Decay studies of <Superscript>210-214</Superscript>Fr using α- γ-coincidences

The -decay fine structure of ^210-214Fr has been studied by --coincidence measurements. The nuclei were produced using the ¹²C on ²⁰⁹Bi reaction. Evaporation residues recoiling out of the target were separated in-flight by the velocity filter SHIP and stopped in a position-sensitive 16-strip PIPS-detector in order to study their subsequent decays. In the present work new and improved results for ^210-214Fr, produced by -decay of the primary reaction products ^214-218Ac, were extracted. The results are discussed and compared to previously published data.     

Investigation of Rust Formed on Steel Surfaces and Related Oxyhydroxides

In order to indentity the corrosion products formed on steel surfaces from ⁵⁷Fe Mössbauer spectroscopy, detailed Mössbauer parameters have been determined for various kinds of iron-oxyhydroxides: -FeOOH, -FeOOH, -FeOOH and -FeOOH. ⁵⁷Fe Mössbauer measurements of the iron oxyhydroxides indicate the following results. Fe occupies a single site in -FeOOH, but below the Néel temperature as at e.g., 300 K the Mössbauer spectrum is always broad, showing a distribution of the strength of the magnetic exchange interactions. Its shape depends on the grain-size and synthetic methods of the specimen. Fe occupies 3 sites in -FeOOH. High-purity reagents of -FeOOH always contain small amounts of -FeOOH and their Néel temperatures depend on the synthetic methods of the specimen. Mössbauer spectroscopy of the synthetic -FeOOH shows very broad distribution of the hyperfine magnetic fields.     

EC and α decays of 235Am

EC and decays of ²³⁵Am have been studied using a gas-jet coupled on-line isotope separator. Excited states in ²³⁵Pu have been established for the first time by means of -ray spectroscopy following the EC decay of ²³⁵Am. The deduced log ft value suggests that the ground state of ²³⁵Am should have the 5/2^-[523] configuration. The - coincidence result has revealed that the 5/2^-[523] state in ²³¹Np populated by the favored transition of ²³⁵Am is located at < 15 keV, which allows us to precisely determine the Q value of ²³⁵Am.     

α-Particle Loss from Cylindrical Magnetized DT Plasma

-particles from fusion reactions in a DT magnetized plasma are confined inside the plasma not only by magnetic fields but also by induced electric fields which are due to the different mobilities of -particles and electrons. Criteria are derived for the -confinement in a cylindrical plasma, inertially confined by a heavy liner. It is observed that the suprathermal population in the DT plasma will influence the overall dynamics.     

Finite-size effects in a field-theoretic model with long-range exchange interaction

We present a systematic approach to the calculation of finite-size (FS) effects for anO(n) field-theoretic model with both short-range (SR) and long-range (LR) exchange interactions. The LR exchange interaction decays at large distances as 1/r ^d+2–2,0⁺,0⁺. Renormalization group calculations ind=d _u – are performed for a system with a fully finite (block) geometry under periodic boundary conditions. We calculate the FS shift of the critical temperature and the FS renormalized coupling constant of the model to one-loop order. The universal scaling variable is obtained and the FS scaling hypothesis is verified.     

Photometric and fluorimetric study of the acid-base behavior of 2,2′-diquinolyl and 2,2′,2″-terpyridyl

