ar*){Co(CO)4}2] 3 and [In(Ar*){Mn(CO)5}2] 4 , have been prepared by the treatment of Ar*InBr2 with Na[Co(CO)4] and Na[Mn(CO)5], respectively. The structure of 3 was established by single-crystal X-ray diffraction: space group P1 (No. 2), Z = 2, a = 8.625(1) Å, b = 10.557(2) Å, c = 17.55(2) Å, α = 88.43(1)°, β = 83.45(1)°, γ = 71.14(1)°. The X-ray crystal structure of [Ga{Mn(CO)5}3] is also reported: space group Pbca (No. 61), Z = 8, a = 12.83(3) Å, b = 11.753(2) Å, c = 29.662(6) Å, α = β = γ = 90°. 相似文献
18.
4a-Methyl-1,3,9-triphenyl-4a-H-fluorene, which is a tetrameric product formed on vigorous dehydration of acetophenone, has structure 1, in which rings A and B form an indene fragment, the diene ring C approximates to half-chair configuration, and the three phenyl rings, D, E, and F, are considerably rotated relative to rings B,C about their connecting bonds. In the Fe(CO)3 complex, 3, a marked change has occurred in the conformation of ring C to allow Fe coordination on the side opposite to the methyl group. The complexed FeC distances are 2.117, 2.049, 2.067, 2.220 Å, and there are marked changes in the bond lengths in the complexed diene, but all other bond lengths correspond closely in the two molecules. 1 (C32H24) is triclinic, a 12.506, b 10.237, c 10.121 Å, α 108.53, β 84.93, γ 112.32°; space group P, Z = 2. The complex, C32H24Fe(CO)3, is monoclinic, a 30.283, b 12.709, c 14.514 Å, β 92.73°; space group B21/c, Z = 8. 相似文献
19.
T.V. Baukova Yu.L. Slovokhotov Yu.T. Struchkov 《Journal of organometallic chemistry》1981,221(3):375-384
The trinuclear cationic complex [Ph4C5(AuPPh3)3+[BF4]- (I) obtained by interaction of C5HPh4AuPPh3 or Ph4C5(AuPPh3)2 with [AuPPh3+[BF4]- in THF was studied by X-ray diffraction. In the presence of benzene, triclinic crystals of the solvate [Ph4C5(AuPPh3)3]+[BF4]-· 2 C6H6 are formed, a = 12.845(6), b = 16.042(8), c = 22.642(11) Å, α = 86.62(4), β = 77.51(4), γ = 76.05(4)°, space group P, Z = 2, 9494 reflections with I > 2σ (λ(Mo-Kα), θ/2θ scan, 2θ < 46°), with absorption correction R = 0.054. The complex represents a diaurated cation of tetraphenylcyclopentadienyl(triphenylphosphine)gold, containing a triangular Au2C fragment (AuAu 2.820(1) Å) which is bonded to the third Au atom (AuAu 3.021(1) Å), coordinated to the cyclopentadienyl ligand by a bond intermediate between η1(σ) and η3 (AuC 2.21(2), 2.60(2) and 2.71(2) Å). 相似文献
20.