A photometric and fluorimetric study of the acid-base behavior of 2,2-diquinolyl and 2,2,2-terpyridyl was performed. In sulfuric acid medium, the doubly charged 2,2-diquinolynium ion undergoes the first dissociation atH ₀=0.20±0.09, as determined by fluorimetry (_ex=336 nm, _em=424 nm). Photometric titration is less accurate because of the overlapping of the absorption spectra. The second dissociation constant of 2,2-diquinolyl was determined by fluorimetric titration (_ex=336 nm, _em=420 nm), obtaining a value of 3.67±0.03. The triply charged 2,2,2-terpyridyl molecule was found to undergo the first dissociation atH ₀=–7.17±0.04, as determined by fluorimetric titration (_ex=316 nm, _em=350 nm), in aqueous sulfuric acid medium. Photometric titration (=335 nm) was performed in the presence of 6.5% ethanol because of the low solubility of the compound in water. In this ethanolicwater medium, a value of the dissociation constant atH ₀=–7.39±0.03 was calculated. The second dissociation constant was determined to be 2.81±0.12 by photometric titration at 285 nm, and values of 4.03±0.26 and 4.16±0.20 were found for the third dissociation constant by photometric titrations at 320 and 295 nm, in 10% ethanol, in close agreement with previously reported values. The fluorimetric titration profile obtained by exciting at 274 nm and measuring the fluorescence emission at 350 nm, in the zone betweenH ₀=–3 and pH=10, is complicated by the several equilibria involved.     

Decay studies of <Superscript>214-216</Superscript>Ac by α- γ- γ-coincidences

The -decay fine structure of ²¹⁴Ac, ²¹⁵Ac and ²¹⁶Ac has been studied using the --coincidence technique. The nuclei were produced by ²⁰⁹Bi( ¹²C, xn)^221-xAc-reactions. Evaporation residues were separated in-flight from the primary beam using the velocity filter SHIP at GSI, Darmstadt. The separated nuclei were implanted into a position-sensitive 16-strip PIPS Si detector and their subsequent decays were measured. In these studies new and improved decay data for ^214-216Ac were obtained.     

Measurements of 110Xe and 106Te decay half-lives

The -decays of ¹¹⁰Xe and ¹⁰⁶Te were studied at the GSI on-line mass separator. By using the grow-in and decay of the activity, observed in pulsed-beam measurement, the half-life of ¹¹⁰Xe was found to be T_1/2 = 105⁺³⁵_-25ms. The lifetime of ¹⁰⁶Te was determined to be T_1/2 = 70⁺²⁰_-10s by measuring the time between two successive ¹¹⁰Xe ^{106} Te ^{102} Sn -decays. The newly determined half-lives were used to calculate reduced -decay widths for ¹⁰⁶Te and ¹¹⁰Xe. Universal systematics of reduced widths are proposed to search for the evidence of enhancement of the formation amplitude in the emitters above ¹⁰⁰Sn.     

Levels in <Superscript>127</Superscript>La fed by the <Superscript>127</Superscript>Ce beta-decay

The low-lying levels in ¹²⁷La have been studied through the -decay of ¹²⁷Ce ( T_1/2 = 29s) produced by bombarding a ^natMo target with a 185-MeV ³⁵Cl beam. Reaction products were on-line mass-separated, and -ray singles and - coincidence measurements were performed. Conversion electrons were also measured and multipolarities of transitions have been derived. The half-life of the 210.9-keV level was determined to be (1.9±0.3)ns by the - delayed coincidence technique. The level scheme obtained has been compared with calculations based on the Nilsson model.     

Collective structures of the <Superscript>131</Superscript>Cs nucleus

The collective structures of ¹³¹Cs have been investigated by in-beam -ray spectroscopic techniques following the ¹²⁴Sn (^11B , 4n) reaction at a beam energy E_lab = 57MeV. The previously established rotational bands, built on g_7/2, d_5/2 and the unique-parity h_11/2 orbitals, have been extended and evolve into new bands involving rotationally aligned (h_11/2)² and (h_11/2)² quasiparticles. In addition, a new multiquasiparticle band based on the g_7/2 g_7/2 h_11/2 configuration has also been observed. Theoretical interpretations for the assigned configurations are discussed in the framework of Total Routhian Surface (TRS) and Tilted Axis Cranking (TAC) model calculations. TAC model calculations predict a decrease in the B(M1) values with increasing rotational frequency for the g_7/2/d_5/2 (h_11/2)² and h_11/2 (h_11/2)² bands, thus indicating a magnetic rotation character for these bands.     

Interactions between dislocations and γ/γ' interfaces in superalloys

In situ transmission electron microscopy observations of the dislocation motion at vicinity of the /' interfaces in a Ni-base superalloy have been performed. They allow to identify the elemental mechanisms, under stress and at different temperatures, of the deformation propagation across the interfaces. It is shown that some of the mechanisms already analyzed in the literature occur. Moreover, new processes are revealed such as the formation of small dislocation pile-ups on the /' interfaces. Such a configuration, which increases the local stress, favors the overcoming of the interface.These observations together with new considerations on stresses are taken into account for proposing a new equilibrium equation for a dislocation abutting on a /' interface. This equation involves all the stress components acting on a dislocation: the applied stress, the misfit stress, the friction stress, the stress concentration due to the dislocation pile-up and the image stress.     

Mössbauer Study of Iron-Containing Carbon Nanotubes

⁵⁷Fe transmission Mössbauer at temperatures between 18 and 298 K and magnetic measurements have been used to characterize Fe-filled carbon nanotubes which were prepared by pyrolisis of Ferrocene + C₆₀ at atmospheric pressure under an Ar atmosphere at 1050°C. The Mössbauer data have shown that the Fe phases encapsulated within the carbon nanotubes are -Fe, Fe₃C and -Fe. The magnetic results are compatible with the Mössbauer data. Taken together the results allow us to propose a simple picture of the distribution of iron phases within the carbon nanotubes which would consist of an -Fe core surrounded by an -Fe shell, finally covered by an Fe₃C layer.     

IR Spectra and Structure of Immunoactive 8–Azasteroids in Model Compounds

The IR spectra of biologically active molecules of 8-azasteroids and model compounds in the region of C=O, C=C, C--N, and C--H vibrations (1800–1400 cm^–1) have been studied in detail. The structure of compounds containing isostructural and isoelectronic --acyl----aminovinylcarbonyl and --acyl----alkoxyvinylcarbonyl fragments have been analyzed. Interpretation of the structure of the IR spectra and of the specificity of the manifestation of the vibrational modes under consideration in the molecules of a particular class of 8-azasteroids is given. The electronic structure of the molecules under investigation complies with the model of mesomeric tautomerism of the aminovinyldicarbonyl fragment.     

On the efficiency of small-angle Čerenkov second harmonic generation in optical waveguides

It is well known that in the non-depleted pump approximation, the efficiency of a second harmonic generation (SHG) of a guided mode in a non-linear optical waveguide increases quadratically with the interaction length (P ₂ L ²), and linearly (P ₂ L) in the erenkov regime. The efficiency of the erenkov SHG in the waveguide with a non-linear substrate and linear guiding layer is known to be strongly peaked at a particular pump wavelength and a particular waveguide thickness, with the erenkov angle approaching zero. The known theory predicts an infinite efficiency value at the peak, however. In this contribution, a simple integral expression for the SHG efficiency in the erenkov regime is derived. For large erenkov angles and interaction lengths it yields the expected P ₂ L dependence, while in the limit of small erenkov angles the dependence is found to have the form of P L ^3/2, possessing also a finite value at the efficiency peak. The condition determining the accurate position of the efficiency peak in the waveguide thickness–pump wavelength plane is given, too.     

Lifetimes of proton unstable states in 113I measured by the particle-X-ray coincidence technique

The -delayed proton decay of ¹¹³Xe was investigated by means of a total absorption -ray spectrometer and a telescope for particle detection. The energy window available for the -delayed proton decay of ¹¹³Xe and the relative branching ratios for proton transitions to the ¹¹²Te states were remeasured. The lifetimes of proton unstable ¹¹³I states populated in the electron capture decay of ¹¹³Xe were determined by means of the particle-X-ray coincidence technique. The results of the lifetime measurements are compared with statistical-model calculations.     

Absorption Spectra and Thermostimulated Luminescence of Irradiated KBr Crystals with a High Content of an Na Impurity

The influence of high concentrations of the Na⁺ impurity on the photo and thermostimulated luminescence in an xirradiated KBr crystal has been studied. It is revealed that at an impurity concentration of 1 mol.% the absorption spectrum of the KBr:Na crystal possesses only the bands belonging to the (, I _A) and (F, H _A) pairs of the centers and that the thermoluminescence spectrum consists of two peaks with a maximum at 140 and 165 K.     

Alpha-decay of neutron-deficient 200Fr and heavier neighbours

A new measurement of the ²⁰⁰Fr -decay half-life, with improved accuracy compared to previous measurements, has been carried out at the Isolde-CERN on-line mass separator. A half-life of 49(4) ms has been obtained, which is substantially different from earlier literature values. For the ¹⁹⁶At daughter decay, a half-life of 389(54) ms and an branching ratio b = 94(5)% were measured. In addition, the half-lives of ^{201, 203, 205}Fr and ^197,199At are reported.     

Covariant Formulation of Electromagnetic 4-Momentum in Terms of 4-Vectors E α and B α

The fundamental difference between the true transformations (TT) and the apparent transformations (AT) is explained. The TT refer to the same quantity, while the AT refer, e.g., to the same measurement in different inertial frames of reference. It is shown that the usual transformations of the three-vectors E and B are - the AT. The covariant electrodynamics with the four-vectors E and B of the electric and magnetic field is constructed. It is also shown that the conventional synchronous definitions of the electromagnetic energy and momentum contain both, the AT of the volume, i.e., the Lorentz contraction, and the AT of E and B, while Rohrlich's expressions contain only the AT of E and B. A manifestly covariant expression for the energy-momentum density tensor and the electromagnetic 4-momentum is constructed using E and B . The 4/3 problem is discussed and it is shown that all previous treatments either contain the AT of the volume, or the AT of E and B, or both of them. In our approach all quantities are four-dimensional spacetime tensors whose transformations are the TT.     

Influence of Close‐Range Dipole‐Dipole Interactions on the Real Part of the Susceptibility of a Dense Resonance Medium

Based on a solution of the stationary modified Bloch equations, an investigation is made of the influence of the effect of internal optical bistability (IOB) on the behavior of the refractive index of a dense resonance medium as a function of the constant b of closerange dipoledipole interactions, frequency detuning, and the intensity of optical radiation. The conditions of existence of the IOB effect of the system dense resonance medium + optical radiation are found and the dynamics of the loop width of the hysteresis dependence of the population difference of the resonance levels of the medium on the characteristics of the system is traced. The domains of the parameters are determined in which the effects of selffocusing and selfdefocusing of the radiation propagating in a dense resonance medium can take place.     

Preparation, Luminescence Properties, and Application of Scintillators Based on Lu3Al5O12:Ce Single‐Crystal Films

The possibility of obtaining scintillators with a high effective atomic number of the element Z _ef based on Lu₃Al₅O₁₂:Ce³⁺ singlecrystal films (SCF) on doping with La³⁺ and Sc³⁺ ions on Y₃Al₅O₁₂ substrates has been investigated. It is established that the SCF of (LuLaY)₃Al₅O₁₂:Ce³⁺ (Z _ef = 58.9 and = 6.67 g/cm²) does not rank below those of Y₃Al₅O₁₂:Ce³⁺ (Z _ef = 29 and = 4.52 g/cm²) in the conversion efficiency of radiation at the band with _max = 515 nm. This allows their use as screens of xray images with a space resolution of 0.75–1.00 m. It is suggested that in the SCF of Lu₃Al₅O₁₂ the isoelectronic impurities of lanthanum and scandium form radiative recombination centers of the type La_Lu, Sc_Lu, and ScAl as well as the centers Lu as a consequence of the effect of replacement of some Lu³⁺ ions by the La³⁺ ions to octanodes of the garnet lattice. The low efficiency of Ce³⁺ radiation in the SCF of (LuSc)₃(AlSc)₅O₁₂:Ce is explained by substantial losses due to excitation of the recombination luminescence in the UV region of the centers formed by the isoelectronic impurities of scandium and to the possible existence of the channel of energy excitation dissipation related to the transitions between extrema of the allowed energy bands and activator levels.